Gas Chromatography Results Summary

Gas Chromatography Result
Analysis date & Time 13-Apr-19

Sample Name BENTONIT 500 C
Issued by Chemical Engineering Dept. FTI-ITS
uV(x10,000) C
5.0
Chromatogram
425.0
4.5
400.0
375.0
4.0
350.0
3.5 325.0
300.0
3.0
275.0
2.5 250.0
225.0
2.0
200.0
175.0
1.5
150.0
1.0 125.0
100.0
0.5
75.0
50.0
0.0
25.0
-0.5 0.0
0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 min
Peak# Area Ret.Time Conc. Area% Height Name

1 52880.4 3.262 14.71% 48.68 17667.7 Hydrogen
2 55756.2 3.505 42.07% 51.3236 25630.1 Methane
Operator
Maktum Muharja, S.T.
Analysis date & Time : 13-Apr-19

Sample Name
uV(x10,000) : BENTONIT 450 C C
5.0
Issued by
Chromatogram
Chemical Engineering Dept. FTI-ITS
425.0
4.5
400.0
375.0
4.0
350.0
3.5 325.0
300.0
3.0
275.0
2.5 250.0
225.0
2.0
200.0
175.0
1.5
150.0
1.0 125.0
100.0
0.5
75.0
50.0
0.0
25.0
-0.5 0.0
0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 min

1 52614.9 3.267 14.79% 58.2866 17499.3 Hydrogen
2 36532.7 3.513 28.32% 40.4707 17205.4 Methane
3 1121.7 4.098 2.33% 1.2426 480.6 Carb. Dioxide
Operator
uV(x10,000) C
5.0
Chromatogram
Analysis date & Time 13-Apr-19 425.0
Sample
4.5 Name BENTONIT 400 C
400.0
375.0
4.0
350.0
3.5 325.0
300.0
3.0
275.0
2.5 250.0
225.0
2.0
200.0
175.0
1.5
150.0
1.0 125.0
100.0
0.5
75.0
50.0
0.0
25.0
-0.5 0.0
0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 min

1 63227.2 3.268 17.32% 68.0899 21065.4 Hydrogen
2 28143.8 3.515 22.32% 30.31 13141.9 Methane
3 1487.3 4.098 3.08% 1.6017 657.5 Carb. Dioxide
Operator
uV(x10,000) Gas Chromatography Result C

5.0
Chromatogram
425.0
4.5
400.0

4.0
Sample Name KARBON AKTIF 500 C
350.0
3.5 325.0
300.0
3.0
275.0
2.5 250.0
225.0
2.0
200.0
175.0
1.5
150.0
1.0 125.0
100.0
0.5
75.0
50.0
0.0
25.0
-0.5 0.0
0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 min

1 68341.1 3.272 17.47% 62.5171 22548.5 Hydrogen
2 37015.2 3.518 28.67% 33.8608 17352 Methane
3 3959.5 4.101 8.21% 3.6221 1724.9 Carb. Dioxide
Operator
uV(x10,000) C
5.0
Chromatogram
425.0
4.5 Gas Chromatography Result 400.0
375.0
4.0
350.0
3.5
Sample Name KARBON AKTIF 450 C 300.0

3.0
Issued by Chemical Engineering Dept. FTI-ITS 275.0
2.5 250.0
225.0
2.0
200.0
175.0
1.5
150.0
1.0 125.0
100.0
0.5
75.0
50.0
0.0
25.0
-0.5 0.0
0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 min

1 41450.4 3.276 12.13% 48.9774 13797.3 Hydrogen
2 43181.3 3.521 33.07% 51.0226 20131.7 Methane
Operator
uV(x10,000) C
5.0
Chromatogram Maktum Muharja, S.T.
425.0
4.5
400.0
375.0
4.0
Gas Chromatography Result 350.0
3.5 325.0
300.0
3.0
Sample Name KARBON AKTIF 400 C
2.5 250.0
225.0
2.0
200.0
175.0
1.5
150.0
1.0 125.0
100.0
0.5
75.0
50.0
0.0
25.0
-0.5 0.0
0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 min
1 50225 3.29 14.22% 58.8535 16595.4 Hydrogen
2 33443 3.538 26.11% 39.1884 15471.3 Methane
3 1671.1 4.127 3.46% 1.9582 682.6 Carb. Dioxide
Operator

