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Pmfias.com Silicon
So, the unwanted impurities must be removed • Coke is a fuel with few impurities and a
and this is done by smelting iron ore in a high carbon content.
blast furnace. • The cooked coal, called coke contains 90 to
93% carbon, some ash and sulfur but
What exactly happens in a blast compared to raw coal is very strong.
furnace?
Role of limestone = Remove Sulphur Page
• In a blast furnace, fuel (coke), iron ore, |2
and flux (limestone) are continuously • It is acts as flux (a substance mixed with a
supplied through the top of the furnace. solid to lower the melting point, especially
• A hot blast of air (sometimes with oxygen in smelting).
enrichment) is blown into the lower • Limestone melts and reacts with Sulphur
section. to form Slag (All solid and liquid
• In a blast furnace, iron oxides are impurities).
converted into liquid iron called "hot
metal". [Limestone marries Sulphur and takes it away
from Iron == Very Good]
[Oxides make iron brittle. To make iron strong
the oxides need to be removed] CaCO3 = CaO + CO2
Inputs in to blast furnace The CaO formed from this reaction is used to
remove sulfur from the iron.
• Ore iron ore;
FeS + CaO + C = CaS + FeO + CO
• Fuel coke;
• Flux limestone. • The CaS [newly married couple] becomes
part of the slag.
Output
• The slag is also formed from any remaining
• Final product liquid slag, liquid iron (pig Silica (SiO2), Alumina (Al2O3), Magnesia
iron) and gases. (MgO) or Calcia (CaO) that entered with the
iron ore or coke.
Beneficiation = Improve Concentration • The liquid slag then trickles to the bottom
of Iron of the furnace where it floats on top of
the liquid iron since it is less dense.
• Ore is either Hematite (Fe2O3) or
Magnetite (Fe3O4) and the iron content
Reduction = Remove Oxygen
ranges from 50% to 70%.
• Oxygen in the iron oxides is reduced
• This iron rich ore can be charged directly
(removed) by a series of chemical reactions.
into a blast furnace without any further
1) 3Fe2O3 + CO = CO2 + 2Fe3O4
processing.
2) Fe3O4 + CO = CO2 + 3 FeO
• Iron ore that contains a lower iron content
3) FeO + CO = CO2 + Fe
must be processed or beneficiated to
increase its iron content. CO or CARBON MONOXIDE is produced by
burning coke.
[Beneficiation Improves the concentration
of iron ore] So CO and CO2 are the gaseous pollutants
coming out of blast furnace.
Why coke and not coal in smelting?
Pig Iron
• To separate impurities, iron needs to be
melted. • Pig iron is the intermediate product of
• The coke is the fuel that melts iron. smelting iron ore.
• Coal has many impurities and the most • Iron (Fe) = 93.5 - 95.0%
dangerous one is SULPHUR. • Silicon (Si) = 0.30 - 0.90%
• Coal is cooked to produce coke. This • Sulfur (S) = 0.025 - 0.050%
process is called destructive distillation. • Manganese (Mn) = 0.55 - 0.75%
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• Phosphorus (P) = 0.03 - 0.09% • Reddish; best quality; 70 per cent metallic
• Titanium (Ti) = 0.02 - 0.06% content.
• CARBON (C) = 4.1 - 4.4% [The strength • Found in Dharwad and Cuddapah rock
of steel can be varied by varying the carbon systems of the peninsular India.
content] • 80 per cent of haematite reserves are in
Odisha, Jharkhand, Chhattisgarh and
Cast iron Andhra Pradesh. Page
• In the western section, Karnataka, | 3
• Carbon content greater than 2%. Maharashtra and Goa has this kind of ore.
• Carbon (C) and silicon (Si) are the main
alloying elements. Magnetite
• Cast iron tends to be brittle.
• Applications: automotive industry parts, • Black ore; 60 to 70 per cent metallic
cast iron pan. content.
• Dharward and Cuddapah systems.
Steel • Magnetic quality.
• Karnataka, Andhra Pradesh, Rajasthan,
• Carbon content is up to 2.1% (by weight). Tamil Nadu and Kerala.
