A + 3B --> 2R

experimento Cao mol l-1 Cbo mol l-1 Cro mol l-1
1 1 1 0.01
2 5 1 0.05
3 5 5 0.112

Cro 0
 A -->c + b
Metodo diferencial

Etano =A Ca Ra- (mol/l*s) ln Ca ln (-ra)

1 1.05E-03 0 -6.85706216 Chart Title
0.1474 5.84E-05 -1.9146053 -9.74853719
-1.4 -1.2 -1 -0.8 -0.6 -0.4 -0.2

0 -1.19146053
-6.8570622 -9.7485372
f(x) = 2.4268323853x - 6.8570622
R² = 1

Metodo integral

Ca Ra- (mol/l*s) ln(Cao/Ca) 1/Ca

1 1.05E-03 0 1
0.1474 5.84E-05 1.914605299 6.784260516
 Chart Title
0
1.2 -1 -0.8 -0.6 -0.4 -0.2 0
-2
-4
-6
f(x) = 2.4268323853x - 6.8570622 -8
R² = 1
-10
-12
 t, min p, atm Ca(mol/*min)dCa/dt grado 3 dCa/dt grado 4
A --> 2R
0 1 0.032268208 0.0275 0.0449
0.5 1.5 0.037242529 0.0219 0.0301
1 1.65 0.040966782 0.0169 0.0189
1.5 1.76 0.043697901 0.0125 0.011
2 1.84 0.045684169 0.0087 0.0061
2.5 1.9 0.04717387 0.0055 0.0039
3 1.95 0.048415288 0.0029 0.0041
3.5 1.99 0.049408422 0.0009 0.0064
4 2.025 0.050277415 -0.0005 0.0105
5 2.08 0.051642974 -0.0015 0.0229
6 2.12 0.052636108 -0.0001 0.0389
7 2.15 0.053380959 0.0037 0.0561
8 2.175 0.054001667 0.0099 0.0721

C K grado 3 grado 4
temperatura 2 100 373 0.0004 -0.0001
temperatura 1 14 287 -0.0059 0.0026
Ya 0.7594 0.0275 -0.0167
Yi 0.2306 0.0101 0.0449
R 0.082 l*atm/mol*k) 0.0052
 grado 3 grado 4
0.06 0.06

f(x) = 0.0001064997x^3 - 0.0018350962x^2 + 0.0111263016x + 0.0276256211

0.05 0.05
f(x) = - 0.000017044x^4 + 0.0003943814x^3 - 0.0034190741
R² = 0.9971363303 R² = 0.9997763578
0.04 0.04

0.03 0.03

0.02 0.02

0.01 0.01

0 0
0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7
dCa/dt grado 5 dCa/dt grado 6 metodo diferencial ln(ca) ln (-ra)
0.0629 1.2613 0.0111987118 -3.4336728152 -4.49195653
0.034065625 0.61206875 0.0086985745 -3.290303911 -4.74459612
0.01595 0.2812 0.0064553717 -3.1949937312 -5.04284267
0.005815625 0.14299375 0.004717387 -3.1304552101 -5.35650023
0.0013 0.1085 0.0034759694 -3.0860034475 -5.66188188
0.000415625 0.12101875 0.0027311188 -3.0539151329 -5.90304393
0.00155 0.1516 0.0022345518 -3.0279396465 -6.10371463
0.003465625 0.19454375 0.0018621265 -3.0076343804 -6.28603618
0.0053 0.2629 0.0016138429 -2.9901993186 -6.42913703
0.00715 0.5948 -3.5 -3.4
0.0077 1.4557
0.01355 3.166
0.0373 5.9141

grado 5 grado 6
f(x) = -
0.00005 -0.0002 R² = 0.9
-0.0011 0.0061
0.0092 -0.0629
-0.0352 0.321
0.0629 -0.8604
0.0026 1.2613
1.0113
 p, atm
grado 4 grado 5 0.06
0.06
0.05
f(x) = - 5.92207520976419E-07x^6 + 0.00001494x^5
0.05
f(x) = 1.05678643704902E-07x^5 - 1.92544739211711E-05x^4 + 0.0004109977x^3 - 0.0034731732x^2 + 0.0143368081x + 0.0259457988 R² = 0.999807213
7044x^4 + 0.0003943814x^3 - 0.0034190741x^2 + 0.014264708x + 0.0259741271 0.04
78 R² = 0.9997766949
0.04
0.03
0.03
0.02
0.02 0.01

