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IIT2020, (Two Year CRP(18-20)-RIT-III-CPM -1

FIITJEE INTERNAL TEST


RANK IMPROVEMENT TEST – III
Batches: NWCM820X1R - X4R, NWTR820C01, D01, CAMP820, NWCM820G1W, NWCM820X1W
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IIT- JEE 2020
QP CODE: 124315
Time: 3 hours Maximum Marks: 264
• Please read the instructions carefully. You are allotted 5 minutes specially for this purpose.
• You are not allowed to leave the examination hall before end of the test.
• Use Blue/Black Ball Point Pen only for writing particulars on Side–1 and Side–2 of the
Answer Sheet. Use to Pencil is strictly prohibited.

Instructions
Note:
1. The question paper contains 3 sections (Sec-1, Chemistry, Sec-II, Physics & Sec-III, Mathematics.)
2. Each section is divided into two parts, Part-A & C.
3. Part – A contains 16 questions which are further divided as follows:
❖ PART – A (01 – 10) contains 10 Multiple Choice Questions which have One or More Correct answer.
For each question in the group Q. 1 – 10 of PART – A you will be awarded
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −2 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in −2
marks, as a wrong option is also darkened.
❖ PART – A (11 – 16) contains 2 Paragraphs. Based upon each paragraph, 3 Multiple Choice Questions. Each
question has four choices (A), (B), (C) and (D), out of which only one is correct. Each question carries +4
marks for correct answer and zero marks if no bubble is darkened. In all other cases, minus one(–1) mark
will be awarded.
4. PART-C (1 – 6) contains 6 Numerical Based questions with Single Digit Integer as answer, ranging from 0 to
9 and each question carries +4 marks for correct answer and zero marks if no bubble is darkened. In all
other cases, minus two (–1) mark will be awarded.
Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of
your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
5. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.

Name of the Candidate :

Enrolment Number :

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IIT2020, (Two Year CRP(18-20)-RIT-III-CPM -2

Section – I (Chemistry)
PART – A
(Multiple Correct Choice Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.

1. Which of the following statement(s) is/are correct?


(A) Zero order reactions are complex reactions
(B) A reaction having first order may be either elementary or complex reaction
(C) A reaction having second order reaction must have molecularity = 2
(D) A reaction with molecularity = 2 must be a second order reaction

2. The degree of dissociation()


D−d
=
(n − 1) d
Incorrect match for the equilibrium (A, B & C are in gaseous phase)
n 2n n n
(A) A B+ C (B) A B+ C
3 3 2 3
n n n n
(C) A B+ C (D) A B+ C
4 4 2 5

3. Predict correct statement(s)


(A) If KC for a reaction at 25oC is 0.02 and at 50oC is 0.002, the reaction is endothermic in forward
direction.
(B) 1% CO2 in air will be sufficient to prevent dissociation of M2CO3 ( s ) M2O ( s ) + CO2 ( g) , if
KP is 0.0095 atm.
(C) Equilibrium constant depends on temperature.
(D) Equilibrium constant depends on stochiometric coefficients of reactants and products.

4. In the reaction, C ( s ) + CO2 ( g) 2CO ( g) , the equilibrium pressure is 12 atm. If 50% of the
CO2 reacts, then
(A) KP will be equal to 16
(B) KP = KC
(C) The initial pressure = 8
(D) The partial pressure of CO2 = 4 atm at equilibrium

5. Which of the following reactions are irreversible ones?


(A) Pb (NO3 ) 2 ( aq) + 2NaI (aq) ⎯⎯ →PbI2 ( s ) + 2NaNO3 (aq)
(B) AgNO3 ( aq) + HCl (aq) ⎯⎯
→ AgCl ( s ) + NaNO3 (aq)
(C) 2Na ( s) + H2O (l) ⎯⎯
→ 2NaOH (aq) + H2 ( g)
(D) KNO3 (aq) + NaCl (aq) ⎯⎯
→KCl (aq) + NaNO3 (aq)
space for rough work

