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Renewable Energy
journal homepage: www.elsevier.com/locate/renene
a r t i c l e i n f o a b s t r a c t
Article history: A mathematical model which was developed to predict steady state performance of a biomass downdraft
Received 20 July 2010 gasifier/spark ignition engine power system is described. A mathematical model of the integrated system
Accepted 3 June 2011 consists of two parts: the fixed bed downdraft gasifier and spark ignition internal combustion engine
Available online 20 July 2011
models. For calculations the gasifier is split into three zones, namely drying e pyrolysis, oxidation and
reduction sections. The gasifier’s mathematical model consists of three separate sub-models, each
Keywords:
describing the processes in the corresponding zone. The process taking place in the reduction zone has
Biomass gasification
been described using chemical kinetic principles in order to avoid introduction of assumptions related to
Fixed bed downdraft gasifier
Spark ignition internal combustion engine
achievement of the thermo-chemical equilibrium state during gasifier’s operation. The model is capable
Modelling to accurately predict molar concentrations of different species in syngas (CO2, CO, H2O, H2, CH4 and N2)
Experiment and the temperature profile in the gasifier along its height. This information then can be used for sizing
the reactor and material selection. The engine’s model is based on the fueleair thermodynamic cycle for
spark ignition engines and such model takes into account the composition of syngas used as fuel. The
engine’s model also takes into account effects of heat losses in the cycle through the walls of the
cylinders and due to the gas blow by. Finally, the influence of dissociation processes during the
combustion and the residual gases remaining in the cylinders at the beginning of the compression stroke
is accounted for computations of the engine’s performance. The numerical results obtained using the
proposed model are in a good agreement with data produced with the use of other theoretical models
and experimental data published in open literature and with experimental data obtained in these
investigations. The proposed model is applicable for modelling integrated downdraft gasifier/engine
biomass energy systems and can be used for more accurate adjustment of design parameters of the
gasifier and the engine in order to provide the higher overall efficiency of the system.
Ó 2011 Elsevier Ltd. All rights reserved.
0960-1481/$ e see front matter Ó 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.renene.2011.06.008
98 F. Centeno et al. / Renewable Energy 37 (2012) 97e108
model of a spark ignition internal combustion engine is used which Thermal power Up to 50 kW
is based on the fueleair thermodynamic cycle. Such the cycle takes Expected engine electrical power Up to 10 kW
into account the composition of syngas as fuel, heat losses in the Specific thermal power 1200 500 kW/m2
Biomass mass consumption rate 12 kg/h
cycle due to heat transfer to the walls of the engine cylinders, the (15% moisture content wet basis)
dissociation processes which occur during combustion of fuel and Biomass particles size 2e6 cm
the blow by (the leakage of gases between piston sealing rings and Air factor 0,35
the cylinder wall). Additionally, the engine’s model accounts for the
influence of residual gases in the cylinder at the beginning of the
compression stroke and for variations in thermo-physical proper- conversion by controlling and adjusting the air flow supplied to the
ties of the fueleair and residual gases mixture and of combustion reactor. The reactor is made of vertical sections and, in general, can
products. be used as either single- or double-stage air-supply reactor with
separate air-inlets to each section.
2. Experimental setup To avoid channeling and bridging within the volume of biomass
inside the reactor, a vibrating mechanism driven by an electrical
Fig. 1 presents an appearance of a 30e50 kWth fixed bed motor with a special timing device is installed and this mechanism
downdraft gasifier built by Thermoequip for tests at NEST of the generates vibration motions inside biomass at regular time inter-
Federal University of Itajuba. The gasifier is for the production of vals. Such vibrations maintain continuous downwards movement
syngas from wood blocks and is coupled to an internal combustion of biomass in the reactor. Another similar vibrating mechanism is
engine. When used with internal combustion engines gas produced installed in the lower part of the gasifier to provide grate shaking
(further referred to as producer gas or syngas) should satisfy the which results in the ash discharge. Fig. 2 presents the system’s
engine’s manufacturer fuel quality requirements regarding the tar schematic including an auxiliary equipment.