0.01 0
0 1 2 3 4 5 6 7
0
0 1 2 3 4 5 6 7 8 9
2 3 4 5 6 7 8 9
 ln (-ra)
0
-3.5 -3.4 -3.3 -3.2 -3.1 -3 -2.9
-1

-2

-3

-4
f(x) = - 4.4971529183x - 19.6563786236
R² = 0.9240871089 -5

-6

-7
 p, atm
0.06

0.05
f(x) = - 5.92207520976419E-07x^6 + 0.00001494x^5 - 0.0001615848x^4 + 0.0010656724x^3 - 0.0049470366x^2 + 0.0158028027x + 0.0254804606
R² = 0.999807213
0.04

0.03

0.02

0.01

0
0 1 2 3 4 5 6 7 8 9
 Metodo difer
t CBr2 dCa/dt grado 3 dCa/dt grado 4 dCa/dt grado 5
0 0.335 -0.0144 -0.0168 -0.0178
2.25 0.2965 -0.013080375 -0.01465449 -0.0152428522
4.5 0.266 -0.0118215 -0.01271067 -0.0129360352
6.33 0.245 -0.0108424134 -0.0112708651 -0.0112087774
8 0.2255 -0.009984 -0.01006208 -0.009724736
10.25 0.205 -0.008880375 -0.00858401 -0.007828996
12 0.191 -0.008064 -0.00754752 -0.006410176
13.5 0.1794 -0.0073935 -0.00673359 -0.0052154527
15.6 0.1632 -0.00650016 -0.0057031334 -0.0035509515
17.85 0.15 -0.005601735 -0.0047310866 -0.0017440667
19.6 0.1429 -0.00494496 -0.0040626342 -0.0002976974
27 0.116 -0.002574 -0.00195972 0.0066163565
30 0.1053 -0.0018 -0.00138 0.009965
38 0.083 -0.000264 -0.00034448 0.021079624
41 0.0767 0.000114 -0.00007364 0.0262166365
45 0.0705 0.00045 0.000255 0.0339978125
47 0.0678 0.000546 0.00042268 0.0383095165
57 0.0553 0.000306 0.00160188 0.0643383965
63 0.0482 -0.000414 0.00285852 0.0836322365

grado 3 grado 4 grado 5

-0.000002 0.00000004 -7E-10
 0.0003 -0.000007 0.0000002
-0.0144 0.0005 -0.00001
0.3273 -0.0168 0.0006
0.3332 -0.0178
0.3347

grado 3 grado 4
0.4 0.4
0.35
0.35
f(x)
0.3= 4.25725981098673E-08x^4 - 7.28966013406854E-06x^3 + 0.0004850569x^2 - 0.01
f(x)
0.3 = - 2.06857605819696E-06x^3 + 0.0002870286x^2 - 0.0143634297x + 0.3273185163 R² = 0.9996983521
R² = 0.9980114274 0.25
0.25
0.2
0.2
0.15
0.15
0.1
0.1
0.05
0.05
0
0 0 10 20 30 40 50 60
0 10 20 30 40 50 60 70

Metodo

t CBr2 ln(Cao/Ca) (1/Ca)

0 0.335 0 2.9850746269
2.25 0.2965 0.1220833134 3.3726812816
4.5 0.266 0.230634223 3.7593984962
6.33 0.245 0.3128723213 4.0816326531
8 0.2255 0.3958103729 4.4345898004
10.25 0.205 0.4911205527 4.8780487805
12 0.191 0.5618571038 5.2356020942
13.5 0.1794 0.6245125822 5.5741360089
15.6 0.1632 0.7191540893 6.1274509804
17.85 0.15 0.8034952377 6.6666666667
19.6 0.1429 0.8519854469 6.9979006298
27 0.116 1.0605403407 8.6206896552
30 0.1053 1.1573171127 9.4966761633
38 0.083 1.395289924 12.0481927711
41 0.0767 1.4742288235 13.037809648
 45 0.0705 1.558517822 14.1843971631
47 0.0678 1.5975683369 14.7492625369
57 0.0553 1.8013576233 18.0831826401
63 0.0482 1.9387715108 20.7468879668

