PHYSICAL CHEMISTRY By: Shailendra Kumar

PHYSICAL CHEMISTRY
by: SHAILENDRA KR.
Meq. Approach
Classes at: -
SCIENCE TUTORIALS; Opp. Khuda Baksh Library, Ashok Rajpath, Patna
PIN POINT STUDY CIRCLE; House No. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna

Topic: Redox Titration

1. How many gram of KMnO4 should be taken to (a) 30.4 g (b) 60.8 g
make up 250 mL of a solution of such strength
(c) 121.6 g (d) 15.8 g
that 1 mL is equivalent to 5.0 mg of Fe in FeSO4
6. 25 mL if 0.50 M H2O2 solution is added to 50
(a) 1.414 g (b) 0.70 g
mL if 0.20 M KMnO4 in acid solution. Which if
(c) 3.16 g (d) 1.58 g the following statements are true :
2. The eq. wt. of Na2S2O3 as reductant in the (a) 0.010 mole of oxygen is liberated
reaction,
(b) 0.005 mole if KMnO4 are left
Na2S2O3 + H2O + Cl2 → Na2SO4 + 2HCl + S
(c) 0.030 g atom if oxygen gas is evolved
(a) (Mol. wt.)/1 (b) (Mol. wt.)/2
(d) 0.0025 mole H2O2 does not react with
(c) (Mol. wt.)/6 (d) (Mol. wt.)/8 KMnO4

3. How many gram of I2 are present in a solution 7. What volume of O2 measured at standard
which requires 40 mL of 0.11 N Na2S2O3 to react conditions will be formed by the action of 100
with it, mL if 0.5 N KMnO4 on hydrogen peroxide an
acid solution ? The skeleton equation for the
S2O2–3 + I2 → S4O2–6 + 2I– react in is,
(a) 12.7 g (b) 0.558 g 2 KMnO4 +4 H2SO4 + 2 H2O2 → 2 KHSO4 + 2
(c) 25.4 g (d) 11.4 g MnSO4 + 2 H2O + O2

4. What mass of MnO2 is reduced by 35 mL of (a) 0.12 litre (b) 0.28 litre
0.16 N oxalic acid in acid solution ? The skeleton (c) 0.56 litre (d) 1.12 litre
equation is,
8. What volume of 0.40 M Na2S2O3 would be
MnO2 + H+ + H2C2O4 → CO2 + H2O + Mn2+ required to react with the I2 liberated by adding
(a) 8.7 g (b) 0.24 g excess of KI to 50 mL of 0.20 M CuSO4 solution

(c) 0.84 g (d) 43.5 g (a) 12.5 mL (b) 25 mL

5. What weight of FeSO4 (mol. wt. = 152) will be (c) 50 mL (d) 2.5 mL
oxidized by 200 mL if normal KMnO4 solution in 9. What volume of 2 N K 2Cr 2 O7 solution is
acid solution : required to oxidise 0.81 g of H2S in acid
medium :

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PHYSICAL CHEMISTRY By: Shailendra Kumar
(a) 47.8 mL (b) 23.8 mL (a) 1.58 g (b) 15.8 g
(c) 40 mL (d) 72 mL (c) 6.32 g (d) 31.6 g
10. The number of mole of Fe2+ ion oxidised by 17. When the ion Cr2O2–7 acts as an oxidant in
one mole of MnO–4 ions is : (acidic medium) acidic aqueous solution the ion Cr+3 is formed.
How many mole of Sn2+ would be oxidised to
(a) 1/5 (b) 2/3
Sn4+ by one of Cr2O2–7ions :
(c) 5 (d) 3/2
(a) 2/3 (b) 3/2
11. What weight of HNO3 is needed to convert 5 g
(c) 2 (d) 3
of iodine into iodic acid according to the
reaction, 18. The eq. wt. of Fe2(SO4)3, the salt to be used
as an acid solution is :
I2 + HNO3 → HIO3 + NO2 + H2O
(a) (Mol.wt.)/1 (b) (Mol.wt.)/2
(a) 12.4 g (b) 24.8 g
(c) (Mol.wt.)/3 (d) (Mol.wt.)/5
(c) 0.248 g (d) 49.6 g
19. What volume of 3 molar HNO3 is needed to
12. How many litre of Cl2 at STP will be liberated
oxidise 8 g of Fe2+ to be Fe3+, HNO3, gets
by the oxidation of NaCl with 10 g KMnO4
converted to NO :
:(acidic medium)
(a) 8 mL (b) 16 mL
(a) 3.54 litre (b) 7.08 litre
(c) 32 mL (d) 64 mL
(c) 1.77 litre (d) None of these
20. Given that 50.0 mL of 0.01 M Na2S2O3 solution
13. The number of mole of potassium salt, i.e.,
and 5 × 10–4 mole of Cl2 react according to
KHC 2 O 4 .2H 2 O oxidised by one mole of
equation, Cl2(g) + S2O2–3 → SO2–4 + Cl– + S.
permanganate ion is ::(acidic medium)
Answer the following,
(a) 2/5 (b) 4/5
(i) The balanced molecular equation is :
(c) 5/2 (d) 5/4
(a) Cl2 + H2O + Na2S2O3 → Na2SO4 + S + 2HCl
14. What volume of 0.1 N oxalic acid solution acid
solution can be reduced by 250 g of an 8 per (b) Cl2 + Na2S2O3 → 2NCl + Na2SO4
cent by weight KMnO 4 solution ::(acidic
(c) Cl2 + S2O2–3 → SO2–4 + S + Cl–
medium)
(d) None of these
(a) 6.3 litre (b) 12.6 litre
(ii) How many mole of S2O2–3 are in the above
(c) 25.2 litre (d) 0.63 litre
sample :
15. The number of mole of ferrous oxalate oxidised
(a) 0.00050 (b) 0.0025
by one mole of KMnO4 is :(acidic medium)
(c) 0.01 (d) 0.02
(a) 1/5 (b) 3/5
(iii) How many equivalents of oxidising agent
(c) 2/3 (d) 5/3
are in this sample for the above reaction :
16. How many gram of KMnO4 are contained in 4
(a) 0.001 (b) 0.080
litre of 0.05 N solution. The KMnO4 is to be used
as an oxidant in acid medium . (c) 0.020 (d) 0.010

