MATERIAL SAFETY DATA SHEET

ADDITIN RC 9200 N 440D/1760S

RHEIN CHEMIE CORPORATION

145 Parker Court
Chardon, OH 44024

TRANSPORTATION EMERGENCY NON-TRANSPORTATION

CALL CHEMTREC......... : (800) 424-9300 RCC EMERGENCY PHONE : (440) 285-3547
INTERNATIONAL ......... : (703) 527-3887 RCC INFORMATION PHONE: (800) 289-2436

Section 1: Product and Company Identification

Product Name: ADDITIN RC 9200 N 440D/1760S

Article Number: 56710691

Section 2: Composition/Information on Ingredients

HAZARDOUS INGREDIENTS

Ingredient Name/ Concentration

CAS Number Exposure Limits Min. Max.

Zinc Alkyldithiophosphate OSHA (PEL): 40% 70%

4259-15-8 Not Established
ACGIH (TLV):
Not Established

Hydrotreated Light Paraffinic Distillates OSHA (PEL): 10% 30%

CAS# is a trade secret 5.00 mg/m3 TWA
ACGIH (TLV):
10.00 mg/m3 STEL
5.00 mg/m3 TWA

Exposure limit for: Oil mist, mineral

Aromatic Hydroxyl OSHA (PEL): 5% 10%

CAS# is a trade secret Not Established
ACGIH (TLV):
Not Established

Proprietary Hazardous Substance OSHA (PEL): 5% 10%

CAS# is a trade secret Not Established
ACGIH (TLV):
Not Established

Material Name: ADDITIN RC 9200 N 440D/1760S Article Number: 56710691

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Solvent-Refined Heavy Paraffinic Distillate OSHA (PEL): 1% 5%
CAS# is a trade secret 5.00 mg/m3 TWA
ACGIH (TLV):
10.00 mg/m3 STEL
5.00 mg/m3 TWA

Exposure limit for: Oil mist, mineral

Section 3: Hazards Identification

EMERGENCY OVERVIEW

WARNING! Color: Dark Brown Form: Liquid Odor: Characteristic

Causes respiratory tract irritation. Causes skin irritation. Causes eye irritation. May
pose an aspiration hazard. Irritating gases/fumes may be given off during burning or
thermal decomposition.

POTENTIAL HEALTH EFFECTS

Route(s) of Entry: Inhalation, Skin Contact, Eye Contact, Ingestion

HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE

Inhalation Hazards
Acute Inhalation Hazards:
However, if conditions exist where this material, may be misted or
vapors are generated from heating, this product may than cause
minor irritation of the mucous membranes and the upper respiratory
tract.

Chronic Inhalation Hazards: None reported for this product as a whole.

Skin Hazards
Acute Skin Hazards: This product can cause skin irritation.

Chronic Skin Hazards: None reported for this product as a whole.

Eye Hazards
Acute Eye Hazards: This product is expected to cause only slight to moderate eye
irritation.

Chronic Eye Hazards: None reported for this product as a whole.

Ingestion Hazards
Acute Ingestion Hazards:
Not a likely route of exposure. However, if ingested in large
quanities, this product may cause nausea and vomiting. If vomiting
occurs, aspiration of mineral oil into the lungs can cause "oil mist
pneumonitis".

Chronic Ingestion Hazards: None reported for this product as a whole.

Carcinogenic Components:
NTP: None

Material Name: ADDITIN RC 9200 N 440D/1760S Article Number: 56710691

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 IARC: None

OSHA: None

Section 4: First Aid Measures

First Aid for Eye: In case of contact, flush eyes with large quantities of water for at
least 15 minutes. Get medical attention if irritation develops or
persists.

First Aid for Skin: Immediately remove contaminated clothing and shoes. In case of
skin contact, wash affected areas with soap and water. Get medical
attention if irritation develops or persists. Wash clothing and clean
shoes before reuse.

First Aid for Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen.
If not breathing, give artificial respiration. Get medical attention.