(-ra)= 0,2735 CBr2^1

Analisis -->
Metodo diferencial de ajuste
dCa/dt grado 6 ln(ca) ln(-ra)
-0.0172 -1.0936247472 -4.0628459
-0.015044065 -1.2157080605 -4.19677172
-0.0130861358 -1.3242589702 -4.33620194
-0.0116474227 -1.4064970684 -4.45267035
-0.0104583322 -1.48943512 -4.56035628
-2 -1.9 -1.8 -1.7
-0.00904585 -1.5847452998 -4.70544919
-0.0080983398 -1.6554818509 -4.8160962
-0.0073910628 -1.7181373294 -4.90748374
-0.0065621031 -1.8127788365 -5.02644414
-0.0058799338 -1.8971199849 -5.13620978
-0.0054944666 -1.945610194 -5.20401376
-0.0052406988 -2.1541650879 -5.25130042
f(x) = 1.3717647948x - 2.5352576
-0.005776 -2.2509418598 -5.15404388 R² = 0.9987285031
-0.0092130202 -2.4889146712 -4.68713756
-0.0114010141 -2.5678535706 -4.47405297
-0.015302125 -2.6521425692 -4.17976357
-0.0177570308 -2.691193084 -4.03097374
-0.0371790768 -2.8949823705 -3.29200913
-0.0572179352 -3.0323962579 -2.86088788 ln(k)
k
grado 6 alfa
-2E-11
 0.000000002 (-rBr2)= 0,079 CBr2^1,3718
-0.00000007
-0.000006
0.0005
-0.0172
0.3342

o4 grado 5
0.4
0.35
406854E-06x^3 + 0.0004850569x^2 - 0.0167729439x + 0.3332197297 f(x)
0.3= - 7.14773369999704E-10x^5 + 1.52144664733353E-07x^4 - 1.31528352399454E-05x^3 + 0.0006135997x^2 - 0.017781926x + 0.3347395855
R² = 0.9998319243
0.25
0.2
0.15
0.1
0.05
0
0 10 20 30 40 50 60 70
40 50 60 70

Metodo Integral

CBr2
0.4

0.35
25
0.3

0.25
f(x) = - 0.0041384644x + 0.2588010569 20
R² = 0.856618786 f(x) = 0.2735280287x + 2.0
0.2
R² = 0.9884276024
0.15 15

0.1
10
0.05

0 5
0 10 20 30 40 50 60 70

0
0 10 2
ln(Cao/Ca)
2.5

2 f(x) = 0.0305105231x + 0.1645767589

 5

0
0 10 2
ln(Cao/Ca)
2.5

2 f(x) = 0.0305105231x + 0.1645767589

R² = 0.9801711997

1.5

0.5

0
0 10 20 30 40 50 60 70
 ln(-ra)
0
.9 -1.8 -1.7 -1.6 -1.5 -1.4 -1.3 -1.2 -1.1 -1

-1

-2

-3

-4
= 1.3717647948x - 2.5352576274
= 0.9987285031
-5

-6

-2.5353
0.079237944
1.3718
 CBr2
0.4
0.35
017781926x + 0.3347395855
f(x)0.3 = - 1.68408271578708E-11x^6 + 2.42671820236168E-09x^5 - 6.70913690261644E-08x^4 - 0.000006112x^3 + 0.0005111482x^2 - 0.0172235532x + 0.3342048575
R² = 0.9998524012
0.25
0.2
0.15
0.1
0.05
0
0 10 20 30 40 50 60 70

(1/Ca)
25

20
f(x) = 0.2735280287x + 2.0966982522
R² = 0.9884276024
15

10

0
0 10 20 30 40 50 60 70
5

0
0 10 20 30 40 50 60 70
 A + B --> R + S Metodo In
experimento t conversion % Ca ln(Cao/Ca) 1/Ca
1 13 11.2 0.1776 0.118783536 5.630630631
2 34 25.7 0.1486 0.297059234 6.729475101
3 59 36.7 0.1266 0.457284857 7.898894155
4 120 55.2 0.0896 0.802962047 11.16071429

Cao (M) 0.2

Cbo (M) 0.2

Ca ln(Cao/Ca)
0.2 0.9
0.18 0.8
0.16 f(x) = 0.0062576333x + 0.0654661373
f(x) = - 0.0007865465x + 0.1800398788 0.7 R² = 0.9927836435
0.14 R² = 0.9642336733 0.6
0.12
0.5
0.1
0.4
0.08
0.3
0.06
0.04 0.2
0.02 0.1
0 0
0 20 40 60 80 100 120 140 0 20 40 60 80 100 120 1
 Metodo Integral