C
425.0
400.0
375.0
350.0
325.0
300.0
275.0
250.0
225.0
200.0
175.0
150.0
125.0
100.0
75.0
50.0
25.0
0.0
min
C
425.0
400.0
375.0
350.0
325.0
300.0
275.0
250.0
225.0
200.0
175.0
150.0
125.0
100.0
75.0
50.0
25.0
0.0
min
C
425.0
400.0
375.0
350.0
325.0
300.0
275.0
250.0
225.0
200.0
175.0
150.0
125.0
100.0
75.0
50.0
25.0
0.0
min
C
425.0
400.0
375.0
350.0
325.0
300.0
275.0
250.0
225.0
200.0
175.0
150.0
125.0
100.0
75.0
50.0
25.0
0.0
min
C
425.0
400.0
375.0
350.0
325.0
300.0
275.0
250.0
225.0
200.0
175.0
150.0
125.0
100.0
75.0
50.0
25.0
0.0
min
C
425.0
400.0
375.0
350.0
325.0
300.0
275.0
250.0
225.0
200.0
175.0
150.0
125.0
100.0
75.0
50.0
25.0
0.0
min
H2 CH4 CO2
Slope 2.39E-06 7.15E-06 2.07E-05
Intercept 0.02239 0.02196 0
Adj. R-square 0.99896 0.99343 0.99236
Area % Concentration
No Variable
H2 CH4 CO2 H2
1 BENTONIT 500 C 52280.4 55756.2 0 14.71%
2 BENTONIT 450 C 52614.9 36532.7 1121.7 14.79%
3 BENTONIT 400 C 63227.2 28143.8 1487.3 17.32%
4 KARBON AKTIF 400 C 50225 33443 1671.1 14.22%
5 KARBON AKTIF 450 C 41450.4 43181.4 0 12.13%
6 KARBON AKTIF 500 C 63841.1 37015.2 3959.5 17.47%
didapat dari linier fitting data menggunakan Origin Pro 8.5
% Concentration Konsentrasi (%mol) Massa (g)
CH4 CO2 H2 CH4 CO2 H2 CH4 CO2
42.07% 0.00% 56.78% 14.22 26.11 3.46 28.66297 418.8582 152.2701
28.32% 2.33% 45.43% 12.13 33.07 0 24.450198 530.5109 0
22.32% 3.08% 42.73% 17.47 28.67 8.21 35.21393 459.9259 361.3114
26.11% 3.46% 43.79%
33.07% 0.00% 45.20%
28.67% 8.21% 54.34%
Komposisi gas
H2 18.23
400°C CH4 10.53
CO2 0
H2 7.25 K
450°C CH4 8.1 35
CO2 5.1
30
H2 4.96
500°C 25
Komposisi (%mol)
CH4 12.24
CO2 4.46 20
H2 14.22 15
400°C ; KA CH4 12.13
10
CO2 17.47
5
H2 26.11
450°C ; KA CH4 33.07 0
400 450
CO2 28.67
H2 3.46
500°C ; KA
5
0
400 450
500°C ; KA CH4 0
CO2 8.21
H2 CH4 CO2
400 18.23 10.53 0
450 7.25 8.1 5.1
500 4.96 12.24 4.46
400 ; KA 14.22 26.11 3.46
450 ; KA 12.13 33.07 0
500 ; KA 17.47 28.67 8.21
Nilai Kalor (cal/g)
H2 CH4 CO2
970.73 5556.08
828.06 7037.14
1192.60 6100.84
Nilai Kalor (MJ/kg)
H2 CH4 CO2
4.06154 23.246629
3.46459 29.443356
4.98981 25.525885
Komposisi Produk Gas

