ALCOHOLS PHENOLS AND ETHERS DPP-1

ICONIC CHEMISTRY CLASSES IITian Sushil Kumar

(B.Tech, IIT Madras)
ALCOHOLS PHENOLS AND ETHERS (M.Tech, IIT Madras)
CHEMISTRY TEST-1
1. Classify the following as primary, secondary and tertiary alcohols :
CH3
(i) CH3  C  CH2OH ; (ii) H2C  CH  CH2OH ; (iii) CH3  CH2  CH2  OH

CH3

CH3
Sol.: (i) CH3  C  CH2OH ; (ii) H2C  CH  CH2OH ; (iii) CH3CH2CH2OH
Pr imary (1* ) Primary (1* )

CH3
Primary (1*)

2. Write the IUPAC name of the following compound : H3C  C  C  CH2  OH

Sol.: H3C  C  C  CH2  OH H3C Br

H3C Br
2-Bromo-3-methylbut-2-en-1-ol
CH=CH–CH 2OH
3. Write the IUPAC name of the following compound :

CH=CH–CH2–OH

Sol.:

IUPAC name :3-Phenylprop-2-en-1-ol

CH3

4. Write the IUPAC name of the following compound : CH3  O  C  CH3

CH3

CH3
Sol.: CH3  O  C  CH3

CH3
IUPAC name : 2-Methoxy-2-methylpropane

CH2–CH2–OH
5. Write the IUPAC name of the given compound :

Sol.: 2-Phenylethanol
O2N OH
6. Write the IUPAC name of the given compound :
NO2
Sol.: 2,5- Dinitrophenol
7. Write the IUPAC name of the given compound : CH2  C  CH2  OH

CH3
Sol.: 2-Methylprop-2-en-1-ol
ICONIC CHEMISTRY CLASSES
Add: Ashoka Tower, Boring Canal Road, Patna-1 Cont: 7903993958, 9534286498 (1)
 ALCOHOLS PHENOLS AND ETHERS DPP-1

8. Write the IUPAC name of the given compound : HO  CH2  CH  C  CH3

Sol.: 3-methylbut-2-en-1-ol CH3

9. Name the following according to IUPAC system : CH3  CH  CH2  CH3

Sol.: Butan-2-ol OH

10. Write IUPAC name of the following compound : HO  CH2  CH  CH2  OH

Sol.: Propane-1,2,3-triol OH
11. Draw the structural formula of 2-Methylpropan-2-ol molecule,
OH
Sol.: CH3  C  CH3

CH3
2-Methylpropan-2-ol
12. Draw the structure of hex-1-en-3-ol compound
Sol.: Hex-1-en-3-ol
OH

H2C  CH  CH  CH2  CH2  CH3

CH3

13. Write the IUPAC name of the following : CH3  C  C  CH2OH

Sol.: 2-Bromo-3-methylbut-2-en-1-ol Br
14. Given the structure and IUPAC name of the product formed when propanone is reacted with
methylmagnesium bromide followed by hydrolysis.
OH
Sol.: CH3  C  CH3

CH3
2-Methylpropan-2-ol
15. Write the structure of the molecule of compound whose IUPAC name is 1-Phenylpropan-2-ol
OH

CH2  CH  CH3
Sol.:

16. Give the IUPAC name of the following compound : H2C  CH  CH  CH2  CH2  CH3
Sol.: Hex-1-en-3-ol OH
17. Write the structure of the following compound : 2-Methyl-2-ethoxypentane.
CH3

Sol.: H3C  C  CH2  CH2  CH3

OC2H5
18. Write the IUPAC name of the following compound : CH3  O  CH2  CH  CH2  CH3
Sol.: 1-methoxy-2-methylbutane CH3
19. The C – O bond is much shorter in phenol than in ethanol. Give reason.
Sol.: Due to resonance C – O bond acquires some partial souble bond character. So, in phenol C – O bond
length is smaller than ethanol

ICONIC CHEMISTRY CLASSES

Add: Ashoka Tower, Boring Canal Road, Patna-1 Cont: 7903993958, 9534286498 (2)