(-ra)= 0,0516 *Ca^2

(Cao/Ca) 1/Ca
12
3x + 0.0654661373 10 f(x) = 0.0515934395x + 4.939899209
R² = 0.9994308248
8

60 80 100 120 140 0

0 20 40 60 80 100 120 140
 A --> R

experimento Q (l/min) Ca(mol/min) t (min) t (min)ordenado Ca ordenado

1 0.5 25 2 0 100
2 0.7 30 1.428571429 0.1 80
3 2 50 0.5 0.5 50
4 10 80 0.1 1.4285714286 30
2 25
Cao (mol/l) 100
V reactor (l) 1
 A + 3B <--> 2R

experimento Cbo (M) Cao (M) Cr(M)

1 1 1 0.01
2 5 1 0.0224
3 1 5 0.05
4 5 5 0.112

a) ¿Qué información se puede obtener de la ecuación cinética a partir de estos experimentos?

b) En un quinto experimento con las condiciones del experimento 4, la composición de la mezcla es CR=1 M tras una
semana de reacción (tiempo infinito). Explique razonadamente si la reacción es efectivamente reversible
c) Si se realizan otros tres experimentos en las condiciones de la siguiente tabla, ¿qué información adicional se puede
obtener de la ecuación cinética? (tiempo transcurrido = 1 minuto).

experimento Cbo (M) Cao (M) Cro(M) CR(M)

6 0 0 1 0.999
7 0 0 5 4.975
8 0 0 25 24.375
?
cla es CR=1 M tras una
e reversible
ción adicional se puede
 A <--> R + S

t, min Ca, M
0 0.1823
36 0.1453
65 0.1216
100 0.1025
160 0.0795
infinito 0.0494

CA0 (M) 0.1823

CR0 (M) 0
CS0 (M) 55
 Cao=Cbo= 1
t (min) Xa Ca ln(Cao/Ca) 1/Ca
15 0.15 0.85 0.162518929 1.176470588
40 0.29 0.71 0.342490309 1.408450704
60 0.37 0.63 0.46203546 1.587301587
100 0.47 0.53 0.634878272 1.886792453

Ca ln(Cao/Ca) 1/C
0.9 0.7 2
0.8 1.8
0.7 f(x) = - 0.0036833603x + 0.8779806139 0.6 f(x) = 0.0054911771x + 0.1053299728 f(x) = 0.008330947
R² = 0.9578080964 R² = 0.9826029133 1.6 R² = 0.9966503468
0.6 0.5
1.4
0.5 0.4
0.4 1.2
0.3 1
0.3
0.2 0.2 0.8
0.1 0.1 0.6
0 0 0.4
10 20 30 40 50 60 70 80 90 100 110 10 20 30 40 50 60 70 80 90 100 110 0.2
0
10 20 30 40 50 6
 1/Ca
2
1.8 f(x) = 0.0083309476x + 1.0669654016
1.6 R² = 0.9966503468
1.4
1.2
1
0.8
0.6
0.4
0.2
0
10 20 30 40 50 60 70 80 90 100 110
 P,atm T, min Ca
1 0 1
1.3 2 0.8
3 4 0.6

Ca k 0.1
1.2
1
f(x) = - 0.1x + 1 #NAME?
0.8 R² = 1
0.6
0.4
0.2
0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5
p, atm 2

t,min
0
20
 T 373 L Ca mol t min
P 1000 6.1 0.262249638 0.5
R 62.36 6.8 0.292343858 1
7.2 0.309540556 1.5
7.5 0.322438079 2
7.85 0.337485189 3
8.1 0.348233125 4
8.4 0.361130648 6
8.7 0.374028172 10
9.4 0.404122392 infinito

t vs 1/Ca
4
0.35
3.5 f(x) = 0.0305291042x + 0
f(x) = 0.0911576289x + 2.6190109551 R² = 0.8493544114
R² = 0.882888116 0.3
3

