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Abridged CHEMISTRY
U = ±Q±W Ka = [H+][A–]
adiabatic [HA]
isothermic
isobaric Kb = [OH-][B+]
[B]
PV = nRT
pKa = -logKa
P1V1 = P2V2 pKb = -logKb

V1 = V2 pH = pKa + log([Conj. Base]/[Acid])

T1 T2
∆Hreaction = ∆Hf(products) - ∆Hf(reactants)
Tkelvin = Tcelsius +273
∆Hreaction = Bonds broken– Bonds formed
M =moles solute/Liter solution
m = moles of solute/kg of solvent
∆Sreaction = ∆Sf(products) - ∆Sf(reactants)
Colligative Properties
Π = MRT ∆Greaction = ∆Gf(products) - ∆Gf(reactants)

∆Tb = Kbm (elevation) ∆G = -nFE; F=105

∆Tf = Kfm (depression) ∆G = -RTlnKeq

Pa = PtotalXsolvent ∆G = ∆H – T∆S

Conductance 1ATM = 760 torr

Avagadro = 6 X 1023
Xa= moles X__ Standard vs. ideal conditions; STP
total moles
HCl, HBr, H2SO4,
%composition= mass X/ total weight HI, HNO3, HClO4 Strong Acids

q = mc∆t NaOH, KOH Strong Bases

q= mL
Hydrogen Bond
E = hf Dipole – Dipole
Van der Waals, Hydrophobic, Intermolecular
v=fƛ
Dispersion Forces
pH = -log [H+]
pOH = -log [OH–] Acidic [H+] > [OH-]
Neutral [H+] = [OH-]
Basic [H+] < [OH-]
[H+][OH–] = 1X10-14
[Ka][Kb] = 1X10-14
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Abridged CHEMISTRY

1. CNOF Satisfy the octet

a. Except carbocation
b. Except radicals
2. O likes H Lewis
3. Center atom usually least
electronegative Structures
4. Obtain formal charge as close
to zero as possible

Fe3+ → Ferric
(AnOx) Anode → Oxidation Fe2+ → Ferrous Common
(RedCat) Cathode → Reduction Cu2+ → Cupric Names
(OiL) Oxidation is Lost Cu2O → Cuprous Oxide
(RiG) Reduction is Gained

Batteries
∆G E Cathode Anode

Galvanic - + + -
Cell
Electrolytic + - - +
Cell

Move across a Period (left to right) /

Move up a Group
↑ Ionization Energy
↑ Electron Affinity Periodic Trends
↑ Electronegativity
↓ Atomic Radius

Q = Products
Reactants

∆G = (-) Q < Keq → moves to the right Thermodynamics

∆G = 0 Q = Keq → moves both ways
∆G = (+) Q > Keq → moves to the left

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