U.N.A.

Facultad de Estudios Superiores Cuautitlan

Quimica Organica I

Semestre 2019-1

Tarea de diagrama de distribucion de especies acido citrico

Grupo:1401
Ingenieria Quimica

Prefesor:Juan Carlos Rueda Jackson

Alumno: Eduardo Garcia del Rio
pH [H^+] ∝H3Cit ∝H2Cit ∝HCit ∝Cit
0 1 0.9992555417 0.0007444454 1.287891E-08 5.17732E-15
0.5 0.316227766 0.9976495121 0.0023503593 1.285821E-07 1.634581E-13
1 0.1 0.9926038222 0.0073948985 1.279317E-06 5.142856E-12
1.5 0.0316227766 0.9769709796 0.0230164286 1.259169E-05 1.600701E-10
2 0.01 0.9305538025 0.0693262583 0.0001199344 4.821364E-09
2.5 0.0031622777 0.8084867177 0.1904711317 0.0010420181 1.324651E-07
3 0.001 0.5688626171 0.4238026497 0.0073317858 2.947378E-06
3.12 0.0007585776 0.4988748413 0.4899456153 0.0111736221 5.92134E-06
3.5 0.0003162278 0.2869485169 0.676021109 0.0369833596 4.701456E-05
4 0.0001 0.1026269294 0.7645706243 0.132270718 0.0005317283
4.5 3.162278E-05 0.0265877459 0.6263798697 0.3426761629 0.0043562214
4.76 0.000017378 0.0114239545 0.4897480737 0.4875496394 0.0112783325
5 0.00001 0.0047717624 0.3554962975 0.6150085946 0.0247233455
5.5 3.162278E-06 0.0005919672 0.139461358 0.7629568788 0.096989796
6 0.000001 5.314717E-05 0.0395946423 0.6849873114 0.2753648992
6.39 4.073803E-07 6.405088E-06 0.0117133573 0.4974248679 0.4908553697
6.5 3.162278E-07 3.388853E-06 0.0079837879 0.4367723079 0.5552405153
7 0.0000001 1.543811E-07 0.001150139 0.1989740451 0.7998756615
7.5 3.162278E-08 5.65754E-09 0.0001332858 0.0729172065 0.926949502
8 0.00000001 1.883191E-10 1.402977E-05 0.0242715041 0.9757144659
8.5 3.162278E-09 6.055751E-12 1.426672E-06 0.0078049545 0.9921936188
9 0.000000001 1.925274E-13 1.434329E-07 0.0024813892 0.9975184673
9.5 3.162278E-10 6.098599E-15 1.436767E-08 0.0007860179 0.9992139677
10 1E-10 1.929583E-16 1.43754E-09 0.0002486944 0.9997513042
10.5 3.162278E-11 6.102916E-18 1.437784E-10 7.865744E-05 0.9999213424
11 1E-11 1.930015E-19 1.437861E-11 0.000024875 0.999975125
11.5 3.162278E-12 6.103348E-21 1.437886E-12 7.8663E-06 0.9999921337
12 1E-12 1.930059E-22 1.437894E-13 2.487556E-06 0.9999975124
12.5 3.162278E-13 6.103392E-24 1.437896E-14 7.866356E-07 0.9999992134
13 1E-13 1.930063E-25 1.437897E-15 2.487562E-07 0.9999997512
13.5 3.162278E-14 6.103396E-27 1.437897E-16 7.866362E-08 0.9999999213
14 1E-14 1.930063E-28 1.437897E-17 2.487562E-08 0.9999999751
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
pKa1 pKa2 pKa3
10^-3.12 10^-4.76 10^-6.39

Ka1 Ka2 Ka3

7.45E-04 1.73E-05 4.02E-07
 ∝H3Cit
∝H2Cit
∝HCit
∝Cit

10 11 12 13 14
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 1 2 3 4 5 6
0.1

0
0 1 2 3 4 5 6
5 6 7 8 9 10 11 12
5 6 7 8 9 10 11 12
 ∝H3Cit
∝H2Cit
∝HCit
∝Cit

11 12 13 14
11 12 13 14