a

fs B 'ulll;i' An electron falls from rest through a vertical

l. A carbon resistor of(47 t 4'7) kA is to be marked 4.
distance h in a uniform and vertically upward
with rings of diiTerent colours for its
directed electric field E The direction of electric
will be
identification. The colour code sequence freld is now reversed, keeping its magnitude the
(1) - Yellow - Orange - Silver
Violet same. A proton is allowed to fall from rest in it
it ro,lgh th" same vertical distance h' The time of
Yellow - Violet - Orange - Silver electron, in comparison tn the time of
uw$
(3\ Yellow - Green - Violet - Gold
iuff
"itft" Proton
fall ofthe t.
J I
t
(4) Green - Orange - Violet - Gold (/ smaller I
\,/ (2)
5 times great€r "f
2. A battery consists of a variable number tr' of
(3) 10 times greater
identical cells Gaving internal resistance 'r'
each) which are connected in series 'The (4) equal
terminals of the battery are short-circuited and b. A tuning fork is used to produce resonance in a
iv6i"h of trr" gtuprr" glass tube. The length of the air mlumn in this
s correct relationship between I and n ? lube can be adjusted by a variable piston' At
room temperatu re of 27"C two successive
tf
I
t +r-- resonances are produced at 20 cm and 73 cm of
column length. If the frequency o115s tr"ning fork
is 320 Hz, the velocity of souad in air at 27'C is
O --+n
(1) 330 m/s
I (2) 339 m/s
Q)
(3) S5O m/s
(4) 300 m/s
o --+n
6 A pendulum is hung from the roof of a
I sulficiently high building and is moving freely to
(3) t and fro like a simple harmonic oscillator' Ttre
acceleration of the bob of the pendulum is
O . --+n 2O mls2 at a distance of 5 m from the mean
position. The time period of oscillation is

I (1) zn6 4" ola

(4) t
2_
O --rn
19ns
(3) 2a
(4) ls
r ,d.
T
Tlt
?In 4p
T
19v
az
b!".
.?
tI'x
7-
s

3. A set of 'n' equal resistors, o,[ value B each, are plates

7. . The electrostatic force between the metal
cop4elt -ed in series t4 .a batt€ry of emf E an-d C having a
of an isolated parallel plate capaqpJ
internai resistance !li. fire currrint drawn is I' e."a area A, is ( '-
Now, the h'resistori are qounected in parallel to "ir.g"independent of the distance '\( between the
JD/
the same battery. Then the current ilrawn fr.om
n; $,,/ .vtates.
rn is
battery becomes 10 I. the talue bf
gq" :L' Iinearly prbportional to tlre distance
]L= e)
(1) 10 Sta(t'?4'. NR ? between the Plates'
(2) 11 vzify,t -- u
I (3) to the square root of the
' 6'" 6?-
vo proportional
ilistance between t'he Plates'
(3) 20 a\ r
(4) I ?du U .ri
2 -.
(4) inversely proportional
between the Plates.
to the distance

!! f Fon noucs wonx tof c English

AcHLA/DD/Pas€z n SP AC
,t'
I
hQ = ,/ zI u)9 ' r\ ..i"
YI: (or V- nr (oR.
-1-

n1 t0K
F-
n
2-- lo . \,,
Y-,o" E- .rf ny' "lgy
h
st\ ?n
8. An electron of mass m with an initial velocity 12. In the circuit shown in the figure, the input
voltage V; is 20 V, VsB = 0 and Vcp = 0. The
V i (V0 > 0) enters an electric field
= V0
values of Ig, Ig and P are given by
E =-Eoi (E0=constant>0)att=0. If \is . 20v.
its de-Broglie wavelength initially, then its
de-Broglie wavelength at time t is RC 4ka
l.s
(1) C
RB
l* "Eo t vt d< --
mvo B
500 ko
E B-?-t-(
(D l.o 1* "Eo
mVo
t e v:l\,
(3) \t Iq: -t9rroil
(4) r0 (1) IB = 40 tti' Ic = 10 mr{, F = 25o f;F, -'
e\ IB =25p4 Ic=5mrl, 9=2OO
t*'1.4j'
9. When the light of frequency 2vs (where vs is -. 5-r
-'1fld
tbreshold frequency), is itrcident on a metal (3) IB=20FA" Ic= 5 mA, P=250
plate, the nq*irntrm vslocitl' of electrons emittcd f .' dxt;e
is v1. When the frequency of tlre incident 'y
Is =a0 p,A, Ic = 5 mAr F = 125
t\
,5't
radiation is increased'to 5vg, the maximun 18. In the combination of the following gates the
velocity of electrons emitted from the same plate ollE{llcan. te written in terms of inputs A ind
is ve. The ratio of 11t'o12 is E' hv r !S Bas
hrrzlmv'A
ul*l t:2 (v-;;- A
(2) l:4 2vo-uo=u' Vir'- 3' B
sq"-u^.: ( u. g-t :
i;; ;,; t
(B) 4: L
=
-.s; f;,=f' ';
5.5u" Y

10. For a radioactive material, half-life iE

lQginutes. If initially there are 600 number of
urrclei, the time tsken (in minutes) -for the (1) A B
disintegration of 450 nuclei is Ce)1 .lo
*s Q) e.S+A.S
20 6aailS9
/) (2) 10
'* '6@ ) toor lgo \x{) A.B +A.B
(3) . lo to.
30 ) (4) A+B
. (4) 15

11. The ratio of kinetic ener$/ to the total energy of

11. In a p-n junction diod", cFglfg t",gp""r.t tt"
due to heating
an electron in a Bohr orbit of the hydrogen atom,
,s (1) affects only reverse resistaDce
(1) 1:1 (2) affects only forward resistance
\91 1:- 1 (3) does not afiect resigtance of pn junction
(3) 2:- 1 (4) afiects the overall V - I characteristics of
(4) 1:- 2 pn junction

^"r" :,j4\ SPACE FOR ROUGH WORK English

15. A body initially at rest and sliding along a 19. -)
The moment of the force, F=4i +5j -6k,
frictionless track from a height h (as shown in (2,0, - 3), about the point (2, - 2, - 2), isgiven L
the figure) just completes a vertical circle of A
diameter AB = D. The height h is equal to
(1) -8i -4j -7k
AA
(2) -4i-j-8k
h
B (3) -7i -8j -4k
(4) -7i -4j -8k
A 20. A toy car with charge q moves on a frictionle
(1) !o
2.
horizontal plane surface urder the influence ol
uniform electric field E . Due to the force q l
(2) D its velocity increases from 0 to 6 rnls in o
second duration. At that instant the direction
e1 Lo
J5 the field is reversed. The car continues to mo
for two more seconds under the inlluence of tl
q.' lo
...qf 4- 4sur" field. The average velocity and the average spe
16. Three objects, A : (a solid sphere), B : (6 thin
IM[" of the toy car between 0 to 3 seconds r
circular disk) and C : (a circulal*riig), each have respectively \: U{ ot
vrtf) 2mls,+nVs
t2) 1m/s,3m./s .'_ ^r4- :;?rff,
the same mass M and radius R. They all spin
with the.same angular speed o about their own b=
symmetry axes. The amounts of work (W) (3) I n/s, 3.5 m/s a'-L - )4'% ! :'!3\
.

