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Self Compacting Concrete Using Fly Ash and Silica Fumes as Pozzolanic
Material
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Baboo Rai
National Institute of Technology Patna
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Self Compacting Concrete Using Fly Ash and Silica Fumes as Pozzolanic
Material
1
Research Scholar, National Institute of Technology Patna, Bihar 800005
2
Assistant Professor, Department of Civil Engineering, NIT Patna, Bihar 800005
Abstract: A comparative study is carried out to study the effect of partial replacement of pozzolanic
materials like silica fume and fly ash by weight of cement on properties of SCC. To achieve the desired
objective 135 cube samples and 90 cylinders of self compacting concrete with different weight percentages of
fly ash and silica fume were cast to study the effect on flowability, compressive strength and split tensile
strength. The water to binder ratios for all mixes was maintained at 0.36. Further, to achieve the desirable
properties like flowability, chemical admixture was also used. The various flowability tests conducted in lab
were Slump Flow Test, J- Ring Test, L-Box Test and V-Funnel Test.
The spread for all mixes were within the specified range recommended by EFNARC (2002).
Concomitant use of both the pozzolanic material in SCC negated the undesirable effects of each other on
flowability characteristics. Acceptable correlation exists between V-Funnel time and T500 time for all SCC
mixes. The compressive strength as well as split tensile strength increased gradually when only silica fume
was used as pozzolanic material as compared to fly ash as pozzolanic material. In general the strength of all
mixes with silica fume was found to be on the higher side as compared to fly ash mixes for same w/b ratio.
Further, the loss in early strength of fly ash induced SCC mix is negated by using silica fume.
Key words: Self Compacting Concrete, fly ash, silica fumes, flowability, Compressive Strength, Split Tensile
Strength
1. Introduction
Concrete mixture, characterized by high resistance to segregation and which can be cast without
compaction or vibration are termed as Self-Compacting Concrete (SCC). Better quality concrete is observed
with substantial improvement in working conditions upon exclusion of compaction or vibration [1-3]. SCC
usually contains super plasticizers in form of high range water reducer (HRWR) and viscosity modifying
additive (VMA) which provides constancy to the mix, resulting in high resistance against bleeding and
segregation.
Moreover, as fine materials are substantial constituents of SCC, the replacement of mineral
admixtures with cement in SCC enhances its fresh and hardened properties and also reduces its cost [4].
Cementitious materials replaced partly with pozzolanic materials like fly ash lessens the heat of hydration and
increases the durability [5-7]. The use of fly ash minimizes the need for viscosity-modifying chemical
admixtures [8] and escalates the slump flow of the SCCs mixes.
Initially, there was no rational proportioning method for using fly ash in concrete, and researchers
used to arbitrarily replace fly ash in the concrete. Smith [9] was first to propose a mix proportioning method
for fly ash concrete. He stated that “fly ash cementing efficiency factor” (k) is defined as that part of the
pozzolanic material which can be considered as equivalent to Portland cement having the same properties as
the concrete without the pozzolanic material. Several researchers have reported that the cementing efficiency
of fly ash will also depend up on the level of replacement, type of fly ash and type of cement used [10-11]. It
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Volume 6, Issue 2, July, 2017, PP.394-407
has been reported that for w/c ratio varying between 0.5 and 0.65 the cementing efficiency of fly ash can be
taken as 0.5.
Viscosity increasing additives or fillers are utilized to avoid separation of large particles in SCC. The
effectiveness of super plasticizer is enhanced by the presence of silica fume. Recently silica fume has been
found to be very effective in manufacturing of high strength high performance concrete [12]. Moreover, the
use of both silica fume and a suitable super plasticizer is beneficial, as it allows use of low water/cement ratios
for a given workability. Silica fume used as pozzolana enriches the workability of concrete, because of its
minute grain size and durability properties that create additional cementitious products due to reaction with
the calcium hydroxide formed during Portland cement hydration [13-14]. Further, it has been reported that
viscosity and elastic stress limit decrease with the addition of silica fume in cement paste [15-16].
