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Plastic Recycling
1
Waste emissions
45,000
40,000
35,000
30,000
25,000
20,000
15,000
10,000
5,000
0
FY 1997 98 99 00 01 02 03 04 05 06 07 08 09 10 11 12 13
Source : Ministry of the Environment, Emissions and Processing of Industrial Waste FY 2013
Sludge
42.7%
Demolition By type
16.4%
Animal excrement
21.5% ◆ Approximately 3% disposed of by landfill
Industrial waste is waste emitted as a result of business
activities at construction sites, livestock farms, factories, and other
business-related establishments. Japan produces a little less than
Ceramic, stone and
clay products 2.0% Miscellaneous industries
400 mil1ion tons of industrial waste per year, and a breakdown
6.3% reveals a little more than 40% of the total to be sludge, followed
Food 2.2% by animal excrement and demolition waste.
Mining 2.3% These three categories account for around 80% of the total.
Chemical and Electricity, Urban infrastructure industries (i.e. electricity, gas, heating and
allied products gas, heat water utilities), agriculture/ forestry and construction produce
3.3% and water almost 70% of the total. Kanto region produces 26%, Chubu
Pulp, paper and 25.5% region produces 15%, Kinki and Kyushu region produce 14%,
paper products respectively.
7.9% By industry We can see from the State of processing graph that the total
Iron and steel increased by 5.56 million tons, and the breakdown reveals the
Agriculture
8.0% and
amount of recycling decreased by 2.15 million tons and the
forestry amount of waste disposed of in landfill decreased 1.38 million
Construction
20.9% 21.6% tons, the amount of reducing increased by 9.09 million tons. It is
remarkable that the decreasing of the amount of recycling and the
increasing of the amount of reducing. The amount of material
going to landfill is around 3% in FY 2013, final disposal
remaining capacity for industrial waste is 170 million m3, and 14.7
Source : Ministry of the Environment, Emissions and Processing of years across the entire nation, especially 5.2 years in the Tokyo
Industrial Waste FY 2013 metropolitan area, so the landfill situation is particular1y severe.
(Source:Ministry of the Environment, Emissions and
Processing of Industrial Waste, 1 April 2014)
2
Waste emissions
6,000 1,200
Domestic waste
Emissions/
← person/day
5,500 1,100
→
5,000 1,000
*In calculating amount of discharge
per person, the foreign population
in Japan was added to the total
4,500 900 population from 2012. If using
the conventional base excluding
the foreign population, this figure
would be 979g, 972g, and 963g
0 800 for FY2012, FY2013, and FY2014,
FY1998 99 00 01 02 03 04 05 06 07 08 09 10 11 12 13 14 respectively.
Source : Ministry of the Environment, Emissions and Processing of Domestic Waste FY 2014
■ Annual waste emissions per person in ■ Annual waste emissions in major countries
major countries
Spain Spain
France France
UK UK
Italy Italy
Germany Germany
USA USA
0 100 200 300 400 500 600 700 800 0 50 100 150 200 250
(kg/person) (million ton)
◆ Garbage discharge in major countries around the world discharge is particularly noticeable in Asia, where many
As a result of expanding economies and a growing pattern countries in the region experienced a rapid demographic shift
of mass production, mass consumption, and mass disposal, to the cities and stimulation of production activities over a
these last decades have seen an increase in the discharge of relatively short period of time accompanying economic
domestic waste on a global basis. For example, the volume of growth. As a result, finding a means of processing this
discharge by the member countries of the Organization for massive amount of waste is now a major issue in these
Economic Cooperation and Development (OECD) as of 2013 countries. Failure to suitably process this waste will trigger a
was 660,000 kt annually or 520 kg per person. Compared wide variety of problems on a global scale, such as soil, air,
with 1990, this was an increase of about 40,000 kt. Also of ocean, and river pollution, global warming, nature and
interest here is that the volume of domestic waste discharged ecosystem destruction, and wasting of finite resources. Of
by the United States itself exceeded 200,000 kt or 730 kg per these, concern about marine litter has been growing in recent
person per year, a volume that overwhelmed those of other years. Much research is focusing on plastics that turn into
countries. This makes the small volume of garbage marine litter, and it is said that marine litter from land-based
discharged per person per year in Japan (about 350 kg) stand sources is considerable as a result of outflows from landfills
out. or inflows to rivers as a result of flooding. Meanwhile, it is
*According to the “World Bank” report, ten years ago, there said that marine litter from ocean-based sources is caused by
were 2,900 million city residents, they discharged 0.64kg of the disposing of fishing gear such as nets and the illegal
waste per person in a day. At present, there are 3,000 million ocean dumping of waste.
city residents, they discharge 1.42kg of waste per person in a Many international organizations such as United Nations
day and at 2025, there will be 4,300 million city residents, Environment Program (UNEP) and NPOs are actively
they will discharge 1.42kg of waste per person in a day. engaged in solving this problem. Furthermore, at the 2015 G7
Summit held at Schloss Elmau, Germany, an agreement was
◆ Increase of waste on a global scale reached on a “G7 Action Plan to Combat Marine Litter” in
The amount of waste discharge is increasing on a global which advanced economies would take the lead on
scale. On entering the 21st century, this trend got only addressing the marine litter problem. This initiative was
stronger. According to the World Bank report cited earlier, the reaffirmed at the 2016 G7 Ise-Shima Summit held in Japan.
amount of municipal solid waste (MSW) was about 680,000 To appropriately manage waste and to promote the reduction,
kt per year ten years ago but 1,300,000 kt at present with a reuse, and recycling of waste, individual transformation of
forecast of 2,200,000 kt by 2025. This growth in waste behavior is desired.