required to bring them to rest, would satisfy ttre l4l l.b m,/s, 3 rn/s '(*6 '
relation 21. A student measured the diameter of a imalfst
ball using a screw gauge of least cor
,P(2) w", ws, wA M\ur.!{o= O +lltv2- 0'001 cm. The main scale reading is 5 mm z
zero of circular scale division coincides w
wA > wB > wc r.A 1rJ: ryraVl 25 diyisions above the reference level. If scr
I
(3) wB>wA>wc gauge has a zero error of - 0.004 cm, the con
/tv, =\f,Vz
(4) WA>W6 >WB tlt= lrv, j5-.rY6xrrr36
\-..,1i%1;;irthebarris
' (2t 0.525 cm , t ,L,
17. A moving block having mass m, collides with ^-< ,'4
(3) 0'053 cm tt o'LYL'' 1't
another stationary block having mass '4m. The
lighter block comes to rest aft€r collision. When ,p 0.529 cm ^ ,.placdd
22. A block
).r4
of mass m is on a smooth inclir
the initial velocity of the lightcr bloc-k is v, then wedge ABC of inclination 0 as shown in
the value of coefficient of r€stitution (e) will be figure. The wedge is given an acceleration
(1) O'5 L-- vu-ut, towards the right. The relation between a an

\t)f o'25 [u.,, ::

for the block to remain stationaqr on the we

8 3:
18. Which one of the
'X;"'trb
following statements is
* IS
A

A'--)
-r"X'"

a
inconect ?
(1) Rolling friction is smaller tha.n sliding c '1 B
friction. (1) u= I
@ Limiting value of static friction is directly msec 0
proportional to normal reaction. f<"//rf.l s
(2)
(3) Fiictional force opposes the relative motion. sin 0
.r ({)" Coefficient of sliding friction has (3) a=gcos0
dirnensions oflength. $rb (4) a=gtaa01/

v
ACHWDD/Page 4 SPACE FOR ROUG H WORK Er
Vy. aetl'
u" 3t eJ I'
23 The volume (V) a monatomic gas varies with
of 27. Unpolarised light is incident from air on a plane
its temperature (T), as shown in the graph. The
surface of a material of refractive index 'p'- At a
ratio of work done by the gas, to the heat
absorbed by it, when it undergoes a change frorr particular anglc of incidence 'i', it is found that
state A to state B, is the reflected and refracted rays are
v irerpendicular to each other. \{hich of the
following options is correct for this situatQn ?
I
\
(1) Reflected light is poladsed with its electric
A '
vector paiallel to the plane of incidence
o
J{
------>
T Reflected light is polarised with its electric
(l) vector perpendicular to the plane of

Y
5
incidence
o\a
'3 . sln-'(t)
.
(3) r= t-l
l.ttl
(3) 1
t' , J.*ii I
(4) , (4) i=ttr, 1f!)
'7 a \sl
%.. the funda.meutal frequency in an open organ
pipe is equal to the third harmonic of a closed 28. In Young's double slit experiment the separation
organ pipe. If the length of the closed organ pipe d between the slits is 2 mm, the wavelength tr of
is 20 cE, the length df the open organ pipe is the light used is 5896 A anil distance D between
(f) 13'2 cm the screeri and slits is 100 cm. It is found that the
(2) 8cm
(3) 12'5 cm angular width of the fringes is 0'20". To increase
(4) 16 cm the fringe angular width to 0 21" (with same I
and D) the separation between the slits needs to
zlt. Al what temperature will the rms speed of
oxygen molecules becone just sufrcient for be changed to
escaping from the Earth's atmosphere ? (1) l'8 mm
(Given :
ka
(2) 1'9 mm
Mass of orygen molecule (m) = 2'76 x 10-%
(3) 2'1 mm
Boltzmairn's constant kg = 1'38 x 1o-B J K-1)
3IsYI (4) 1'7 mm
(1) 2.508 x 104 K
r
.t* 8.360 x 104 K
(3)
(4)
5.016 x 104 K
11264 x 104 K
L :,ffi 1
?.
r? ,
?
29. An astronomical refracting teleseope wiII have
Iarge angular magnification ahd high angular
resolution, when it has an objective lens of
26. The efficiency of a.n itleal heat engine working
(1)
between the fre€zing point and boiling point of small focal lengtJr and large diameter
water, is
(1)
tl,2r tl.2X bstozxS z .J' (2) large focal length and smirll diameter

(2)
26'87o
2O9o
lxs'3 L+) (3) large focal length and large iliam*ter
(3) 6.25% lzlrto6y *+ \ 6 ' (4) ' imall focal length and small 'liFrneter .

(4) l2'57o %Y1

\ t.0

ACHLA,/DD/Page 5 .ro"6 ROUGH WORK English

 F
.-q'f.\d'. -9-trr&
30. An em wave is propagating in a medium with a 34. cr.r"nt
""iitiri,/)* " -o.,ir,g -il galvanometer
velocity V = Vi. The instantaneous oscillating is 5 div/mA and its voltage sensitivit5r (angular
deflection per unit voltage applied) is 20 div/V.
electric field of this em wave is along +y axis.
The rgglg@ne of the galvanometer is . .-<a^
Then the direction of oscillating magnetic fietd of
V],' 40o s ' gctP' "^-:-
the em wave will be
t/:JQ(2) a
25
-t -5 -..Pv'
' >>
25oa 6 e.,rl
\(- o
\-g(2) - z direction
* R=v.(3)
L (4\ 50OO glzzovg
- + z direction r3
v,
(3) - y direction I!V rsxto 9rao
A metallir rod of mass S"
-, .a ,"**
aro.
(4) - x direction i vx2o
O:rxfrD 0.5 kg m-r is .Iying horizontally on smooth
Y'si:e:'"'
31. The refractive index of the materiil ofa pisin is
inclined plane which makes an angle of 80" with
the horizontal. The rod is not allowed to slide
JI aqd the angle ofthe prism is 80.. One ofthe down by flowing a current through it when a
two refracting surfaces of tlie prism is made a magnetic field of induction 0.2S T is acting on it
mirror inwards, by silver coating. A beam of in the vertical direction. The surrent flowing in
monochromatic light entering.the prism from the the rod to keep it stationary is
-w\
other face will retrace its path (aftcr rcflection (f ) 7.74 A '( -- R ti "c
from the silvered surface ) if its angle of incidence Q) 5.s8A -9
on the prism is (3) 14.76 A q-o x lo- a
(1) OO. \ -.ry (4) 11.32 A Lo -D ! I oo )e
t.o-3
c trlJot,r
36.
Q) 45
(3) 30. I .\! e
An inductor 20 mlr, or"r?.
"
resistor 50 e are connected in series acrosa
*u "
a
(4) zero ,t' '19
\,: \
source of emf, V = 10 sin 814
the circuit is
t. The power loss in

(r) 0.79 W P-. T'R .