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6. In Arrhenius equation : k = Ae–Ea/RT


(A) The pre exponential factor has the units of rate of the reaction
(B) The pre exponential factor has the units of rate constant of the reaction
(C) The exponential factor is a dimensionless quantity
(D) The exponential factor has the units of reciprocal of temperatures
7. Which of the following is/are true for the first order reaction?
(A) t 3 4 = 2t1 2 (B) t15 16 = 4t1 2 (C) t15 16 = 3t 3 4 (D) t 7 8 = 2t 3 4

8. Which of the following change(s) take(s) place by increasing the average energy of reactant
molecules?
(A) The activation energy of forward reaction decreases
(B) The value of rate constant increases
(C) Rate of reaction increases
(D) The fraction of molecules crossing the energy barrier increases
9. Which of the following statement(s) is/are correct for a zero order reaction?
(A) The unit of rate constant is mol L-1 sec-1
(B) The unit of half-life is time-1
(C) The half-life time is directly proportional to the initial concentration of reactant
(D) The rate of reaction is directly proportional to temperature

10. The rate of disappearance of A at two temperatures is given by A B


−d[A]
(i) = 2  10−2 [A] − 4  10−3 [B] at 300K
dt
−d[A]
(ii) = 4  10−2 [A] − 16  10−4 [B] at 400K
dt
From the given values of heat of reaction which are incorrect.
(A) 3.86 kcal (B) 6.93 kcal (C) 1.68 kcal (D) 1.68 × 10−2 kcal
PART – A
(Single Correct Choice Type Q. No. 11 - 16)
Comprehension Type
Paragraph for question nos. 11 – 13

Variation of equilibrium constant K with temperature is given by Van’t Hoff equation


So Ho
nK = −
R RT
From this equation, Ho can be evaluated if equilibrium constant K1 and K2 at two temperature T1 and T2 are
know
K  Ho  1 1 
log  2  =  − 
 K1  2.303R  T1 T2 

11. For an isomerisation X ( g) Y ( g) , the temperature dependency of equilibrium constant is given


by
1000
nK = 2 −
T
The value of So at 300 K is
2
(A) 2R (B) (C) 1000 R (D) none of these
R
space for rough work

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IIT2020, (Two Year CRP(18-20)-RIT-III-CPM -4

12. Select the correct statement


(A) value of Keq always increases with increasing temperature
(B) for exothermic reaction value of Keq increases with decreasing temperature
(C) for endothermic reaction value of Keq increases with decrease in temperature
1
(D) for exothermic reaction slope of log K vs is negative
T

13. The equilibrium constant KP for the following reaction is 1 at 27oC and 4 at 47oC.
A ( g) B ( g) + C ( g)
Calculate the enthalpy change for the reaction B ( g) + C ( g) A ( g) (Given R = 2 cal/mol-K)
(A) -13.31 Kcal mol-1 (B) 13.31 Kcal mol-1 (C) -19.2 Kcal mol-1 (D) 55.63 Kcal mol-1

Paragraph for question nos. 14 – 16

Radioactive disintegration is a first order reaction and its rate depends only upon the nature of nucleus and
does not depend upon external factors like temperature and pressure. The rate of radioactive
disintegration(activity) is represented as

dN
− = N
dt
Where  = decay constant, N = no. of nuclei at time t, N0 = initial no. of nuclei
The above equation after integration can be represented as
2.303 N
= log 0
t N

14. Half life period of U237 is 2.5  105 years. In how much time will the amount of U 237 remaining be only
25% of the original amount?
(A) 2.5  105 years (B) 12.5  105 years (C) 5  105 years (D) 106 years

15. Calculate the half life period of a radioactive element which remains only 1/16 of its original amount in
4740 years.
(A) 1185 years (B) 2370 years (C) 52.5 years (D) none of these