4
Processing and recycling of plastic waste
1,400
1,200
1,000
800
600
400
200
0
05 06 07 08 09 10
80
85
90
95
00
11
12
13
14
96
97
98
99
01
02
03
04
20 20
19
19
19
19
20
Resin production Domestic resin product Industrial plastic waste Domestic plastic waste
consumption
Source:Plastic Waste Management Institute (PWMI)
Year 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014
年 waste 1990
Total 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006
plastic emissions 990 1,001 1,013 1,006 1,005 994 998 912 945 952 929 940 926
有効利用量 万トン 144 221 358 399 435 452 494 535 542 575 611 628 721
Mechanical
152 164 181 185 204 213 214 200 217 212 204 203 199
Effective utilization
recycling
有効利用率 % 26 25 39 42 44 46 50 53 55 58 60 62 72
Feedstock
recycling 25 33 30 29 28 29 25 32 42 36 38 30 34
Thermal
recycling 337 344 364 368 457 449 494 456 465 496 502 535 534
Total 516 541 575 582 688 692 733 689 723 744 744 767 768
Effective
utilization(%) 52 54 57 58 69 69 73 75 77 78 80 82 83
pushing the effective plastic utilization rate up to 83%, (by field) (by resin type)
one point higher than the previous year. Source:Plastic Waste Management Institute (PWMI)
5
● Flowchart of plastic products, plastic waste and resource
(kt=thousand tons)
Resin
production
10,610 kt
Resin import
2,630 kt
Product export
810 kt Total
plastic
Product import
waste
1,970 kt discharge
Liquid resin, etc. 9,260 kt
810 kt
Resin processing
waste
550 kt
Production
Resin production Production
and
waste and Non-use processing
170 kt processing
waste
waste
discharge
720 kt
720 kt
Reclaimed
products ●●●Resin production does not include the quantity shown for resin production waste.
250 kt ●●●The quantity shown this year for reclaimed products is based on that of mechanical recycling
excluding exported portion (1,680 kt) and the amount used for fiber from PET bottles(90 kt).
The figure for post-use products discharge is computed by a PWMI estimation system based on
and different resin types (from 1976) and product lifetimes for different demand areas (60-years
※ Some figures may not exactly match due to rounding.
6
Processing and recycling of plastic waste
recovery 2014
Mechanical
recycling
recycling
650 kt Mechanical
Liquefaction, gasification, recycling
blast furnace 1,990kt (22%)
270 kt
Densified-refuse derived fuel/
cement material and fuel
Chemical
recycling
280 kt Liquefaction,
Incineration with gasification,
power generation blast furnace
2,000 kt 340 kt (4%)
Domestic
waste Incineration with heat
utilization facility
4,420 kt 300 kt
Incineration without power Densified-refuse
derived fuel/cement Utilized
generation or heat utilization facility plastic waste
660 kt
material and fuel
1,540 kt (17%) 7,680 kt (83%)
Thermal recycling
(Energy recovery)
Landfilling
270 kt
Incineration with
power generation
2,960 kt (32%)
Industrial waste
Mechanical
recycling Incineration
1,340 kt with heat
Liquefaction, gasification, utilization facility
blast furnace 840 kt (9%)
80 kt
Densified-refuse derived fuel/
Industrial cement material and fuel
waste 1,260 kt
4,830 kt Incineration with Incineration without
power generation power generation or
960 kt heat utilization facility
910 kt (10%)
Unused
Incineration with
heat utilization facility Non-utilized
540 kt plastic waste
Incineration without power 1,580 kt (17%)
generation or heat utilization facility Landfilling
250 kt 670kt (7%)
from the previous year (2,030 kt)
Landfilling
410 kt
usage for different demand areas
discharge model created by PWMI).
7
● Recovery systems supporting mechanical recycling
■ Breakdown of mechanical recycling (1,990 kt/page 7)
0 5 10 15 20 25 30 35 40 45 50 55
(10 kt)
Source : Plastic Waste Management Institute (PWMI)
8
Processing and recycling of plastic waste
Food and condiment Tempura and salad oil, soy sauce, sauce
PET, polyethylene, polypropylene
bottles mirin (sweet sake used as seasoning)
Food packs Margarine, tofu, natto (fermented soybeans), fruit, EPS Polystyrene
(EPS and non-EPS vegetables, processed foods, prepared foods, Non- Polystyrene, polypropylene,
Packs and cups
Food cups Miso (soybean paste), tamago-dofu (steamed egg EPS Polystyrene
(EPS and non-EPS custard), miso soup, yogurt, ramen, yakisoba (fried Non- Polystyrene, polypropylene,
packs) noodle), jelly, custard pudding, deserts food cups EPS PET, polyethylene, composite materials
Polystyrene, PET, polypropylene,
Cup and pack lids
polyethylene, composite materials
EPS Polystyrene
Trays and blister packs
EPS and Meat, fish, sashimi (slices of raw fish), sliced ham,
non-EPS trays vegetables, processed foods Non- Polystyrene, polypropylene,
EPS PET
Drugs (tablets), processed meat and fish products,
Polyethylene, polypropylene, PET,
Blister packs roast ham, bacon, curry roux, household tools,
polystyrene, PVC resin
toothbrushes, cosmetics
Egg boxes PET, polystyrene
Note : The types of resin indicated in the table are those mainly used.
