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1. The pressure gage on a 2.5 m³ oxygen tank reads 500 kPa.

determine the amount of oxygen in the


tank if the temperature is 28˚C and the atmospheric pressure is 97 kPa.

V=2.5 m³
O₂ T= 28˚C + 273
= 301 K
Pgage= 500 kPa
Patm= 97 kPa

SOLUTION:

𝑷𝑽 = 𝒎𝑹𝑻
𝑷𝑽
𝒎=
𝑹𝑻

𝑷𝒂𝒃𝒔 = 𝑷𝒈𝒂𝒈𝒆 + 𝑷𝒂𝒕𝒎


= 500 kPa + 97 kPa
= 597 kPa

(𝟓𝟗𝟕 𝒌𝑷𝒂_(𝟐. 𝟓m3 )


𝒎=
𝒌𝑱
(𝟎. 𝟐𝟓𝟗𝟖 − 𝑲) (𝟑𝟎𝟏𝑲)
𝒌𝒈
= 19.08 kg

2. A 400-L rigid tank contains 5 kg of air at 25˚C. Determine the reading on the pressure gage if the
atmosphere pressure is 97kPa.

𝑷𝑽 = 𝒎𝑹𝑻
𝑷 = 𝒎𝑹𝑻/𝑽
m3
(𝟓𝒌𝒈) (𝟎. 𝟐𝟖𝟕 𝒌𝑷𝒂. . K)
kg
𝑷=
0.4 m3

𝑷 = 𝟏𝟎𝟔𝟗. 𝟏 𝒌𝑷𝒂
𝑷𝒈𝒂𝒈𝒆 = 𝑷 − 𝑷𝒂𝒕𝒎
𝑷𝒈𝒂𝒈𝒆 = 𝟏𝟎𝟔𝟗. 𝟏 𝒌𝑷𝒂 − 𝟗𝟕𝐤𝐏𝐚

𝑷𝒈𝒂𝒈𝒆 = 𝟗𝟕𝟐. 𝟏 𝒌𝑷𝒂


3. A 1-m³ tank containing air at 25˚C and 500 kPa is connected through a valve to another tank containing
5 kg of air at 35 ˚C and 200kPa. Now the valve is opened and the entire system is allowed to reach
thermal equilibrium with the surroundings which are at 20˚C. determine the volume of the second tank
and the final equilibrium pressure of air.

Tank A Tank B

V= 1 m³ M= 5 kg
T= 25˚C T= 35 ˚C

P= 500 kPa P= 200kPa

Volume of the tank A, VA = 1 m3


Temperature of air in tank A, TA = 25oC = 298 K
Pressure of air in tank A, PA = 500kPa
Mass of air in tank B, mB = 5 kg
Temperature of air in tank B, TB = 35oC = 308 K
Pressure of air in tank B, PB = 200 kPa
Surrounding temperature, Tsurr = 20oC = 293 K
For air, gas constant R = 0.287 kJ/kmol K
From ideal gas equation, mass of air in tank A is determined by
𝑃𝐴𝑉𝐴 500×1
Ma= = 0.287×298
𝑅𝑇𝐴

𝑀𝑎= 5.846 kg
Volume of the tank B can be determined from
𝑀𝐵𝑅𝑇𝐵
VB = 𝑃𝐵
5×0.287×308
= 200

VB = 2.21 m3

Total volume:
𝑉 = 𝑉𝑎 + 𝑉𝑏
𝑉 = 1 + 2.21
𝑉 = 3.21 m3
Total mass of air:
𝑚 = 𝑀𝑎 + 𝑀𝑏
𝑚 = 5 + 5.846
𝑚 = 10.846 𝑘𝑔

𝑚𝑅𝑇𝑠𝑢𝑟𝑟
𝑃=
𝑉
10.846 × 0.287 × 293
𝑃=
3.21
𝑃 = 284.13 𝑘𝑃𝑎
4. The pressure in an automobile tire depends on the temperature of the air in the tire. When the air
temperature is 25˚C, the pressure gage reads 210 kPa. If the volume of the tire is 0.025 m³, determine
the pressure rise in the tire when the air temperature in the tire rises to 50 ˚C. also, determine the
amount of air that must be bled off to restore pressure to its original value at this temperature. Assume
the atmospheric pressure is 100 kPa.

Solution:
The gas contant for air is:

R = 0.287 kJ/kg・K

The absolute pressure in the tire is


Pabs = Pg + Patm

Pabs = 210 + 100

V = 310 𝑘𝑃𝑎

𝑇1 = 25 + 273

𝑇1 = 298 𝐾

𝑇2 = 50 + 273

𝑇2 = 323 𝐾
Assume the tire volume is constant (also the mass)

PV=𝑚𝑅𝑔 𝑇
𝑃
= 𝐶𝑂𝑁𝑆𝑇𝐴𝑁𝑇
𝑇
𝑃1 𝑃2
=
𝑇1 𝑇2
𝑇 323
P2=𝑇2 𝑃1=298 (310) = 336𝑘𝑃𝑎
1

∆𝑃 = 𝑃2 − 𝑃1 = 336 − 310 = 26𝑘𝑃𝑎

𝑃𝑉 310 × 0.025
𝑚1 = = = 0.0906𝑘𝑔
𝑅𝑎𝑖𝑟 𝑇1 0.287 × 298

𝑃𝑉 310 × 0.025
𝑚2 = = = 0.0836𝑘𝑔
𝑅𝑎𝑖𝑟 𝑇2 0.287 × 323

∆𝑚 = 𝑚1 − 𝑚2 = 0.0906 − 0.0836 = 0.007𝑘𝑔

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