16. What is the activity in Ci(curie) of 1.0 mole of Plutonium-239? (t1/2 = 24, 000 years)
(A) 1.49 Ci (B) 14.9 Ci (C) 5.13  1011 Ci (D) None of these

PART – C
This section contains 06 multiple choice questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive)

1. 2X ( g) + 3Y ( g) ⎯⎯
→ 4Z ( g)
What would be the rate of above reaction in mol L-1 s-1 unit if the rate of formation of ‘Z’ is 8 mol L-1s-1?
space for rough work

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2. For a second order reaction


T75% = Xt50%
Find the value of X

3. The frequency factor(A) of a chemical reaction with zero activation energy is 8 sec –1. What is the rate
constant of the reaction in sec–1 unit?

4. To the system,
LaCl3 (s) + H2O(g) LaClO(s) + 2HCl(g) − Heat
already at equilibrium, more water vapour is added without altering temperature or volume of the
system. When equilibrium is re-established, the pressure of water vapour is doubled. and the
pressure of HCl present in the system increases by a factor of 21/x, what is the value of X?

5. At temperature T, a compound AB2(g) dissociates according to the reaction 2AB2 (g)


2AB(g) + B 2 (g) with degree of dissociation , which is small compared with unity. The expression for
PT  x
Kp in terms of  and the total pressure PT is . What is the value of x–y?
y

6. The Kp for the reaction N2O4 (g) 2NO2 (g) is 640 mm at 773 K. Then the pressure at which the
dissociation will be 50% is 120x. The value of x is :
space for rough work

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IIT2020, (Two Year CRP(18-20)-RIT-III-CPM -6

Section – II (Physics)
PART – A
(Multiple Correct Choice Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.

1. Two friends P and Q (each weighing 40 kg) are sitting on a frictionless platform at some distance d
apart. P rolls a ball of mass 4 kg towards Q which Q catches. Then, Q rolls the ball towards P and P
catches it. The ball keeps on moving back and forth between P and Q. The ball has a fixed speed 5
ms–1 on the platform. Choose the correct option(s).
10 –1
(A) Speed of P after he catches the ball for the first time is ms
11
10 –1
(B) Speed of P after he catches the ball for the first time is ms
9
(C) The centre of mass of the system remains stationary irrespective of the direction of motion of the
ball.
(D) P can roll the ball only for 6 times.

2. Which of the following is/are correct?


(A) if centre of mass of three particles is at rest and it is known that two of them are moving along
different lines then the third particle must also be moving.
(B) If centre of mass remains at rest, then the net work done by the forces acting on the system must
be zero.
(C) If the centre of mass remains at rest then the net external force must be zero.
(D) If the speed of the centre of mass is changing then there must be some net work being done on
the system.

3. A ball moving with velocity v hits a massive wall moving towards the ball with a velocity u. An elastic
impact lasts for time t
m( u + v )
(A) the average elastic force acting on the ball is
t
2m ( u + v )
(B) the average elastic force acting on the ball is
t
(C) the kinetic energy of the ball increases by 2mu ( u + v )
(D) the kinetic energy of the ball remain the same after the collision

4. Four bricks each of length l are put on the top of one another in such
a way that part of each extends beyond the one beneath. The largest
equilibrium extension are I
II
III
(A) top brick over hanging the one below by IV
2
(B) second brick from top over hanging the one below
4
(C) third brick from top overhanging by bottom one by
6
11
(D) the total overhanging length on the edge of the bottom brick is
12
space for rough work

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5. If the external forces acting on a system have zero resultant, the centre of mass
(A) must not move (B) must not accelerate (C) may move (D) may accelerate

A
6. Three particle A,B and C of equal masses move with equal speeds v
along the medians of an equilateral triangle . After collision A comes
to rest while B retraces its path with speed v. Then
(A) the speed of C is V
(B) direction of motion of C OA
O
(C) the speed of C is 2V
(D) direction of motion of C BO
B C