32. An object is placed at a distance of40 cm from a
concave mirror of focal length lb cn. If the object *
(2) O.{li} W ?" {t5oo+ 1

(3) 2.74W
96
iaoa (4) l'rs w

3 ,frO diamagnetic rod is placed vertically

!$ ^i
between the poles of an electromagaet. When
thl
4 urreat in the electromagnet is switahed on, then .

(4) 36 cm towards the miror \ .- \-) -- 1 the di:magagtic rod is ptshed up, out of the ]

',J 7f '4 6
'-

horizontal magnetic field. Henir the r-od giins j

33. The magaetic potential energy stored in a
certain
gravitational potential enerry. . the work t'
inductor is 25 mJ, when the current in the
required to do '\iF comes from t,
1.
inductor is 60 mA. Ihis inductor i.s of inductance
(l) the current source '
l:
l

(1) 0.138 H . the magaetic field il

i
Q) 138.88 H 4-Lrg{--'"
| tt'.,zllxt -d(3) the lattice structure of the material of the !
I
1/
(3) r'389 H gz 1,!-6t61r
rod !
I

(rlr" 13.89 H 6
U) the inducdd electric field due to the lili
gor 60 x [0
{CHLA,/DD/Page 6
chaaging magnetic field
t;
t:
FOR ROUGH WORK t3 English ' IJ
--SPACE
.SP x ro3 .g
\AD
wTi; ti
lr
?66V t( ll
"'61
1e 70 I

<n
--7 I
I
li
 t

38. A small sphere of radius 'r' falls from rest in a 42. A solid sphere is rotating freely about its
viscous liquid. As a result, heat is produced due symmetry axis in free space. The radius of the
to viscous force. The rate of production of heat sphere is increased keeping its miss .ame.
u'hen the sphere attains its terminal velocity, is Which of the following physical quantities would
.proportional to remain constant for [e_sphere ?
(1) r3 (1) Angular velocity
(2) r2 e) Moment of inertia
(3) a5 (3) Rotational kinetic energy
(4) ,4 Angular momentum
\2
39 The power radiat6d by a black body is P and it 43. The kinetic energies of a planet in an elliptical
radiates maximum etrergy at wavelength, 1.6. If orbit about the Sun, at positions 4 B and C are
the temperature of the black body is now
Kl, Kg ard It, respectively. AC is the major
axis and SB is perpendicular to AC at the
changed so that it radiates maximum energy at position of the Sun S as shown in the figure.
wavelength qr" power ratliated by it Ttren
|;,, EaAT B
becomes nP. TiT e value of n is P = )=bT{
(1)
q \--'} 11 A c'
(2)
4

! ?' $'q)I L
1r
T? 1,'l
V.) V, )vg '
3 3 JW (1) Ke<Ks<Kc
(3)
256 l>. ) rr (z) KerKsrKc

9Y
8l
81
\5"
h.\I-
-- <r\
)

t f'. \'\
-w(4) Ks. KA < Kc
256 ..> KerKArKc
,10. A sample of 0 1 g of water at 100'C and normal 44. A solid sphere is in rolling motion. In rolling
pressure (1'013 x 105 Nm-2) requtes 54 cal of mot6i'--ffiy possesses translational kineticp
hdat energy to convert to steam at 100'C. If the energy (I!) as well as rbtational kinetic energr *
volume of the steam produced is 167'1 cc, the (Kr) simultaneously. Th.e ratio IQ : 0! + \) for
change in internal energy of tJre sample, is the enhere is I t.w '-r ! ,-' '
(1) au=1{ d' ,.*6
'z
to t *-r,l
Q)
104.3 J
208.7 J
*,*Y
-S= 5q*an (2) 6:7
, -! rt Ro*-.
2'
, !* axto?
T .-n L 1
(3) 42.2 J (3) 10:7 Fr'- y"
(4) (4) 2:5
41.
84'5 J

Tho wbes are made of the same materiel a.ud

\-J, +- {ttnvifurlo)
. The first wire has il6. ff the mass of the Sun wer€ ten times smsller
have the same vol and ulu
ten times . which of .the
cross-sectional area_.3A. If the length of the first crM
IS,tot correct ?
wire is increased by Al on applying a force F, *= E
how much force is needed to stretch the sedond
(1) Raindrops will fall faster.
wir'e bv the same amount ? a\,, \\
6lr= L- (2) Walking on the gmund woulil become t )re

' o; gr At'tr'i-'lu A,9 Ye ilifficult, 12-

g i
\rs 6F Alt =gAt' o11
5x !r A (3) Time period of a simple pendulr'''' gn the
(3) 4F !tly =t bL fw I, Earth would deciease. ,
r t' >'r'[L ' |?
(4) F on the Earth will not

ACHLL/DD/Page 7 SPACE FOR ROT'GH WORK \/u Rorr:l+ E rn'.zlndbh Yl

5 r313 z-\ E
!+
F;
?xq
F>'3F'
e l-( !SrnCttcv
*4
)
f+t
r'

13r 7 *a'-
4,{t
t ?z -
S i.t +
!
l.L
+
46. Which of the following is an amino acid derived 50. Ciliates differ from all other protozoans in
hormone ? (1) using flagella for locomotion

t4\ Epinephrine
(2) having a contractile vacuble for removing
excess water
(2) Ecdysone (3) using pseudopodia for capturing prey
(3) Estradiol ,/l<) having two ty?es of nuclei
(4) Estriol 51. Identify the vertebrate group of animals
characterized by crop and gizzard in its digestive
system.
47. Which of the following structures or regions is
iry2y9fut paied with its tunction ? (1) Amphibia
'(2\ Reptilia
(1) Medulla oblongata : controls respiration
Aves
and cardiovascular \rtb
reflexes. (4) Osteichthyes

,y Limbic system consists of fibre

tracts that
52, Which of the following organisms are known as
chief producers in the oceans ?
interconnect (1) Dinoflagellates
different t'egions of
brain; controls vl2) Diatoms
movement. (3) Cyanobacteria
(3) Hypothalamus production of (4) Euglenoids
releasing hormones
and regulation of 53. Which .one of these animals is zol a
temperature, homeotherm ?
hunger and thirst. (1) Macropus
(4) Corpus callosum band offibers
counecting Ieft and uEl cheton"
right cerebral (3) Camclus
hemispheres.
(4) Psittarula
48. _
Tlie tratrsparent lens in the human eye is held in 54. Which of the following animals does.zot undergo
place by metamorphosis ?
,its
ligameaas aftached to the ciliary body
WP ,.fr Earthworm,
Q) ligaments attached to the iris (2) Tunicate..
(3) smooth mwcles attached to the iris' (3) Moth
(4) smooth muscleg attached to the ciliary body (4) Starfish

{9. Which of the following hormones can play a 55. Which of the follorring featuips is useil to identi&
a male cockroach from a female ipckroach ?
significant role in ost€oporosis ?