Source:Plastic Waste Management Institute (PWMI)“Basic Survey for Recycling of Municipal Solid Waste”(March 1999)”
9
Information about plastics
* kt (thousand tons)
Basic petrochemical
Petroleum products Plastics
products
Volatile oil Polyethylene 2,640 kt
53,540,000kl(28%) Ethylene 6,650 kt
Polypropylene 2,350 kt
Naphtha
Propylene 5,670 kt PVC resin 1,480 kt
18,300,000kl(10%)
Polystyrene 1,160 kt
Crude oil Kerosene
Butane/Butylene 2,850 kt Other thermoplastic resins 1,790 kt
(distillation) 16,830,000kl(9%)
191,140,000 kl Thermosetting resins 920 kt
Gas oil Aromatic series 14,940 kt Other resins 230 kt
40,980,000kl(21%)
Fuel oil Others
34,700,000kl(18%)
(materials is 10,570 kt)
Total of plastic raw
Imported naphtha
25,860,000 kl
Chemical raw materials
other than plastics
(Total ofproducts
naphtha for basic petrochemical
is 44,160,000 kl )
(The discrepancy with the quantity of resin produced as shown on p.6 is due to data being aggregated over different months.)
(Source : Japan Petrochemical Industry Association, Present State of the Chemical Industry 2015)
◆ Plastics are made from naphtha ◆ Plastics account for just several % of total petroleum consumption
Plastics are mainly highly polymerized compounds Japan presently uses around 200 million kiloliters of crude
consisting of carbon and hydrogen, made from substances oil per year. Most crude oil is refined into gasoline, kerosene,
such as petroleum and natural gas. In Japan, naphtha (crude gas oil, and fuel oil; less than 10% is turned into naphtha. In
gasoline) produced by refining crude oil is used as the raw 2014, 18.3million kiloliters of naphtha was produced from
material for making plastics. 191.14 million kiloliters of crude oil. Combined with
Naphtha produced by distilling crude oil is first heated and imported naphtha, 25.86 million kiloliters of naphtha was
cracked to extract substances with a simpler structure (i.e. used as the raw material for basic petrochemical products
compounds with low molecular weight) such as ethylene and such as ethylene, propylene, butane/butylene, etc. Of this
amount, 10,570 kt of naphtha (*kt = thousand tons) was used
propylene. The molecules obtained are then chemically
in the production of plastic materials.
coupled (polymerized) to form substances with new
The quantity used to produce plastic products accounts for
properties, such as polyethylene and polypropylene, which
around 5.9% of combined crude oil and imported naphtha
are called synthetic resins and polymers. As the newly
used per year.
formed polyethylene and other such substances are difficult
The amount of crude oil used in plastics is around 2.7% of
to handle in powder or lump form, they are first melted, the total amount – most crude oil is burned and consumed as
additives added to make them easier to process, and they are thermal energy.
formed into pellets. (It is from this stage that they are
Turning crude oil and naphtha into weight-based values requires
normally called plastics.) They are then shipped to the weight conversions on the basis of density.
Here, densities of 0.85 g/cm 3 and 0.70 g/cm 3 are used for crude
molding plant to be manufactured into plastic products. oil and naphtha, respectively.
10
Information about plastics
Note ; The large difference between resin production ■ Breakdown of production by use
(10,830 kt) and production by use (5,600 kt) in
Reinforced products
Urethane foam(1.6%) the graphs is because production by use was
Other resins(2.0%)
1.3% Synthetic leather 1.0% * kt = thousand tons
calculated according to the following parameters
nol resins(2.6%)
(1) only primary products directly molded and processed Board 2.0%
were included
(2) only products made by business establishments with Others
Others 50 or more works were included Foam 4.9%
Polyethylene
(3.8%) (3) secondary processed products, plants, adhesives, products
(24.1%)
wiring and cables, synthetic fibers and urethane foam, 4.4%
・etc.
Low density 14.0%
were excluded. Daily
・High density 8.3% necessities
Others ・Ethylene-vinylacetate and sundries
(13.3%) Thermosetting copolymer 1.8% 5.2%
resins Source : Tabulated by the Japan Plastics Industry Federation
from monthly reports issued by the Research and Building
(8.0%)
materials
Statistics Department, Minister’s Secretariat, Ministry 5.3% Film and sheet
BS resins
Production of Economy, Trade and Industry Production 43.3%
(4.0%)
Thermoplastic resins
Different plastics have different characteristics and are
(90.0%)
Polypropylene
Polystyrene accordingly put to different
(23.1%)uses. Equipment
(7.0%) and
A large proportion of production is of polyethylene and machinery parts
11.2%
polypropylene,
PVC resins
and these two combined account for around Containers
13.6%
half of total output. This is because around 40% of plastic
(15.2%)
11
● Plastics as the foundation of industry and modern lifestyles
◆ Advantages of plastics
・Light and robust
Plastics can be used to make light yet strong products,
unlike metal and ceramics.