Page
|5
Coal
Iron Ore in Karnataka • Also called black gold.
• Found in sedimentary strata [layers of
soil].
• Contains carbon, volatile matter, moisture
and ash [in some cases Sulphur and
phosphorous]
• Mostly used for power generation and
metallurgy.
• Coal reserves are six times greater than oil
and petroleum reserves.
Formation of Coal
million years ago. Its duration is • The weight of the top layers and the water
approximately 60 million years. and dirt packed down the lower layers of
plant matter.
The name Carboniferous refers to coal-bearing • Heat and pressure produced chemical and
strata. physical changes in the plant layers which
forced out oxygen and left rich carbon
Amount of oxygen, nitrogen and moisture
deposits. In time, material that had been Page
content decreases with time while the |7
plants became coal.
proportion of carbon increases [The quantity
of carbon doesn’t increase, only its proportion • Coals are classified into three main ranks,
increases due to the loss of other elements]. or types: lignite, bituminous coal, and
anthracite.
Capacity of coal to give energy depends upon • These classifications are based on the
the percentage or carbon content [Older the amount of carbon, oxygen, and hydrogen
coal, much more is its carbon content]. present in the coal.
• Coals other constituents include hydrogen,
Percentage of carbon in coal depends upon the oxygen, nitrogen, ash, and sulfur.
duration and intensity of heat and pressure • Some of the undesirable chemical
on wood. [carbon content also depends on constituents include chlorine and
depth of formation. More depth == more sodium.
pressure and heat == better carbon • In the process of transformation
content]. (coalification), peat is altered to lignite,
lignite is altered to sub-bituminous, sub-
bituminous coal is altered to bituminous
coal, and bituminous coal is altered to
anthracite.
• Brown coal.
• Lower grade coal.
• 40 to 55 per cent carbon.
• Intermediate stage.
• Dark to black brown.
• Moisture content is high (over 35 per cent).
• It undergoes SPONTANEOUS
COMBUSTION [Bad. Creates fire accidents
in mines]
Bituminous Coal
Gondwana coal is 100 million years • First coal mine was opened in 1774 at
younger than Carboniferous coal]. Raniganj in West Bengal.
• Gondwana coal is free from moisture, but • Coal industry was nationalized in 1973-74.
it contains Sulphur and phosphorus. [The present government made some
• These basins occur in the valleys of certain serious changes during the last year [2015]
rivers viz., the Damodar (Jharkhand-West by allowing private sector to play a bigger
Bengal); the Mahanadi (Chhattisgarh- role in coal production]. Page
Odisha); the Son (Madhya Pradesh • India is now the third largest coal producer | 9
Jharkhand); the Godavari and the Wardha in the world after China and the USA.
(Maharashtra-Andhra Pradesh); the • Coal industry provides employment to
Indravati, the Narmada, the Koel, the nearly seven lakh persons.
Panch, the Kanhan and many more. • Gondwana Coalfields == exclusively found
in the Peninsular plateau of India
Distribution of Gondwana Coal in India
Gondwana Coalfields in Chhattisgarh
Coalfield Extent
• Korba coalfield Korba district.
• Birampur coalfield Surguja district.
• Hasdo-Arand coalfield
• Chirmiri coalfield
• Lakhanpur coalfield
• Jhilmili coalfield Shandol district & Koriya district
• Johilla coalfield Johilla valley
• Sonhat coalfield Surguja district
• Tatapani-Ramkota coalfields north-eastern part of Surguja district
Gondwana Coalfields in Jharkhand • Major coalfields are present in Dumka
(Santhal Parganas), Hazaribagh, Dhanbad
• 1st in reserves [28%]. and Palamu.
• 2nd in production [20%]. • Jharia, Bokaro, Girdih and Karanpura are
• Most of the coal fields are located in a the major coal fields
narrow belt running in east-west direction.
