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6 Online Chapter Test

Online Chapter Tests

1. SOLUTIONS

Time : 3 Hrs. MM : 45
General Instructions
1. This test consists of 29 questions, grouped according to their type, consist a total of 45 marks.
2. Marks related to each question are mentioned clearly.
3. Time allotted to complete this test is 3 hrs.
4. It is advisable that you should attempt this test in a single slot of time and without the help of books or teachers.
5. To assess your chapterwise understanding, once you complete this test compare your answers/solutions with our
solutions given with each test and score yourself.

I. Multiple Choice Questions [1 Mark each]

1. A solute in 1 molal aqueous solution has mole fraction

(a) 0.1770 (b) 0.00177 (c) 0.0177 (d) 0.344
2. Which statement is false about osmotic pressure (p), volume (V) and temperature (T)?
(a) pµT , at constant V (b) pV is constant if, T is constant
1
(c) pµ , at constant T (d) pµV , at constant T
V
3. For the solvent decrease in vapour pressure depends on
(a) quantity of solution (b) nature of solution
(c) quantity of non-volatile solute (d) nature of non-volatile solute
4. DTb represents
(a) depression in boiling point of solvent in solution (b) elevation in boiling point of solvent in solution
(c) Both (a) and (b) (d) None of these
5. A compound undergoes tetramerisation in a solvent. The van’t Hoff factor is
(a) 0.5 (b) 0.125 (c) 0.25 (d) 2.0
6. Among the following compounds, which one show highest value for van’t Haff factor?
(a) Glucose (b) NaCl (c) Urea (d) K 4 [ Fe(CN ) 6 ]

II. True and False [1 Mark each]

7. Common salt is less soluble in water than sugar.
8. van’t Hoff factor of Na[Ag(CN)2] is nearly 4.
9. Partial pressure of the gas in vapour phase (P) is proportional to mole fraction of gas.
10. Colligative property only depends on the amount of solute.
11. At the same temperature, Henry’s constant (KH ) is smaller for O2 than N2.

III. Fill in the Blanks [1 Mark each]

12. van’t Hoff factor for 0.1 M ideal solution is ……… .
13. ……… are the constant boiling mixture of two miscible liquids of definite mole fraction.

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SOLUTIONS 7

14. ……… phenomenon is used in desalination of water.

15. DV mix for a non-ideal solution showing positive deviation is ……… .
16. ……… colligative property is best for determination of molecular mass of polymers.

IV. Match the Columns [2 Marks each]

17. Match the Column I with Column II.

(a) Osmotic pressure (p) DTb = K b m
(b) Henry’s law (q) p = c1 p 1°+ c2 p°2

(c) Boiling point elevation (r) p x = KHc

(d) Rault’s law (s) p = CRT

18. Match the Column I with Column II.

(a) Binary solution (p) Solution in solid phase
(b) Ideal solution (q) Carbondisulphide + acetone
(c) Solid solution (r) Solution with two components
(d) Non-ideal solution (s) Benzene + toluene

V. Very Short Answer Type Questions [1 Mark each]

19. How does water from the bottom of soil rises to the top of tree?
20. Vapour pressure of a solution of glucose in water is less than that of water. Explain.
21. Which one will have higher boiling point 0.1 M sucrose or 0.1 M KCl solution?
22. X and Y liquids on mixing produces cold solution. Which type of deviation is shown by them?
23. Melting point is generally considered as a criterian for testing purity of a compound. Why?

VI. Short Answer Type (I) Questions [2 Marks each]

24. NaCl and glucose solution with 0.1 M concentration have osmotic pressure of 0.465 atm and 0.245 atm.
Find van’t Hoff factor and degree of dissociation for NaCl solution.
25. Write the limitations for Henry’s law.

VII. Short Answer Type (II) Questions [3 Marks each]

26. Which one of the following has higher concentration a 1 molar or 1 molal solution.
27. Write two advantages of osmotic pressure method over other colligative properties.

VIII. Long Answer Type Questions [5 Marks each]

28. (i) Differentiate between an ideal and non-ideal solution.

(ii) Vapour pressure for water at a given temperature is 23.75 mm of Hg. Calculate the vapour pressure of
5% aqueous solution of urea at the same temperature.
29. (i) Discuss three types of solution on the basis of concentration and applied osmotic pressure.
(ii) What does the value of ‘i ’ greater than 1 and less than 1 represents?

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