2.5 0.25

2 0.2
1.5
0.15
1
0.1
0.5
0.05
0
0 2 4 6 8 10 12
0
0 2 4
 ca mol 1/ca ln cao/ca
0.404122392 2.474497872 0
0.374028172 2.673595402 0.077386664
0.361130648 2.769080952 0.112477983
0.348233125 2.871639506 0.148845628
0.337485189 2.963092994 0.180196157
0.322438079 3.101370667 0.225806669
0.309540556 3.230594444 0.266628663
0.292343858 3.420629412 0.323787077
0.262249638 3.813160656 0.432420918

t vs ln Cao/Ca
0.35
f(x) = 0.0305291042x + 0.0600392404
R² = 0.8493544114
0.3

0.25

0.2

0.15

0.1

0.05

0
0 2 4 6 8 10 12
PO, Torr 86.5 164 290 360
t1/2, s 634 393 255 212
 Metodo Integra
V (L) 50 Fa0 (mmol/h) Ca(mmol/l) moles mmoles
T (K) 973 13250 43 3.133381796 3133.381796
p (atm) 5 2150 27 3.133381796 3133.381796
R(l*atm/mol* 0.082 375 15 3.133381796 3133.381796
Cao 0.062667636 62.66763593 100 9 3.133381796 3133.381796
25 5 3.133381796 3133.381796

ln(Cao/Ca)
3

2.5 f(x) = 0.0137138075x + 0.9662257302

R² = 0.7210272354

1.5

0.5

0
0 20 40 60 80 100 120 140

Metodo diferencial

t(h) Ca(mmol/l) dCa/dt grado dCa/dt grado dCa/dt grado

0.236481645 43 3.995155747 -15.3506226 0
1.457386882 27 4.277725567 -10.9445943 0
8.35568479 15 5.756669242 4.930458542 0
 31.33381796 9 9.24135011 -27.1268769 0
125.3352719 5 0.404735108 115.863048 0

grado 3 grado 4 grado 5

-0.0007 0.0003 0.0003
0.1175 -0.0577 -0.0577
3.9397 1.9495 1.9495
38.816 -16.263 0.0006
46.738 -0.0178
0.3347

Grado 4
grado 3)
50 50
f(x) = - 0.000704087x^3 + 0.1175277248x^2 - 3.9397264576x + 38.8155692624 f(x) = 0.0003440373x^4 - 0.0576604554x^3 + 1.9495300384x^2 - 16.2629
45 45
R² = 1
R² = 0.9285529437
40 40
35
35
30
30
25
25
20
20
15
15
10
10 5
5 0
0 0 20 40 60 80 100 120 14
0 20 40 60 80 100 120 140
 Metodo Integral
t(h) ln(Cao/Ca) 1/Ca
0.236481645 0.376645025 0.023255814
1.457386882 0.842008275 0.037037037
8.35568479 1.42979494 0.066666667
31.33381796 1.940620564 0.111111111
125.3352719 2.528407229 0.2

1/Ca
0.25

0.2 f(x) = 0.0012994087x + 0.0442869956

R² = 0.9308877267
0.15

0.1

0.05

0
0 20 40 60 80 100 120 140

etodo diferencial de ajuste

dCa/dt grado ln(ca) ln(-ra)

0 3.761200116 Err:502
0 3.295836866 Err:502
0 2.708050201 Err:502
 0 2.197224577 Err:502
0 1.609437912 Err:502

grado 6
-2E-11
2E-09
-0.00000007
-0.000006
0.0005
-0.0172
0.3342

Grado 4

- 0.0576604554x^3 + 1.9495300384x^2 - 16.262981684x + 46.7376334624

60 80 100 120 140

 Ca
1.2

0.8
f(x) = - 0.0053041037x + 0.738200
0.6 R² = 0.7179701019
0.4

0.2

0
0 20 40 60 80 1

Metodo difere

t, min Xa Ca dCa/dt grado dCa/dt grado dCa/dt grado

0 0 1 -0.0264 -0.0362 0.0432
2 0.1 0.9 -0.0252108 -0.03345936 0.047363176
5 0.22 0.78 -0.0234675 -0.029565 0.052749063
15 0.45 0.55 -0.0180075 -0.018305 0.063974063
28 0.61 0.39 -0.0117168 -0.00700384 0.065618816
50 0.74 0.26 -0.00315 0.0063 0.043825
80 0.82 0.18 0.00432 0.02076 -0.02144
100 0.85 0.15 0.0066 0.0338 -0.0868
160 0.9 0.1 0.00048 0.13148 -0.48544