and particulate matter concentration which should be less than If the gasifier works with a single stage of the air supply then the
35 mg/Nm3 at the gasifier’s exit and less than 10 mg/Nm3 at the controlled amount of air is provided to its middle section. When
fabric filter outlet, respectively. The gasifier’s design specification is used as a double-stage gasifier, the air supply to the reactor’s first
presented in Table 1. The gasifier is made of carbon steel with an stage provides conditions for biomass partial combustion with
internal refractory layer. Its total height considering the biomass
feeding hopper and the ash discharge system is about 2.2 m. The
internal and outer diameters of the casing are 300 and 500 mm,
respectively. Several K-type thermocouples are installed inside the
reactor along the gasifier’s height to measure temperature levels in
its different sections. Information on the thermal state inside the
reactor is required to maintain optimal operational conditions to
efficiently carry out thermo-chemical processes of biomass
Fig. 1. An appearance of the fixed bed downdraft gasifier tested at the Federal
University of Itajuba. Fig. 2. Schematic diagram of the downdraft gasifier.
F. Centeno et al. / Renewable Energy 37 (2012) 97e108 99
a heat release maintaining the drying and pyrolysis phases. The conditions. In the tests the mass flow rates of syngas and air were
drying section is located in the gasifier’s top part, where the gradually increased and the engine’s speed was maintained at
distillation process of the lighter compounds of biomass takes 1800 rpm by increasing the engine’s load. The electrical power
place. In the pyrolysis zone, which is located just below the drying produced by the engine’s generator varied from 1.45 to about
zone, the volatilization of the biomass organic compounds occurs 5 kWe. The original engine built for operation with LPG produces up
and char is produced. This char is gasified later in the process. The to 10 kWe and therefore the engine’s power de-rating when fuelled
main goal for using the second stage of the air supply to the with syngas is about 50%.
oxidation zone is efficient conversion of tar into syngas to such
a level which satisfies requirements for its application in ICEs.
3. Calculation scheme of the gasifier
Additionally, the second stage air supply also contributes to the
oxidation and reduction processes taking place in the reactor.
Fig. 4 shows the calculation scheme of the downdraft gasifier
Syngas leaves the reactor through the exit in its lower part
with three separate zones used in the mathematical modeling
passing through a layer of glowing char and ashes and this provides
process. The downdraft gasifier is a fixed bed reactor, in which
an additional cleaning effect. As mentioned above, the grate sup-
biomass is fed from the top whilst air is supplied to the reactor in its
porting the bed is vibrated at regular time intervals for discharging
middle section and syngas comes out the exit at the bottom of the
ashes. The particulate matter in syngas is removed in two phases:
reactor.
first syngas flows through a cyclone separator, which has an
Drying and pyrolysis processes take place at the top section.
internal insulation layer to maintain the high temperature of
With the increase in the biomass temperature moisture is released
syngas which is necessary for the efficient operation of the catalytic
and thermal decomposition of biomass takes place resulting in
reformer reactor e CRR. In this reactor tar, which was not thermally
production of char, water vapour and a number of volatile species
cracked in the gasifier, is catalytically converted into hydrogen and
such as CO, CO2, H2, CH4 and C2H2. The sub-model for description of
methane. The CCR is made of nickel wire coils placed in the ther-
these processes in the gasifier’s top section is based on the model of
mally insulated cylindrical steel casing and operates at the
the dryingepyrolysis zone proposed by Ratnadhariya and Channi-
800e900 C temperature range. After passing the CCR syngas is
wala [5].
cooled down and then is directed to the fabric filter in which the
The products leaving the zone of drying and pyrolysis enter the
further particulate matter removal process takes place. Finally, the
second section, namely the oxidation zone. An accurately
cleaned and cooled down syngas is accumulated in the special
controlled amount of air is continuously supplied to the reactor in
reservoir which stabilizes its flow rate to the engine. The heat
this section of the gasifier. In this zone combustible gases and solid
released during the cooling process of syngas is used to pre-heat air
fuel react with oxygen, contained in supplied air, to produce char,
supplied to the gasifier in a specially made air pre-heater.
tar and a mixture of CO, CO2, H2, CH4, N2 gases and water vapour.
