Irish Standard

I.S. EN ISO 10723:2002

Natural gas - Performance evaluation for

on-line analytical systems (ISO
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10723:1995)

© NSAI 2002 No copying without NSAI permission except as permitted by copyright law.
 EN ISO 10723:2002/AC:2004
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I.S. xxx: Irish Standard – national specification based on the consensus of an expert panel and
subject to public consultation.

S.R. xxx: Standard Recommendation - recommendation based on the consensus of an expert

panel and subject to public consultation.

SWiFT xxx: A rapidly developed recommendatory document based on the consensus of the
participants of an NSAI workshop.

EN ISO 10723:2002 EN ISO 10723:2002 6 November, 2002

ICS number:
This document was published 75.060
under the authority of the NSAI
and comes into effect on:
6 November, 2002

1 Swift Square, T +353 1 807 3800 T +353 1 857 6730

Northwood, Santry F +353 1 807 3838 F +353 1 857 6729
Dublin 9 E standards@nsai.ie W standards.ie
W

Údarás um Chaighdeáin Náisiúnta na hÉireann

 I.S. EN ISO 10723:2002

EUROPEAN STANDARD EN ISO 10723:2002/AC

NORME EUROPÉENNE September 2004
Septembre 2004
EUROPÄISCHE NORM September 2004

ICS 75.060

English version
Version Française
Deutsche Fassung

Natural gas - Performance evaluation for on-line analytical systems (ISO

10723:1995)

Gaz naturel - Evaluation des performances Erdgas - Bewertung der Leistungsfähigkeit

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des systèmes d'analyse en ligne (ISO von On-line-Analysensystemen (ISO

10723:1995) 10723:1995)

This corrigendum becomes effective on 22 September 2004 for incorporation in the three official
language versions of the EN.

Ce corrigendum prendra effet le 22 septembre 2004 pour incorporation dans les trois versions
linguistiques officielles de la EN.

Die Berichtigung tritt am 22.September 2004 zur Einarbeitung in die drei offiziellen Sprachfassungen
der EN in Kraft.

EUROPEAN COMMITTEE FOR STANDARDIZATION

COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: rue de Stassart, 36 B-1050 Brussels

© 2004 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members.
Tous droits d'exploitation sous quelque forme et de quelque manière que ce soit réservés dans le monde entier aux
membres nationaux du CEN.
Alle Rechte der Verwertung, gleich in welcher Form und in welchem Verfahren, sind weltweit den nationalen Mitgliedern
von CEN vorbehalten.
Ref. No.:EN ISO 10723:2002/AC:2004 D/E/F
 I.S. EN ISO 10723:2002
EN ISO 10723:2003/AC:2004 (E/F/D)

English version

The title on the title page has to read as follows:

Natural gas - Performance evaluation for on-line analytical systems (ISO 10723:1995, including
Technical Corrigendum 1:1998)

The last paragraph of the foreword has to be replaced as follows:

The text of ISO 10723:1995, including Technical Corrigendum 1:1998, has been approved by
CEN as EN ISO 10723:2002 without any modifications.
This is a free 13 page sample. Access the full version online.

Version française

Le titre sur la page de titre doit être le suivant:

Gaz naturel - Evaluation des performances des systèmes d'analyse en ligne (ISO 10723:1995,
Rectificatif Technique 1:1998 inclus)

Le dernier paragraphe de l’avant-propos doit être remplacé comme suit:

Le texte de l'ISO 10723:1995, Rectificatif Technique 1:1998 inclus, a été approuvé par le
CEN comme EN ISO 10723:2002 sans aucune modification.

Deutsche Fassung

Der Titel auf der Titleseite ist wie folgt zu ersetzen:

Erdgas - Bewertung der Leistungsfähigkeit von On-line-Analysensystemen (ISO 10723:1995,

einschließlich Technische Korrektur 1:1998)

Der letzte Absatz des Vorworts ist wie folgt zu ersetzen:

Der Text der Internationalen Norm ISO 10723:1995, einschließlich Technische Korrektur
1:1998, wurde von CEN als Europäische Norm ohne irgendeine Abänderung genehmigt.