Cao=Cbo ,(mol/l) 1 grado 3 grado 4 grado 5

 -0.0000009 0.00000002 -3E-10
0.0003 -0.000005 0.0000001
-0.0264 0.0007 -0.00002
0.9424 -0.0362 0.0011
0.9728 0.0432
0.9864

Grado 3 grado 4
1.2 1.2

1 1
f(x) = - 0.000000944x^3 + 0.0002831296x^2 - 0.0264299148x + 0.9424136627 f(x) = 1.53229083601272E-08x^4 - 5.42348250681866E-06x^3 + 0.0006676167x^2 - 0.0361920903x + 0.9728430083
0.8
R² = 0.986717875 R² = 0.9971996746
0.8
0.6
0.6
0.4
0.4
0.2
0.2
0
0 20 40 60 80 100 120 140 160 180
0
0 20 40 60 80 100 120 140 160 180
 Metodo Integral
t, min Xa Ca ln(Ca0/Ca)
0 0 1 0
2 0.1 0.9 0.105360516
5 0.22 0.78 0.248461359
15 0.45 0.55 0.597837001
28 0.61 0.39 0.94160854
50 0.74 0.26 1.347073648
80 0.82 0.18 1.714798428
100 0.85 0.15 1.897119985
160 0.9 0.1 2.302585093

Cao=Cbo ,(mol 1

Ca ln(Ca0/Ca)
2.5
f(x) = 0.0146452008x + 0.3012173562
R² = 0.9103831648
2

1.5
x) = - 0.0053041037x + 0.7382006271
= 0.7179701019
1

0.5

20 40 60 80 100 120 140 160 180 0

0 20 40 60 80 100 120 140 160 180

Metodo diferencial de ajuste

ln(-ra)
dCa/dt grado 6 ln(ca) ln(-ra)
0
-0.0502 0 -2.99174025 -1.6 -1.4 -1.2 -1 -0.8 -0.6 -0.4 -0.2 0
-1
-0.0434642387 -0.10536052 -3.13581678
-2
-0.0349592438 -0.24846136 -3.35357236
-0.0171774813 -0.597837 -4.06415598 f(x) = 2.8542672588x - 2.7026404494 -3
R² = 0.9294083829 -4
-0.0080730045 -0.94160854 -4.81922956
-0.000825 -1.34707365 -7.10012717 -5

0.0170256 -1.71479843 Err:502 -6

0.0298 -1.89711998 Err:502 -7

0.2194192 -2.30258509 Err:502 -8

grado 6
 7E-12
-0.000000003
0.0000005
-0.00004
0.0018
-0.0502
0.9957

grado 5 grado 6
1.2 1.2

1 1
167x^2 - 0.0361920903x + 0.9728430083 f(x) = - 2.54523742833544E-10x^5 + 1.03297806495838E-07x^4 - 1.56084868529771E-05x^3 + 0.0011306352x^2 - 0.0431676399x + 0.9863729793 f(x) = 6.76812219960419E-12x^6 - 2.94666438104828E-09x^5 + 4.91314455061892E-07x^4 - 4.0648638118156E-05x^3 + 0.0018386835x^2 - 0.0501693854x + 0.995692754
0.8R² = 0.9992293873 R² = 0.9998478232
0.8
0.6
0.6
0.4
0.4
0.2
0.2
0
0 20 40 60 80 100 120 140 160 180
0
0 20 40 60 80 100 120 140 160 180
 1/Ca
1
1.111111111
1.282051282
1.818181818
2.564102564
3.846153846
5.555555556
6.666666667
10

1/Ca
12

10
f(x) = 0.0564589112x + 1.0002113233
8 R² = 0.9999385915

0
0 20 40 60 80 100 120 140 160 180
140 160 180

0
-0.4 -0.2 0
-1
-2

494 -3
-4
-5
-6
-7
-8
x^4 - 4.0648638118156E-05x^3 + 0.0018386835x^2 - 0.0501693854x + 0.9956927543
FAO, mol h-1 12 25 58 90 150
CA, mol h-1 0.22 0.3 0.42 0.49 0.57
300
0.69
t, min 10 15 40 55 70
CA* mol l-1 3.8 3 2.5 2.2 1.9
 85 100 120
1.72 1.5 1.35
T, °C 694 757 812
Po, atm 0.392 0.48 0.46
t1/2, s 1520 212 53
FAO, mol h-1 12 25 58 90 150
CA, mol l-1 0.22 0.3 0.42 0.49 0.57
300
0.69