・Resistant to rust and corrosion
Most plastics are resistant to acid, alkalis and oil and
do not rust or corrode.
・Transparent and freely colorable
Some types of plastics are highly transparent and can
be easily colored, making it possible to create bright,
attractive products.
・Mass producible
Many types of plastics that can be molded and
processed by a variety of methods, so products with
complex shapes can be efficiently mass-produced, 1. Household appliances : LCD televisions
helping to bring down costs. Liquid crystal display (LCD) televisions with
・Excellent electrical and electronic properties their vivid and detailed high picture quality
wide angle screens are made up of a number
Their outstanding insulation properties and dimensional
of plastics layered together: polarizing film,
stability allows plastics to be used in components and
phase contrast film and a diffuser panel for the
electrical and electronic products.
backlight. Plastics are also used in electrical
・High heat-insulation efficiency components, circuits and housings.
Plastics conduct heat poorly, and foam is a particularly
good heat-insulating material.
・Hygienic with a strong gas barrier
Plastics are clean and impermeable to oxygen and water,
effectively protecting foods from contamination by
microorganisms.
◆ Drawbacks of plastics
・Susceptible to heat
Some types of plastics deform when placed near a
flame or heat source.
Photo : Japan Polyethylene Corporation
・Susceptible to scratchers and dirt
2. Automobiles: Gasoline tanks
Plastics have a soft surface compared to metal and
Four different resins are applied in six layers
glass and are easily scratched. They are also susceptible
to prevent fuel from permeating through the
to static electricity and stains are highly visible. tank, which can be molded in a single stage
・Vulnerable to petroleum benzine and thinner into a complex shape that frees up space
Some plastics melt or discolor if exposed to petroleum inside the car. Plastic tanks are lighter and
benzine, thinner or alcohol. also compatible with biofuels, which are
expected to come into widespread use. They
meet the US safety standards for use over 15
years or 150,000 miles (286,000km).
12
Information about plastics
13
● Main characteristics and uses of plastics
JIS abbr. Resin name Standard thermal Acid resistance Alkali resistance Alcohol resistance
resistance (℃)
Low density Good Good Good
70~90
polyethylene
PE
High density
Polyethylene polyethylene 90~110 Good Good Good
Some products
PA Polyamide (nylon) 80~140
somewhat vulnerable
Good Possible infiltration
Some products
POM Acetal resin (polyacetal) 80~120
somewhat vulnerable
Good Good
Polybutylene terephthalate
PBT (PBT resin)
60~140 Good Good Good
Standard thermal resistance (℃) is the heat resistance of each resin type in normal use. It does not apply to generic resins, engineering plastics or thermosetting
resins. (Generic resins are measured in terms of short term thermal resistance, and engineering plastics and thermosetting resins in terms of long-term resistance.)
The entries on this table have been arranged into standard grades to give a rough idea of their physical properties. Consult the manufacturer if you require particular
physical properties for product design.
14
Information about plastics
Good Colorless, transparent, good chemical resistance, excellent gas barrier. Cling film, ham and sausage casing, film coating.
Colorless and transparent, highly resistant to acids but vulnerable DVDs and CDs, electronic part housings (e.g. mobile phones), automobile
Good
to alkalis. Excellent resistance to shocks and heat. headlight lenses, camera lenses and housings, transparent roofing materials.
Milky white, scratch-resistant resistant to low temperatures, good Automobile parts (air inlet pipes, radiator tanks, cooling fans,
Good
shock resistance. etc.), food film, fishing line and monofilament, gears, fasteners.
White, opaque, excellent shock resistance and good abrasion Gears (DVD player, etc.), automobile parts (fuel pumps, etc.),
Good
resistance. fasteners and clips.
White, opaque, good balance of electrical and other physical
Good Electrical parts, automobile parts.
properties.
Milky while and thermally resistant, high chemical resistance with Frying pan coatings, insulating materials, bearings, gaskets, all kinds of packing
Good
non-stick properties. material, filters, semiconductor industry applications, wire coverings.
Good electrical insulating properties, acid resistance, heat resistance Printed circuit boards, iron handles, distribution board breakers,
Good
and water resistance. Does not burn easily. pan and kettle handles and knobs, plywood adhesive.
Good Good water resistance. Resembles ceramic. Hard surface. Tableware, decorative laminate, plywood adhesive, paint.
15
Methods of plastic recycling
Cement kiln
Thermal recycling Energy Recovery
Waste power generation
RPF(*1), RDF(*2)
*1. Refuse Paper & Plastic Fuel (high-calorie solid fuel made from waste paper & plastic)
*2. Refuse Derived Fuel (solid fuel made from burnable waste, plastic waste, etc.)