Aim of this research is to explore the benefits of concurrent use of silica fume and fly ash as cementitious
material. The ensuing results may permit the use of high percentage of fly ash as it is expected that the
presence of silica fume will negate some of its undesirable effects such as loss in initial strength.
2. Material Properties
2.1. Cement and fillers
Ordinary Portland Cement (OPC) of grade 43 conforming to IS: 8112-1989 [17] was used in the
present work. The various laboratory tests conforming to IS: 4031-1996 (PART 1a to 15) [18] specification
were carried out. Samples of Low calcium fly ash shown in Figure 1 were taken from Kahalgaon Thermal
Power Plant, NTPC were used ‘as received’ used in this study. The physical properties of cement and fly ash
are presented in table 1 while table 2 presents the chemical properties of fly ash. Silica fume (figure 1b) was
provided by Elkem South Asia Pvt. Ltd. The chemical and physical properties of micro silica grade 920D
were analyzed for mandatory parameters of ASTM C 1240[19] and the results are presented in table 3 and
table 4 respectively.
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Figure 1a: Fly Ash Sample Figure 1b: Silica Fume Sample
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2.5 Mix-Proportioning
The preamble of IS 10262-2009 [21] is used for mix proportioning of self-compacting concrete.
Fifteen trial mixes with varying weight percentage of fly ash and silica fume were prepared to study their
effect on flowability parameters of SCC. Further, 135 cube samples and 90 cylindrical samples were cast to
study the strength parameters of SCC mixes. For incorporating fly ash in concrete, there is no theoretical
background given in code. A guideline in the form of numerical example has been incorporated in IS: 10262-
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2009 where the total binder content is increased arbitrarily. However, in the present work, for the same water
to cement ratio, and in order that the strength and flowability of fly ash concrete be comparable with that of
conventional concrete without fly ash, a cementing efficiency factor (k) of 0.55 has been considered for the fly
ash. The water to powder ratio for all the mixes was fixed at 0.36. Further, the dose of HRWR with inbuilt
VMA was fixed at 2.2% by weight of cement. The mix proportioning for all fifteen trial mixes are given in
table 8.
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that spread diameter and L Box ratio decreases with increase in silica fume content indicating increase in
viscosity of the mix. The blocking ratio ranged from 0.7 to 0.8 which means there is increase in viscosity
which in turn retards the flow of the mix. This may be attributed to the fact that silica, in finely divided form,
reacts with calcium hydroxide which in turn leads to formation of secondary cementitious calcium silicate
hydrate which makes the concrete mix denser and more cohesive.
SSC mixes made with ternary cementitious blends of fly ash and silica fumes the flowability test
results were more consistent and a more balanced viscous flow was observed. This may be due to contrasting
particle geometry of fly ash and silica fume. These effects on flowability are similar to the results obtained by
Brooks et al (2000) [25] and Sonebi (2004) [26]. From the experimental findings it can be concluded that
concomitant use of both the pozzolanic material in SCC will negate the undesirable effects of each other on
flowability characteristics.
750
700
650
S pread Diameter in mm
726
725
710
705
700
600
680
672
670
655
652
651
620
550
584
577
565
500
0 10 20 30 40 2 4 6 8 10 2 4 6 8 10
1.2
0.8
B loc king ratio (H2/H1)
0.6
0.4
0.2
0
0 10 20 30 40 2 4 6 8 10 2 4 6 8 10
% F ly As h % S ilic a fumes % S ilic a fume +30% F ly as h
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From the visuals (figure 3) of the trial mixes using different weight percentage of silica fume and 30%
fly ash, it was observed that at 2% and 10% replacement level of silica fume and at 30% replacement level of
fly ash, no mortar halo was observed in the slump flow patty. However, a slight evidence of bleed or air
popping on the surface of SCC was observed. At 4%, 6%, 8% replacement level of silica fume with 30% fly
ash, the segregation and bleeding almost disappeared. During the flowability test, it was observed that the
addition of silica fume in fly ash induced SCC nullified the stickiness observed in mixes without silica fumes
and further, the mixes were highly cohesive.
