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FIRST PUC AL EXAil TION -2()18


Time: 3-15 hours Max Marks:7o
STRY Total No.of Ques.:37
No.of Pages: (Xl
Genei'al Instirictions:
il Thequestionpaperhas fou parts A, are compulsory.
iil Write balancedchemical equations d^[H.r*"
diagrams wherevernecessary.
iiil Use log tablesand simple calculatorsi lseiif6Aentinc calculators is not allowed)
;..

m
Answer All the following in one.gqryd or in a sentence.Each question

carries one marh ,,';.,u':


,:li:+aa,:
10x1:10

co
oc
l) Writetherelation n anarehffi,$)
2) Write ideal gas for'n'moles, $the g*.
3) Whatishydronitrmion? ' ::
4) StatemodernPeriodic

g.
5) Define the term oxidati
6) Whichalkalimetalis
7) Writethe general shell ofp-block elements .

lo
8) Write oneuse of
9) GivethelUPACname cH.-crL
10) Writethe gureral
Answer any FrvE of the
i PART-B
fo[owing
I

ib
for alkenes,

q"*fi61,fach question carries


'illS;
ik
12\ calculate thevalueof Rin s.L unit foronemoleofagas.
lciuen P= 105 N/m2 V$.OZZtaS8m3, i='i?3. 15K' n 1 1 Tole. '
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l3) Wit. tn. electsnic corifigurAtion oflitliiiim (Lir) molecule .
What is its bond order? ',

14) Write anytwobiologic{importance ofiMagnedium


ia

151 What areZeolites? Givq one use of Zeolite


:' '
16) uk"n", aoitiffdina with an example '
Explain the preparation ff dihalides
17) ofibe-"n" withreaction
ed

expUinsutptronation
tej i, gr"", chemistr5fl Writeaol{mfii;-t1fnce of green chemishv'
: plrrc
Wtrat
'

Answer any FIVE of the folbwing quqstionsEach question carries' -llf=i,


.p

dqwn the
I 9) Define ionisatibn enthafpy. How does it varies along a period and
group in the Periodic table .
20) Cive anytfreernainpoStulates ofvalenrie bondtheory (VBT)'
w

2l) Writethelewis dotsyribols for


I
I

of the foflOftng molecules based on VSEPR


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22) dirJtfr. geometical iiirp"r !

23) Balance the redo-x reaction by Half reaction ryethod'


w

(acidne&m)
24) al What is water gas?
(? chlorine and (ii) fluorine
bJ How Oo"s Oiiyarogen reacts with halogens tik"
25) Mentionanytt"*oirg*.rrelationship similarities between Beryllium and
Aluminium.
26) Explain the structure of Diborane '
P.T.O.

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it

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t
PART.D
r Answer any F'IVE of the
ffi.11
I

quotioo{r""n question carries 5 marks.


: 5xF25
27) aJAcompoundcontairyffii % 24.47Yo carbon and 7 1.65a/o
chlorine . Its molecula&uu r is 98.969. its empirical formula. J

m
bJ State gaylusaacc's rofgaseous 2
28) a] Give any three of Bohr's ofatomic model.
b] State Heisenberg'si . Give its mathematical expression

co
2e) alWrite Rydberg's explain 2
J
a
30) ofgases. J
in theterms. 2

g.
3l) work done in an isothermal
J
2

lo
32) a] Define standard entlidlpy,ofreaction, , 2
b] What is lattice enthilg8How doybu the lattice enthalpy of
sodium chloride by qfft tsorn-Haber cycle? J
33)

.
al State Le chatelier's.ptibiple.
bl Describe the experiririirtal study of
equilibrium. Fe3* + Seir"t,,=-' 1p"1< ib
effect of concentration on the
!'* .
2
ik
34) al Write the expressioa for.the equitli n constant (Kc) for the tbllowing

(i) H2e) + I,,e) ==2IlI (g)


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(ii) 4NHr($ + 5O2G) + 4NO1d + 6 o(e)
bl (i) What is arrheniG ficid?
(ii) The concentratidn gfhydrogen i in asample of soft drink is
ia

3.8 x l0-'M Whatisits pHvalue?

AnswerdnyTWO ofthe
ed

question carries 5 marks.


2x5=10
35) al What is functional ii$b;ism ? Give example. 2
bl (i) Write the Reson$4.$slructure of
.2
.p

(ii) Write one elechoph I


36) al Give anytwo"xampffiar
Aifer6difubetween effect and Electromeric
-' effect.
2
w

blDescribe the estimation of nitogen b Dumas method J


37) al Describe the preparatign of alkenes b Kolbe's electrolytic method.. 2
bl Explain the free radeal,aechanism of ofmethane. J
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