First Aid for Ingestion: If material is ingested, do not induce vomiting unless directed to do
so by medical personnel. Should vomiting occur, keep patients head
below hip level to prevent aspiration of fluid into the lungs. Get
medical attention.

Section 5: Fire Fighting Measures

Flash Point: 288 °F (142 °C) Cleveland Open Cup (ASTM D-92)

Flammable Limits:
Upper Explosion Limit Not Established
(UEL %):
Lower Explosion Limit Not Established
(LEL %):
Auto-ignition Temperature: Not Established

Extinguishing Media:
Suitable: Carbon Dioxide, Dry Chemical, Foam, Water

Special Fire Fighting Evacuate non-emergency personnel to a safe area. Full emergency
Procedures: equipment with self-contained breathing apparatus and full
protective clothing should be worn by firefighters. During a fire,
irritating and toxic gases may be generated by thermal
decomposition or combustion.

Section 6: Accidental Release Measures

Spill or Leak Procedures: Keep unnecessary personnel out of spill area. Emergency clean-up
personnel should wear appropiate protection when entering the spill
area for clean-up. Cover spill with absorbent material, such as sand,
sweeping compound or diatomaceous earth; collect material for

Material Name: ADDITIN RC 9200 N 440D/1760S Article Number: 56710691

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Section 7: Handling and Storage
Storage Temperature:
Shelf Life:
Handling/Storage Precautions:
Section 8: Exposure Controls/Personal Protection
Personal Protection Equipment
Eye Protection Requirements:
Skin Protection Requirements:
Ventilation Requirements:
Respirator Requirements:
Section 9: Physical and Chemical Properties
Physical Form:
Color:
Odor:
pH:
Boiling Point:
Melting/Freezing Point:
Viscosity:
Solubility in Water:
Solubility (non Aqueous):
Specific Gravity:
Vapor Pressure:
Vapor Density:
Material Name: ADDITIN RC 9200 N 440D/1760S
disposal.
Not Established - Ambient Recommended
Not Established
Avoid contact with eyes and skin. Avoid prolonged or repeated
contact with skin. Wash thoroughly after handling. Avoid inhalation
and skin or eye contact with processing fumes. Use local exhaust
ventilation above processing equipment. Store in a dry place away
from excessive heat.
Chemical safety goggles., In a splash hazard environment chemical
goggles should be used in combination with a full face-shield.
Permeation resistant gloves (neoprene, nitrile, or PVC) and
impervious clothing (long sleeve shirts) are recommended.
Use local exhaust ventilation if dusting or misting is a problem, to
maintain air levels below the recommended exposure limit. Thermal
processing equipment should be ventilated to control gases and
fumes given off during processing.
Under conditions of frequent use or heavy exposure, A
NIOSH/MSHA respirator is recommended. Observe OSHA
regulations for respirator use (29 CFR 1910.134.)
Liquid
Dark Brown
Characteristic
Not Established
Not Established
-16.6 °F (-27 °C)
145 mm2/S @ 104F (40C)
Essentially Insoluble
Soluble in mineral oils and synthetic base oils
1.03 @ 59 °F (15 °C)
Not Established
Not Established
Article Number: 56710691
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Section 10: Stability and Reactivity

Stability: Stable

Hazardous Polymerization: Will not occur

Substances to Avoid: Reducing agents., Oxidizing agents., Acids., Bases.

Conditions to Avoid: Extremes of temperature and direct sunlight

Decomposition Temperature: Not Established

Decomposition Products: Oxides of carbon, Oxides of sulfur

Section 11: Toxicological Information

Toxicity Data for ADDITIN RC 9200 N 440D/1760S

Toxicity Note: No data available for this product.

Toxicity Data for Zinc Alkyldithiophosphate

Acute oral toxicity: LD50 = 4,359 mg/kg (Rat)

Eye Irritation: Slightly irritating (Rabbit)

Skin Irritation: Non-irritating (Rabbit)

Mutagenicity: Negative test results (Ames Salmonella Test)

Toxicity Data for Hydrotreated Light Paraffinic Distillates

Toxicity Note: No data available for this component.