The test methods described in EFNARC 2002 are devised specifically for SCC and are mainly
definitive. No correlation has yet been developed between the different flowability parameters to standardize
these test methods. Many researchers in the past have used T500 and V Funnel time as indicator of viscosity in
case of self-compacting concrete, and have indicated co relations between these two parameters. Through the
different flowability test results an effort has been made to develop correlation between different flowability
parameters using regression analysis. Good correlation exists between V-Funnel time and T500 time for all
SCC mixes with a correlation coefficient R2=0.9321 as indicated in figure 4a. Relationship between V-Funnel
time and T500 time has also been reported in the past and is presented in table 9. It is necessary to mention, that
different authors used different mixture constituent for SCC mixes.
Correlations were also developed between T-500 Time and L-Box Blocking Ratio and between V-
Funnel time and L Box blocking ratio with a correlation coefficient R2=0.9752 and R2=0.9308 respectively
which can be inferred from figure 4b and figure 4c respectively.
H2/H1 = 1.0596* (T500)-0.1902
H2/H1 = 4.2761 *(VFtime)-0.6663
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15
12.5
y = 0.8844x + 8.1662
10 R2 = 0.9321
V- F unnel time
7.5
2.5
0
0 1 2 3 4 5 6 7 8 9 10
T -500 time
1.2
1 y = 1.0596x
-0.1902
2
R = 0.9752
0.8
L- Box Blocking Ratio
0.6
0.4
0.2
0
0 1 2 3 4 5 6 7 8 9
T-500 Time in Sec
Figure 4b: Correlation between T-500 Time and L-Box Blocking Ratio
1.2
0.8
L B0x Blocking Ratio
y = 4.2761x-0.6663
0.6 2
R = 0.9308
0.4
0.2
0
0 2 4 6 8 10 12 14 16 18
V Funnel Time
Figure 4c: Correlation between V Funnel Time and L-Box Blocking Ratio
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Cube specimens prepared for compressive strength were tested in laboratory and different crushing
strengths were found. The results of cube compressive strength test are shown graphically in figure 5a and
figure5b. From the results it can be concluded that at 30% replacement of fly ash by weight of cement the 28
days compressive strength increased by about 1.2% as compared to the reference mix. However, the
compressive strength nominally decreased at 40% replacement of fly ash as compared to 30% replacement of
fly ash by weight of cement, and this laid the basis for optimizing the fly ash content at 30% by weight of
cement for further trial mixes. However, 56 days strength was more as compared to 28 days strength.
The compressive strength increased gradually when only silica fume was used as pozzolanic material
as compared to when fly ash was used as pozzolanic material. An increase in strength is expected due to the
pozzolanic action of silica fume. The same has been observed by Sahmaran et al (2009) [31] owing to the
physical nature of better packing and fineness of silica fume. An increase in strength is also expected due to
the pozzolanic action of silica fume as it is a highly active mineral additive when added to concrete [32,33]
(Xincheng, 1999, Paulon et al., 2004).
When fly ash and silica fume were concurrently used the compressive strength, compared to the
reference mix further increased. At 6% and 30% replacement level of silica fume and fly ash respectively, by
weight of cement the increase in 28 days compressive strength was 7% while the increase was about 9% when
percentage replacement was 8% and 30% respectively. The above observations are also true for compressive
strength at 56 days.
