X1 Y1 P

0 0 41.98
0.1 0.18048717 46.103
0.2 0.331342333 50.226
0.3 0.459309279 54.349
0.4 0.569229717 58.472
0.5 0.664669702 62.595
0.6 0.748313798 66.718
0.7 0.822221595 70.841
0.8 0.887999573 74.964 DIAGR
0.9 0.946919216 79.087 90
1 1 83.21
80

70

60

50

40

30
0 0.1 0.2 0.3 0.4
 P1sat P2sat
83.21 41.98

A B C
Acetonitrilo (1) 14.2724 2495.47 224
Nitrometano (2) 14.2043 2972.64 209

DIAGRAMA P-X-Y
90

80

70

60

50

40

30
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 T1SAT
X1 T °C P1Sat P2Sat 68.85
0 69.85 70.01296332 34.81928404
0.1 71.823 74.85357718 41.7566381
0.2 73.796 79.95800286 50.24210817 Acetonitrilo (1)
0.3 75.769 85.33637513 60.63272261 Nitrometano (2)
0.4 77.742 90.99902034 73.36651572
0.5 79.715 96.95645333 88.9796359
0.6 81.688 103.2193742 108.1265305
0.7 83.661 109.798665 131.6035775
0.8 85.634 116.7053861 160.3765216
0.9 87.607 123.9507726 195.6120385
1 89.58 131.5462304 238.7136927

X1 T °C P1Sat P2Sat
0.000136402 89.58 131.5462304 69.99160384
0.0768851 87.607 123.9507726 65.50650676
0.157716708 85.634 116.7053861 61.25446291
0.242969156 83.661 109.798665 57.22661288
0.33301256 81.688 103.2193742 53.41427708
0.428252698 79.715 96.95645333 49.80895785
0.529134885 77.742 90.99902034 46.40234141
0.636148335 75.769 85.33637513 43.18629965
0.74983105 73.796 79.95800286 40.15289173
0.870775318 71.823 74.85357718 37.2943655
0.999633906 69.85 70.01296332 34.60315872
T2SAT P=CTE
89.58 70kPa

A B C
14.2724 2945.47 224
14.2043 2972.64 209
 ejemplo 10.3 Raoult & Raoult Modificado

X1 P Yi G1 G2 P
0 65.6084563 0 3.02526896 1 65.6084563
0.1 63.4741569 0.069737771 2.45142625 1.0111315 70.5562508
0.2 61.3398576 0.144328547 2.03090194 1.04527499 72.8428656
0.3 59.2055582 0.224297163 1.72018183 1.10476208 73.5806076
0.4 57.0712588 0.310246968 1.48961843 1.19377434 73.3684744
0.5 54.9369594 0.402875068 1.31883662 1.31883662 72.4528739
0.6 52.80266 0.502991279 1.19377434 1.48961843 70.7984102
0.7 50.6683606 0.611541865 1.10476208 1.72018183 68.0895054
0.8 48.5340613 0.729639537 1.04527499 2.03090194 63.664533
0.9 46.3997619 0.858601739 1.0111315 2.45142625 56.3658123
1 44.2654625 1 1 3.02526896 44.2654625

A B C
METANOL (1) 16.5785 3638.27 239.5
AC. METILO (2) 14.2456 2662.78 219.64

P1 SAT 44.26546249
P2 SAT 65.60845632

Y1 P X1 G1 G2 Pnueva
0 65.6084563 0 3.02526896 1 65.6084563
0.1 62.5905941 0.141398261 2.26161016 1.02237952 69.3656543
0.2 59.8381546 0.270360463 1.80279431 1.08427973 72.7168106
0.3 57.3175967 0.388458135 1.51285665 1.18180862 74.0313642
0.4 55.0008022 0.497008721 1.32322409 1.31448974 72.535956
0.5 52.8640226 0.597124932 1.1968287 1.48395365 68.6180136
0.6 50.8870616 0.689753032 1.11243607 1.69327663 63.3505781
0.7 49.0526355 0.775702837 1.05727231 1.94662749 57.7833146
0.8 47.3458658 0.855671453 1.02332755 2.24906869 52.5867484
0.9 45.7538753 0.930262229 1.00539825 2.6064374 48.0596134
1 44.2654625 1 1 3.02526896 44.2654625
 Yi
0
0.15379717
80
0.24682943
0.31045399 70
0.35949309
0.40287507 60

0.44783186 50
0.50274947
0.58141736 40
0.71465985
30
1
20

10

0
0 0.2 0.4 0.6 0.8 1 1.2

%error
0
10.8244062
21.5224818
29.1599236
31.8816327
29.8009691
24.4925058
17.7985934
11.0693563
5.03943784
0