(1) ,aO Presence of a boat shaped stemum on the

Aldostei'one and Prolactin
9u abdominal segn.ent
(2) foogesterone and Aldosterone
(2) Presence of caudal st5rles
9(d tstrogen a-nd Parathyroid hormone (3) Forewings with darker tcgmina
(4) Parathyroid hormone and Prclactin
Q) Presence ofanal cerci

ACHLA/DD/Page 8 SPACE FOR ROUGH WORK English

56. Which one of the following population
61. Hormones secreted by the placenta toma]3g!
interactions is widely used in medical science for
pregnanclLare
the production of antibiotics ? .-
(1) Commensalism hcc, hPL, progestogens, prolactin
g Mutualism
(3) Parasitism
Ll9l
(2) hCG, hPL, estrogens, relaxin, ox5rtocin
(3) hCG, hPt, progestogens, estrogens
(4) Amensalism
(4) hCG, progestogens, estrogeDs,
57. All of the following are included in 'Ex-situ glucocorticoids
conseryation' ercep,
(1) Wildlife safari parks
62. Ihe contraceptive'SAIIELI
\/(27 Sacred groves
(1) blocks estrogen receptors in the uterus,
(3) Botanical gardens
(4) preventing eggs from getting implanted,
Seed banks
irLcreases the concentration of estmgen and
58. Match the items given in Column I with those in r';!21 prevents ovulation in females.
Column II and select the correct option given
below : (3) is an IUD.
Column I Column II (4) is a post-coital contraceptive.
a. Eutrophication i. IJV-B radiation
b. Sanitarylandfill ii. Deforestation 68. the rrnnion of marnmqlian embryo is derived
c. Snow blindness iii. Nutrient from
enrichment (1) ectoderm and mesoderln
d. Jhum cultivation iv. Waste disposal (2) endodern and mesodem
abcd (3) mesoderm and trophoblast
(1) ii i iii iv
(.2) i (4) ectoderm and endoderm
iii iv
a (4)
ltl
I
lv
u
I
lv
ii
tl
iii -6-4. Tte difference between spermiogenesis and
spermiatioD is
69, In a cTggilglglul$on of a country, (1) In spermiogenesis spermatids are formed
\'/Jn
pre-reductive individu"ls are more than
while in spermiation Bpermatozoa are
the reproductive individuals.
formed.
(2) r€pmductive individuirls are tsss +han ttrs
po8t-tpprcductive individuals. (2) Ia spermiogeneeis spermatozoa are formed,
(3) reproductive and prc-reproductive wtrile in spermiatiotr slrermatials are
iatlividuale are equal in number. ' formed.
(4) pre-r€prductive indiviiluals are less than (3) In spermiogenesis ipermatozoa from sertoli
the rep,roductive individugls. cells ari: released into the cavity of
.
60. Which part of poppy plaut is used to obtain the ssminifelqqs tubules, while in spermiation
drug "Smack" ? spermatozoa are formed.
(1) F'lowers.
,.Jz) Latex ,P In spermiogenesis spermatozoa are formed,
while in spermiation spermatozoa are
(S) Roota released from sertoli cells intb tJre cavity of
(4) Leaves seminifercus tubules.
ACHLA/DD/Page I SPACE FOR ROUGH WORK English
 65. Which of
.the- following options correctly
represents the lung conditions in asthma ani 68. Match the items given in Column
I with those in
e_I9Pbylgga, respectively ? Column II and select the coraect option g-iven
Inflammation of bronchioles; Decreased belou:
respiratory surface
(2) Increased number of bronchioles: Increased
I Column Column II
respiratory surface a. Glycosuria i. Accumulation ofuric
(3) Increased respiratory acid in joints
Inllammation of bronchioles
surface; .
b. Gout ii. Mass of crystallised
(4) Decreasid respiratory surface; salts within the kidney
Inllamrnation of bronchioles
c. R-enal calculi iii- Inflammation in
66. Match the items given in Colum-n I *ith thosu
in glomeruli
Column II and select the corzect option given
below : d. Glomerular iv. presence ofglucose in
Column I nephritis urine
Column II
a. TYicuspid valve l. Between left atriim a b c d
and left ventricle (r) iii ii
b. Bicuspid valve
iv i
ll. Between right o) i ii ul iv
ventricle and
(3) ii iii i
pulnonary.artery iv
c. S6milunar valve lll. Between right u) iv i u iii
atrium and right \-/
ventricle 69 Match the items given in Column
I with those in'
abc Coh'mn 11 aad select the corrzcf
option given
,llr I ll below :

e)i iii ii I
Coiumn Cofumn II
(3) i ii iii (Function) (part of Enretory
(4) ii i iii gletem)
,
67. Match the items given in Col,rrnh I with
those in a. Ultrafiltration i. IJenIe,e Ioop
Colurnn 11 and select the conect option given
below : b. Concentration ii. Ureter
of urine
Column I Column II
a. fidal volume i. c. Ttansportof iii. Urinarybladrter
2500 - 3OOO mL urine
b. rnspiratory R€serve ii. 1100 - 1200 mI.
volume d. Storage ofurine iv. Malpighian
Expiratory Reeerve corpuscle
c. iii. 500 - 550 rnl
VOltrne v. Proximal
.d. Residual volume iv. 1000 1100 mI. . convoluted tubule
-
abc d a b c d
iii ii
d,, iii i lv (1) iv ii iii
J2) i iv u \-ly iv i ii ..:
TT
(3) iivii
lu (3) lv i u
G) iv iii ii I Q) iv I rI
ACHLA,/DD/page 10
SPACE FOR ROUGH WORK
English
?0. Which of the following events does not occur in 76. All of the following are part of an operon €xcep,
rough endoplasmic reticulum ? (1) an operator
(1) Protein folding (2) structural genes
(D Proteinglycosylation
an enhancer
(3) Cleavage ofsignal peptide -6,(4) a promoter
Phospholipidsynthesis
,r!{f 77. Match the items given in Column I with those in
?1. Which of these statements is inconect ? Column II and select the cortect option given
( f ) Enrymes .of TCA cycle are present in below :
mitochon&ial matrix. Column I Column II
Q) Glycolysis occurs in cytosol.
a. Proliferative Phase i. Breakdown of
(3) Glycolysis operat€s as long as it is supplied endometrial
with NAD that can pick up hydggen atoms. lining
(ft Oxidative phosphorylation takes place in b. SecretoryPhase ii. Follicular Phase
\/ outer mitochondriat menrbrane.
c. Menstruation iii. Luteal Phase
72 Nissl bodies are mainly composed of
abc
(1) Proteins and lipids (1) iii ii i
(D DNAand RNA
(3) (2) i iii ii
Nucleic acids and SER
(4) Free ribosomes and RER ,.y ll lll I
(4) iii ii
79- Which of the following terms describe human
dentition ? 78. According to Hugo de Vries, the mechanism of
(1) Thecodont,DiphyodontHomodont evolution is

eJSf Tlhecodont, Diphyodont, Heterodont (1) Multiple step mutations

(3) Pleurodont,Monophyodont,Homodont .t/ *2) Saltation
Q) Pleurodont, Diphyodont, Heterodont (3) Phenotl"picvariations
(4) Minor mutations
Select the incorrecf matrh :
(1) Lampbrush - Diplotene bivalents 79. A woroan has an X-linked conilition on one of her
c-hromosomes X chmmosomes. l1ris chronosome gan be
Q) Allogomes - Sex diromosomes irherited bv
(S) Submetacenhic - Lshaped cbromoaoamea (1) Only daugbtera
chromosomes (2) Only sons
(4)z Polytene - Oocytes of amphibians (3) Onlygrande.hildren
.,/ chromosomes
. Both sons anil daugDrtere
76. Many ribosomes may associate' with a single JA
mRNA-to form multiple copies bf a polypeplide 80. AGGTATCC'CAT is a sequeace from the coding
simultaneously. Such strings of riboeomes are strand of a geoe. What will be the corresponiiinE
termed as seqtence of the tr,''scribed$RlilA ?