Jharia coalfield Danbad district One of the oldest and the richest coalfields of India; store
house of the best metallurgical coal [coking coal]
Karanpura and
Ramgarh coalfields
Auranga coalfield Palamu district inferior quality; used in cement furnaces and brick kilns
Hutar coalfield
Deltenganj
coalfield
Devgarh coalfields Dumka district inferior quality
Page
| 10
Talcher field Talcher town to Rairkhol Ranks second in reserves (24,374 million tonnes)
in Dhenkanal and after Raniganj;
Sambalpur districts Coal from this field is most suitable for steam and
gas production.
Most of the coal is utilised in thermal power and
fertilizer plants at Talcher.
Rampur-Himgir Sambalpur and Coal occurs here in middle and lower Barakar
coalfields Sundargarh seams.
inferior quality
Ib river coalfield Sambalpur and Much of the coal is of inferior quality.
Jharsuguda district
Gondwana Coalfields in Madhya
Pradesh
Singrauli (Waidhian) Sidhi and Shandol largest coalfield of Madhya Pradesh
coalfield districts Jhingurda, Panipahari, Khadia, Purewa and Turra are
important coal seams
Jhingurda with a total thickness of 131 m is the
richest coal seam of the country.
thermal power plants at Singrauli and Obra
Pench-Kanhan- Chhindwara district Ghoravari seam in Kanhan field is 4.6 m thick and
Tawa contains coking coal
Sohagpur coalfield Shandol district
Umaria coalfield Umaria district inferior quality with high percentage of moisture and
ash.
Page
| 11
Tertiary Coal
• All data from 2013-2014. For latest 1) Jharkhand [More than 90% of India’s
data you must follow newspapers or Coking coal comes from Jharkhand]
Reports published by Ministry of Coal. 2) West Bengal
• Remember top 3 positions in all data 3) Madhya Pradesh
below.
1) Chhattisgarh
2) Odisha
3) Madhya Pradesh
4) Jharkhand
5) Andhra Pradesh Page
| 14
Total Coal Production By State
1) Chhattisgarh
2) Jharkhand
3) Odisha
4) Madhya Pradesh
5) Andhra Pradesh
Page
| 15
• All sedimentary rocks do not contain oil. • Most of the oil reserves in India are
• An oil reservoir must have three associated with anticlines and fault traps
prerequisite conditions. in the sedimentary rock formations of
1. Porosity [tiny gaps in soil] so as to tertiary times.
accommodate sufficiently large • In tertiary period, aquatic life was
amounts of oil; abundant in various forms, especially the
2. permeability [allowing liquids or gases minor microscopic forms of flora and Page
to pass through it.] to discharge oil fauna. | 17
and/or gas when well has been drilled; • Conditions for oil formation were
3. the porous sandstone beds or fissured favourable especially in the lower and
limestone containing oil should be middle Tertiary period.
capped below by impervious beds [not • Dense forests and sea organisms
allowing fluid to pass through]. flourished in the gulfs, estuaries, deltas
• Most of the oil gets collected in the and the land surrounding them during this
anticlines or fault traps. period.
• Oil on a commercial scale is usually found
in crests of anticlines [where the Extent of Oil Bearing Strata in India
sedimentary rock strata are inclined and
folded]. • 14.1 lakh sq km or 42 per cent of India
covered with sedimentary rocks.
• 10 lakh sq km form marine basins of
Mesozoic and Tertiary times.
• Total continental shelf of probable oil
bearing rocks amounts to 3.2 lakh sq km.
• The total sedimentary area including both
on shore and offshore comprises 27
basins.
• Mumbai High, the Khambhat Gulf and
the Assam are the most productive areas.
• Brahmaputra valley of north-east India. • The main oil bearing strata extend for a
• Barmer area of Rajasthan. distance of 320 km in upper Assam along
• Gujarat coast in western India. the Brahmaputra valley.
• Cauvery on-shore basin in Tamil Nadu. • Oilfields of Assam are relatively
• Andhra Pradesh has both on-shore and inaccessible and are distantly located
offshore oil reserves. from the main consuming areas.
