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HEAT
Phases of matter
Temperature
Temperature Scales
Thermal expansion
hshshs
Phases of matter
Solid
Some movement of
molecules is possible, all
linked by spring-like
forces. Average
positions of molecules
are fixed. Solid has
rigidity and retains shape
Liquid
Molecules are freer to move
but always remaining
close to each other. A
liquid flows and does not
retain shape.
Gas
Molecules move anywhere
with little interaction with
each other. A gas flows
and does not retain shape.
Temperature and Heat
Brownian motion
T = 25 C
Water
Freezing 0 32 273.15
Absolute
-273.15 -459.69 0
zero
CelsiusoC Fahrenheit oF Kelvin, K
(absolute)
Example
Tyres have higher pressure when hot compared
with cold.
Ideal gas:
Is a collection of atoms or molecules
• move randomly
•exert no long-range forces on each other.
•considered to be point-like
•occupy negligible volume.
-273.15 -273.15
T K T C 273.15
Example: Freezing point of water : 273.15 K
Boiling point of water: 373.15 K
Converting Temperatures
Celsius to Fahrenheit :
T F 9 T C 32
5
Fahrenheit to Celsius :
Thermometers
•Alcohol in glass
•Mercury in glass
Depends on expansion
Example.
Body temperature can increase from 98.60F to
1070F during extreme physical exercise or during
viral infections. Convert these temperatures to
Celsius and Kelvin and calculate the
difference in each case.
T C 5 T F 32
9
T C 5 98.6F 32 37oC
9
T K T C 273.15
Dental drilling
linear expansion:
DL ( L)(a )(DT )
DL = change in length
L = original length
DT = change in temperature
Example
10oC temperature change for 1 sec
Little change in bulk material dimensions
Example
Amalgam 8 mm wide, oral temperature
decreases by 10oC. Compare contraction of
amalgam with that of enamel.
DL ( L)(a )(DT )
DL (8mm)(25 106 C 1 )(10 oC) 2 103 mm
Bimetallic strip
brass
steel
23oC
Switch open
Mercury or Alcohol thermometer
.
−
Why is there a reservoir at the −
−
bottom of a thermometer? −
−
temperature is 35 to 43°C, −
−
Reservoir
DL 4.8 x 10 m = 0.048mm
-5
A+ DA ≈ L2 + 2L DL
Thus DA = 2L DL = 2L(LaDT)
DA = L2(2a)DT = A(2a)DT
Therefore
2.4ml – 0.018ml = 2.38 ml will spill out
Exercise:
A steel measuring tape used by a civil engineer
is 50metres long and calibrated at 20oC.
The tape measures a distance of 35.694m
at 35oC. What is the actual distance measured?
Coefficient of linear expansion of steel
a = 1.2 x10-5 oC-1
DL ( L)(a )(DT )
DL = 900x10-5m =0.009m
Length of tape at 35oC = 50.009m
Error =6mm
Example.
Concrete slabs of length 25 m are laid end to end
to form a road surface. What is the width of the
gap that must be left between adjacent slabs at a
temperature of -150C to ensure they do not buckle
at a temperature of +450C.Coefficient of thermal
expansion for concrete a = 12x10-6 0C-1