The gasifier is coupled to the modified two-cylinder Yanmar
The nitrogen fraction of supplied air is considered to be inert in the
diesel engine which is shown in Fig. 3. The engine alterations
modeling process. The sub-model for the description of chemical
include installation of spark plugs in the head of cylinders (one per
cylinder) and application of a set of double regulating valves in the
engine’s syngas and air induction system. The double valve system
provides a finer adjustment of syngas and air mass flow rates. The
engine has the cylinder bore and piston stroke equal to 90 mm with
the compression ratio being 12. The ignition timing in the cylinders
can be regulated.
During experimental investigations the reactor was filled with
eucalyptus wood blocks and the gasifier operated in a single-stage
air-supply regime. Air was supplied to the oxidation zone of the
gasifier. The spark ignition engine was fuelled by syngas produced
in the gasifier and tested under variable loadeconstant speed
Fig. 3. A spark ignition internal combustion engine coupled to the gasifier. Fig. 4. A calculation scheme of the downdraft gasifier.
100 F. Centeno et al. / Renewable Energy 37 (2012) 97e108
processes in the oxidation zone is based on the model proposed by 26=16, see Storm et al. [13]; Berends and Brem [14]; Mastral
Ratnadhariya and Channiwala [5] and Baxter [6]. et al. [15]; Parikh et al. [16] and Van De Steene et al. [17].
The third (bottom) section of the reactor is the reduction zone
also known as the gasification zone. In this section of the gasifier The chemical reaction occurring in the zone can be presented as
products formed in the oxidation zone react with each other
according to the following four simultaneous reactions: the Bou- CbvC HbvH ObvO /np C C þ np CO2 CO2 þ np CO CO þ np CH4 CH4
douard, the water-gas (primary), the methanisation and the steam þ np H2 H2 þ np C2 H2 C2 H2 þ np H2 O H2 O ð3Þ
reforming. In the reduction zone nitrogen and tar are considered to
be inert. The final products formed in this zone are CO, CO2, H2, CH4, The mass balance in the zone is
N2 gases and water vapour with a relatively high concentration of
combustible gases. The sub-model for the description of processes bvC ¼ np C þ np CO2 þ np CO þ np CH4 þ 2np C2 H 2 (4)
in the reduction zone of the biomass gasifier is based on proposals
presented in studies by Giltrap et al. [1], Baxter [6]; Giltrap [7] and bvH ¼ 4np CH4 þ 2np H2 þ 2np C2 H 2 þ 2np H2 O (5)
Babu and Sheth [8].
bvO ¼ 2np CO2 þ np CO þ np H2 O (6)
4. Mathematical model of the gasifier
The energy balance in the zone is
As described above, the mathematical model of the gasifier h i
consists of three separate sub-models e one for each zone of the hfb þ w Dhf ¼ npt C Dhf pt C
þ np CO2 Dhf p CO2
þ np CO Dhf p CO
H2 O
gasifier. In accordance with chemical analysis the wet biomass
substance can be presented as the sum of the volatile and non- þ np CH4 Dhf p CH4
þ np H2 Dhf p H2
It is assumed that CO, CO2 and H2O produced during oxidation 4.3. The reduction zone sub-model
are added to the corresponding values of the same substances
produced during pyrolysis; The sub-model for the reduction zone is based on the model that
It is assumed that N2 entering the oxidation zone is an inert gas was originally presented by Giltrap [7] and Giltrap et al. [1]. In these
and does not participate in chemical reactions; articles authors propose that during the reduction process the
The products of reactions in the oxidation zone are char, CO, following four simultaneous reactions take place:
CO2, CH4, H2, H2O and N2, see Giltrap [7] and Giltrap et al. [1].
