& kmole/hr

Cooling Medium Requirement:

QTotal = −QSH

473.15
QSH = mSH ∫ Cp SH dT
303.15

Table 8.X Operating Parameters of Cooling Medium (Shell HTO S2)

Operating Pressure 101.325 kPa

Inlet Temperature 30oC
Outlet Temperature 200oC

Solving for 𝐦𝐒𝐇 ,

kJ
Cp SH ( ) = C1
kg − K

Table 8.2X. Constant for Heat Capacity of Shell HTO S2

C1 2.2227

Reference:

473.15
QSH = mSH ∫ Cp SH dT
303.15

473.15
QSH = mSH ∫ (C1)dT
303.15

473.15
QSH = mSH ∫ (2.2227)dT
303.15

kJ
QSH = mSH (377.859 )
kg

kJ
QTotal = −QSH = −mSH (377.859 )
kg
 kJ
kW = −mSH (377.859 )
kg
𝐤𝐠
𝐦𝐒𝐇 = 𝟒. 𝟕𝟑
𝐬

Cooling Water Requirement:

QTotal = −QCW
343.15
QCW = mCW ∫ Cp cw(l) dT
303.15

Table 8.X Operating Parameters of Cooling Water for Sodium Chloride Mixing Tank

Operating Pressure 101.325 kPa

Inlet Temperature 30oC
Outlet Temperature

Solving for 𝐦𝐂𝐖 ,

J
Cp CW(l) ( ) = C1 + C2T + C3T 2 + C4T 3 + C5T 4
kmole − K

Table 8.2X. Constant for Heat Capacity of Liquid Water

C1 276370
C2 -2090.1
C3 8.125
C4 -0.014116
C5 9.3701E-06

Reference: Heat Capacities of Inorganic and Organic Liquids, Perry's Chemical Engineers’
Handbook, 8th Edition

343.15
QCW = mCW ∫ Cp cw(l) dT
303.15

343.15
QCW = mCW ∫ (C1 + C2T + C3T 2 + C4T 3 + C5T 4 )dT
303.15
 343.15
(276370 − 2090.1T + 8.125T 2 − 0.014116T 3 + 9.3701E
QCW = mCW ∫
303.15 −06T 4 )dT

J 1 kJ 1 kmole
QCW = mCW (3,013,014.26 )( )( )
kmole 1000 J 0.01802 kg

kJ
QCW = mCW (167.39 )
kg

kJ
QTotal = −QCW = −mCW (167.39 )
kg
kJ
−792.271 kW = −mCW (167.39 )
kg
𝐤𝐠
𝐦𝐂𝐖 = 𝟒. 𝟕𝟑
𝐬

Steam Requirement

QTotal = QS
343.15
QS = mS ∫ Cp S dT
303.15

Table 8.X Operating Parameters of Steam for Ammonia Pre-Heater

Operating Pressure 101.325 kPa

Inlet Temperature 180oC
Outlet Temperature 130oC

Solving for 𝐦𝐒 ,

J
Cp S ( ) = C1 + C2T + C3T 2 + C4T 3 + C5T 4
mole − K

Table 8.4X. Constant for Heat Capacity of Steam

C1 33.933
C2 -0.00842
C3 3.00E-04
C4 -1.78E-08
 C5 3.69E-12

Reference: Table 2. Heat Capacity of Gas - Organic and Inorganic Compounds. Yaws, C. L.
(1999). Chemical Properties Handbook.

343.15
J
QS = mS ∫ Cp S ( ) dT
303.15 mole − K

343.15
QS = mS ∫ (C1 + C2T + C3T 2 + C4T 3 + C5T 4 )dT
303.15

343.15
(33.933 − 0.00842T + (3.00E − 04)T 2 − (1.78E − 08)T 3
QS = mS ∫
303.15 + (3.69E − 12)T 4 )dT

J 1 kJ 1 mole 1000 g
QS = mS (−4,200.77 )( )( )( )
mole 1000 J 18.02 g 1 kg

kJ
QS = mS (−233.38 )
kg

kJ
QTotal = QS = mS (−233.38 )
kg
kJ
468.77 kW = mS (−233.38 )
kg
𝐤𝐠
𝐦𝐒 = 𝟏. 𝟕𝟗
𝐬

cal
Cp SA ( ) = C1
mole − K

Table 8.2X. Constant for Heat Capacity Sodium Carbonate

C1 28.9

Reference: Heat Capacities of Elements and Inorganic Compounds, Perry's Chemical Engineers'
Handbook, 8th Edition
 363.15
QSA = mSA ∫ Cp SB dT
298.15