35
30
25
Komposisi (%mol)
20 H2
CH4
15
CO2
10
0
400 450 500 400 ; KA 450 ; KA 500 ; KA
Temperatur (oC)
5
0
400 450 500 400 ; KA 450 ; KA 500 ; KA
Temperatur (oC)
External Method
H2 RT 3.4min
ml Inject Area mean mol
70221
0.04 70362 71401.00
20% 73620 1.64E-06 18%
165959
0.08 162499 163412.40
40% 161779.2 3.27E-06 36%
236522.2
0.12 240789.8 239047.03
60% 239829.1 4.91E-06 54%
326337.4
0.16 333034.3 328174.23
80% 325151 6.54E-06 72%
404164.6
0.2 410852.6 407524.33
100% 407555.8 8.18E-06 90%
Slope 2.39E-06 Intercept 0.02239 Slope

adj. R-Square 0.99896 adj. R-Square
Y calc Y exp Dev AAD Y calc

19.3% 20.0% -7.104E-03 3.56% 17.1%
41.2% 40.0% 1.256E-02 3.14% 38.5%
59.3% 59.9% -6.833E-03 1.14% 53.9%
80.5% 79.9% 5.954E-03 0.75% 69.3%
99.4% 100% -4.579E-03 0.46% 91.2%
CH4 RT 3.7 min CO2 RT 4.2 min
ml Inject Area mean mol ml Inject Area
19890.8 10324.1
0.04 21368.5 20774.20 0.04 11130
21063.3 1.64E-06 20% 11481.9
51470.1 22146.4
0.08 50504.8 50819.23 0.08 22339.3
50482.8 3.27E-06 40% 22147.6
71072.8 31067.6
0.12 72457.8 72269.87 0.12 30993.8
73279 4.91E-06 60% 33608.2
94093.8 34409.9
0.16 93546.8 93875.37 0.16 34938.8
93985.5 6.54E-06 80% 36739.3
123546.5 45720.2
0.2 125311.5 124484.60 0.2 47535.5
124595.8 8.18E-06 100% 47282.9
7.15E-06 Intercept 0.02196 Slope 2.32E-05 Intercept

adj. R-Square 0.99343 adj. R-Square 0.98877
Y exp Dev AAD Y calc Y exp Dev

18.0% -9.487E-03 5.27% 17.8% 20.0% -2.208E-02
36.0% 2.536E-02 7.04% 42.5% 40.0% 2.577E-02
54.0% -1.248E-03 0.23% 63.1% 59.9% 3.140E-02
72.0% -2.675E-02 3.72% 76.4% 79.9% -3.499E-02
90% 1.213E-02 1.35% 99.9% 100% -1.072E-04
mean mol
10978.67
11481.90
1.64E-06
22211.1
22147.00
3.27E-06
31889.87
30993.80
4.91E-06
35362.67
36739.30
6.54E-06
46846.2
46846.20
8.18E-06
-0.08889 Slope 2.07E-05 Intercept 0

adj. R-Square 0.99236
AAD Y calc Y exp Dev AAD

11.05% 22.8% 20.0% 2.783E-02 13.93%
6.45% 46.1% 40.0% 6.093E-02 15.25%
5.24% 66.1% 59.9% 6.181E-02 10.31%
4.38% 73.3% 79.9% -6.598E-02 8.26%
0.01% 97.1% 99.9% -2.768E-02 2.77%
SPL1 Column
Temperature Temperature 50 C
Injection mode Equilibration 3 min
Carier Gas N2
Flow control mode Linier Velocity
Pressure 126.7 kPa
Total flow 43.3 mL/min
Column Flow 1.92 mL/min
Linier Velocity 41.6 cm/sec
Purge Flow 3 mL/min
Split Ratio 20
Column Rt-Qbond
PRE-TCD
Temperature 200 C
Sampling Rate 40 msec
Stop time 5 min
Delay time 0 min

Current 30 mA
Make up flow 8 mL/min

Gas Chromatography Results Summary

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Gas Chromatography Result

Analysis date & Time 13-Apr-19

Peak# Area Ret.Time Conc. Area% Height Name