The overall chemical reaction taking place in the oxidation zone Reaction 1: C þ CO2 42CO (19)
can be presented as
!
E1 P2
npt C þ np CO2 þ np CO þ np CH4 þ 2np C2 H 2
r1 ¼ ðCRFÞA1 e PCO2 CO (23)
RT K2
¼ nox C þ nox CO2 þ nox CO þ nox CH4 (13)
E2 P PH
- For oxygen r2 ¼ ðCRFÞA2 e PH2 O CO 2 (24)
RT K3
8 0 9 q < qs
X dv X > >
dT 1 dP <1
>
pðq qs Þ =
¼ P i ri DHi v P x Rx cx T (29)
dz v x nx cx dz dz c ¼ 1 cos qs < q < qs þ qb (36)
>
>2 qb >
;
:
P P P
dv 1 x nx c x x Rx r DHi dP v 1 q>qs þ qb
¼ P i i
dz x nx cx þ nR n T dz T
where qs and qb are the angular positions of the shaft corresponding
P X
v x nx c x to the start of the heat release and the burn angle, respectively.
þ x Rx cx (30)
P The mass of the gas mixture in the cylinder is defined as
dP v2 C 0 ðq q1 Þ
¼ 1183 rgas þ 388:19v 79:896 (31) u
dz rair m ¼ m1 e (37)
The Runge-Kutta method was used in Matlab software to solve where m1 is the initial mass at q ¼ q1 (the start of the compression
the above system of the differential equations to obtain information stroke) and is specified from knowledge of the volumetric effi-
on the distribution of the concentration of six gas species, the ciency and the residual fraction.
temperature, the velocity and the pressure along the height of the The amount of the gas lost as a result of leakage between walls
reduction zone. of the cylinder and sealing rings is considerable in internal
combustion engines and the change rate of the mass of the gas
5. Mathematical model of the engine mixtures taking into account blow by can be expressed as
dm m_l C 0 m
The fueleair thermodynamics model was used to describe the ¼ ¼ (38)
operation of the syngas fuelled spark ignition engine. The detailed dq u u
description of such a model can be found in the textbook by Fer- where C0 is the blow by constant dependent on the design of sealing
guson [27] and the following are the main equations of this model rings and the cylinder.
which determine the calculation procedure for the engine. The enthalpy of the blow by gas
During the operation of the spark ignition engine the mixture of
fuel (syngas) and air is inducted into its cylinders through the inlet hl ¼ 1 c2 hu þ c2 hb (39)
valve. For a control volume, which represents the cylinder with its
content, the energy balance equation can be written as and this expression takes into account that a larger proportion of
the unburned gas will be leaking though sealing rings compared to
du dm dQ dV m_ h the unburned gas mass fraction.
m þu ¼ Pen l l (32)
dq dq dq dq u The magnitude of the heat introduced into the system will be
where m and u is the mass and internal energy of the mixture, expressed in terms of the heat loss:
respectively, in the cylinder of the engine; q is the engine’s crank
angle; Q, P, V are the heat transfer into the system, the pressure in dQ Q_ l Q_ b Q_ u
¼ ¼ (40)
the cylinder, respectively; m_ l and hl are the mass flow rate and the d q u u
enthalpy of the blow by gas, respectively; u is the angular speed of where
the shaft.