363.15
QSA = mSA ∫ (C1)dT
298.15

kg 363.15
QSA = ∫ (28.9)dT
hr 298.15

kg cal 4.184 J 1 kJ 1 mole

QSA = ( )( )( )( )
hr mole 1 cal 1000 J 0.106 kg

𝐤𝐉
𝐐𝐒𝐀 =
𝐡𝐫

cal
Cp A ( ) = C1 + C2T
mole − K

Table 8.X. Constant for Heat Capacity of Ammonia Gas

C1 6.70
C2 0.0063

Reference: Heat Capacities of Inorganic and Organic Liquids, Perry's Chemical Engineers’
Handbook, 8th Edition

298.15
QA = mA ∫ Cp A dT
293.15

298.15
QA = mA ∫ (C1 + C2T)dT
293.15

kg 298.15
QA = 11,442.98 ∫ (6.70 − 0.0063T)dT
hr 293.15

kg cal 4.184 J 1 kJ 1 mole

QA = 11,442.98 (489.66 )( )( )( )
hr mole 1 cal 1000 J 0.017 kg

kJ
QFeed = QA = 1,379,031.54
hr
 cal
Cp SC ( ) = C1 + C2T
mole − K

Table 8.2X. Constant for Heat Capacity Sodium Chloride

C1 10.79
C2 0.00420

Reference: Heat Capacities of Inorganic and Organic Liquids, Perry's Chemical Engineers’
Handbook, 8th Edition

363.15
QSC = mSC ∫ Cp SC dT
298.15

363.15
QSC = mSC ∫ (C1 + C2T)dT
298.15

kg 363.15
QSC = ∫ (10.79 + 0.00420T)dT
hr 298.15

kg cal 4.184 J 1kJ 1 mole

QSC = ( )( )( )( )
hr mole 1 cal 1000J 0.05845 kg

𝐤𝐉
𝐐𝐒𝐂 =
𝐡𝐫

cal
Cp SAM ( ) = C1
mole − K

Table 8.2X. Constant for Heat Capacity Sodium Carbonate Monohydrate

C1 34

Reference: Heat Capacities of Elements and Inorganic Compounds, Perry's Chemical Engineers'
Handbook, 8th Edition
 291.15
QSA1 = mSA1 ∫ Cp SB dT
313.15

291.15
QSA1 = mSA1 ∫ (C1)dT
313.15

kg 291.15
QSA1 = ∫ (34)dT
hr 313.15

kg cal 4.184 J 1 kJ 1 mole

QSA1 = ( )( )( )( )
hr mole 1 cal 1000 J 0.106 kg

𝐤𝐉
𝐐𝐒𝐀𝐌 =
𝐡𝐫

cal
Cp AH ( ) = C1 + C2T
mole − K

Table 8.7. Constant for Heat Capacity of Ammonia Hydroxide

C1 2.6955
C2 0.1392

Reference: Heat Capacities of Inorganic and Organic Liquids, Perry's Chemical Engineers’
Handbook, 8th Edition

303.15
QAH = mAH ∫ Cp AH dT
298.15

303.15
QAH = mAH ∫ (C1 + C2T)dT
298.15

kg 303.15
QAH = 23,297.12 ∫ (2.6955 + 0.1392T)dT
hr 298.15

kg cal 4.184 J 1 kJ 1 mole

QAH = 23,297.12 (13.83 )( )( )( )
hr mole 1 cal 1000 J 0.017 kg

𝐤𝐉
𝐐𝐀𝐇 = 𝟑𝟖, 𝟓𝟎𝟒. 𝟎𝟖
𝐡𝐫
 cal
Cp AC ( ) = C1 + C2T
mol − K

Table 8.2X. Constant for Heat Capacity Ammonium Chloride

C1 9.80
C2 0.0368

Reference: Heat Capacities of Inorganic and Organic Liquids, Perry's Chemical Engineers’
Handbook, 8th Edition