2
 A
I.S. EN ISO 10723:2002
INTERNATIONAL STANDARD ISO 10723:1995
TECHNICAL CORRIGENDUM 1

Published 1998-07-01

INTERNATIONAL ORGANIZATION FOR STANDARDIZATION • Ã≈∆ƒ”Õ¿–ŒƒÕ¿fl Œ–√¿Õ»«¿÷»fl œŒ —“¿Õƒ¿–“»«¿÷»» • ORGANISATION INTERNATIONALE DE NORMALISATION

Natural gas — Performance evaluation for on-line analytical

systems
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TECHNICAL CORRIGENDUM 1

Gaz naturel — Évaluation des performances des systèmes d’analyse en ligne

RECTIFICATIF TECHNIQUE 1

Technical Corrigendum 1 to International Standard ISO 10723:1995 was prepared by Technical Committee
ISO/TC 193, Natural gas, Subcommittee SC 1, Analysis of natural gas.

Page 6

Subclause 6.2

In the equation, replace s by ys so that the equation reads:

y
x s = y s × x std
std

Correct the definition of xstd and ystd to read:

xstd is the concentration in the standard;

ystd is the response to the standard.

It should be noted that the expression “standard” as used here, and elsewhere in the document (e.g. subclause
6.3), means the calibration gas.

ICS 75.060 Ref. No. ISO 10723:1995/Cor.1:1998(E)

Descriptors: natural gas, gas analysis, test equipment, specifications, performance.

© ISO 1998
Printed in Switzerland
 I.S. EN ISO 10723:2002
ISO 10723:1995/Cor.1:1998(E) © ISO

Page 13

Subclause 6.4

In the second line, correct the year of publication of ISO 7504 from 1994 to 1984.

Page 20

Table A.2 (concluded)

In the last column (mixture No. 307) of the second section (ethane), correct the fourth figure given for the area from
16 970 400 to 16 981 100. This part of the table will then read:

16 990 700
16 995 200
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16 970 400
16 981 100
16 981 800
16 959 400

In the fourth column (mixture No. 304) of the third section (propane), correct the last figure (standard deviation) from
3468,6 to 3486,6.

In the first column (mixture No. 301) of the last section (n-butane), correct the last figure given for the area from
32 732 to 33 732.

2
 I.S. EN ISO 10723:2002

EUROPEAN STANDARD EN ISO 10723

NORME EUROPÉENNE
EUROPÄISCHE NORM September 2002

ICS 75.060

English version

Natural gas - Performance evaluation for on-line analytical

systems (ISO 10723:1995)

Gaz naturel - Evaluation des performances des systèmes Erdgas - Bewertung der Leistungsfähigkeit von On-line-
This is a free 13 page sample. Access the full version online.

d'analyse en ligne (ISO 10723:1995) Analysensystemen (ISO 10723:1995)

This European Standard was approved by CEN on 19 August 2002.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Management Centre or to any CEN member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Management Centre has the same status as the official
versions.

CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece,
Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom.

EUROPEAN COMMITTEE FOR STANDARDIZATION

COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: rue de Stassart, 36 B-1050 Brussels

© 2002 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 10723:2002 E
worldwide for CEN national Members.
 I.S. EN ISO 10723:2002
EN ISO 10723:2002 (E)

CORRECTED 2002-11-13

Foreword
The text of ISO 10723:1995 has been prepared by Technical Committee ISO/TC 193 "Natural
gas” of the International Organization for Standardization (ISO) and has been taken over as
EN ISO 10723:2002 by the Technical Board of CEN.

This European Standard shall be given the status of a national standard, either by publication of
an identical text or by endorsement, at the latest by March 2003, and conflicting national
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standards shall be withdrawn at the latest by March 2003.

According to the CEN/CENELEC Internal Regulations, the national standards organizations of

the following countries are bound to implement this European Standard: Austria, Belgium, Czech
Republic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg,
Malta, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and the United Kingdom.

Endorsement notice

The text of ISO 10723:1995 has been approved by CEN as EN ISO 10723:2002 without any
modifications.

2
 I.S. EN ISO 10723:2002

INTERNATIONAL ISO
STANDARD 10723
First edition
1995-12-15
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Natura1 gas - Performance evaluation for

on-line analytical Systems

Gaz na turel - haluation des petformances des systemes d’analyse en

ligne

Reference number
ISO 10723: 1995(E)
 I.S. EN ISO 10723:2002
ISO 10723:1995(E)

Contents
Page

1 Scope ..................................................... ....................... .................. 1

2 Normative references .... .............................. ......................... .......... 1

3 Principle .... .......................................... ...................... ................. 2

4 Suitability of analytical Systems ....... ......................................... 2

5 Test gases . . . . . . . . . . . . . . . . . .... ..*.m.......................... .I...........................

3

5.1 Definition . .. .. ... . .. .. .. .

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5.2 Test gas compositions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...*... 4

