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Stoichiometric problems, limiting reactants, and 11. Suppose 6.

00 mol of H2 reacted with sufficient


percent yield: nitrogen. How many moles of ammonia would be
produced?
1. How many moles of HCl are needed to react N2 + H2 → NH3
with 0.87 moles of Al?
Al + HCl → AlCl3 + H2
12. We want to produce 2.75 mol of NH3. How many
moles of nitrogen would be required?
2. How many grams of Al can be created N2 + H2 → NH3
decomposing 9.8g of Al2O3?
Al2O3 → Al + O2
13. How many moles of H2O are produced when
5.00 moles of oxygen are used?
3. How many moles of oxygen react with H2 + O2 → H2O
2.25 moles of nitrogen?
N2(g) + O2(g) → 2NO(g) 14. If 3.00 moles of H2O are produced, how many
moles of oxygen must be consumed?
4. How many moles of NO gas are formed H2 + O2 → H2O
from 2.25 moles of nitrogen?
N2(g) + O2(g) → 2NO(g) 15. 1.50 mol of KClO3 decomposes. How many
grams of O2 will be produced?
5. What is the mass of mercury produced KClO3 ---> KCl + O2
from the decomposition of 1.25 g of
orange mercury(II) oxide? The atomic 16. If 80.0 grams of O2 was produced, how many
mass of mercury is 200.59 grams per one moles of KClO3 decomposed?
mole (g/mol.) The molar mass of orange KClO3 ---> KCl + O2
mercury(II) oxide is 216.59 grams per
one mole (g/mol.) Sometimes you will see 17. We want to produce 2.75 mol of KCl. How many
the atomic mass and molar mass of grams of KClO3 would be required?
chemicals listed as their Molecular Weight KClO3 ---> KCl + O2
or MW.
HgO(s) → Hg(l) + O2(g) 18. Consider the following reaction:
Al + HBr → AlBr3 + H2
6. How many grams of hydrogen gas are needed a. When 3.22 moles of Al react with 4.96 moles
to react completely with 54.0 g of oxygen gas? of HBr, how many moles of H2 are formed?
H2 + O2 → H2O b. What is the limiting reactant?

7. How many grams of hydrogen gas are needed 19. Consider the following reaction:
to produce 105.0 grams of water? Si + N2 → Si3N4
H2 + O2 → H2O a. When 21.44 moles of Si react with 17.62
moles of N2, how many moles of Si3N4 are
8. How many grams of hydrogen gas are needed formed?
to produce 85.2 grams of ammonia? b. What is the limiting reactant?
N2 + H2 → NH3
20. Consider the following reaction:
CuCl2 + KI → CuI + KCl + I2
9. How many grams of chlorine can be liberated a. When 0.56 g of CuCl2 reacts with 0.64 g of KI,
from the decomposition of 64.0 g. of AuCl3 by how many grams of I2 are formed?
this reaction? b. What is the limiting reactant?
AuCl3 → Au + Cl2
21. Consider the following reaction:
10. If we have 2.00 mol of N2 reacting with sufficient FeS2 + O2 → Fe2O3 + SO2
H2, how many moles of NH3 will be produced? a. When 26.62 grams of FeS2 reacts with 5.44
N2 + H2 → NH3 grams of O2, how many grams of SO2 are
formed?
b. What is the excess reactant?
22. Take the reaction:
NH3 + O2 → NO + H2O
Answers:
In an experiment, 3.25 g of NH3 are allowed to
react with 3.50 g of O2. 1. 2.6 mol HCl
a. Which reactant is the limiting reagent? 2. 5.1 g Al
b. How many grams of NO are formed? 3. 2.25 moles Oxygen
c. How much of the excess reactant remains 4. 4.50 moles NO
after the reaction? 5. 1.16 g Hg
6. 6.80 g H2
23. A reaction container holds 5.77 g of P4 and 5.77 7. 11.75 g H2
g of O2.The following reaction occurs: P4 + O2 → 8. 15.8 g H2
P4O6. If enough oxygen is available then the 9. 22.4 g Cl
P4O6 reacts further: P4O6 + O2 → P4O10. Hint 10. 4.00 moles NH3
a. What is the limiting reagent for the formation 11. 4.00 moles NH3
of P4O10? 12. 1.38 moles N2
b. What mass of P4O10 is produced? 13. 10.0 moles H2O
c. What mass of excess reactant is left in the 14. 1.5 mol O2
reaction container? 15. 72.0 g O2
16. 1.67 mol KClO3
24. Consider the reaction of 17. 337 g KClO3
C6H6 + Br2 → C6H5Br + HBr 18. a. 2.48 mol H2
a. What is the theoretical yield of C6H5Br if 42.1 b. HBr
g of C6H6 react with 73.0 g of Br2? 19. a. 7.15 mol Si3N4
b. If the actual yield of C6H5Br is 63.6 g, what is b. Si
the percent yield? 20. a. 0.24 g I2
b. KI
25. Consider the reaction of 21. a. 7.68 g SO2
C6H6 + Br2 → C6H5Br + HBr b. FeS2
a. What is the theoretical yield of C6H5Br if 42.1
g of C6H6 react with 73.0 g of Br2?
b. If the actual yield of C6H5Br is 63.6 g, what is
the percent yield?

26. A reaction container holds 5.77 g of P4 and 5.77


g of O2.The following reaction occurs: P4 + O2
→ P4O6. If enough oxygen is available then the
P4O6 reacts further: P4O6 + O2 → P4O10
a. What is the limiting reagent for the formation
of P4O10?
b. What mass of P4O10 is produced?
c. What mass of excess reactant is left in the
reaction container?

27. Silicon nitride (Si3N4) is made by a combining Si


and nitrogen gas (N2) at a high temperature.
How much (in g) Si is needed to react with an
excess of nitrogen gas to prepare 125 g of
silicon nitride if the percent yield of the reaction
is 95.0%?

28. Use the following reaction:


C4H9OH + NaBr + H2SO4 H2SO4 → C4H9Br +
NaHSO4 + H2O
If 15.0 g of C4H9OH react with 22.4 g of NaBr
and 32.7 g of H2SO4 to yield 17.1 g of C4H9Br,
what is the percent yield of this reaction?

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