LEADER COURSE (PHASE – ELS, ELC, ELD & ELP)

TARGET : JEE (MAIN) 2015

SCORE – I DATE : 01 - 03 - 2015
MAJOR TEST Test Pattern : JEE (Main)
ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Ans. 2 4 3 1 4 4 2 1 1 4 4 2 1 2 3 1 1 4 4 2

Que. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

Ans. 4 1 2 2 4 3 3 4 1 2 3 4 1 4 4 2 2 3 2 1

Que. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Ans. 1 1 4 2 2 3 1 1 4 1 1 2 3 2 1 3 4 4 3 4

Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

Ans. 2 3 1 1 2 1 2 2 4 1 2 4 3 1 1 2 2 4 1 2

Que. 81 82 83 84 85 86 87 88 89 90

Ans. 4 4 2 3 4 3 2 1 2 3

HINT – SHEET

I max For steady state, P net received

= P net emitted
1. Inet = I0 + I0 + 2I0 cos =  2I 0
2
 A  4   2T     A  3T    4 
4 4
 2
 cos  = 0   = n   x
2  1/ 4
  97 
4
   16T  81T  4 4 4     T
  x =  2n  1  2
4

2. P= RT
M  
4. R1 =  2R R2 = R
P1 1M 2 4  4 2 8 kA 2kA
    1   
P2 2 M1 3 2 3 3 9 in configuration 1 ; equivalent R = 3R
2T  3T 2
in configuration 2 ; equivalent R = R
3

3.
T T
Q1  t1 ; Q 2  t
3R 2R 2
3

preceived precieved T 3T 2

pemitted  t1  t 2  t 2  t1  2 sec.
pemitted 3R 2R 9

Kota/01CE314058 HS-1/4
 Target : JEE(Main) 2015/01-03-2015
14. Cp – Cv = R Always constant
3RT
5. vrms  Cp
M = decreases with atomicity
Cv
 vrms  He  M Ar 40 (C p + C v ) depends on degree of freedom
   10 = 3.16 therefore. It will be more for diatomic gas.
 vrms  Ar M He 4
2 T
f  f  15. F1 
6. Q=U+W = nRT + PV =   1 nR T 2 m
2 2
3  5
=   1 2  8.31  5  208 J F2 
4
F1
2 
 16. n1 = n2
7. In resonance column experiment  1  e so,
4 1 T1 2 T2

 v 2 m 2 m
1  e   0.3d
4 4f T1 = 4T2
336  100 cm 1 = 2
=   0.3  4 cm   16.4  1.2  15.2 cm
4  512 T1 × x = 2 × (L – x)
5.6 1 4x =  – x
8. No. of moles = n  
22.4 4 
TV –1 = constant T 1 (5.6) 2/3 = T 2 (0.7) 2/3 x
5
T1(8)2/3 = T2 4T1 = T2
1 R  3T1   3 3v 3  340
 nRT 9 17. n   340 Hz
W gas =     RT1 . 4 4  75
 1 42 8 100
9 Shring Fork Beats
Therefore Wexternal = RT
8 1 340 344 or 336 4
T 2
 v   v  v0  18. Frequency is the characteristics of source.
9. f   f
 v  vs   v 
1
 320   320  10  19. T1 = 2 = 2 sec
g
 f      8
320  10   320 
 f   8.50 kHz 1.21
T2 = 2  = 2.2 sec
g
11. By principle of calorimetry
m × 2100 × 5 + 10–3 × 3.36 × 105 = 420 T2 × 10 = 22 sec ; T1 × 11 = 22 sec
 m = 8 gm
d2 x
12. Apparent frequency of sound reflected from car 21.  ax  2 x
dt 2
 v  v0   2v 
f  f0   1  0  f0
 v  v0   v   a
f 2v 1.2
  100 1.2  0  2
f0 v 100  a
T
18
 v0  2ms 1  2  km / h 7km / h 2
5 T
a
 