vtA)- Polysome (1) AE,GUAUCCCAU

(2) Polyhedral bodies (il ue,crurtccar
(3) Plastidome (3) ACCUAUC'CGAtI
(4) Nucleosome UCCAUAC.CGUA
ACHLNDD/Page 11 SPACE FOR ROUGH WORK English
 81. Which of the following gastric cells indirectly 85' the following is pr an autoimmune
help in e iesis ? H:::""r,
(1) Chiefcells
(1) Psoriasis
(2) Rheumatoidarthritis
(2) Mucous cells
(3) --*$ Alzheimer'sdisease
Goblet cells (4) Vitiligo
Paneal cells
U!9/ 86.
{1ons the
.following sets of exa.mples for
Slrversent evolution, select the itcorttcf opfion:
82. Match the items given in Column I with those
in (1) Forelimbs of man, bat and cheetah
Column II and select tJnLe conect option given
e) Heart of bat, man and cheetah
below :
uJ*l/ Brain dfbat; man and cheetah
I Column Column II (4) Eye of octopus, bat a.nd man
a. Fibrinogen 47.
i. Osmotic balance Co1191sio1
9f r-nilU to curd improves its
nutritional value by increasing the --
. b. Globulin ii. Blood clotting ,-;;t;
(1) Vitamin D
c. Albumin. +. Defence mechanism (2) Vitamin A

(r) iii
abc ..n (4)
Vitamin B12
ii i Vita:ain E
Q) i ii iii 88. In.,which disease does mosquito transmitted
(3) i pathogen cause chronic inllammation
iii ii luphatic-yessef. of
?
\2' iii i
, (ll" Elephantiasis
8:1. Which of the following is an (2) Ascariasis
occupational (3) Ringworm disease
respiratory disorder ?
(4) Amoebiasis
(1) Anthracis
89. The similarity of bone- structure in the forelimbs
..-(91' silicosis
(3) Botulism V.JII Homology
(4) Emphysema (2, Analogy
(3) Convergentevolution
84. Calcium is important in skeletal muscle (4) Adaptive radiation -

conhaction beceuse it 90. Which of the following charactcrisd& repr€sent

2 binds to troponin to remove the masking

active sites on actin for myosin.
of
'Inhedtanceofhlood groups,in humiins ? ' -----
rJ 'Dominanc€
(2) activatcs thd myosin ATpase by binding ,). Co{omingnss
to \.(
. it. Multiple allele
(3) d. Incompletedominance
detaches the myosin head from
the actin e. Polygenicinheritance,
filament. '
(1) b, c and e
(4) prevents the formation of bonds
between
the myosin cross bridges aad .the actin ,pf a,bailc
filament.
(3) b, d and e
(4) a, c and e.
ACH LA,/DD/page 12
SPACE FOR ROUGH WORK
English
91. Which of the following flowers only once in its 98. In India, the organisation responsible for
life-time ? asses-sing the safety of introducing genetically
,..Ltf Bamboo spccies uiodified o ls
(.2) Jackfruit (1) Indian Council of Medical Research (ICMB)
(3) Mango (2) Council ior Scientific ancl Industrial
(4) Papaya Research (CSIR)
92. Which of the following pairs is torongl! (3) Research fammilfas on Genetic
mat€hed ? Manipulation (RCGM)
,-+A pea :
Shrch synthesis in Multiple alleles . (4)r' Genetic Engineering Appraisal Qsmmills€
(2) ABO blood grouping : Co-dominance (GEAC)
(3) XO type sex : Grasshopper
determination
99. Which of the following is commonly used as a
vector for introduchg a DNA fragnent in humap
(q T.H. Morgan : Linkage
JYmPhocvtes ?
93. Select the corrsc, statement : ()) R€tmvirus
(l) t-/
Franklin Stahl coined the term "linkage". (2) Ti plasmid
Punnel,t square was developed by a British (3) ). Phage
\./I scientist.
(3) Spliceosomes take part in translation.
(4) pBF-322
(4) Tlansduction was discoversd by S. Altman. l0O. The.correct order of steps in Polymerase, Chain
experimental proof for sgmiconservalive neac66n (PCn) is
94, The
rcpIqqlf9!-ol-DNAwas first shown in a
(1) Extension,Denaturation,Annealing
(1) Fungus Q) Annealing,Extension,Denaturation
,-lZ Bacterium (3) Denaturation,Extension,trnnealing
(3) Plant Denaturation, Annealing, Extension
(4) Virus -P
95. Offsets are produced bY lO1. A'new'variety of rice was patented by a foreign
(1) Meiotic divisions cogtjauy, thoqgh . sup|- varreties . have been
present in Inilia for a long tirie. Ihis is related to
WP Mitotic divisions (1) Co-667
(3) ParthenocarPY
: (4) Parthenogenesis Q\ Sharbati Sonora

