Академический Документы
Профессиональный Документы
Культура Документы
THEORY
Lakshya Educare
2 Aldehydes , Ketones and carboxylic acids
Lakshya Educare
4 Aldehydes , Ketones and carboxylic acids
Lakshya Educare
6 Aldehydes , Ketones and carboxylic acids
Lakshya Educare
8 Aldehydes , Ketones and carboxylic acids
Lakshya Educare
10 Aldehydes , Ketones and carboxylic acids
Lakshya Educare
12 Aldehydes , Ketones and carboxylic acids
Lakshya Educare
14 Aldehydes , Ketones and carboxylic acids
62
Lakshya Educare
16 Aldehydes , Ketones and carboxylic acids
Lakshya Educare
18 Aldehydes , Ketones and carboxylic acids
Lakshya Educare
20 Aldehydes , Ketones and carboxylic acids
Lakshya Educare
22 ALDEHYDES , KETONES AND CARBOXYLIC ACIDS
(a) isopropyl methyl ketone 8. Reaction of acetaldehyde with HCN followed by hydrolysis
gives a compound which shows
(b) 2-methyl-3-butanone
(a) Optical isomerism (b) Geometrical isomerism
(c) 4-methyl-isopropyl ketone
(d) 3-methyl-2-butanone (c) Metamerism (d) Tautomerism
3. The IUPAC nameof the following structure is 9. Ethanedial has which functional group(s)
1% HgSO
4 o A
3 CH MgX O (a)
HC { CH
20% H SO
o B
o
2 4
Lakshya Educare
24 ALDEHYDES , KETONES AND CARBOXYLIC ACIDS
(c) – COCl Rosenmund 's reduction (c) Etard reaction (d) Reimer-Tiemann reaction
o CHO
30. Methyl ethyl ketone is prepared by the oxidation of
(d) – C { N Stephen
reduction
o CHO
(a) 2-propanol (b) 1-butanol
26. Which of the following compounds containing carbonyl
group will give coloured crystalline compound with (c) 2-butanol (d) t-butyl alcohol
31. The oxidation product of 2-propanol with hot conc.
HNO3 is
37. Oxidation of acetaldehyde with selenium dioxide produces: 44. Which of the following reagents converts both acetaldehyde
and acetone to alkanes ?
(a) ethanoic acid (b) methanoic acid
(a) Ni/H2 (b) LiAlH4
(c) glyoxal (d) oxalic acid
Reduction Reactions (c) I2/NaOH (d) Zn-Hg/conc.HCl
45. What reagent is used in the Rosenmund’s reduction ?
38. In the following reaction, product P is
(a) H2/Pd-BaSO4
(b) LiAlH4
(c) NH2NH2/KOH/CH2OH-CH2OH
(a) Reimer-Tiemann reaction 47. Which of the following compound will undergo self aldol
condensation in the presence of cold dilute alkali
(b) Cannizzaro reaction
(c) Rosenmund reaction (a) C6H5CHO (b) CH3CH2CHO
40. Catalyst used in Rosenmund reduction is 48. Which of the following will not undergo aldol condensation
(a) reduction of carbonyl compounds into hydrocarbons (a) Benzyl alcohol (b) Benzoic alcohol
(b) reduction of carbonyl compounds into alcohols (c) Hydrobenzamide (d) Cinnamic acid
(c) reduction of nitrobenzene into aniline
50. The following reagent converts C6H5COCHO to
(d) reduction of carbohydrates into alcohols
C6H5CHOHCOONa
42. Reduction of acetonitrile in presence of SnCl 2 /HCl,
followed by hydrolysis gives : (a) Aq. NaOH (b) Acidic Na2S2O3
(a) HCHO (b) CH3CHO
(c) Na2CrO4/H2SO4 (d) NaNO2/HCl
(c) CH3CH2CHO (d) CH3COCH3
51. Treatment of propionaldehyde with dilute NaOH solution
43. If pentan-2-one is reacted with NaBH 4, followed by gives
hydrolysis with D2O, the product will be :
(a) CH3CH2COOCH2CH2CH3
(a) CH3CD(OD)CH2CH2CH3
(b) CH3CD(OH)CH2CH2CH3 (b) CH3CH2CHOHCH(CH3)CHO
Lakshya Educare
26 ALDEHYDES , KETONES AND CARBOXYLIC ACIDS
52. Aldol condensation is : 58. Which compound does not form iodoform with alkali and iodine
(a) self condensation of aldehydes only having atleast one (a) Acetone (b) Ethanol
alpha hydrogen
(c) Diethyl ketone (d) Isopropyl alcohol
(b) self condensation of ketones only having atleast one
alpha hydrogen 59. Which compound does not gives yellow ppt. with iodine
(c) self condensation of both aldehydes and ketones having and alkali
atleast one alpha hydrogen (a) 2-hydroxy propane (b) Acetophenone
(d) self condensation of both aldehydes and ketones having
(c) Methyl ketone (d) Acetamide
no alpha hydrogen
53. Cannizzaro’s reaction is not given by : Chemical Tests
(a) CH3CHO (b) HCHO 60. Which of the following is incorrect
(c) benzaldehyde (d) triethyl acetaldehyde (a) FeCl3 is used in the detection of phenols
54. does not show aldol condensation (c) Tollen’s reagent is used in detection of unsaturation
4. Name the reagent used to bring about the following (c) CCl3CHO (d) CHCl2CHO
transformation : But-2-ene to ethanal (AMU 2010)