16
Methods of plastic recycling
● Mechanical recycling
④ ③
⑤
②
⑰
⑦
⑩
⑭
⑪
⑱
⑫
⑮
⑬ ①
⑯
17
● Mechanical recycling process
■ From the collection of PET bottles to recycling into new products
Consumer Recycling businesses Recycled product manufacturing process End product
Pellets
Textiles
Sewing Working-clothes, uniforms
Play your part in recycling
resources ! Melting/spinning
PET flakes
Municipality
Raw cotton Yarn Shirts
Sheeting
Shredding
Selection
Molding Assembly Stationery
Bottles
Injection molding Stretch blow molding Detergent bottles for the kitchen
Compression Selection
Source : Council for PET Bottle Recycling
18
Methods of plastic recycling
Input of BHET
HOーCH2CH2ーOOCー
O ーCOOーCH2CH2ーOH
used PET
DMT
bottle flakes
Methanol H2O H3COOCー
O ーCOOCH3
EG
HOーCH2CH2ーOH
TPA
HOOCー
O ーCOOH
Hopper
DMT
Ester TPA
separation
exchange production
refinement
Liquid-state polymerization
Solid-state polymerization
EG
EG
Resin
for
PET
BHET bottles
BHET
refinement
(de-coloration/
distillation etc.)
19
● Blast furnace feedstock recycling
Pre-treatment
(waste bag shredding, sorting out of
unsuitable waste, removal of impurities, Hydrogen
shredding, magnetic sorting) chloride gas
Granulator
Plastics other than PVC
Classifier
Tuyere
20
Methods of plastic recycling
Chemical
Plastic waste from households feedstock for
(various plastic composites) plastics, etc.
Chemical
Hydrocarbon oil
conversion
40%
Coal plant
Pre-treatment
(pre-grinding,
removal of impurities) Blast
Coke furnace
20% (iron ore reducing
agent)
PVC
removal system Coke oven
Compactor Power
Coke oven gas
generation,
(granulator) 40%
etc.
%=recycling rate
21
● Gasification 〈Feedstock Recycling〉
■ Gasification process
Low-temperature High-temperature
Plastic waste from households gasification furnace gasification furnace
(various plastic composites)
Oxygen+Steam
Shredder
Gas scrubbing
Oxygen+ Synthetic gas
Steam facility
RDF molder
22
Methods of plastic recycling
Exhaust gas
■ Liquefaction Plastic waste from households Hydrogen
chloride gas
combustion Recovered
(hydrochloric and hydrochloric acid
process
(various plastic composites)
condensed and recovery)
Deaerating
tank
Exhaust gas
(shredding, separation, sorting)
Melted
Pre-treatment
plastics
Pyrolysis
tank
Power
generation
Residue
Steam
Dehydrochlorination unit
Heating
furnace
Waste
Residue extraction heat boiler Water
Residue
and energy recovery
Nippon Steel & Sumitomo PET Refine Technology Co., Ltd. (Kawasaki)
metal Corporation (Oita) 27.5kt/y/monomerization, bottle to bottle
50kt/y/coke oven
feedstock Nippon Steel & Sumitomo metal Corporation
(Nagoya) 50kt/y/coke oven feedstock
23
● Thermal recycling (Energy recovery)
■ Incinerator mechanisms
◆ From waste plastic and landfill to thermal recycling
Waste plastics are currently collected and processed
Stoker incinerator
differently by different municipalities, but the Ministry of the
Refuse crane
Environment is unifying the previously separate categories
Exhaust gas of waste into one (“burnable”), with an amendment to the
Refuse hopper
Waste Disposal Law on May 2005 which changes its basic
policy to state that “first, emission of waste plastic should be
reduced, after which recycling should be promoted; any
remaining waste plastic should not go to landfill as it is
suitable for use in thermal recovery”. In a similar move, the
Tokyo municipal area, which had since 1973 been putting
Refuse feeder
household waste plastics into landfill as non-burnable
Stoker
garbage, set a goal in 2008 of sending zero household waste
Drying plastic to landfill and instead using it for incineration and
Forced Combustion thermal recycling by default.
draft fan Post-
combustion As a result, data on the effective use of heat energy for FY
Bottom
ash 2014 as recorded by the Clean Association of TOKYO23
showed that total generated power came to 1,130 million
Fluidized-bed incinerator
kWh, electricity sold came to 590 million kWh, and supplied
Exhaust gas
Refuse crane heat (fee-based) came to 526,000 gigajoule(GJ) , the income
Sand of electricity and heat sold came to 10.6 billion yen.
circulation
elevator
Thermal recycling encompasses liquefaction, gasification
and solid fuel (RPF, etc.), which are all recognized under the
Refuse hopper
Container and Packaging Recycling Law, but also waste
power generation, conversion to cement kiln fuel and solid
Refuse feeder fuel made from waste (RDF).
Typical waste incineration systems in use today include
stoker incinerators, fluidized-bed incinerators, and
Incinerator gasification melting furnaces.
A stoker incinerator burns refuse while transporting it
Forced Sand
Air along a stoker. It consists of a drying section for evaporating
draft fan Sand separator moisture in the refuse, a combustion section for vigorously
burning the refuse, and a post-combustion section to fully
Incombustibles burn the refuse. A fluidized-bed incinerator, on the other
Gasification melting furnace hand, burns refuse by adding it to heated sand that swirls
about much like boiling water by air forced in from below. A
Refuse crane gasification melting furnace, meanwhile, decomposes
Flammable gas
and char Exhaust refuse into gas at high temperatures and recovers the
gas
Refuse Secondary
resulting pyrolysis gas and char for use as fuel to drive a
hopper combustion fan steam turbine and generate electricity. The char is melted
Sand
into slug at this time.