The variation of the cylinder volume is defined as Q_ b ¼ hAhtsb ðTb Twall Þ (41)
2
r1 1
V ¼ V0 1 þ
2
1 cos q þ 1 1 x sin2 q Q_ u ¼ hAhtsu ðTu Twall Þ (42)
2 x
(33) Here h is the average heat transfer coefficient; Ahts is the heat
transfer surface and Twall is the cylinder wall temperature.
where V0 is the cylinder volume at the instance when the piston is The heat transfer surfaces are calculated as
at its top dead centre (TDC) position; r e is the compression ratio; !
pb2 4V
x ¼ S/2l with S and l being the piston stroke and the connecting rod Ahtsb ¼ þ c1=2 (43)
length, respectively. 2 b
It is assumed that internal energy of this system is made up of
and
corresponding internal energies of burned and unburned mixtures
!0 1
as follows: pb2 4V @ 1=2 A
Ahtsu ¼ þ 1c (44)
u ¼ cub þ ð1 cÞuu (34) 2 b
where c is the mass fraction of the cylinder content which was In calculations it is assumed that the pressures of the burned
burned at the temperature Tb; ub and uu is the energy of the burned and unburned gases are equal.
gas and unburned gas at the corresponding temperatures Tb and Tu The model employed also allows to determine the composition
respectively. of the exhaust gases in the engine and the influence on the engine’s
Similarly, the specific volume of the system is performance of the fraction of the residual gases remaining in the
cylinder at the beginning of the compression stroke.
V Syngas is made of the mixture of combustible and incombustible
y¼ ¼ xyb þ ð1 xÞyu (35)
m gases and this was reflected in the description of fuel as having
F. Centeno et al. / Renewable Energy 37 (2012) 97e108 103
C 0 mh i
Here
dHl
¼ 1 c2 hu þ c2 hb (61)
Mi0 0 X6 d q u
x0i ¼ y with M ¼ 0
y0 M0 (50)
M0 i i¼1 i i In equations (56)e(61)
M 00 X6 1 dV VC 0
x00i ¼ i00 y00i with M 00 ¼ y00 Mi00 (51) A ¼ þ (62)
M i¼1 i m dq u
!
y0i ¼ v0i=X6 v0 (52) pb2
4V
i¼1 i þ "
2 b vb vlnvb 1=2 Tb Twall
B ¼ h c
y00i ¼ v00i =X6 v00 (53) um cpb vlnTb Tb
i¼1 i #
vu vlnvu Tu Twall
The residual mole fraction is determined as þ 1 c1=2 (63)
cpu vlnTu Twall
1
M 00 1
yr ¼ 1þ 0 1 (54) c c2 C 0
M f dc vlnvb hu hb dc
C ¼ ðvb vu Þ vb (64)
dq vlnTb cpb Tb dq u
where f is the residual mass fraction and its numerical value should
be defined before starting calculations. " #
The final composition of the products taking into account the v2b vlnvb 2 vb vlnvb
D ¼ c þ (65)
main dissociation processes is defined as cpb Tb vlnTb Pen vlnPen
Table 3
Proximate and ultimate analysis of Rubber Wood, Jayah et al.
(2003).
Proximate analysis
Volatile material 80.1
Fixed carbon 19.2
Ash content 0.7
Ultimate analysis (% dry basis)
C 50.6
H 6.5
N 0
Ash content (A) 0.7
O ¼ 100 e (C þ H þ N þ A) 42.2
Table 5
Gasification parameters used during experiments and modeling.
concentrations of CO and H2, but underestimates the production of Fig. 7. Comparison of species concentrations obtained using various models and from
methane. experimental data.