• Oil from Assam is therefore, refined mostly Page
Assam Oilfields in the refineries located at Digboi, | 18
Guwahati, Bongaigaon, Barauni and
• Oldest oil producing state in India Numaligarh.
The Digboi field Tipam hills, Dibrugarh district Oldest oil field of India
The Naharkatiya Left bank of Burhi Dihing river 32 km southwest of Digboi
field Oil from this area is sent to oil
refineries at Noonamati in Assam (443
km) and Barauni in Bihar (724 km)
through pipeline.
The Moran- 40 km south-west of Naharkatiya
Hugrijan field
Supergiants
Page
| 21
Page
| 22
• The discovery that transformed Saudi • Volga-Caspian Region has many oil and
Arabia into a leading oil country was Al- gas fields.
Ghawār oil field. (still has 70 billion
barrels after 60 years of production)
• Another important discovery was the
Saffaniyah offshore field in the Persian
Gulf. It is the third largest oil field in the Page
world and the largest offshore. | 23
Upstream Sector
• This sector involves refining, processing seam. [water will occupy the gaps and
and marketing of products and byproducts pores and will push out the gas]
of crude oil. • It is now becoming an important source of
natural gas.
Unconventional Gas Reservoirs • Unlike much natural gas from
conventional reservoirs, coalbed methane
• Conventional reservoirs of oil and natural contains very little heavier hydrocarbons Page
gas are found in permeable sandstone. such as propane or butane. | 28
• Unconventional Gas Reservoirs occur in • The presence of this gas is well known
relatively impermeable sandstones, in from its occurrence in underground coal
joints and fractures or absorbed into the mining, where it presents a serious safety
matrix of shales [Shale is a Sedimentary risk.
Rock], and in coal seams.
• Given current economic conditions and Fire Accidents in Coal Mines are mainly due to
state of technology, they are more Coalbed Methane, and Lignite deposits which
expensive to exploit. undergo spontaneous combustion.
• Example: Tight gas, shale gas, and coal-
Coalbed Methane in India
bed methane.
• With one of the largest proven coal
reserves, and one of the largest coal
producer in the world, India holds
significant prospects for commercial
recovery of coalbed methane.
• The country has an estimated 700-950
billion cubic metre of coalbed methane.
Page
| 30
Zinc
• Australia (31.34%),
• China (18.41%),
• Brazil (13.93%),
• Guinea (8.36%), etc.
of very low grade. The mining has almost • Countries with significant deposits: South
ceased due to little or no profitability. Africa, Australia, Indonesia, Canada,
• The Kolar Gold Field has also run out of Ghana, Chile, China, USA, Russia etc.
quality reserves and is on the verge of
closure. Countries with highest gold deposits
Kerala
• Odisha (44%),
• Karnataka (22%),
• Madhya Pradesh (13%),
• Maharashtra (8%),
• Andhra Pradesh (4%)
• Jharkhand and Goa (3% each),
• Rajasthan, Gujarat and West Bengal
(remaining 3 per cent).
Maharashtra
Andhra Pradesh
Karnataka
Madhya Pradesh
• Metallic nickel is used for making storage • Most of the graphite is formed at
batteries and as a catalyst for convergent plate boundaries where
hydrogenation or hardening of fats and organic-rich shales and limestones were
oils intended for use in soap and subjected to metamorphism due to heat
foodstuffs and in making vanaspati.
• Important occurrences of
nickeliferous limonite are found in Page
the Sukinda valley of Jajapur | 40
district, Odisha. Here it occurs as
oxide.
• Nickel also occurs in sulphide form
along with copper mineralization in
east Sighbhum district, Jharkhand.
• In addition, it is found associated with
uranium deposits at Jaduguda,
Jharkhand.
• Other important occurrences of nickel
are in Karnataka, Kerala and
Rajasthan.
• Polymetallic sea nodules are another
source of nickel.
• About 92 per cent resources are in
Odisha.
• The remaining 8 per cent resources are
distributed in Jharkhand, Nagaland
and Karnataka
Graphite
• Graphite is a naturally-occurring form
of crystalline carbon.