Toxicity Data for Aromatic Hydroxyl

Acute oral toxicity: LD50 = Greater than 5,000 mg/kg (Rat)

Acute dermal toxicity: LD50 = > 10 g/kg (Rabbit)

LD50 = > 10 g/kg (Guinea pig)

Eye Irritation: Moderately irritating

Skin Irritation: Moderately irritating

Toxicity Data for Proprietary Hazardous Substance

Acute oral toxicity: LD50 = > 340 mg/kg (Rat)

Toxicity Data for Solvent-Refined Heavy Paraffinic Distillate

Acute oral toxicity: LD50 = > 5,000 mg/kg (Rat)

Acute dermal toxicity: LD50 = > 3,160 mg/kg (Rat)

Acute inhalation toxicity: > 5,000 mg/m3, (Rat)

Material Name: ADDITIN RC 9200 N 440D/1760S Article Number: 56710691

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Section 12: Ecological Information

Ecological Data for ADDITIN RC 9200 N 440D/1760S

Ecological Note: No data available for this product.

Ecological Data for Zinc Alkyldithiophosphate

Fish Toxicity: 1 - 10 mg/L,

Invertebrate Toxicity: 1 - 10 mg/L, Water flea (Daphnia magna)

Biodegradation: 5 %,

Ecological Note: Water Pollution Class WGK 2 - impairment of water quality

(German Water Resources Act), This product is considered toxic to
aquatic organisms and may cause long-term adverse effects in the
aquatic environment.

Ecological Data for Hydrotreated Light Paraffinic Distillates

Ecological Note: No data available for this component.

Ecological Data for Aromatic Hydroxyl

Ecological Note: No data available for this component.

Ecological Data for Proprietary Hazardous Substance

Ecological Note: No data available for this component.

Ecological Data for Solvent-Refined Heavy Paraffinic Distillate

Ecological Note: No data available for this component.

Section 13: Disposal Considerations

Waste Disposal Method: Disposal must be in compliance with federal, state and local
environmental control regulations.

Empty Container Precautions: Recondition or dispose of empty container in accordance with

government regulations.

Other Disposal Notes:
Rhein Chemie requires that CHEMTREC be immediately notified
(800-424-9300) when this product is unintentionially released from
its container during its course of distribution, regardless of the
amount released. Such notification must be immediate and made by
the person having knowledge of the release. Distribution includes
transportation, storage incidental to transportation, loading and
unloading.

Section 14: Transportation Information

Technical shipping name: Additive Mixture Containing 2,6-Di-Tert-Butylphenol

Marine Pollutant Components:

Material Name: ADDITIN RC 9200 N 440D/1760S Article Number: 56710691

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 Component(s)/ Concentration
CAS Number Min. Max.
Aromatic Hydroxyl 5% 10%
NJTSRN:000000185

Product Label: Product Label Established

Domestic Surface Transportation (DOT)

Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S.
Hazard Class or Division: 9
UN/NA Number: UN3082
Packing Group: III
Hazard Label(s): Class 9
Hazard Placard(s): Class 9
DOT Postnote: * Only bulk packages (greater than 119 gallons) are regulated as
Marine Pollutants when shipped by highway or rail (See 49 CFR
171.4 (c)).

