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EXAMPLE 10.

1
P-x1 and P-y1 at 75° C 90
x1 P1 sat P2 sat P y1
t = 75°C
0 83.21 41.98 41.98 0
0.1 83.21 41.98 46.103 0.180487 80
0.2 83.21 41.98 50.226 0.331342
0.3 83.21 41.98 54.349 0.459309 70
0.4 83.21 41.98 58.472 0.56923
0.5 83.21 41.98 62.595 0.66467
0.6 83.21 41.98 66.718 0.748314 60 1
P- x

P/ kPa
0.7 83.21 41.98 70.841 0.822222
0.8 83.21 41.98 74.964 0.888 50
0.9 83.21 41.98 79.087 0.946919
1 83.21 41.98 83.21 1 y1
P-
40

30

20
0 0.1 0.2 0.3 0.4 0.5 0.6
x1 , y1

t-x1 and t-y1 at 70 kPa


95
t/ °C P P1 sat P2 sat x1 y1
P = 70 kPa
89.58 70 131.5462 69.9916 0.000136 0.000256
88 70 125.4354 66.38102 0.061282 0.109814 90
86 70 118.0235 62.02604 0.142399 0.240091 t-y
1
84 70 110.9618 57.9031 0.227991 0.361404
82 70 104.2384 54.00314 0.318439 0.474193 85 t-x
80 70 97.842 50.31727 0.414158 0.578886 1
78 70 91.76107 46.83681 0.515605 0.675893
76 70 85.98447 43.55324 0.623285 0.765612 80
t/ °C

74 70 80.50123 40.4583 0.737751 0.848426


72 70 75.30058 37.54386 0.859612 0.924704
70 70 70.37194 34.80205 0.989543 0.994801 75
69.84 70 69.98908 34.58993 1.000308 1.000152

70

65
0 0.1 0.2 0.3 0.4 0.5
x1, y1
70

65
0 0.1 0.2 0.3 0.4 0.5
x1, y1

PROBLEM 10.2 (a)


P-x1 and P-y1 at 90° C 160
x1 P1 sat P2 sat P y1 t = 90°C
0 136.4968 24.26032 24.26032 0 140
0.1 136.4968 24.26032 35.48397 0.384672 120
0.2 136.4968 24.26032 46.70762 0.584473
0.3 136.4968 24.26032 57.93126 0.706856 100

P / kPa
0.4 136.4968 24.26032 69.15491 0.789513 80
0.5 136.4968 24.26032 80.37856 0.849087
0.6 136.4968 24.26032 91.60221 0.894062 60
0.7 136.4968 24.26032 102.8259 0.929219 40
1
0.8 136.4968 24.26032 114.0495 0.957457 P-x
0.9 136.4968 24.26032 125.2732 0.980634 20
1 136.4968 24.26032 136.4968 1 0
0 0.1 0.21 0.3 0.4 0.5 0.6
P-y
x1, y1

t-x1 and t-y1 at 90 kPa


140
t/ °C P P1 sat P2 sat x1 y1
P = 90
131.84 90 394.6122 90 0 0 t-y
130 1
130 90 378.6417 85.54093 0.015213 0.064005
125 90 337.6751 74.27845 0.059688 0.223945
120
120 90 300.1211 64.22537 0.109263 0.364356
t-x
115 90 265.7997 55.28672 0.164898 0.487 1
110
110 90 234.5321 47.37134 0.227765 0.593535
105 90 206.1414 40.39202 0.299295 0.685524
100
t/ °C

100 90 180.4528 34.26565 0.381253 0.764425


95 90 157.2942 28.91331 0.475824 0.831604 90
90 90 136.4968 24.26032 0.585725 0.888328
85 90 117.8953 20.23635 0.71436 0.935774 80
80 90 101.3287 16.77541 0.866017 0.975026
76.2 90 90.00252 14.48359 0.999967 0.999995 70

60
0 0.1 0.2 0.3 0.4 0.5
x1, y
60
0 0.1 0.2 0.3 0.4 0.5
x1, y

PROBLEM 10.2 (b)


P-x1 and P-y1 at 90° C 160
x1 P1 sat P2 sat P y1 t = 90°C
0 142.7112 28.234 28.234 0 140
0.1 142.7112 28.234 39.68172 0.35964
0.2 142.7112 28.234 51.12944 0.558235 120
0.3 142.7112 28.234 62.57716 0.684169
0.4 142.7112 28.234 74.02488 0.771153 100
0.5 142.7112 28.234 85.4726 0.834836
0.6 142.7112 28.234 96.92032 0.883475 80
0.7 142.7112 28.234 108.368 0.921839
0.8 142.7112 28.234 119.8158 0.952871 1
P-x
60
0.9 142.7112 28.234 131.2635 0.978491
1 142.7112 28.234 142.7112 1 40
1
P-y
20

0
0 0.1 0.2 0.3 0.4 0.5 0.6

t-x1 and t-y1 at 90 kPa 140


t/ °C P P1 sat P2 sat x1 y1 P = 90 kPa
127.352 90 370.8229 90 0 0 130 t-y
125 90 351.3302 84.30102 0.021342 0.083313 1
120 90 312.4487 73.13163 0.070485 0.244701 120
115 90 276.8939 63.1667 0.125549 0.386265
t-x
110 90 244.4837 54.31173 0.187663 0.509784 1
110
105 90 215.0374 46.47591 0.258209 0.61694
100 90 188.3766 39.5723 0.338886 0.709313
100
95 90 164.3254 33.51797 0.431795 0.788388
90 90 142.7112 28.23409 0.539548 0.855551
90
85 90 123.365 23.64606 0.66541 0.912092
80 90 106.1218 19.68356 0.813488 0.959209
80
75 90 90.82124 16.28059 0.988983 0.998007
74.7135 90 90.00012 16.10125 0.999998 1
70

60
0 0.2 0.4 0.6
t = 75°C

3 0.4 0.5 0.6 0.7 0.8 0.9 1


x1 , y1

P = 70 kPa

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1


x1, y1
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1, y1

t = 90°C

1 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1


x1, y1

P = 90 kPa
t-y
1

t-x
1

1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1


x1, y1
1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1, y1

t = 90°C

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

P = 90 kPa

0.4 0.6 0.8 1 1.2

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