7. A cannon shell is fired to hit a target at a horizontal distance R, however it breaks into two equal parts
at its highest point, one part returns to the cannon. The other part
(A) will falls at a distance R beyond target (B) will falls at a distance 3R beyond target
(C) will hit the target (D) have nine times kinetic energy of first

8. A particle of mass ‘m’ is moving towards a body of infinite mass at rest. If the particle collides
elastically and head on then,
(A) momentum of the particle will change
(B) momentum of the body of infinite mass will change
(C) momentum of the system containing particle and infinite mass body will change.
(D) none of these

9. Three identical blocks kept in a straight line on a friction


less horizontal surface. The coefficient of restitution is u
1
for all collisions. If the left mass block has been A B C
2
given a velocity ‘u’ towards right as shown in figure,
then finally
1 13
(A) speed of left most block = u (B) speed of left most block = u
4 64
3 15
(C) speed of middle block = u (D) speed of middle block = u
16 16

10. Suppose a cannon of mass M fires a shell of mass m with initial velocity u (relative to cannon) at an
angle  to the ground. In the process cannon recoils freely (friction neglected). Then:
u2 sin 2 M u2 sin 2
(A) Range of the projectile is (B) Range of the projectile is
g m g
M u2 sin 2 M u2 sin 2
(C) Range of the projectile is (D) Range of the projectile is
M+m g M−m g
space for rough work

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PART – A
(Single Correct Choice Type Q. No. 11 - 16)
Comprehension Type
Paragraph for question nos. 11 – 13

A small particle travelling with a speed u towards right collides with


a spherical body of equal mass as shown in figure. The centre of
u
3 R 3/2
this spherical body is located a distance R away from the
2
direction of motion of the particle. The coefficient of restitution R

1
between them is . Then answer the following questions.
2

11. The speed of the sphere after the collision


4 3u 3u
(A) (B) (C) (D) none of these
8 8 4

12. The speed of the small particle after the collision


4 7u 3u
(A) (B) (C) (D) none of these
8 8 8

13. The angle of deviation of the motion of the small particle due to collision will be
3 3 3 3
(A) sin−1 (B) cos−1 (C) 30° (D) none of these
14 14
Paragraph for question nos. 14 – 16

M
A
A small block of mass M moves on a frictionless surface of
v
an inclined plane, as shown in figure. The angle of the incline 60o B
suddenly changes from 60o to 30o at point B. The block is initially at
rest at A. Assume that collisions between the block and the incline
are totally inelastic (g = 10 m/s2). 30o C
3m 3 3m

14. The speed of the block at point B immediately after it strikes the second incline is
(A) 60 m / s (B) 45 m / s (C) 30 m / s (D) 15 m / s

15. The speed of the block at point C, immediately before it leaves the second incline is
(A) 120 m / s (B) 105 m / s (C) 90 m / s (D) 75 m / s

16. If collision between the block and the incline is completely elastic, then the vertical (upward)
component of the velocity of the block at point B, immediately after it strikes the second incline is
(A) 30 m / s (B) 15 m / s (C) 0 (D) − 15 m / s
space for rough work

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PART – C
This section contains 06 multiple choice questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive)

The mass per unit length of a rod varies as m = 


 M0  x where M is a constant and x is the distance
1.  0
 L 
of any point on rod measured from one end. Centre of mass of the rod from the given end is at a
KL
distance on the rod. Find the value of ‘K’.
3

2. Three objects A, B and C are kept in a straight line on a


frictionless horizontal surface. These have masses m, 2m
and m, respectively. The object A moves towards B with a 2m
speed 9 ms–1 and makes an elastic collision with it. m m
Thereafter, B makes completely inelastic collision with C. All A B C
motions occur on the same straight line. Find the final speed
(in ms–1) of the object C.

