Antoine Equation Graph For Benzene and P-xylne

Made by:
Name- ABHIJEET BINJVE (0101PC161001)
Subject: CA lab PC 606 (Assignment 2)
VI SEMESTER

Steps to use this exce as a tool to solve for values of X and Y (mole fractions) using Antoine Equation and its coeffi
1. Deteremine the tempertaure range for which you want to solve the equation. Once done copy the temperature ran
2. Set the Antoine coefficients next to both the temperature columns. To auto fill the cells in rows, (B,C,D) and (K,L,M)
3. Once you set these above paarmeters and values, the remaining data will be calculated automatically and the value
4. Also the values of X and Y for making a TXY graph would be obtained.
5. The graph would be drawn automatically based on this excel sheet. For how to draw graph for excel one can refer t
6. Graph is in the J31 cell

Formula CompoundA B C TMIN TMAX

C6H6 benzene 6.90565 1211.033 220.79 -16 104
C8H10 p-xylene 6.99052 1453.43 215.307 27 166

Benzene Antoine Coefficients Basic calaculation for Antoine equation P-xylene Antoine Coefficients
TemperatA B C T+C B/T+C A-B/T+C Pa (mm Hg) TemperatA
138.326 6.90565 1211.033 220.79 359.116 3.372261 3.533389 3414.984 138.326 6.99052
135 6.90565 1211.033 220.79 355.79 3.403786 3.501864 3175.88 135 6.99052
130 6.90565 1211.033 220.79 350.79 3.452302 3.453348 2840.194 130 6.99052
125 6.90565 1211.033 220.79 345.79 3.502221 3.403429 2531.798 125 6.99052
120 6.90565 1211.033 220.79 340.79 3.553605 3.352045 2249.288 120 6.99052
115 6.90565 1211.033 220.79 335.79 3.606519 3.299131 1991.274 115 6.99052
110 6.90565 1211.033 220.79 330.79 3.661033 3.244617 1756.375 110 6.99052
105 6.90565 1211.033 220.79 325.79 3.71722 3.18843 1543.229 105 6.99052
100 6.90565 1211.033 220.79 320.79 3.775158 3.130492 1350.491 100 6.99052
95 6.90565 1211.033 220.79 315.79 3.834931 3.070719 1176.843 95 6.99052
90 6.90565 1211.033 220.79 310.79 3.896628 3.009022 1020.991 90 6.99052
85 6.90565 1211.033 220.79 305.79 3.960342 2.945308 881.6738 85 6.99052
80 6.90565 1211.033 220.79 300.79 4.026174 2.879476 757.6622 80 6.99052

145
140
135
130
125
120
115
T(C)

110
 135
130
125
120
115

T(C)
110
105
100
95
90
85
80
0 0.1 0.2 0.3 0.4
x, y (mo
raph For Benzene and P-xylne

ng Antoine Equation and its coefficients as a tool.

e done copy the temperature raneg starting from cell A20 till vertical down limit. Same has to be done for compound 2 starting from J20 to
cells in rows, (B,C,D) and (K,L,M) select the first individual row of these set and double click on the green plus sign at bottom left corner of
lated automatically and the values for Pa and Pb (Satuarated pressure for A and B in column H and Q) could be obtained

w graph for excel one can refer this short video (https://youtu.be/IHw_PnQYdPM)

Antoine Coefficients Basic calaculation for Antoine equation X

B C T+C B/T+C A-B/T+C Pb(mm Hg) Pb-Pt Pa-Pb X=(Pb-Pt/Pb-Pa)
1453.43 215.307 353.633 4.109995 2.880525 759.4945 -0.5055 -2655.5 0.00019
1453.43 215.307 350.307 4.149018 2.841502 694.228 -65.772 -2481.7 0.026503
1453.43 215.307 345.307 4.209095 2.781425 604.5398 -155.46 -2235.7 0.069537
1453.43 215.307 340.307 4.270938 2.719582 524.3029 -235.7 -2007.5 0.117409
1453.43 215.307 335.307 4.334625 2.655895 452.7884 -307.21 -1796.5 0.171006
1453.43 215.307 330.307 4.40024 2.59028 389.2963 -370.7 -1602 0.231404
1453.43 215.307 325.307 4.467872 2.522648 333.1564 -426.84 -1423.2 0.299914
1453.43 215.307 320.307 4.537615 2.452905 283.7295 -476.27 -1259.5 0.378143
1453.43 215.307 315.307 4.609571 2.380949 240.4081 -519.59 -1110.1 0.468066
1453.43 215.307 310.307 4.683845 2.306675 202.6164 -557.38 -974.23 0.572129
1453.43 215.307 305.307 4.760552 2.229968 169.8117 -590.19 -851.18 0.693377
1453.43 215.307 300.307 4.839814 2.150706 141.4836 -618.52 -740.19 0.835618
1453.43 215.307 295.307 4.921759 2.068761 117.1549 -642.85 -640.51 1.00365
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x, y (mol e fra ction)
 r compound 2 starting from J20 to vertical down limit.
n plus sign at bottom left corner of selected cell.
uld be obtained

Y
X*Pa Y=(X*Pa/Pt)
0.650131 0.000855
84.17132 0.110752
197.4979 0.259866
297.2547 0.391125
384.6409 0.506107
460.7884 0.6063
526.762 0.693108
583.5607 0.767843
632.1187 0.831735
673.3064 0.885929
707.9318 0.931489
736.7427 0.969398
760.4276 1.000563