Refuse
feeder Gasification
circulation
elevator
In any of the above systems, the heat and exhaust gas
furnace Secondary
combustion
generated by incinerating refuse can be used as new sources
Forced
draft fan
chamber of energy.
Combustion
melting furnace Refuse can also be effectively used as a raw material for
Molten slug
Sand cement kilns thanks to its high calorific value and good
Sand separator combustibility. The demand for refuse paper and plastic fuel
Slug (RPF)—a mixture of plastic waste and used paper—has also
been growing among pulp manufacturers as an alternative
Incombustibles Water
granulation tank fuel to oil.
24
Methods of plastic recycling
2,000 1,907
Total generated power
1,000
500
0
FY2001 02 03 04 05 06 07 08 09 10 11 12 13 14
85
and swimming pools. Recently, however, the use of waste for 80 75
generating electric power has been attracting attention, and as
of FY 2014, the number of waste incineration sites equipped 60
with power generating facilities came to 338 or about 29% of all 40 31
waste incineration sites in Japan. The total power generating 24
capacity of these sites was 1,907 MW. At 7,958 GWh in FY 20
2014, the total amount of power generated in this way could 0
cover the power needs of about 2,450,000 households Under 5% 5%-10% 10%-15% 15%-20% Above 20%
(calculated on the basis of 271.2 kWh/month/household as Power-Generating Efficiency (%)
estimated by the Federation of Electric Power Companies
Note ; For 329 (out of 338) power-generating sites responding to the survey.
(FEPC), FY 2013).
However, the efficiency of waste power generation is still
less than satisfactory : there are only 24 sites with a power
generation efficiency of 20% or greater. Additionally, there are ■ Number of waste incineration sites by power-generating capacity
217 small-scale sites with a power generating capacity less than 120
5,000 kW, or 65% of all sites. This figure reflects the need for 99
improving the efficiency of waste power generation by 100 95
consolidating facilities, upgrading equipment, deploying new
80
Number of sites
25
● High calories provide a valuable energy resource
■ Calorie comparison*
Group Material Unit MJ kcal Source
Coal for coke ovens kg 29.1 6,952
Imported fuel coal kg 25.7 6,139
Based on“Study on Standard Calorific Values Applied
Kerosene Liter 36.7 8,767
Fuel since FY 2005 and Revised Values,”Agency for Natural
Fuel oil A Liter 39.1 9,341
Resources and Energy, May 2007
LPG kg 50.8 12,136
Manufactured gas Nm3 44.8 10,702
PVC resins kg 24.1 5,760
“Ecological efficiency analysis on the processing of
Polystyrene kg 40.2 9,600
plastic containers and packaging” Plastic Waste
Plastics Polypropylene kg 44.0 10,500
Management Institute (PWMI), September 2006
Polyethylene kg 46.0 11,000
PET kg 23.0 5,500 Website of the Council for Pet bottle Recycling
50.0
40.0
30.0
20.0
10.0
0.0
Coal for coke ovens
Kerosene
Fuel oil A
LPG
Manufactured gas
PVC resins
Polystyrene
Polypropylene
Polyethylene
PET
Paper
Kitchen waste
Textiles
Wood, grass
Incineration waste
Waste plastic
**Note : MJ/liter for kerosene and fuel oil A; MJ/Nm3 for manufactured gas
26
Methods of plastic recycling
Source : Ministry of the Environment Source:Clean Authority of TOKYO, Waste Report 23 2016, December 2015
(Partly revised by PWMI)
27
Life Cycle Assessment
◆ History of LCA
LCA is said to have begun in 1969 with research conducted by a beverage company in the United States on techniques for assessing the
environmental load of returnable bottles and beverage cans. In Japan, full-scale LCA activities began with the founding of the Life Cycle
Assessment Society of Japan in 1995, and the establishment of LCA techniques and the construction, expansion, and spread of LCA
databases were promoted by two LCA national projects overseen by the Ministry of Economy, Trade and Industry (METI). Then, in 2004,
The Institute of Life Cycle Assessment, Japan was founded, and collaborative relationships in LCA from an academic viewpoint have since
been formed and strengthened as a result.
28
Life Cycle Assessment
For example, the amount of energy/resources used in the manufacturing of one ton of bags by inflation molding using LDPE can be
calculated as follows.
(1) Resource energy (originating in resin raw material and additives) 46,103 MJ/t × 1.066 (basic unit) = 49,151 MJ/t
(2) Process energy (originating in resin raw material and additives) 26,132 MJ/t × 1.066 (basic unit) = 27,861 MJ/t
(3) Process energy (of that process) = 7,696 MJ/t
(1)+(2)+(3) = 84,709 MJ/t
In general, (1) represents the total amount of heat generated by LDPE resin (pellets), (2) the amount of process-related energy from the
gathering of resin raw material (crude oil) to the refining of naphtha and manufacture of LDPE resin (pellets), and (3) the amount of energy
used for turning resin (LDPE) pellets into a product (manufacture of bags by inflation molding) at the bag-making company.