06.. Which of the following has lroved helpfrrl in

(3) Irerma Rojo
ars :lossils ? Basmati
PrPqgryiirg-Pgllgg
(1) Pollenkitt ".19
101!. Select the corzwct natrch :
(2) Cellulosic intine tlN.rclei"
(3) Oil content ulZf Rihozycre - ."id
(D F2 x Recessive parent - Dihybdd.rbss
g[y',)z SPoroPollenin
(3) T.II. Morgan - Tlensdriction
57, Select the corzrct natrh :
(4) G. Mendel
(1) Alec Jefteys - Strept@occus ' -
Transformation
pnzumoniae 103. Use of bioresources by multinational comp-aoies
and organisations without.authodsation-Aolq the
(2) Alfred Hershey and -. rMv concerned countrJr and its people is called
Martha Chase (1) Bio-infringement
(3) Matthew Meselson - Ptsum sdtiuum
yI2)' BioPiracY
and F. Stahl (3) Biodegradation
Francois Jacob and
,y Monod
- Lac oPerot
(4) Bioexploitation
English
fiCHLA,/DD/Page 13 SPACE FOR ROUGH WORK
 104. Natality refers to
I10. The two functional gloups
dZ) Death rate sugars are
characteristic of
Birth rate
-12)
(3) Number of i ndividuals leaving (1) hydroxyl and methyl
(4) Number ofindividuals enteringthe habitat (2) carbonyl and methyl
a habitat (3) carbonyl and phosphate
lO5. Niche is G) carbonyl and hydroxyl
(1) all the biological factors in
the organism's I I l. Which among the followins is nof a prokaryote ?
envrronment
e) ;14 Saccharomlces
the physical space where
an orgaaism lives (2) Mycobacteriun
(3) the range oftemperature that (3) /Vostoc
the organism
needs to live (4) Osciltatori.a
,2 the functional role played by
where it lives
the organism ll2. Stomatal moyement is ao,
(1) Temperature affected by
106. \{hat type of ecological (2) Light
obtained with the following P5,ramid would be
data ? (3) O2 concentration
Secondary consumer : 120
g @) CO2 concentration
Primary consumer : 60 g
113. Which of the following
Primary producer : 10 g is twt a pmduct of light
reaction ofph otosprthesis
(1) Inverted pyrarnid of biomass (T) ?
ATP
(2) Bramid of energr
(3) Upright pyraaid of nunbers .._ls, NADH
(3) NADPH
(4) Upright pyramid ofbiomass G) Oxygen
107. In,shatosphere, which
ff4. Ihe Golgi complex participates
in
of the following elements
acts as a catalyst in degradation (1) Fatty acid breakdown
fi;;;;
release of molecular orygen
? .)b Formation of secretory vesicles
(1) Carbon (3) Respiration
in bacteria
lizr'ct
(3) Fe
(4) Activation of
amino acid
115. Which of the following
is true for nucleolus
Q) Or5ryen
?
j:] Larger nucleoli are present in dividf'cells.
;
(2) It is a membraae_bound
ry) Worlil OmaeDay is celebrated (3) It takes parr i" etruc.ture- :
on
(1) 66Jrine l._ ro.--"ilol'
vl4 lt is a site for "pioar"
active .ribosomal RNA
synthesie.
Q) 2riAprit 116. the stage d unng
which
(s) re6s.pt"-U1
(1) Pachytene
G) z,"dAlxit .1121 Diplotcte
'9. Which ofthe folloring
is a eecondary pollutant
(3)
Dielcinssig
(1) co ? (4)
Zygotene
117. Stomata in grass
Q) coz (1)
leaf are
Dumb_bell shaped
,J8, soz @ Kidaey shaped
Q) os (3) Rectaagular
lLNDDlpage 14 \--<4) Barrel shaped
SPACE FOR ROUGH
WORK
Engtish
118. Casparian strips occur in 125. Winged pollen grains are present in
(1) Epidermis (1) Mustard
(2) Pericycle (2) Cycas
(3) Cortex (3) Mango

i$/ Endodermis \!) Pinus

I19. Plants.having little or no are 126. After karyogamy followed by meiosis, spores are
Grasses
.-W, produced exogenousl ln
(2) Deciduousangiosperms (1) Neux)spora
(3) Conifers (2) Alternaria
($ Cycads
v/<1) Agafbus
(4) Saccharomyces
120, Pneumatophores occur in
)n Halophytes 127. Match the items given in Column I with those in
" (21 Free-flt ating hydrophytes Column II and select the. correol option given
(3) Carnivorous plants below :

(4) Submergedhydrophytes Column I " Column II

121. Sweet Dotato is a modified a. Herbarium i. It is a place having a
(1) Stem collection of preserved
Advenlitious root plants and animals.
^-!2Y
(3) Tap root b. Key lr. A list that enumerates
(4) Rhizome methodically all the
species found in an area
122. Qesga&ry-xylem and p.hloe4 in dicot stem are with brief description
produced by
aiding identification.
(f ) Apical meristems
c. Museum iii Is a place where dried and
Vascular cambium
J<{Z) pressed plant specimens
Phellogen
n14) Axillary meristems mormted on sheets are
kept.
123. Which ofthe following statements is corzuct ? d. Catalogue iv. A booklet containing a list
n) Ovules are not enclosed by ovary wall in of charact€rs arrd their
gyurnosperms. alternetes which are
. e) Selaginzlla is het€msporous, while Saluinia helpfirl in identification of
is homosporous. veriorx taxa.
(3) Horsetails are glmnosperurs. a b c d
(4) Stems are usually unbrarched in both (1) i iv lu ii
Cycas and, Cgdrus. (2) iii ii i lv
124. Seleci the rorong statement : ' (3) ii iv iii I
'
(1) Cell wall is present in members of Fungi lll lv i ii
irnd Plantae.
\-9+
128. Which one is prongr, matched ?
(2) Mushrooms belong to Basidiomycetes.
(3) Pseuilopodia are locombtory- and feeding
y)lY Uniflaellate gamet€s - Polysiphonia
(2) Biflagellate zoospores - Brown algae
structures in Sporozoans.r,/
(3) Gemma cups - Marchantb
(4) Mitochondria are the powerhouse of$re cell (4)
in all kingdoms except Monera. \
Unicellular organism - Cl orella'
AeH LA,/DD/Page 15 SPACE FOR ROUGH WORK English
 129. Which one of the following plants shows a very 136. Which of the following statements
is nof true for
close relationship with a species of moth, where halogens ?
none ofthe two can complete its life cycle without
the other ? r./ ),/(, A.ll form monobasic oxyacids.
( 1) Hyd,rilla
- l2t All are oxidizing agents.
.(2) Yucca
(3) Bananh
.g All but fluorine show positive oxidation
states.
(4) Vinla (4) Chlorine has the highest electron-gain
130. Pollen grains can be stored for. several years in enthalpy.
liquid ritrogen having a tcmperature of 137. Considering Ellingham diagram, which of the
. (1) - 120"C following metals can be used to reduce alumina ?
(2) -80'C (1) Fe
r'fi) -196C Jfr Zn
(4) - r60.c V (tt Mg
131. Which of the following elements is responsible for
maintaining turgor in cells ?
(4) cu
(1) Magnesium 138. In the structure of ClF3, the number of lone pairs
e) Sodium ofelectrons on central atom.Cl'is t
j4) Potassiun (U one 1', >
D.

(4\ Calcium 1;-' '

132. Double fertilization is
,rd t*o - "v
(31 four
(1) Fusion of two male gametes ofa pollen tube (4) three
with two diferent eggs
(2\ Fusion of one male gametc with two polar 139. The correct order of atomic radii in goup 13
nuclei elements is
(3) Fusion of two male gametcs with one egg (1) B<AI<In<Ga<Tl
\tq S1'ngamy and triple fusion (2) B<Al<Ga<In<Tl
133. Orygen is zo! produced during photosynthesis by (3) B<Ga<A]<Tl<In
,6) Green sulphur bacteria
v (2) Nostoc (4) B<Ga<AI<In<TI
(3) Cycas 140. The conect order of N-compounds in its
(4) Clwrz .
decreasing order ofoxidation states is

134. What is the role of NAD+ in cellular

. respiratiou ? -1. Tlgu,Uo, {,r{*91
Q) HNO3, NO, NH4CI,
(1) It functions as an enzyne. N2