6 Test procedures . . .. .. . . ................... ............ ............................. 5

6.1 System efficiency test ........................................... ................. 5

6.2 Repeatability . . . . . . . . . . . .... ............................................. ............... 6

6.3 Response concentration relationship ..................................... 9

6.4 Component separationlinterference ..................................... 13

7 Evaluation of results ....... .......................... ............................... 14

7.1 System efficiency ................................ ................................. 14

7.2 Repeatability ...................... .................................. ................. 14

7.3 Response/concentration relationship ................................... 14

7.4 Component separation/interference ..................................... 15

7.5 Further testing and evaluation ............................... ............... 15

Annexes

A Example of application using chromatography ...................... 16

B Statistical tests and methods ........................... ..................... 31

C Bibliography .................. ..................................... ..................... 43

0 ISO 1995
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced
or utilized in any form or by any means, electronie or mechanical, including photocopying and
microfilm, without Permission in writing from the publisher.
International Organization for Standardization
Case Postale 56 l CH-l 211 Geneve 20 l Switzerland
Printed in Switzerland

ii
 I.S. EN ISO 10723:2002
0 ISO ISO 10723:1995(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide
federation of national Standards bodies (ISO member bodies). The work
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of preparing International Standards is normally carried out through ISO

technical committees. Esch member body interested in a subject for
which a technical committee has been established has the right to be
represented on that committee. International organizations, governmental
and non-governmental, in liaison with ISO, also take part in the work. ISO
collaborates closely with the International Electrotechnical Commission
(IEC) on all matters of electrotechnical standardization.
Draft International Standards adopted by the technical committees are
circulated to the member bodies for voting. Publication as an International
Standard requires approval by at least 75 % of the member bodies casting
a vote.
International Standard ISO 10723 was prepared by Technical Committee
ISO/TC 193, Natura/ gas, Subcommittee SC 1, Analysis of natura/ gas.
Annexes A, B and C of this International Standard are for information only.

...
Ill
 I.S. EN ISO 10723:2002
ISO 10723:1995(E) 0 ISO

This International Standard describes a method for evaluating the per-

formante of analytical Systems intended for the analysis of natura1 gas.
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Natura1 gas is assumed to consist predominantly of methane, with other

saturated hydrocarbons and non-combustible gases.
Performance evaluation makes no assumptions about equipment for
and/or methodology of analysis, but gives test methods which tan be ap-
plied to the Chosen analytical System, including the method, equipment
and Sample handling.
This International Standard contains an informative annex (annex A) which
Shows the application for an on-line gas chromatographic System which,
as described, is assumed to have a response/concentration relationship for
all components which is represented by a straight line through the origin.
lt contains two additional informative annexes (annexes B and C).
 I.S. EN ISO 10723:2002
INTERNATIONAL STANDARD 0 ISO ISO 10723:1995(E)

Natura1 gas - Performance evaluation for on-line

analytical Systems
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1 Scope

This International Standard specifies a method of determining whether an analytical System for natura1 gas is sat-
isfactory, on the assumptions that

a) the analytical requirement has been clearly and unambiguously defined, for the range and uncertainty of
component concentration measurements, and the uncertainty of properties which may be calculated from
these measurements;

b) the analytical and calibration procedures have been fully described;

c) the method is intended to be applied to gases having compositions which vary over ranges normally found in
transmission and distribution networks.

If the Performance evaluation Shows the System to be unsatisfactory, all the stages, such as

- the analytical requirement;

- the analytical procedure;
- the choice of equipment;
- the choice of calibration gas;
- the calculation procedure;

must be re-examined in the light of the test data to assess where improvements tan be obtained.

This International Standard is applicable to analytical Systems which give the component concentrations and re-
sulting uncertainties. With the present state of knowledge, the method Chosen is likely to be gas chromatography.

Performance evaluation of an analytical System should be performed during installation, then at regular intervals,
according to the application, and/or whenever any critical component of the analytical System is changed or re-
placed.

2 Normative references

The following Standards contain provisions which, through reference in this text, constitute provisions of this
International Standard. At the time of publication, the editions indicated were valid. All Standards are subject to
revision, and Parties to agreements based on this International Standard are encouraged to investigate the possi-
bility of applying the most recent editions of the Standards indicated below. Members of IEC and ISO maintain
registers of currently valid International Standards.
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