• It is also known as plumbago or black and pressure.
lead. • Metamorphism produces marble, schist
• The carbon content in Graphite is never and gneiss that contains tiny crystals and
less than 95%. flakes of graphite.
• Graphite may be considered the highest • Some graphite forms from the
grade of coal, just above anthracite. metamorphism of coal seams. This
graphite is known as “amorphous
Carbon content in Peat < Lignite < Bituminous graphite”.
< Anthracite < Graphite < Diamond • Graphite is a non-metal and it is the only
non-metal that can conduct electricity.
• It is not normally used as fuel because it is
difficult to ignite. Applications of Graphite
• It is found in metamorphic and igneous
rocks. • Natural graphite is mostly consumed for
• Graphite is extremely soft, cleaves [splits refractories, batteries, steelmaking,
into layers] with very light pressure. expanded graphite, lubricants etc.
• It is extremely resistant to heat and is • A refractory material is one that retains its
highly unreactive. strength at high temperatures.
• Natural and synthetic graphite are used to • Graphite is not mined in the United States.
construct the anode of all major battery U.S. substitutes graphite with synthetic
technologies graphite.
• The lithium-ion battery utilizes roughly
twice the amount of graphite than lithium Diamonds
carbonate.
• Natural graphite in this end use mostly • Diamond is the hardest naturally Page
goes into carbon raising in molten steel. [to occurring substance found on Earth. | 41
make steel stronger] • Diamonds are formed in mantle. They
• Natural amorphous graphite are used in brought to the earth’s crust due to
brake linings for heavier vehicles, and volcanism. Most of the diamonds occur in
became important with the need to dykes, sill etc. [Volcanic Landforms].
substitute for asbestos. • Diamond is the Diamonds are used in
• Graphite lubricants are specialty items for ornaments, polishing the surfaces of
use at very high or very low temperatures. metals and in gem cutting.
• Modern pencil lead is most commonly a • The most important industrial use of
mix of powdered graphite and clay. diamonds is in cutting-edges of drills used
for exploration and mining of minerals
Major Producers of Graphite – India & [Diamond is the hardest substance and it
World can break other substances without itself
getting broken].
• India is a major global producer of flake
graphite. Diamonds in India
• The new kimberlite fields are discovered • South Africa has the most diverse range of
recently in Raichur-Gulbarga districts of diamond deposits in the world. Deposits
Karnataka. include open pit and underground
• Reserves of diamonds in India are not yet kimberlite pipe/dyke/fissure mining.
exhausted and modern methods are being
applied for intensive prospecting and
mining. Page
• Cutting and polishing of diamonds is done | 42
by modem techniques at important centres
like Surat, Navasari, Ahmedabad,
Palampur etc.
Graphite Diamond
Graphite contains 95% or more carbon. Diamond is 100% carbon.
Graphite is a non-metallic mineral that forms Diamond is also a non-metallic mineral that
when carbon is subjected to extreme heat and forms when carbon is subjected to extreme heat
pressure in Earth’s crust and in the upper and pressure in the mantle.
mantle.
Graphite is one of the most stable substances Diamond (one of the most stable) is less stable
on earth. than graphite.
The carbon atoms in graphite are linked in a In contrast, the carbon atoms in diamond are
hexagonal network that forms sheets that are linked into a frameworks structure. Every
one atom thick. These sheets are poorly carbon atom is linked into a three dimensional
connected and easily cleave or slide over one network with strong covalent bonds. This
another if subjected to a small amount of arrangement holds the atoms firmly in place and
force. This gives graphite it’s very low make diamond an exceptionally hard material.
hardness, its perfect cleavage and its slippery
feel.
[Pencil Lead is not made of lead as we
normally beleive. It is made of graphite. You
know why?]
Page
Non-Metallic Minerals 5. Bihar (2 per cent)
6. Jharkhand (Less than 1 per cent) | 43
Andhra Pradesh
Rajasthan
• The discovery of nuclear fission began with Fissile → That can undergo Controlled or Self-
the discovery of the neutron in 1932 by Sustained nuclear fission chain Reaction.