In general the strength of all mixes with silica fume was found to be on the higher side as compared to
fly ash mixes for same w/b ratio. The same has been reported by T. Nochaiya et al (2010) [34]. They stated
that the filler effect of adding silica fume accelerates the matrix expansion. This results in a denser
microstructure due to alkali – silica reaction leading to strength gain. Blanco et al (2006) [35], also stated the
same reasons for strength gain in case of silica fume concrete. Further, the delayed early gain in strength of fly
ash induced SCC mix is negated by using silica fume.
80
75
70
65
60
COMPRESSIVE STRENGTH IN MPa
55
50
45
40
35
30
25
20
15
10
0
0 10 20 30 40 2 4 6 8 10 2 4 6 8 10
14 Day Strength 37.87 35.56 35.77 36.72 36.65 38.12 38.31 38.72 38.19 37.74 37.84 38.48 39.52 39.37 38.26
28 Day Strength 53.26 51.52 51.82 53.86 53.46 53.56 54.24 55.54 55.91 55.69 53.85 54.94 56.77 57.95 57.18
56 Day Strength 67.52 67.82 68.56 68.97 67.76 67.92 68.48 69.52 69.94 68.56 67.96 68.94 70.78 72.05 70.89
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10
-2
-4
-6
0 10 20 30 40 2 4 6 8 10 2 4 6 8 10
% Increase / Decrease at 28 Days 0 -3.27 -2.70 1.13 0.38 0.56 1.84 4.28 4.98 4.56 1.11 3.15 6.59 8.81 7.36
% Increase / Decrease at 56 Days 0 0.44 1.54 2.15 0.36 0.59 1.42 2.96 3.58 1.54 0.65 2.10 4.83 6.71 4.99
% Fly Ash % Silica fumes Silica Fumes +30% Fly ash
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4.50
3.75
Split tensile strength (MPa)
3.00
2.25
1.50
0 10 20 30 40 2 4 6 8 10 2 4 6 8 10
4
% Increase In Tensile Strength
1.5
-1
-3.5
-6
0 10 20 30 40 2 4 6 8 10 2 4 6 8 10
% Increase at 28 Days 0 -3.18 -1.16 1.00 0.25 0.43 1.16 2.02 2.31 1.73 0.29 2.02 3.47 5.49 4.34
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4.00
3.75
3.50
y = 0.0528x + 1.1844
3.25
Split Tensile Strength
R2 = 0.8616
3.00
2.75
2.50
2.25
2.00
30.00 35.00 40.00 45.00 50.00 55.00 60.00
Figure 6c: Correlation between Cylindrical Split Tensile and Compressive Strength
4. Conclusions
The experimental findings have led to following conclusions
1. Spread diameter increases with increase in fly ash percentage thus indicating that fly ash lowers the
viscosity of the SCC mixes which in turn results in segregation. In contrast, Spread diameter and L
Box ratio decreases with increase in silica fume content indicating increase in viscosity of the mix.
2. Concomitant use of both the pozzolanic material in SCC negated the undesirable effects of each other
on flowability characteristics. Addition of silica fume in fly ash induced SCC nullified the stickiness
observed in mixes without silica fumes and further, the mixes were highly cohesive.
3. Acceptable correlation exists between V-Funnel time and T500 time for all SCC mixes. The
correlations presented in this paper may be helpful in standardizing the flowability test methods.
4. The compressive strength as well as split tensile strength increased gradually when only silica fume
was used as pozzolanic material as compared to when fly ash was used as pozzolanic material
5. In general the strength of all mixes with silica fume was found to be on the higher side as compared to
fly ash mixes for the same w/b ratio. Further, the loss in early strength of fly ash induced SCC mix is
negated by using silica fume.
This paper explored the benefits of concurrent use of silica fume and fly ash as cementitious material in SCC.
The experimental results presented here may lead to results that will encourage the use of high percentage of
fly ash with silica fume as it will negate some of the undesirable effect of fly ash such as loss in initial
strength.
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Journal of Engineering Technology (ISSN: 0747-9964)
Volume 6, Issue 2, July, 2017, PP.394-407
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