Q) It functions ag an electron csrier. (3) HNO3, NH4CI, NO, N2

(3) It is a nucleotide source for ATp synthesis, (4) NH4CI, N2, NO, HNO3
Q) It is the final electmn acceptor for anaerobic
respiration. l4l. Which one of the following elements is unable
to
t$5. In which of the following forms is iron abeorM form J[Fu3- ion ?
' by plaots ?
(l) Ga
(1) Ferric
Q) Ferrous (2) Ar
(3) Flee element ,,J9 B
Both ferric and ferrous (4) In
ACHWDD/Page 16 SPACE FOR ROUGH WORK
English
 (?'.!rl
(-tHI €i"lq (P(\(--\ ^d^
' r (1kl <'"
t1h5(\ coro'l
142. The compound A on treatment with Na gives B, 146. Following solutions were prepared by mixing
and with PCl5 gives C. B and C react together to
different volumes of NaOH and HCI of different
concentrations : M'f,loa'- 6-\ =
t
give diethyl ether. A, B and C are in the order
t\^ , o' L
a. 60mL HCI+4omL 14 wuon
(1) C2H5OH, C2H6, C2H5C1 #
s-<-\'r\s
(2) czH5oH, c2H5cl, c2H5oNa b. ssmL
# HCr+45*
# lr$,fi
tdv'
til czHscl, c2I{6, c2H5oH c. zs mL y HCI + 2b mL $ r.rron
Db pn- -lg tx/i
'ett
{))z C2H6OH, C2H5ONa, C2HsCl
d. 1oo mL 4
HCI + too mL l4 N"on teoi (
= -.
t0 10 .Kl
ll3. Hydrocarbon (A) reacts with - bromine by
=- ,_-i-o,,:1rro6tt{
pH ofwhich one of them will be equal to 1 ?
substitution to form an alkyl bromide which by 6)b \r- <
Wurtz reaction is converted to gaseous (Da \s
hydrocarbon containing less than four carbon
atoms. (A) is
(3) d 5'rE
iso
(o4

c Htqv ,,j4 c

(r) CH=CH en;'LAa 147. On which of the following properties does the
coagulating power ofan ion depend ?
(2) CII2=CIJ.2 (1) The magnitude of the charge on the ion
(3) cH3
alone -?
- cH3
(D sizeoftheionalone
(3)
"-18t"---i'
G)- cHr Both magnitude and sign of the charge on
the ion r , 24aXlo- 3x I
144. The compound C7H, undergoes the follolylPC
- 1&'r Y r.-r -
reactions , ( r- 148, The solubility of BaSOa i., -iutrt". =lxlo
is
3Clr/A BrclFe Zn/HCt
'C7Hr -----:----+ 6 -i",---* B.,,1# C' 2.42xLOa gl.-l at 298 I( The value of its
rheproduct,c,is' \y' -6 solubility product (qe) will be

(1) zr-bromotoluene ,', a.) (Given molar mass of BaSOe = 233 g mol-l)
I Roso" t*" t;*
(2) o-brumotoluene ,1ilN t.wxr0-10 mor2 L-2:
(3) 3-bromo-2,4,6-trichlorotoluene -& Q) 1.08 L-2
x 10-u moll
(a) 1.08 x to-ra mol2 L-2
Krr;*l*,r_")
.
"
(4) p-bromotoluene { i,
(4) 1.08 x 10{ mol2 L-2 '- "r)
145. Which oxide of nitrogen is not a corrrmon
1 49. Given van der Waals constant for NH3, II2, 02
pollutant introduced into the atmosphere both
and CO2 are respectively 4.17, 0.2U, 1.36 altl
due to natural and human activity ?
3'59, which one of the following gases is most
(1) NzOs ---:-
(2\ NOz NH
(2) H2
(3) NzO
(3) 02
(4) NO"/ @) coz
dCHLNDD/Page'17 SPACE FOR ROUGH WORK English
 150. Match the metal ions given in Column I with the f55. Identifu the
major products P, Q 'and R in the
spin magrretic moments of the ions given in
Column II and assign the corzec! code :
follou'ing sequence of reactions :

Column I Column II
a. ^3+
uo i. JE B.M.
Anhydrous
cH3cH2cH2cl Alcl3
b. Cr3* \ J5E s.Ll.
+ >

F:'* - B.M. [tttt

iii. J3 (i) o"
". i \ \l I P ------:--------- Q+R
d. r,'* iv. Jzn s.u. (ii) HBo+/A
v. JlS B.M. 5 C5r>')
gx?
a b c d
PQR
'.,/-q
tq * ,)
u*f(2) * u i- VhY ( cH2cH2cH3 CHO
i It iii iv ,t-tq
'(3) iv
(4) iii
i ii.
i
iii -
ii
{.!trrr)
ffi
g , cH3cH2-oH
l\ n t rr
161. Iron carbonyl, Fe(CO)6 is ,{6,1:r,
(1) tetranuclear G\ cH2cH2CH3 cHo cooH
Q) mononuclear
(3)
(4)
trinuclear
dinuclear .
Q)
0
L52, The geometry and magnetic behaviour of the
complex [Ni(CO)d are tl n r l. ) llt r r
CH(CH s)z OH
(1) square planar geometry and diamagnetic (3) cHscH(oH)CH3
(2) tetrahedral geometry and diemagnetic ,
(3) square planar geometry and paramagnetic
(4) tetrahedral geometry and paramagnetic OH
153 Which one of . the following ione exhibits cH(cH3)2
d-d transition and paramagnetism as well ? (4) cHs
, -CO- CH3
(1) (}O'zi-

(2) Ci2O 7
(3) MnO 1
156, Which of the following compounds can form a
(4) I\,InO 4
2-
zwitterion ?

154, The type of isomerism ehown by the complex (1) Aniline

[CoCl2(en)2| ie
(1) Geometricalisomerism (2\ Acetanilide
Q) Coordinationisomerism (3) acid ..or,
Benzoic
(3) Ionizationisomerismi l.
(4) LinLnge iaomerism
1 UIAY GUcine H- c-NH-
ACHLA"/DD/PaSe 18 SPACE FOR ROUGH WORK Fl
English
r

157. Which of the following molecules represents the 160. Magnesium reacts with an element (X) to form an
order of hybriilisation sf, =C, .1, from left to ionic compound. If the ground stat€ electronic
"l configuration of (X) is 1s2 2s2 2p3, the simples!
right atoms ?
formula for this compound N is I
(1) HC=C-C=CH (1) Msz\ ", 6ir, $rl6.-
CHz=CH-C=CH (2) M8&
(3) CH2 = CH - CH = CH2 (3) Ms2x
(4) CH3 - CH = CH - CH3 Ms{'
"J*l
181. Imn erhibits bcc Btruc'ture at room te. Dperature.
Above 900"C, it transforms to. fcc structure. The
158. \{ihich of the following carbocations is expec'ted to
ratio of density of iron at rooE-temperatur.e to
be most stable ?
that at 900'C (assuming mJilar-Eass and atomic
Iadii of i"o,n ,"-ains constant with temperature)
Noz IS da?-rt59"'
Nx-
J5
(1)
(r)
Jz l=
d,1,
3-
4
YH (2\
4Jg olr
3J2 aL
3J5
Noz (3)
4J2
1
_/ ,/1) ,
YH 162. Which one is a rrr?zg statement ?
(1) Total orbital angular momentum of electron
in 's' orbiial Is equal to zero.
Noz
I
(2) An orbital is designated by three quantum
numbers while an electron in an atom is
(3) designat€d by four quantum numbers.