James Chadwick in England.
• Nuclear fission of heavy elements was • If controlled in a nuclear reactor, such a
discovered in 1938 by German Otto Hahn chain reaction can be used to generate
and Fritz Strassmann. power. If uncontrolled [atomic bomb], it
• It was explained theoretically in 1939 by can lead to an enormous explosion. Page
Lise Meitner and Otto Robert Frisch. • Uranium is the most common fissile used | 47
• In nuclear physics, nuclear fission is a in nuclear reactors and nuclear weapons.
radioactive decay process in which the • Uranium isotopes in natural uranium are
nucleus of an atom splits into smaller Uranium-238 or U-238 or 238U (99.27%)
parts [lighter nuclei]. and Uranium 235 or U-235 or 235U
• The fission process often produces free (0.72%).
neutrons and gamma photons [gamma • Uranium-235 can undergo fission when
rays], and releases a very large amount of bombarded with slow neutrons only.
energy [exothermic reaction]. • Uranium-238 can undergo fission when
bombarded with fast neutrons only.
[When urea is dissolved in water, the • The nuclei of other heavy elements, such
temperature of water solution falls. This as thorium also fissionable, but with fast
reaction is called endothermic reaction]. neutrons.
Exothermic == Liberation of Heat during a How Nuclear Fission Releases Energy?
reaction. [CaCO3(calcium carbonate or lime) +
H2O (water) → Ca(OH)2(calcium hydroxide) + • Nuclei consist of nucleons [neutrons +
CO2 + HEAT] protons = mass number].
• The actual mass of a nucleus is always
Endothermic == Absorption of Heat during a
less than the sum of the masses of
reaction. [Urea + Water]
nucleons.
• The nuclear fission process may take place • This difference is known as the mass
spontaneously in some cases or may be defect and is a measure of the total
induced by the excitation of the nucleus binding energy (and, hence, the stability) of
with a variety of particles (neutrons, the nucleus.
protons, deuterons, or alpha particles) or • This binding energy is released during the
with electromagnetic radiation in the form formation of a nucleus.
of gamma rays. • This conversion of mass to energy follows
• In the fission process, radioactive products Einstein’s equation, E = mc2, where E is
are formed, and several neutrons are the energy equivalent of a mass, m, and c
emitted. is the velocity of light.
• These neutrons can induce fission in a
Common Fissile Material
nearby nucleus of fissionable material and
release more neutrons causing a chain
• Uranium-235, Plutonium-239 and
reaction.
Thorium-232 are the common fissile
material.
• A slow neutron can be captured by a
uranium-235 nucleus.
• A fast neutron will not be captured, so
neutrons must be slowed down by
moderation to increase their capture
probability in fission reactors.
• Natural uranium is composed of 0.72% U-
235 (the fissionable isotope), 99.27% U-
238, and a trace quantity 0.0055% U-234.
Fissionable material → That can undergo
nuclear fission chain reaction.
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• The 0.72% U-235 is not sufficient to • The heat is carried out of the reactor by
produce a self-sustaining critical chain coolant, which is most commonly just
reaction. plain water.
• For light-water reactors, the fuel must be
enriched to 2.5-3.5% U-235.
• While uranium-235 is the naturally
occurring fissionable isotope, Plutonium- Page
239 can be produced by "breeding" it from | 48
uranium-238.
• Uranium-238, which makes up 99.3% of
natural uranium, is not fissionable by
slow neutrons.
• U-238 has a small probability for
spontaneous fission and also a small
probability of fission when bombarded with • The coolant heats up and goes off to a
fast neutrons, but it is not useful as a turbine to spin a generator or drive shaft.
nuclear fuel source.
• The coolant is the material that passes
• Thorium-232 is fissionable, so could through the core, transferring the heat
conceivably be used as a nuclear fuel. from the fuel to a turbine. It could be
• The other isotope can undergo fission upon water, heavy-water, liquid sodium, helium,
slow-neutron bombardment is uranium- or something else.