Recycling
CObales
Form into 2 CO2
Recycling CO2
Manufacture CO2
Use recycled CO2
Waste disposal
and transport plant recycled pallet pallet
Recycling Form into bales Recycling Manufacture Use recycled
Waste disposal
and transport plant recycled pallet pallet
Each process results in the generation of CO2 emissions, so calculating the total of these amounts gives the environmental load for
recycling in terms of CO2. What then do we do for the case of “no recycling?” An easy mistake to make here would be to consider the case
of “no recycling” to consist only of the “waste disposal” step. If so, the amount of CO2 generated for this case would be extremely small
and the “no recycling” option would end up being the most “eco.” Is this really the case? In actuality, there is a huge error in this
assumption. Manufacturing a recycled product means that there is no need to manufacture a new product of the same kind. In other words,
disposing a product as waste without recycling means that a new product having the same function as that product made by material
recycling must be manufactured.
CO2 CO2 CO2 CO2 CO2
That is to say, if choosing the “no recycling” option, the amount of CO2 generated must be calculated not only for the waste-disposal
process but also for the gathering of resources (crude oil) for manufacturing the new product, the refining of naphtha, the manufacturing of
resin raw material (pellets), the processing of those pellets, the manufacturing of the pallet, use of the pallet, and waste disposal of the
pallet. The total amount of generated CO2 must be calculated in this way to determine which of “recycling” or “no recycling” is “eco.”
29
Legislation and arrangement
for the creation of a recycling-oriented society
● Basic law and recycling laws
Put into force in January 2001
To ensure material recycling in society;
Fundamental Law for Establishing a Sound to reduce consumption of natural resources;
Material-Cycle Society (basic framework law) to reduce environmental burden
・Basic principles・Obligations of the national and local governments, businesses and citizens・Measures to be taken by the national government
Fundamental Plan for Establishing a Sound Material-Cycle Society : Basis of other national plans
Source : Towards a 3R-Oviented, Sustainable Society : Legislation and Trends 2010, etc. Ministry of Economy, Trade and Industry.
◆ Clarification of the roles of central and local of a Recycling-oriented Society. This basic law lays down the
government, businesses and consumers basic principles for the formation of a recycling-oriented
The creation of a recycling-oriented society is the biggest society, delineates the division of roles among the government,
challenge facing Japan in the 21st century. A recycling- municipalities, businesses and consumers, and specifies the
oriented society is defined by the Basic Law for Promoting the measures to be taken by central government.
Creation of a Recycling-oriented Society as a society that limits Building on the framework laid down by this law, a number
consumption of natural resources and minimizes the burden of individual recycling laws such as the Law for Promotion
on the environment through ① curbing waste emissions, ② of Effective Utilization of Resources, were enacted, amended
recycling resources and ③ disposing of waste appropriately. and strengthened. These laws provide the concrete framework
Declaring 2000 as the start of the development of a recycling- in each field for effectively promoting the three Rs, i.e.
oriented society, the government enacted six recycling-related reduction and reuse as well as recycling of the waste generated
laws based around the Basic Law for Promoting the Creation by society.
30
Legislation and arrangement for the creation of a recycling-oriented society
Sorted collection
Japan Containers and
of post-use Packaging Recycling
containers and Association
packaging
Pay
outsourcing
Sale of
fee
recycled Manufacture
Pickup contract
materials of products
by business
Competitive users of
Recycling business recycled
bidding
Hand over bales collected at designated storage facilities (recycler) materia
Municipality (* Transport to plant is handled by recycler)
Source: Website of Japan Containers and Packaging Recycling Association
Example of mark for Example of mark for PET drinks Cup noodles
single material composite material
PE Bottles:PE, EVOH
Caps :PP
Source:
“Container and Packaging Recycling FY2001”The Ministry of Economy, Trade and Industry
◆ Identification marks and material may also contract out recycling work for a recycling fee to
labeling to assist sorted collection the Japan Containers and Packaging Recycling Association.
The Law for Promotion of Sorted Collection and Recycling ● Role of municipalities:
of Containers and Packaging, known as the Containers and Municipalities must establish sorted collection plans and
Packaging Recycling Law for short, aims to promote recycling take the necessary measures to collect container and packaging
and reduce the amount of container and packaging waste waste separately in their areas.
produced by households, which accounts for 60% of its volume In order to assist sorted collection, containers and packaging
and 20-30% of its weight. are also required by law to be labeled with identification
Under this law, consumers, municipalities and businesses marks. Because of the wide variety of materials from which
are each required to play their part in reducing emissions and plastic products are made, it is recommended that such
recycling waste. Changes from the amendment in 2006 products also bear a “material mark” as well as an
include promotion of emission reductions, high quality sorted identification mark.
collections (contributing funds to municipalities) and altering As well as the identification and material marks specified
the PET bottle category (to include containers such as noodle by the Containers and Packaging Recycling Law, the symbols
broth bottles). below are sometimes seen. They are the material identification
● Role of consumers: SPI codes used on containers in the USA.(*)
Consumers must reduce their waste emissions through
making reasonable choices of containers and packaging and
sort their container and packaging waste for collection.