M
3. A block of mass M is placed on the top of a bigger block of mass 10
M as shown in figure. All the surfaces are frictionless. The system is
released from rest, then find the distance (in metre) moved by the
10 M
bigger block at the instant the smaller block reaches the ground:

22 m

4. A sphere of mass m collides elastically with another stationary sphere of mass m/2 obliquely. Both the
spheres are smooth and there are no external forces acting on them. Maximum angle through which

sphere of mass m can be deflected wrt its initial direction of motion is . Value of x is
x

5. Two blocks of masses m1 = 2 kg and m2 = 5 kg are moving in


the same direction along a frictionless surface with speeds
10 m/s and 3 m/s respectively, m 2 being ahead of m 1. An
ideal spring with k = 1120 N/m is attached to the back side of
m2. The maximum compression of the spring when the
 1
blocks collide is   metre .
n
Y

6. Figure shows a uniform disc of radius R from which


a hole of radius R/2 has been cut out from left of
the centre and is placed on right of the centre of (-R/2,0) (-R/2,0)
disc. The centre of mass of resulting disc is at a
distance R/n from centre of uniform disc. Find the
value of n

space for rough work

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IIT2020, (Two Year CRP(18-20)-RIT-III-CPM -10

Section – III (Mathematics)


PART – A
(Multiple Correct Choice Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.

x4 + 1
1.  x6 + 1 dx is equal to

1 1
(A) tan−1 x − cot −1 x3 + c (B) tan−1 x + tan−1 x3 + c
3 3
1 1
(C) tan−1 x3 − cot −1 x + c (D) − tan−1 x − tan−1 x3 + c
3 3

sin x − cos x
2. If I =  ( sin x + cos x ) sin x cos x + sin x cos x
2 2
dx = cosec–1(g(x)) + c  x  R, then

(A) g(x) = 1 + sin2x (B) g(x) = 1 – sin2x (C) g(x)  0 (D) – 1  g(x)  1

1
dx
3. If I = then
0 4 − x 2 − x3
   
(A) I (B) I (C) I (D) I
6 6 4 2 4

1 1

4. Let I =  1 + x dx and J =  1 − x dx , then correct statement is


0 1− x 0 1+ x
(A) I + J = 2 (B) I − J =  (C) I = 2 +  (D) J = 4 − 
2 2

5. Let the function f(x) be thrice differentiable and satisfies f(f(x)) = 1 − x for all x  [0,1], If J =  f(x)dx
0

and f " ()
4 =0
5
, then which of the following is(are) true?

(A) f ( ) + f ( ) = 1
1 2
3 3
1
(B) J =
2
1 3
(C) f "(x) = 0 has at least one root in x  ,
4 4 ( )
1 4
(D) f ”(x) = 0 at least one root in x  ,
2 5 ( )
space for rough work

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4
dx
6.

3
3 log x
is

1
(A) less than 1 (B) less than 2 (C) greater than (D) none of these
2

1
7. If I =

0
(1 + x ) (1 + x3 )dx , then

15 15
(A) I  (B) I 
8 8
(C) the integral is not evaluable (D) none of these

x2
dt
8. If f(x) =  (log t)
x
2
, x  0 , then f(x) is

(A) Monotonically increasing in (2, ) (B) monotonically increasing in (1, 2)


(C) Monotonically decreasing in (2, ) (D) monotonically decreasing in (0, 1)

9. Let f ( x ) be a continuous and positive function in [0, 5] and the area bounded by the graph of
y = f ( x ) and x-axis for 0  x  5 is 8. A(c) denotes the area between the graph of y = f ( x ) and x-
axis for 0  x  c and B(c) denotes the area between the graph of y = f ( x ) and x-axis for c  x  5 .
A (c ) dR
Also R ( c ) = , R ( 3 ) = 1 and = 7 at c = 3,, then
B (c ) dc
(A) The value of A3 = 4 (B) Value of A' (5) + B' (5) = 0
(C) Value of f (3) = 16 (D) The value of f (3) = 14