233. • The turbine transfers the heat from the
coolant to electricity, just like in a fossil-
Uranium Enrichment
fuel plant.
• Natural uranium is only 0.7% U-235, the • The containment is the structure made of
fissionable isotope. steel-reinforced concrete that separates the
reactor from the environment. Chernobyl
• The other 99.3% is U-238 which is not
did not have a strong containment
fissionable.
structure.
• The uranium is usually enriched to 2.5-
3.5% U-235 for use in light water reactors. Nuclear Reactor Coolant
• Centrifugal separators and laser
enrichment procedures are used in • A nuclear reactor coolant — usually water
uranium enrichment. or molten salt — is circulated past the
• The enriched uranium fuel used in fission reactor core to absorb the heat that it
reactors cannot be used to make a bomb. generates.
• It takes enrichment to over 90% to obtain • The heat is carried away from the reactor
the fast chain reaction necessary for and is then used to generate steam.
weapons applications.
• Enrichment to 15-30% is typical for Neutron Moderator
breeder reactors.
• A neutron moderator is a medium that
Nuclear Reactor reduces the speed of fast neutrons,
thereby turning them into thermal
• A nuclear reactor is a system that contains neutrons capable of sustaining a nuclear
and controls sustained nuclear chain chain reaction.
reactions. • When a large fissile atomic nucleus such
• Fuel [Enriched uranium-235 or Plutonium- as uranium-235 or plutonium-239 absorbs
239] is placed into the reactor vessel along a neutron, it may undergo nuclear fission.
with a small neutron source. • The heavy nucleus splits into two or more
• The neutrons start a chain reaction where lighter nuclei, (the fission products),
each atom that splits releases more releasing kinetic energy, gamma radiation,
neutrons that cause other atoms to split. and free neutrons.
• Each time an atom splits, it releases large • A portion of these neutrons may later be
amounts of energy in the form of heat. absorbed by other fissile atoms and trigger
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• There are various types of reactors based • Fission reactors can be divided roughly
on moderators, coolants, technologies into two classes, depending on the energy
used. of the neutrons that sustain the fission
• All commercial power reactors are based chain reaction: thermal reactors and fast
on nuclear fission. neutron reactors.
• They generally use uranium and its
product plutonium as nuclear fuel, though Thermal Reactors and Fast Neutron Page
a thorium fuel cycle is also possible. Reactors [Breeder Reactors] | 50
• SCWRs resemble light water reactors the reactor to make use of alternate fuel
(LWRs) but operate at higher pressure and cycles.
temperature like the pressurized water
reactor (PWR) and with a direct once- Advantages of Pressurized Heavy-Water
through cycle like a boiling water reactor Reactor (PHWR)
(BWR).
• It can be operated without expensive Page
• The SCWR is a promising advanced
uranium enrichment facilities. | 52
nuclear system because of its high thermal
• The mechanical arrangement places most
efficiency and simpler design.
of the moderator at lower temperatures.
• It is still in development stage.
The resulting thermal neutrons are "more
Advantages of Supercritical Water Reactor thermal" making PHWR more efficient. So,
(SCWR) PHWR uses fuel more efficiently.
• Since unenriched uranium fuel
• Supercritical water has excellent heat accumulates a lower density of fission
transfer properties allowing a high power products than enriched uranium fuel, it
density, a small core, and a small generates less heat, allowing more compact
containment structure. storage.
• As a BWR is simpler than a PWR, a SCWR
is a lot simpler and more compact than a Disadvantages of Pressurized Heavy-Water
less-efficient BWR. Reactor (PHWR)
• There are no steam separators, steam
• The reduced energy content of natural
dryers, internal recirculation pumps, or
uranium as compared to enriched uranium
recirculation flow inside the pressure
necessitates more frequent replacement of
vessel.
fuel.
