~

..j::>.

G T1 Tm (A) Tz

~
n:.
~
0
I
I I ~
;:::
!::>
(a) A B (b)A B (C)A b C B ~
Et
T !::>
Tm(B) T3 ;:::
T, la ITm (A) !::>..
'1::::
;:s-.
!::>
T2~-~~---i liquidu5 ""n:.
!::>..
!:S.
~
!::>
5 T3~ / dl'" ~
sol idus ""
J I I
A B A B A 8
(d) (e) (f)
Fig. 1.29 The derivation of a simple phase diagram from the free energy curves for
the liquid (L) andsolid (S).
 T, T2 T3
G
solid
I solid

I I
I I I ,
I
0., ,'+ 0., I : 1+ 0. 2:0.2 O::l
S·
;::,
A ~ XB B A B A B ~
'"I::l
T4 r, ~
'"'"
T2 ;::,.
TB ~.
solid T ;::;
T3 ~
:y><; T4
I I I
I I I I I
r T5
0., 1I + 0., I~
11+0.2
l 0. 2 0.'1 0.,+ 0. 2 I 0. 2 0., + 0. 2

A B A B A ----- X B B
Fig. 1.32 The derivation of a eutectic phase diagram where both solid phases have
the same crystal structure. (After A.H. Cottrell, Theoretical Structural Metallurgy,
Edward Arnold, London, 1955,©Sir Alan Cottrell.) tH
-...J
 ~
T2 T3 00

f
I
I
I
~ I ~
~
I I I
I I ~
I I \:)
a. I 1+ a. I a I l+all+ß:ß ~
;::
$:)

A -Xe 8 A A 8 ~
~r
T4 $:)
;1 TI ;::
$:)..
~
;::-
T ~
~
$:)..
~.
t i:l
~
T4 '"
I I , n I
a a+ß ß
A 8 A ---xB 8
Fig. 1.33 The derivation of a eutectic phase diagram where each solid phase has a
different crystal structure. (After A. Prince, Alloy Phase Equilibria, Elsevier , Amster-
dam, 1966.) .
 T, T2 T3

tl::l
A BA B A B S·
$:)
(0) (b) (c)
~
'1::1
~
$:)
T4 T5 TI <"1>
'"
liq~id - ---Fi 1:l...
~.
~
~
'"

ß+Y
ß + I.y
A B A B A B
(d) (e) (f)
Fig. 1.34 The derivation of a complex phase diagram. (After A.H. Cottrell, Theo- VJ
\0
retical Structural Metallurgy, Edward Arnold, London, 1955,©Sir Alan Cottrell.)