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Such substances that donate their hydrogen ion (H+) (proton donor) and accepts
the electron to another is called an acid. They have pH less than 7.0. But such
substances that accept the proton and donate electron is called as the base. They
have pH more than 7.0. Acids are sour, while bases are bitter.
Acids and Bases are one of the most important parts of chemistry, but also play
their significant role in another field of science. There are many definitions which
differentiate the substances as acid and base, but the most accepted are the
Arrhenius theory, Bronsted-Lowry theory and the Lewis theory of acid/base.
Together acids and bases react to form salts.
Acids and Bases are everywhere, right from the soaps used during the shower to
the citric acid or vinegar present in the kitchen. Though it is sometimes difficult
to distinguish between them and so to check them, certain theories were provided
which are discussed below along with brief description.
Comparison Chart
BASIS FOR
ACIDS BASES
COMPARISON
Arrhenius Concept Acid is the substance when The base is the substance
dissolved in water, when dissolved in water,
increases the increase the concentration of
concentration of H+ ions. OH- ions.
Lewis Concept Such species that accepts Such species that donates the
the pair of electrons (an pair of the electron (a
electrophile) and will have nucleophile) and will have a
vacant orbitals are known lone pair of electrons are
as Lewis acid. known as Lewis base.
BASIS FOR
ACIDS BASES
COMPARISON
Litmus test Turns blue litmus paper to Turns red litmus paper to
red. blue.
Definition of Acid
The word acid derived from the latin word ‘acids’ or ‘acere’, which means “sour”.
An acid is the chemical substances that accept electrons and donates hydrogen
ions or protons. Most acids containing hydrogen bonded atoms dissociate to give
cation and anion in water.
Some acids are strong, and some are weak. Strong acids are those which
completely dissociate in water, for example, hydrochloric acid, which completely
dissociates into ions when dissolved in water. Such acids which partly dissociates
in water and hence the solution contains water, acid, and ions are called weak
acids, for example, acetic acid.
Mainly acids are defined in many ways, but Arrhenius or Bronsted-Lowry acid is
acceptable. Although Lewis acid is called as “Lewis acid”, as these definitions do
not include the same set of molecules.
Lewis acid – There are certain compounds which do not contain hydrogen
atom, but qualify as acid like boron trifluoride, aluminum trichloride. So such
compound which accepts the electron pair to form a covalent bond is called as
Lewis acid.
Properties of acids
Importance
Biologically nucleic acids such as DNA (Deoxy ribonucleic acids) and RNA
(Ribonucleic acids) contain the genetic information and other are heredity
material which is transferred from one generation to another. Even the amino
acids are of great of great importance as they help in making proteins. Fatty acids
and its derivatives are the groups of carboxylic acids also play a significant role.
Even the hydrochloric acids, which is the part of gastric acid secreted in a
stomach of animals helps in hydrolyzing proteins and polysaccharides. Acids are
also helpful by acting in defense mechanism like in ants which produce formic
acid, while octopi produce a black acid called as melanin.
Other acids like lactic acid, vinegar, sulfuric acid, citric acid are found in nature
are known for their different and important uses.
Definition of Base
Bases donate electrons and accept hydrogen ions or protons. Bases can be said as
the chemical just opposite to that of acid, as in water the role of the base is to
reduce the concentration of hydronium (H3O+) ion while acid act in increasing the
concentration. Although it is seen that some strong acids serve as bases also.
Bases are measured between the 7-14 range in pH meter scale.
However, there is a lot of confusion between bases and alkalis. Many bases do not
dissolve in water, but if a base dissolves in water, it is called an alkali. When in
an aqueous solution a base reacts with an acid and the solution becomes neutral,
it is called neutralization reaction.
Lewis Base – One of the most widely accepted concept, after the Bronsted-
Lowry concept of acids and bases. An atom, molecule or an ion with a lone-pair of
electrons can be said as Lewis base as these bases are Nucleophilic. It means with
the help of lone pair they attack the positive charge of the molecule. NH3 is a
Lewis base. In other words, we can say that substance like OH– ion, that can
donate a couple of nonbonding electrons are said as Lewis base or electron-pair
donor.
Properties of Base
Importance
Bases (Sodium hydroxide) are used in manufacturing paper, soap, and the fiber
called rayon. Calcium hydroxide is used as bleaching powder. Magnesium
hydroxide used as ‘antacid’ which is used at the time of indigestion and to reduce
the effect of access to stomach produced. Bases like Sodium carbonate is used as
washing soda and for softening the hard water. Sodium hydrogen is also used in
preparations of baking powders, as baking soda, and also in the fire extinguisher.
What is Water?
Water is made up of billions of molecules. Each molecule is made of one oxygen
and two hydrogen atoms held together by strong covalent bonds. ... Water on our
planet flows as liquid in rivers, streams, and oceans; is solid as ice at the North
and South Poles; and is gas (vapor) in the atmosphere.