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Chemistry
Atomic Structure
Date: 16-08-2019

61 Agas of mono atomic hydrogen is excited by an energy of 12.75 eV/atom. Which spectral lines of
the following are formed in Lymann, Belmer and paschen series respectively.
1) 3, 2, 1 2) 2, 3, 1 3) 1, 3, 2 4) 1, 2, 3
62 Hydrogen electron is excited from the 1st shell to the 2nd shell. The maximum number of possibilities
that the electron is present with different spin values, and with different orientations of the orbitals
1) 1 2) 2 3) 4 4) 8
63 What electronic transition in Li 2+ produces the radiation of same wavelength as the first line in the
Balmer's series of hydrogen spectrum.
1) n2 =3 to n 1 =2 2) n2 =6 to n 1 =3
3) n2 =9 to n 1 =6 4) n2 =9 to n 1 =8
64 In which case the wavelength emitted is minimum?
1)An electron jumps from 2 nd to 1 st level
2) An electron jumps from 3 rd to 2 nd level
3)An electron jumps from 4 th to 3 rd level
4)An electron jumps from 5 th to 4 th level
65 Transition of an electron from n=3 level to n=2`level results in a line
1) the intra-red spectrum 2) in the visible spectrum
3) in the ultraviolet spectrum 4) in the far infrared spectrum.
66 Which of the following transitions of electrons in the hydrogen atom will emit maximum energy ?
1) n 5  n 4 2) n 4  n 3 3) n 3  n 2 4) all will same energy
67 In Hydrogen atom electron is present in the N shell If it loses energy, a spectral line may be
observed in the region
1) infra-red 2) visible 3) ultra- violet 4) any of these
4
68
69
70
71
72 When
The
If
1)
3) 
n55wave
hydrogen
lines
the
5R
remains
becomesn4 spectrum
electron
electronic
which
mass
/the
36 electron
number
unchanged
of
double
appear
present
the
transition
electron
of
in
isin
the
5th H
Lyman
2)5th
that
n10
3R 
orbit
isorbit
-line3
/reduced
emits
series
16
njumps
ininexcited
maximum
of
Balmer
to
into
hydrogen
half
the
hydrogen
series
the
3)first
2)
4) 2
energy
n420
21R
becomesn1 [none
Rydberg
spectrum
orbit
of/ hydrogen
atoms
is
100 half
constant.
=returned
represents
fourth
the
spectrum
number
4)back
3R 
n613orbit] 2
is/to4ofnground
spectralstate.
lines
1|The
produced
Pno.
a gof
e in
73 Rydberg constant is
1) Same for all elements
2) Different for different elements
3) A universal constant
4) Is different for lighter elements but same for heavier elements
74 Values of n1 and n2 for H  spectral line in the hydrogen emission spectrum
1) 1 and 2 2) 2 and 3 3) 3 and 2 4) 2 and 4
75 Which of the following gives neither emission spectrum nor absorption spectrum
1) He+ 2) H2 3) H+ 4) He
76 In hydrogen spectrum, the spectral line of Balmer series having lowest wavelength is
1) H - line 2) H - line 3) H - line 4) H -line
77 In hydrogen spectrum the following series of lines belongs to U.V. region
1) Balmer series 2) Paschen series
3) Bracket series 4) Lyman series
78 When the electron jumps from n = 5 to n = 2 level, the spectral line observed in the hydrogen
spectrum belongs to
1) Balmer series 2) Lyman series 3) Bracket series 4) Pfund series
79 When the electron jumps from 5th orbit to 2nd orbit, the spectral line of the hydrogen spectrum is
called
1) H -line 2) H -line 3) H -line 4) H  -line
80 Normal hydrogen atoms can not give
1) absorption spectrum 2) line spectrum
3) band spectrum 4) atomic spectrum
81 The wave length of the radiation emitted by Hydrogen when compared to He+ is
1) 2 times that of He+ ion 2) 3 times that of He+ ion
3) 4 times that of He+ ion 4) Same as He+
82 Among the first lines Lyman, Balmer, + Paschen and Brackett series in hydrogen atomic spectra which
83
84 Assertion
Reason
When
1)
2)
3)
4)
has(A)
lower
spectrum.
Lyman
Balmer
Both
higher
level
an (R)
is(A)
true
false(A)
:which
electron
energy?
for
and
but
He
but:(R)
+
The
(R)(R)
in
is are
also
an
spectrum
isnis
2)false
excited
=ture
true
true
Balmer
Lyman
an
2 the
one
and
of
spectral
hydrogen
electon
(R)
He isisnot
the
expected
line
specties
atom
correct
the
is3)observed
correct
jumps
Paschen
Brackett
toexplanation
befrom
explanation
similar
in the
an to
............
energy
of(A)
that
of4.(A)
4)
of
Brackett
level
series
Paschen
hydrogen
for
ofwhich
the hydrogen
n =2|
-5 toP aa g e
85 Which of the following process will be accompained by absorption of energy ?
1) separating an electron from an electron
2)separating a proton from a proton
3) removing an electron from neutral atom
4) Adding an electron to a neutral atom
86 The ratio of the radii of the first three Bohr orbits is
1) 1:0.5:0.33 2)1:2:3 3)1:4:9 4)1:8 27
87 As we move away from nucleus, the energy of orbit
1) decrease 2) increase
3)remain unchanged 4)none of the above
88 Which of the following electronic transition in a hydrogen atom will require the largest amount of
energy
1) From n=1 to n=2 2) from n= 2 to 3
3) From n= to 1 4) From n= 3 to n= 5
89 According to Bohrs theroy, the angular momentum for an electron in 5th orbit is
1)2.5 h /  2) 5 h /  3) 25 h /  4) 5/ 2h
90 For the electron moving in the circular orbit in the hydrogen atom, the forces of attraction of the
nucleus is balanced by the force equal to
2 2
1 2 mv e m
1) mv 2) 3) 4)
2 2 2r Vr2

K EY

Q.NO K EY Q.NO K EY Q.NO K EY Q.NO K EY Q.NO K EY

1 2 2 2 3 1 4 2 5 3
6 4 7 2 8 3 9 3 10 1
11 2 12 2 13 4 14 3 15 4
16 4 17 1 18 2 19 3 20 3
21 1 22 1 23 1 24 3 25 3
26 2 27 1 28 1 29 2 30 3| P a4g e