QAC = mAC ∫ Cp AC dT
303.15

QAC = mAC ∫ (C1 + C2T)dT

303.15

kg
QAC = ∫ (9.80 + 0.0368T)dT
hr 303.15

kg cal 4.184 J 1kJ 1 mole

QAC = ( )( )( )( )
hr mole 1 cal 1000J 0.05845 kg

𝐤𝐉
𝐐𝐀𝐂 =
𝐡𝐫

J
Cp CW(l) ( ) = C1 + C2T + C3T 2 + C4T 3 + C5T 4
kmole − K

Table 8.2X. Constant for Heat Capacity of Liquid Water

C1 276370
C2 -2090.1
C3 8.125
C4 -0.014116
C5 9.3701E-06
Reference: Heat Capacities of Inorganic and Organic Liquids, Perry's Chemical Engineers’
Handbook, 8th Edition

298.15
QW = mW ∫ Cp cw(l) dT
303.15

298.15
QW = mW ∫ (C1 + C2T + C3T 2 + C4T 3 + C5T 4 )dT
303.15

298.15
(276370 − 2090.1T + 8.125T 2 − 0.014116T 3 + 9.3701E
QW = mW ∫
303.15 −06T 4 )dT

kg J 1 kJ 1 kmole
QW = ( ) (3,013,014.26 )( )( )
hr kmole 1000 J 0.01802 kg

𝒌𝑱
𝐐𝐖 =
𝒉𝒓

kJ
Cp SB ( ) = C1
kg − K

Table 8.2X. Constant for Heat Capacity Sodium Bicarbonate

C1 1.01

Reference:

QSB = mSB ∫ Cp SB dT
303.15

QSB = mSB ∫ (C1)dT

303.15

kg
QSB = ∫ (1.01)dT
hr 303.15

kg kJ
QSB = ( )
hr kg
 𝐤𝐉
𝐐𝐒𝐁 =
𝐡𝐫

kJ
Cp AB ( ) = C1
kg − K

Table 8.2X. Constant for Heat Capacity Ammonium Bicarbonate

C1 1.67

Reference:

QAB = mAB ∫ Cp AB dT
303.15

QAB = mAB ∫ (C1)dT

303.15

kg
QAB = ∫ (1.67)dT
hr 303.15

kg kJ
QSB = ( )
hr kg

𝐤𝐠
𝐐𝐒𝐁 =
𝐡𝐫

J
Cp N ( ) = C1 + C2T + C3T 2 + C4T 3 + C5T 4
mole − K

Table 8.4X. Constant for Heat Capacity of Nitrogen Gas

C1 29.342
C2 -3.54E-03
C3 1.01E-05
C4 -4.31E-09
C5 2.59E-13
Reference: Table 2. Heat Capacity of Gas - Organic and Inorganic Compounds. Yaws, C. L.
(1999). Chemical Properties Handbook.

298.15
J
QN = mN ∫ Cp N ( ) dT
303.15 mole − K

298.15
QN = mN ∫ (C1 + C2T + C3T 2 + C4T 3 + C5T 4 )dT
303.15

298.15
(29.342 − (3.54E − 03)T + (1.01E − 05)T 2 − (−4.31E − 09)T 3
QN = mN ∫
303.15 + (2.59E − 13)T 4 )dT

kg J 1 kJ 1 mole 1000 g
QN = ( )( )( )( )( )
hr mole 1000 J 28 g 1 kg

𝐤𝐉
𝐐𝐍 =
𝐡𝐫

J
Cp O ( ) = C1 + C2T + C3T 2 + C4T 3 + C5T 4
mole − K

Table 8.4X. Constant for Heat Capacity of Oxygen Gas

C1 29.526
C2 -8.90E-03
C3 3.81E-05
C4 -3.26E-08
C5 8.86E-12

Reference: Table 2. Heat Capacity of Gas - Organic and Inorganic Compounds. Yaws, C. L.
(1999). Chemical Properties Handbook.

298.15
J
QO = mO ∫ Cp O ( ) dT
303.15 mole − K

298.15
QO = mO ∫ (C1 + C2T + C3T 2 + C4T 3 + C5T 4 )dT
303.15
 298.15
QO = mO ∫ (29.526 − (8.90E − 03)T + (3.81E − 05)T 2 + (−3.26E − 08)T 3 + (8.86E
303.15
− 12)T 4 )dT

kg J 1 kJ 1 mole 1000 g
QO = ( ) ( )( )( )( )
hr mole 1000 J 32 g 1 kg

𝐤𝐉
𝐐𝐎 =
𝐡𝐫