• The stored thermal and radiologic energy
• The increased rate of fuel movement
in the smaller core would also be less than
through the reactor also results in higher
that of either a BWR's or a PWR's.
volumes of spent fuel than in LWRs
• Water is liquid at room temperature, employing enriched uranium.
cheap, non-toxic and transparent,
simplifying inspection and repair. Nuclear proliferation and PHWR
• A fast SCWR could be a breeder reactor,
like the proposed Clean And • Opponents of heavy-water reactors suggest
Environmentally Safe Advanced Reactor. that such reactors pose a much greater
• A heavy-water SCWR could breed fuel from risk of nuclear proliferation than
thorium (4x more abundant than comparable light water reactors.
uranium), with increased proliferation • Natural Uranium-238 fissile [because
resistance over plutonium breeders. enrichment is not required] of a heavy-
water reactor is converted into plutonium-
Pressurized Heavy-Water Reactor 239, a fissile material suitable for use in
(PHWR) nuclear weapons.
• As a result, if the fuel of a heavy-water
• Uses heavy water (deuterium oxide D2O) reactor is changed frequently, significant
as its coolant and neutron moderator. amounts of weapons-grade plutonium can
• The heavy water coolant is kept under be chemically extracted from the irradiated
pressure, allowing it to be heated to higher natural uranium fuel by nuclear
temperatures without boiling, much as in a reprocessing [Pakistan is pretty good at
pressurized water reactor. this].
• While heavy water is significantly more • In this way, the materials necessary to
expensive than ordinary light water, it construct a nuclear weapon can be
creates greatly enhanced neutron obtained without any uranium enrichment.
economy, allowing the reactor to operate • In addition, the use of heavy water as a
without fuel-enrichment facilities moderator results in the production of
(offsetting the additional expense of the small amounts of tritium when the
heavy water) and enhancing the ability of
Thorium
consumption; or give them greater Yttrium etc. –– (names are very strange
efficiency, performance, miniaturization, and hence I am avoiding them)]
speed, durability, and thermal stability.
• There are 17 elements that are considered Nuclear Power Plants in India
to be rare earth elements. [Scandium,
Page
| 55
Page
| 56
Thorium Distribution
• The recent Indo-US Nuclear Deal and the [In PWHR, enrichment of Uranium to improve
NSG waiver, which ended more than three concentration of U-235 is not required. U-238
decades of international isolation of the can be directly fed into the reactor core]
Indian civil nuclear programme, have
created many hitherto unexplored [Natural uranium contains only 0.7% of the
alternatives for the success of the three- fissile isotope uranium-235. Most of the
stage nuclear power programme. remaining 99.3% is uranium-238 which is not Page
• Thorium itself is not a fissile material, and fissile but can be converted in a reactor to the | 58
thus cannot undergo fission to produce fissile isotope plutonium-239].
energy.
[Heavy water (deuterium oxide, D 2O) is used
• Instead, it must be transmuted to as moderator and coolant in PHWR].
uranium-233 in a reactor fueled by other
fissile materials [plutonium-239 or • PHWRs was a natural choice for
uranium-235]. implementing the first stage because it had
• The first two stages, natural uranium- the most efficient reactor design
fueled heavy water reactors and [uranium enrichment not required] in
plutonium-fueled fast breeder reactors, terms of uranium utilisation.
are intended to generate sufficient fissile • India correctly calculated that it would be
material from India's limited uranium easier to create heavy water production
resources, so that all its vast thorium facilities (required for PHWRs) than
reserves can be fully utilized in the third uranium enrichment facilities (required for
stage of thermal breeder reactors. LWRs).
• Almost the entire existing base of Indian
nuclear power (4780 MW) is composed of
first stage PHWRs, with the exception of
the two Boiling Water Reactor (BWR) units
at Tarapur.
Obstacles
Page
• The U.S. could perhaps emerge as the | 61
greatest obstacle to plutonium commerce.
• U.S. cannot prevent countries from trading
in plutonium, it has the power to make it
uncomfortable for them via sanctions,
reduced scientific cooperation, and other
mechanisms.
• The strong non-proliferation lobby in the
U.S. would not like a non-signatory of the
NPT [India] to open and regulate trade in
plutonium.
• The challenge for Delhi is to convince
Washington to sponsor rather than oppose
such a venture.
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