Marine Transportation (IMO / IMDG)

Proper Shipping Name:
Hazard Class Division
Number:
UN Number:
Packaging Group:
Hazard Label(s):
Hazard Placard(s):
Environmentally Hazardous Substance, Liquid, N.O.S.
9
UN3082
III
Miscellaneous, Marine Pollutant (Mark)
Miscellaneous, Marine Pollutant

Air Transportation (ICAO / IATA)

Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S.
Hazard Class Division 9
Number:
UN Number: UN3082
Packing Group: III
Hazard Label(s): Miscellaneous
Radioactive?: Non-Radioactive
Passenger Air - Max. Qty.: 450 L
Passenger Packing Instruction: 964
Cargo Air - Max. Qty.: 450 L
Cargo Air Packing 964
Instruction:

Section 15: Regulatory Information

United States Federal Regulations

OSHA Hazcom Standard Hazardous

Rating:

TSCA Inventory List: On TSCA Inventory

CERCLA Hazardous Substance:

Component(s) Reportable Quantity
Zinc Alkyldithiophosphate (Regulated as: Zinc and

Material Name: ADDITIN RC 9200 N 440D/1760S Article Number: 56710691

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 Compounds (No RQ established for this general class.))

SARA Title III

SARA Section 302 Extremely Hazardous Substances:
Component(s)/ Concentration
CAS Number Min. Max.
None

SARA Section 311/312 Hazard Immediate Health Hazard

Categories:

SARA Section 313 Toxic Chemicals:

Component(s)/ Reporting Concentration
CAS Number Threshold Min. Max.
Zinc Alkyldithiophosphate (Regulated as: Zinc 1.0 % 40% 70%
Compounds)
4259-15-8

RCRA Status: Under RCRA, it is the responsibility of the product user to

determine at the time of disposal, whether a material containing the
product or derived from the product, should be classified as a
hazardous waste. (40 CFR 261.20-24)

The following chemicals are specifically listed by individual states; other product specific health and safety
data in other sections of the MSDS may also be applicable for state requirements. For details on your
regulatory requirements you should contact the appropriate agency in your state.

State Right-to-Know Information

Component(s)/ Concentration
CAS Number State Code Min. Max.
Zinc Alkyldithiophosphate PA-H, PA-E, NJ-H, NJ- 40% 70%
4259-15-8 E
Hydrotreated Light Paraffinic Distillates PA-H, NJ-H, MA-H 10% 30%
NJTSRN:000000955
Aromatic Hydroxyl PA-N, NJ-N 5% 10%
NJTSRN:000000181
Proprietary Hazardous Substance PA-N, NJ-N 5% 10%

Solvent-Refined Heavy Paraffinic Distillate PA-H, NJ-H, MA-H 1% 5%

NJTSRN:000000883

The following component(s) are listed under Massachusetts Extra-ordinary Hazards:

Hydrotreated Light Paraffinic Distillates MA-X 10% 30%
NJTSRN:000000955

State Code Translation Table

PA-N = Pennsylvania Non-hazardous
PA-H = Pennsylvania Hazardous Substance List
PA-E = Pennsylvania Environmental Hazardous Substance List
NJ-N = New Jersey Other - includes predominant ingredients
NJ-H = New Jersey Hazardous Substance List
NJ-E = New Jersey Environmental Hazardous Substance List
MA-H = Massachusetts Hazardous Substance List
MA-X = Massachusetts Extra-ordinary Hazardous Substance List

Material Name: ADDITIN RC 9200 N 440D/1760S Article Number: 56710691

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Section 16: Other Information

HMIS Rating
Health 1
Flammability 1
Reactivity 0
0=Minimal 1=Slight 2=Moderate 3=Serious 4=Severe
*=Chronic Health Hazard

RHEIN CHEMIE CORPORATION’s method of hazard communication is comprised of Product Labels

and Material Safety Data Sheets. HMIS and NFPA ratings are provided by RHEIN CHEMIE
CORPORATION as a customer service.

Contact: HES Dept.

Phone: (440) 285-3547
MSDS Number: 000000007416
Version Date: 03/15/2011
MSDS Version: 1.2

This information is furnished without warranty, expressed or implied, except that it is accurate to the best
knowledge of RHEIN CHEMIE CORPORATION. The data on this sheet relates only to the specific
material designated herein. RHEIN CHEMIE CORPORATION assumes no legal responsibility for use or
reliance upon these data.

Indicates Relevant Change Made.

Material Name: ADDITIN RC 9200 N 440D/1760S Article Number: 56710691

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