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PHYSICAL CHEMISTRY By: Shailendra Kumar
(iv) What is the molarity of Na 2SO4 in this 27. For the reaction,
solution :
2Fe3+ + Sn2+ → 2Fe2+ + Sn4+
(a) 0.080 M (b) 0.040 M
The normality of SnCl2 (mol. wt. = 189.7)
(c) 0.020 M (d) 0.010 M solution prepared by dissolving 47.5 g in acid
solution and diluting with H2O to a total of 2.25
21. What weight of HNO3 is required to make 1
litre is :
litre of 2 N solution to be used as an oxidising
agent in the reaction, (a) 0.222 N (b) 0.111 N
3Cu + 8HNO3 → 3Cu(NO3)2 + 2NO + 4H2O (c) 0.333 N (d) 0.444 N
(a) 63 g (b) 21 g 28. In the reaction, 2S2O2–3 + I2 → S4O2–6 + 2I–, the
eq. wt. of Na2S2O3 is equal to its :
(c) 42 g (d) 84 g
(a) Mol. wt. (b) Mol. wt./2
22. What is the normality of a KMnO4 solution to
be used as an oxidant in acid medium, which (c) 2 ´ mol. wt. (d) Mol. wt./6
contains 15.8 g of the compound in 100 mL of
solution ? Mol.wt. of KMnO4 is 158 : 29. In the reaction, VO + Fe2O3 → FeO + V2O5,

(a) 2 N (b) 3 N the eq. wt. of V2O5 is equal to its :

(c) 4 N (d) 5 N (a) Mol. wt. (b) Mol. wt./8

23. The eq. wt. of KMnO4 in the reaction, (c) Mol. wt./6 (d) None of these

MnO–4 + Mn2+ + H2O → MnO2 + H+ 30. A 0.518 g sample of lime stone is dissolved in
HCl and then the calcium is precipitated as
(unbalanced) is : CaC 2 O 4 . After filtering and washing the
precipitate, it requires 40.0 mL of 0.250 N
(a) 52.7 (b) 158
KMnO4, solution acidified with H2SO4 to titrate
(c) 31.6 (d) None of these it as,
24. What volume of N K2Cr2O7 solution is required MnO–4 + H+ + C2O2–4 → Mn2+ + CO2 + 2H2O
to oxidize (in acid solution) a solution containing
The percentage of CaO in the sample is :
10 g of FeSO4. (mol. wt. of FeSO4 = 152)
(a) 54.0%
(a) 65.78 mL (b) 134 mL
(b) 27.1 %
(c) 35 mL (d) 33.5 mL
(c) 42%
25. How many milli litre if 0.5 N SnCl2 solution will
reduced 600 mL of 0.1 N HgCl2 to Hg2Cl2 : (d) 84%
(a) 120 mL (b) 60 mL
(c) 30 mL (d) 240 mL
26. How many milli gram of iron (Fe2+) are equal to
1 millilitre of 0.1055 N K2Cr2O7 equivalent :
(a) 5.9 mg (b) 0.59 mg
(c) 59 mg (d) 5.9 × 10–3 mg

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PHYSICAL CHEMISTRY By: Shailendra Kumar
A N S W E R
1. b
2. d
3. b
4. b
5. a
6. b
7. C
8. b
9. b
10. c
11. a
12. a
13. c
14. a
15. d
16. c
17. d
18. b
19. b
20. (i) a (ii) a (iii) a (iv) d
21. c
22. d
23. a
24. a
25. a
26. a
27. a
28. a
29. c
30. a

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