CONFIDENTIAL* (SULIT*) 2

PUSAT TINGKATAN ENAM MOD (II), SMK TAMAN JOHOR JAYA 1

UJIAN PENILAIAN PRA-PENTAKSIRAN (1) SEM 1 2016
SUBJECT : CHEMISTRY
Name : ____________________________________ Tingkatan : LOWER 6 ___________
Section A [15 marks]

1 A 6 D 11 C
2 C 7 A 12 D
3 C 8 D 13 D
4 D 9 A 14 C
5 B 10 D 15 D

16. a) i. - peak with label [1] - scale labeled [1] iii. mol of salicylic acid = 9.26 / 138 @ 0.0671 mol [1]
mol of acetic anhydride = 8.54 / 102 @ 0.0837 mol [1]
mass of aspirin = 0.0671 x 180 @ 12.1 g [1]
% yield = 10.9 / 12.1 = 90.1% (3 s.f.) [1]
19.a) - Li2+ has 1 electron / single electron system [1]
- electron absorbed energy and excite to higher level [1]
- electron at excited state is unstable [1]
- as e- fall from higher level to lower, excess energy is
ii.- Ar = 28(29.8) + 29(1.5) + 30(1.0) / 29.8 + 1.5 + 1.0 [1] released / electromagnetic wave emitted / photon energy is
= 28.1 (3 sf) [1] released [1]
b) i. m/e 18 : (H2O)+ ; 34 : (CH318OH)+ ; 60 : (CH3COOH)+ - ∆E = hf @ ∆E = hc / λ [1]
All 3 correct [2] ; 2 or 1 correct [1] - Energy level diagram [1] Spectra [1] [2]
ii. C-18O bond broken [1] n=∞
17. a) i. Lyman ; I - draw ↓ from n = 3 to n = 1 [1] n= 5
Balmer ; II - draw ↓ from n = 4 to n = 2 [1] n= 4
ii) ∆E = hf @ ∆E = hc / λ [1] n= 3
∆E = 6.63 x 10-34 x 3.0 x 108 / 480 x 10-9 @ 4.14 x 10-19 [1]
∆H = 4.14 x 10-19 x 6.02 x 1023 = 249 kJ mol-1 (3 s.f.) [1] n= 2
b) i. Orbital obey Pauli's Exclusion Principle [1]
ii. half filled 3d orbitals has extra stability [1]
iii. in a set of degenerate orbitals (orbitals with same n= 1
energy level) , electrons occupied each orbital with single b) - X : 1s22s22p63s23p63d84s2 @ 1s22s22p63s23p64s23d8 [1]
parallel spin electron before pairing [1] - Y : 1s22s22p63s23p63d104s1 @ 1s22s22p63s23p64s13d10 [1]
18. a) i. A is negative charge [1] - In Y, full filled 3d orbital has extra stability [1]
- as cation (or positively charged ion) is attract to it [1] - 4s orbital in Y is filled singly / with 1 e- [1]
ii. Atom with the same number of proton (atomic num) [1] c) i. orbital is space with high probability to find an
- different nucleon number / number of neutron / mass electron [1]
number [1] - 1s orbital [1] ; 2s orbital [1] ; shape of 2p [1]
- yFe+ deflect further than xFe+ [1] - label 2px ; 2py and 2pz [1]
- since m/e @ yFe+ is heavier [1]
b) i. mol of aspirin = 0.400 / 180 @ 2.22 x 10-3 [1]
- mass of salicylic acid = 2.22 x 10-3 x 138 [1]
- = 0.307 g (3 s.f.) [1]
ii. % yield = actual mass / theoretical mass x 100 [1]
74.9 = 0.307 / a x 100 [1] (no axis penalise 1 mark)
a = 0.410 g [1]

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20 a) i. each structure [1] x 2 [2] b) - Ground state [1] - Hybridised state [1]

ii. - NaCl consist of ionic bond [1] - overlapping orbital diagram [1]
- hold by giant ionic crystal lattice [1] - labelled π-bond and σ-bond [1]
- which give NaCl a high melting point [1] - shape : trigonal planar [1]
- but made solid NaCl an insulator of electricity [1] - angle of bond pair electron repulsion = 120o [1]
iii. - at room temperature, aluminium chloride exist as dimer [1]
- Structure of dimer [1] π σ
σ
σ
σ
- when heated, Al2Cl6 dissociate / decomposed to AlCl3 [1]
σ

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