13. A  A12  A22  =   A  4 2 3 2 5
 2

HS-2/4 Kota/01CE314058
 Leader Course/Phase-ELS, ELC, ELD & ELP/Score-I/01-03-2015
22. amax  g 27. x  A sin t  Bcos t
2A  g 1cm
1cm  A B 
g x  A2  B  2 2
sin t  cos t 
A B
2 2
 A B 
A
x  A2  B2 [cossint + sin cost]
A
T  2
g x  A 2  B2 sin(t  )

0.01 1
T  2 30. kE  mv 2
g 2

1 kE m v
T2×  2
10 kE m v
T  0.2 sec kE
 100  2  2  3
t = T/4 1 2 1 2 2
kE
RE = KA =  m A
t=0 4 4 = 8%
31. due to H-bonding b.p. of (II) is maximum.
1 g 2 1
=  1   A =  1  10  0.01 32. for Aldol condensation compound must have -
4 A 4
H.
1 33. Zn-Hg/HCl can reduce all functional group.
= Joule
40 34. Oxidation of Toluene in (i) and (ii) gives
t = T/4 benzaldehyde in (iii)
RE = 0.025 Joule. Cl
t=0 CH3 CH ΘOH
Cl 2
1 1

h Cl 
24. P1  V12  P2  V22
2 2 O
OH
1 CH C H
P1 – P2 =  (V22  v12 ) 
2 OH 
 H2 O


1 Aliphatic Aromatic
h × 13600 × g = × 1000 (V22  V12 ) 36. Reactivity Aldehyde Aldehyde Ketone
2
O
d(volume)
A1 V1 = A2 V2 = 37. C–CH2 is better enolet and
dt

500 CH3 CHO is acceptor.

V1   100cm / s  1m / s
5
O
500 NaOCl
V2   250 cm / s  2.5 m / s 38. Ph C CH3 
Haloform
 CHCl3 + PhCOONa
2 Rx n
CH3—C—CH3
1 O
1000(0.25  1)
h 2 m Chloretone
13600  10
39. Aromatic Aldehyde can not reduce fehling soln
1 5.25  100 40. In both cases benzylic intermediate is more
h  cm stable which gives major product.
2 136
43. HgSO4/H2SO4 is KUCHEROV's Reaction.

Kota/01CE314058 HS-3/4
 Target : JEE(Main) 2015/01-03-2015

0.059 [Zn 2 ] 15 C
44.
0
E cell  E cell  log 88. R = 5, p  3
2 [Cu 2 ] 5
 Length of chord (3,4)
45. Equivalent = F = mole × V.f R p
=1×2=2 2 2 A B
=2 R  p  8
i 1 i 1
47. = = 0.2 = Area is maximum when ABC is isosceles.
n 1 2 1
i = 1.2 1
A   8  (3  5) = 32 sq. units
(Tf)obs = (Tf)thero × i 2
= Kf × m × I = 1.86 × 0.2 × 1.2 89. Let a = p + q; b = p + 3q; c = p + 6q
Gº –nFEº where p is first term and q is common difference.
50. =   ax + by + c = 0
Hº Hº
 p(x + y + 1) + q(x + 3y + 6) = 0
–1  96500  Eº
0.7  x  y  1  0 3 5
–300  1000   x ; y
x  3y  6  0  2 2
1000 M
51. m 90. y + 1 = m(x + 3)
1000d – MM A
 mx – y + 3x – 1 = 0
1000M Distance from (0,0) = 1
3
1000  1.1 – M  40 y
53. Gas which have maximum value of 'a' can be
most easily liquefied.
58. None of given molecule can be hydrolysed but O x
SF6 is the only molecule which is inert towards (–3,–1) (0,–1)P
water due to steric hinderence rest are inert due
to absence of vacant orbital.
3m  1 3
  1  m = 0 or
1 2 1 2 4
1 1 m
85. Area = 4 × | 1 1 1 | = 6
2  Reflected ray : 3x – 4y + 5 = 0
0 3 1
86. C1  (1, –2), r1 = 3
C2  (4, 2), r2 = 2
|C1C2| = 5 = r1+r2
 3 tangents
87.
A
3 3

4
P(4, 4) M C(1, 1)

B
 3
AM = 3 sin 
4 2
3
AB = 2 AM = 2 × = 3 2
2
HS-4/4 Kota/01CE314058