10. Which compound gives iodoform test?
+
(a) K2Cr2O7 in acidic medium (b) CrO2Cl2/H3O
(MP PMT 2010)
(c) PCC (d) O3/H2O–Zn dust
(a) CH3CHO (b) CH3CH2CH2OH
5. Arrange the following compounds in increasing order
(c) C6H5CH2CH3 (d) C6H5CH2OH
of their reactivity in nucleophilic addition reactions.
Ethanal (I), Propanal (II), Propanone (III), Butanone (IV) 11. The correct sequence of step involved in the mechanism
(AMU 2010) of Cannizzaro’s reaction is (KCET 2010)
(a) III < II < I < IV (b) II < I < III < IV (a) nucleophilic attack, transfer of H– and transfer of
H+.
(c) IV < III < II < I (d) I < II < III < IV
(b) transfer of H–, transfer of H+ and nucleophilic attack.
6. When ethanal is treated with Fehling’s solution, it gives
a precipitate of (AFMC 2010) (c) transfer of H+, nucleophilic attack and transfer of H–.
(a) Cu2O (b) Cu (d) electrophilic attack by OH–, transfer of H+ and transfer
of H–.
(c) Cu3O (d) CuO
Lakshya Educare
28 ALDEHYDES , KETONES AND CARBOXYLIC ACIDS
12. Aldol condensation would not occur in 19. Arrange the following compounds in decreasing order
of their boiling points. (AMU 2009)
(Manipal 2010)
CH3CHO, CH3CH2OH, CH3OCH3, CH3CH2CH3
(a) CH3COCH3 (b) CH3CH2CHO
(a) CH3CH2CH3 < CH3OCH3 < CH3CHO < CH3CHO
(c) HCHO (d) CH3CHO
(b) CH3CH2CH3 < CH3CHO < CH3OCH3 < CH3CHO
13. The most reactive compound towards formation of
cyanohydrin on treatment with HCN followed by (c) CH3CH2CH3 > CH3CHO > CH3OCH3 > CH3CHO
acidification is (JCECE 2010)
(d) CH3CHO > CH3CHO > CH3OCH3 > CH3CH2CH3
(a) benzaldehyde
20. Which of the following is the industrial method of
(b) p-nitrobenzaldehyde preparation of acetaldehyde? (AMU 2009)
(c) phenylacetaldehyde
SnCl 2 3H O
(a) CH3CN
HCl
o CH3CH NH o CH3CHO
(d) p-hydroxybenzaldehyde
Pd
14. Aldehyde are the first oxidation product of (b) CH3 COCl H 2 o CH3 CHO HCl
BaSO 4
(c) tertiary alcohol (d) dihydric alcohol (d) None of the above
15. Oxidation of acetaldehyde with selenium dioxide 21. Which of the following will respond to Cannizzaro’s
produces (BVP 2010) reaction? (Manipal 2009)
(a) ethanoic acid (b) methanoic acid (a) 2,2-dimethylpropanal (b) Acetaldehyde
16. The compound, with which ethanol does not react is 22. Which is necessary for the conversion of butane-2-one
(AFMC 2009) into propanoic acid?
(c) PCl5 (d) aq. NaHSO3 (a) Tollen reagent (b) Fehling solution
17. The reaction by which benzaldehyde is converted in (c) NaOH/I2/H+ (d) NaOH/NaI/H+
benzyl alcohol, is (AFMC 2009)
23. Which one of the following does not form sodium
(a) Fittig reaction (b) Cannizzaro reaction bisulphite addition product iwth sodium bisulphite
solution (AFMC 2009)
(c) Wurtz reaction (d) aldol condensation
(a) CH2O (b) C6H5COCH3
18. If heavy water is take as solvent instead of normal water
while performing Cannizzaro reaction, the products of (c) C6H5CHO (d) CH3CHO
the reaction are (AIIMS 2009)
24. Acetophenone when reacted with a base, C2H5ONa, 27. 3-hydroxy butanal is formed when X reacts with Y in
yields a stable compound which has the structure dilute Z solution. What are X, Y and Z?