I
H
Y v the electronic configuration ofN atom is
lri 2.2 zprr2pty zpl
E E
I

I
Noz t t I
H (4) The value ofm for d'r2 iszero.
(4)
Y
i 188. Consider the following species :
169. Which of the following is correct with respect to cN+, cN-, No and cN
_ I effect of the substituents ? (R = alkyl)
I
Which one of these will have the highest bond
(1) -NH2<-OR<-F i---- ? 8
order
(1) NO" 2's
I
.lzl" -NR2<-oR<-F
(3) -NH2>-OR>-F
0f tjk-s
Llsl
I
.c[r
i
(4) -N&>-OR>-F (4) 4ch
ACHWDD/Page 19 SPACE FOR ROUGH WORK English
 164. In t,l:e reaction 167. I'he correct difference between frrst- and
seco d-order reactions is
that
OH O-Na*
the rate of a first-order reaction does not
+ CHCIB + CHO depend on reactant concentration.s; the rate
NaOH ------>
of a second-order reaction d.,o. deocnd o,n
reactant concentrations
the electrophile involved is (2) the half-life of a first-order reaction does not
(1) dichloromethyl cation i SffCt2l
depend on tAlo; the half-life of a
second-order reaction does depend on
[A]o
@
e) formyl cation ( CHO ) (3) a first-order reaction can be catal;zed; a
second-order reaction cannot be catalyzed
(3) dichtoronethyl anioo t SffCq) the rate of a first-order r€action does
deienC on reactant concentrations; the EE
gfi dichlof carbene (:CClz) of a second-order reaction does not depend
on reactant concentrations

166. Carborylic acids have higher boiling points than 168. Among CaH2, BeHr, BaH2, the order of ionic
aldehydes, lietones and even alcohols of character is
couparable molecular mass. It is due to their (f) BeH2 <CaH2 <BalI2
(f) formation of intramolecutar H-bondinp (2) CaH2 < BeH2 < BaH2

(2) formation of carboxylate ion t4,,-tl -"a (3) BeH2 < BaH2 < CaH2
(4) BaH2 < BeH2 < CaII2
(3) more extensive association of carboxylic
acitl via van der Waals force of attraction 169. Consider the change in oxidation state of
(4 formation of intermolecular H-bonding Bromine corresponding to diflerent emf values
as
shown in the diagram below :

166. Compound A, CBHloO, is found to react 1.82 V 1.5 V

with BrO 4 -------+ BrOi ___-_-t
NaOI (produced by reacting y with NaOH) and
1? tr " + ri
yields a tate with characteristic Br <- B"z
1.0652 V r.595 V
smell. - Lttlf
-t o
Itren the species undergoinq. disproportinnrtio_n
A and Y are respectively
. N;gt.
(r)
(1) HsC
G cH2-oHand ,c Q)
BrO,
BrOJ

(2)
G CH2 - CH2 - OH a:od 12
(3)

(4)
B"z
IIBrO
(3)
G cH- CH3 and 12
I
OH
170. In which case is the number of molecules of
maxmum ? lfl; i-"o
water
(1) 18 mL of water r/
cHs (2) 0'18 g of water 4 o.ol r^ol a --D rrr'rr
G) CHs OH and I, . J?) 0.Q0224 L of water vapour€ at I atm and
Ll.\'' 273K o 'ooo1
(4) 10{ mol ofwater
ACHWDD/Page 20
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41
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171. Regarding cross-linked rs, l?6. For the redox reaction
incorrecl ?
rvhich of the following statements is
Mno. +C2o!- + H*-- ) Mn2* + Co, + Hro
(1) They contain covalent bonds betrveen
various linear PolYmer chains. the correct coellicients of the reactants for the
(2\ They are formed from bi- and tri-functional balanced equation are
monomers. MnO[ rO'r-
C H*
(3) Examples are bakelit€ and melamine.
(1)16 5 2
{y They contain strong covalent bonds in their
polymer chains.
(D2 5 16
(3) 2 16 5
1?2. Nitration of aniline in strong acidic medium also (4)5 16 2
gives m-nitroaniline because
(1) In spite of substituents nitro group always 177. The conection factor'a'to the ideal gas equation
goes to onlY m-Position. corresponds to
(2),/h electrophilic substitution reactions (1) density ofthe gas molecules
V amino SrooP i8 meta alirective. (2) volume ofthe gas molecules
(3) In absence of substitueuts uitro group (3) electric field present between the gas
alwaYs goes to m-Position. molecules
(4) In acidic (strong) medium qniline is
a5 eniliniun iga.
prree€nt

2 forces
molecules
of attraction

17S. tr/hich of the following oxides is lnost acific in 178. Which one of the following conditions will favour
between the gas

nature ? maximum formation of the product in the

(1) Mso reaction,
e) Be€ 4@) + Bz@) + xrG) +H =-x k.I ?

(3) BaO A) low temperature and high pressure

(4) CaO (2\ Low temperature and low pressure
174. The difference between amylo.se and amylopectin (3) High tenperature and high pressure
is (4) High temperature and low pressure
(1) Amylopectin have 1 --r 4 o-linkage and
179. The bond dissociation energies of X2,.Y2 and XY
1 -t 6 cl-Iinkage
are iir the ratio.of 1 : 0'5 : 1. AH for the formation
(D Amylose have L --; 4 clinl<qge and
of XY is - 200 k I mol{ . llre bond dissociation
f -r 6 Flinkage | -*
(s) --Amylopectin have 1 -+ 4 <r-lin}age and
enerry ofX2 will be tr?-i)c+t
(- tc
Y 1'r 6 Pli"k"g" YLn.{-rY o,
zoow ultf
(2) 100 kJ mof y..{ ) p-r y
^ot-r l-- 2<
(4) Amyloee i8 rnade up of glucose aud
cooa
galactose tz-o'rhi :@ h (3) 800kJmol{ :I xz*-LY'+ YY 1", *,"2 -
1?5. A mixture of 2'3 g formic acid ald 4'5 g oxalic (4) 400 k I mol-r t#r '-
acid is treated with conc.'H2SO4. The evolved
gaseous mixture is passed through KOH pellets' 180. When lBiliel concentration of the reactant
is

Weight (in g) of the remaining Product at STP doubled, the half-life perioil- of a zero order
Taz 7 \,." &-Au .1 *o&t-r
will be ir -Igactiotr
(1) E- , 7
(1) r.4 is halved a l.(1 -
, b9
Q) 3'0 try
(3)
is doubled
is tripled l.<
(3) 2.8 t, -A
(4) 4.4 (4) remains unchanged
? English
ACHLL/DD/Page 21 €PACE FOR ROUGH WORK
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