−x2
Consider a circle x 2 + ( y − 1) = 1 and the parabola y =
2
10. . The common tangents to the two
4
curves constitute a triangle ABC, the point A and B being on the x-axis and C on the y-axis. CA
produced touches the parabola at P and CB produced touches the parabola at Q, then which of the
following statements are correct?
−x2
(A) Area enclosed by the parabola y = , the x-axis and the lines AP and BQ is 3 sq. units.
4
(B) Area of the portion between the upper arc of the circle and the common tangents QC and PC is
 
 3 − 6  sq. unit
 
(C) Equation of common tangent BC is 3x − y + 3 = 0
(D) Equation of common tangent BC 3y − x + 3
space for rough work

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IIT2020, (Two Year CRP(18-20)-RIT-III-CPM -12

PART – A
(Single Correct Choice Type Q. No. 11 - 16)
Comprehension Type
Paragraph for question nos. 11 – 13

Consider a polynomial f(x), which satisfies the following conditions:


f(x) = f (x) , x  R
2
(i)
1
19
(ii)
 f(x)dx = 12
0
(iii) f(0) > 0

11. The function f(x) can be


(A) a linear function (B) a quadratic function
(C) a cubic function (D) any polynomial of even degree

12. The value of f(0) is


1 1
(A) 0 (B) (C) (D) 1
4 2

13. The function f(x) is


(A) even (B) odd
(C) neither even nor odd (D) may be either even or odd

Paragraph for question nos. 14 – 16


Consider the integrals of the form: I = ex ( f(x) + f (x)) dx .
By product rule considering exf(x) as first integral and ex f(x) as second one, we get

 
I = ex f(x) − ex f (x)dx + ex f (x)dx = e x f(x) + c .

e ( f(x) + f (x)) dx = ex f(x) + c .


x
Hence

 1 + sin x cos x 
e
x
14.   is equal to
 cos2 x 
(A) ex sec2x + c (B) ex tan x + c (C) ex log |secx| + c (D) none of these

 1 1 
15.   ln x − (ln x) 2  dx is equal to

x
(A) ln(lnx) + c (B) x + ln x + c (C) +c (D) none of these
ln x
space for rough work

FIITJEE Ltd., Punjabi Bagh Centre, 31, 32, 33 Central Market, West Avenue Road, Punjabi Bagh, New Delhi – 110026, Ph: 011 - 45634000
IIT2020, (Two Year CRP(18-20)-RIT-III-CPM -13

 e (tan x − logcos x)dx = F(x) , where F(x) = f(x) log |sec x| with F(0) = 0, then range of f(x) is
x
16. If
(A) (−, ) (B) R+ (C) R− (D) R − {1}

PART – C
This section contains 06 multiple choice questions. The answer to each question is a single digit integer, ranging from 0
to 9 (both inclusive)

 x  f (x)
1. Let f be a differentiable function satisfying the condition f   = ( y  0, f ( y )  0 )
 y  f (y)
 x, y  R and f ' (1) = 2 . If the smaller area enclosed by y = f ( x ), x2 + y2 = 2 is A, then find [A],
where [.] represents the greatest integer function.

 1− x
2
2. dx is equal to _______
−2

k k
3. Let f be a positive function. Also let I1 =  xf ( x (1 − x ) ) dx, I2 =  f ( x (1 − x ) ) dx , when
1−k 1−k
I2
2k − 1 > 0. Then is equal to ________
I1

x
 1 2 ln t
4. If F (x) = f ( x ) + f   , where f (x) =  1 + t dt , then 2F (e) equals ________
x 1

5. Number of non-negative integral values of a satisfying


 /2
 2  cos 3x 3   a2
 a  4 + 4 cos x  + a sin x − 20 cos x dx  − 3 is ______
   
0

 /2
  2
6. For a positive integer n, let In =   2 − | x |  cos 2nx dx . If nlim ( I1 + I2 + I3 + I4 + ... + In ) = , then the
− /2   → k
1 1 1 1 1 2
value of ‘k’ by using rule + + + + + ... = , is _______
12 22 32 42 52 6
space for rough work

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