(CBSE AIPMT 2008) (AIIMS 2008)
X Y Z
(a)
(a) CH3CHO, (CH3)2CO, NaOH
25. A strong base can abstract an a-hydrogen from (a) 2-methyl-2-butene (b) 3-methyl-1-butene
(CPMT 2006)
Lakshya Educare
30 ALDEHYDES , KETONES AND CARBOXYLIC ACIDS
34. Acetaldehyde reacts with chlorine to give 42. A compound A o C5 H10 Cl2 on hydrolysis gives C5H10O
(BHU 2006) which reacts with NH2OH, forms iodoform, but does not
give Fehling test. A is (DUMET 2005)
(a) CCl4 (b) CHCl3
(c) CCl3.COCH3 (d) CCl3.CHO
(a)
39.
46. Acetone is mixed with bleaching powder to give 55. Schiff’s solution B is obtained when (RPMT 2004)
(AFMC 2004)
(a) sulphurous acid is passed through magents dye
(a) chloroform (b) acetaldehyde
(b) chlorine is passed through magenta dye
(c) ethanol (d) phosgene
(c) Both (a) and (b)
47. The reagent used for the separation of acetaldehyde from
acetophenone is (AIIMS 2004) (d) None of the above
(a) NaHSO3 (b) C6H5NHNH2 56. Assertion Hydroxyketones are not directly used in
Grignard reaction.
(c) NH2OH (d) NaOH–I2
Reason Grignard reagents react with hydroxyl group.
48. Assertion Isobutanal does not give iodoform tests. (AIIMS 2003)
Reason It does not have D-hydrogen (AIIMS 2004) (a) A (b) B
(a) A (b) B (c) C (d) D
(c) C (d) D
49. Acetaldehyde gives orange coloured precipitate on
treatment with (Punjab PMET 2004)
(a) 2,4-DNP (b) NH2OH
(c) NaHSO3 (d) NaOH
50. Which of the following yield 2 moles of formaldehyde
on ozonolysis? (RPMT 2004)
(a) CH CH (b) CH2 CH2
(c) CH3—CH CH2 (d) C6H6
51. Which of the following compound yield 2,5-
dimethylhexan-1,6-dial? (RPMT 2004)
(a) 3,6-dimethyl cyclohexene
(b) 3,4-dimethyl cyclohexene
(c) 4,6-dimethyl cyclohexene
(d) 3,5-dimethyl cyclohexene
52. Fenton’s reagent is (RPMT 2004)
(a) FeSO4 + H2O2 (b) HgSO4 + H2O2
(c) FeSO4 + H2O (d) None of these
53. Brady’s reagent is (RPMT 2004)
(a) 2,4-DNP (b) conc. HCl + ZnCl2
(c) DMSO (d) None of these
54. The compound which reacts with hydroxyl amine but
does not react with Tollen’s reagent is (RPMT 2004)
(a) CH3CHO (b) HCHO
(c) C2H5OH (d) CH3COCH3
Lakshya Educare
32 ALDEHYDES , KETONES AND CARBOXYLIC ACIDS
ANSWER KEY
9. (b) 10. (c) 11. (a) 12. (d) 13. (a) 14. (a) 15. (d) 16. (c)
17. (c) 18. (d) 19. (d) 20. (c) 21. (a) 22. (d) 23. (a) 24. (c)
25. (b) 26. (b) 27. (a,c) 28. (c) 29. (c) 30. (c) 31. (a) 32. (a)
33. (a) 34. (b) 35. (a) 36. (a) 37. (c) 38. (c) 39. (c) 40. (a)
41. (a) 42. (b) 43. (d) 44. (d) 45. (a) 46. (a) 47. (b) 48. (c)
49. (a) 50. (a) 51. (b) 52. (c) 53. (a) 54. (b) 55. (b) 56. (d)
57. (b) 58. (c) 59. (c) 60. (c) 61. (c) 62. (b) 63. (a) 64. (c)
9. (c) 10. (a) 11. (a) 12. (c) 13. (d) 14. (a) 15. (c) 16. (a)
17. (b) 18. (b) 19. (b) 20. (c) 21. (a) 22. (c) 23. (b) 24. (a)
25. (c) 26. (a) 27. (d) 28. (a) 29. (a) 30. (c) 31. (a) 32. (d)
33. (c) 34. (d) 35. (b) 36. (c) 37. (a) 38. (d) 39. (b) 40. (d)
41. (b) 42. (a) 43. (d) 44. (b) 45. (a) 46. (a) 47. (a) 48. (c)
49. (a) 50. (b) 51. (a) 52. (a) 53. (a) 54. (d) 55. (a) 56. (a)