1 2 3 4 5 6 7
PETE HDPE V LDPE PP PS OTHER
● Role of businesses: (PVC)
Businesses that manufacture or use products covered by
(*) Note that this display differs from the Japanese system and should
the law are required to recycle those products. Businesses be used with that in mind.
31
Legislation and arrangement for the creation of a recycling-oriented society
Fund flow
vehicle
Fund flow
vehicle
Automakers, etc.
Recycling businesses ELV Auto dealer etc.
Automakers, etc.
Recycling businesses Auto dealer etc.
CFCs
Designated take-back site
Designated take-back site
CFCs CFC recovery operator
Sale Transportation CFC CFC recovery
recovery operator
charge
Sale Transportation CFC recovery charge Reusable
Airbags Reusable parts, etc.
Municipality
Consumer
Designated
Municipality
recycler
Consumer Metals,
recycler
Collection
Collection and
and Transportation
Transportation
◆ TVs (cathode-ray tube, liquid crystal and plasma), ◆ CFCs, shredded waste and airbags covered
refrigerators/freezers, washing machines/clothes
The End-of-life Vehicles Recycling Law requires that
dryers and air conditioners covered manufacturers and others recover, recycle and appropriately
The Law for Recycling of Specified Kinds of Home dispose of the CFCs in car air conditioners, shredder dust from
Appliances, known as the Home Appliance Recycling Law scrapped cars and airbags from end-of-life vehicles (ELVs).
for short, covsers the recycling of home appliances (TVs, ● Manufactures and importers :
refrigerators, washing machines and air conditioners), and Businesses must take back and recycle the CFCs, airbags
since April 2009 it also covers LCD and plasma TVs and and shredder dust from ELVs. (CFCs must be broken down).
clothes dryers. It imposes the following duties on ● Handling agents :
manufactures, importers, retailers, municipalities and Handling agents take ELVs back from vehicle owners and
consumers. pass them on to CFC recovery operators and dismantles for
● Manufactures and importers : recycling.
Manufactures and importers are required to take back, if ● CFC recovery operators :
requested, products that they manufactured or imported CFC recovery operators are required to appropriately
and that are covered by the law, and to provide an recover CFCs and pass them on to automakers. (A recovery
appropriate location for this purpose. They must also recycle charge may be made for this service).
the waste from these products. ● Dismantlers :
● Retailers : Dismantlers must appropriately recycle and process ELVs
Retailers must under certain conditions and if so requested and pass on airbags to automakers. (A recovery charge may
take back products covered by the law. These products are be made for this service)
then passed on to the manufacturer or importer (or designated ● Shredders :
recycler). Shredders must appropriately recycle and process
● Municipality : dismantled vehicles (ELV shells) and pass on the shredder
Municipalities must drop off collected products covered dust to automakers.
by the law to the manufacturer or importer (or designated ● Owners :
recycler) or recycle such products themselves. Owners must hand over used vehicles to handling agents
● Consumers : and pay a recycling fee.
Consumers must take waste products back to the retailer
and pay a charge for collection, transportation and
recycling.
32
■ ABOUT PWMI
History :
Originally founded in December 1971 as the Plastic Management Research Association, the Plastic
Waste Management Institute (PWMI) received its current name in July of the following year as
operations expanded. For the last 40 years or so, PWMI has endeavored to research and develop
technology for the optimal processing and effective use of plastic waste and to publicize its findings.
In addition, PWMI re-defined its mission in April 2013 as Through conducting researches relating to
cyclical use of plastic aiming to contribute to the reduction of environmental impact through the life
cycle of plastic, PWMI well contribute to the construction of a sustainable society as well as healthy
development of plastic related industries.
Business Content :
(1) LCA based study on environmental impact of plastic and its products.
(2) Research and study relating to cyclical use of plastic, generation of plastic waste etc.
(3) Enhancing public awareness and supporting school education about plastic.
Activities :
The three core activities of PWMI are summarized below.
(1) Provision of life cycle assessment (LCA) base data and LCA evaluation of recycling & recovery (R&R)
technologies
PWMI provides scientific and high-reliability data for widespread use by related industries and
general citizens for application to carbon footprint systems, etc. It also works to solve technical
issues so that the effective use of plastic waste can be evaluated by LCA.
(2) Preparation of the Flowchart of Plastic Products, Plastic Waste and Resource Recovery and ongoing
improvements to its accuracy
PWMI strives to obtain a clear understanding of the entire lifecycle of plastic from its production
stage to its disposal and R&R and to prepare and provide a highly accurate flowchart of this process.
(3) Support of environmental education
PWMI continues to hold instructor training courses and on-site classes and works to raise the
level of consciousness in society regarding the usefulness of plastic. In addition to holding on-site
classes on plastic R&R at primary and middle schools especially in Japan’s Kanto region, PWMI
will honor as much as possible requests for instructor training courses in line with new teaching
guidelines and for lectures at universities specializing in environmental science.
33
Plastic Waste Management Institute
Kayabacho Square Bldg. 9F
3-7-6 Nihonbashi-Kayabacho, Chuo-ku, Tokyo 103-0025, Japan
Tel: +81-3-6855-9175~9177
Fax: +81-3-5643-8447
Web site: http://www.pwmi.or.jp
2016.12. 1,000-(O)