Dissimilarity in experimental and theoretical results can be
explained by a number of factors. Thus, due to the effect of vibrating Fig. 8 shows results obtained during the experiments with the
mechanism the gasifier in real conditions operates in the unsteady modified Yanmar engine fuelled by syngas, which was produced by
regime. Furthermore, to improve the mathematical model’s accu- the single-stage air-supply downdraft gasifier, and results of
racy it is necessary to take into account all heat losses which take modelling the performance of this engine. The experiments and
place during the operation of the gasifier and also the influence of modelling were performed for variable loadeconstant speed
the catalytic reformer reactor. conditions, as it was described previously. In theoretical simula-
However, the overall accuracy of predictions by the proposed tions of the engine’ working process the composition of syngas was
model is adequate for engineering purposes and it can be obtained using the gasifier’s model. In experiments the electrical
successfully used in the designing process. power output varied from about 1.5 to 5 kWe at the engine’s speed
of 1800 rpm and it can be seen in Fig. 8 that at the higher loads the
6.2. Calibration of the engine’s model predicted values of the electrical power output are greater than
experimental data. This can be explained by overestimation of the
In reality syngas is a mixture of several gases such as hydrogen, hydrogen concentration in syngas during modelling the gasifier
carbon monoxide, methane and nitrogen. As highlighted in the operation. It was also found that the results of the engine modelling
description of the mathematical model of the engine syngas is are very sensitive to the amount of air/fuel mixture in the cylinder
assumed to be hydrocarbon fuel with a chemical composition being at the beginning of the compression process and this value was
CaHbOgNd, where coefficients a, b, g and d are defined using infor- assumed to be proportional to the positions of the regulating
mation on the syngas chemical composition obtained during the valves.
gasifier modelling process. Data on the syngas composition is also In general, the engine’s model provides an acceptable accuracy in
used to calculate the calorific value of fuel. Due to this assumption predicting the engine’s performance and can be used jointly with the
made the heat release rate calculated during modelling the oper- mathematical model of the gasifier for the analysis of the operation
ation of the engine is not an accurate representation of the real of the power system which includes a single-stage air-supply
syngas combustion process. Furthermore, an accurate quantitative downdraft gasifier coupled to an internal combustion engine.
prediction of pollutant emissions is an extremely challenging task
even for most advanced mathematical models which take into 6.3. Mathematical modelling of the operation of the whole biomass
account detailed kinetics of chemical reactions during the power system
combustion processes in IC engines. Due to the assumptions
described above the model is unable to accurately predict pollut- The mathematical models of the downdraft gasifier and of the
ants formation and more complex approaches should be deployed engine were verified separately against experimental information
to resolve this problem. Therefore attention in this work is focused
Table 7
on presenting results on the integral performance characteristic of
Results of proximate and ultimate analysis of biomass
the engine such as its power output. (eucalyptus) used in tests.
Eucalyptus
Table 6 Proximate analysis
Proximate and ultimate analysis of Douglas Fir tree bark. Volatile matter 75.35
Ash 3.35
Proximate analysis
Fixed carbon 21.30
Parameter % d. b.
HHV 18.64 MJ/kg
Volatile material 73
Moisture 10.32
Fixed carbon 25.8
Ultimate analysis
Ash content 1.2
C 46.04
Ultimate analysis
H 5.82
Parameter %
N 0
C 56.2
Ash 3.35
H 5.9
O 44.78
N 0
Ash content (A) 1.2
O ¼ 100 - CþH þ N þ A) 36.7
106 F. Centeno et al. / Renewable Energy 37 (2012) 97e108
Table 8
Comparison of theoretical and experimental fractions of CO, CH4 and H2 gases in
syngas.
and the comparison performed demonstrated a satisfactory accu- operation when qs ¼ 24 before TDC and f ¼ 0.9434. The
racy of these mathematical models in the prediction of the gasifier increasing rate of the reduction of power for the case in which
and engine performance. In the following stage of investigations syngas is used as fuel is determined by the decrease in the volu-
these two models were coupled together in such a way that output metric ratio and by the reduction in the heat release rate during the
data from the gasifier’s model was used as input information in the combustion process of syngas.
engine’s model. The operation of the whole biomass power system Fig. 10 demonstrates that the highest maximum power for the
for a range of values of different operational parameters such as the engine running at the full throttle conditions at the 1800 rpm speed
speed of the engine, the spark advancement, the air factor and the is achieved by setting the spark ignition to occur at the instance of
biomass moisture content was analyzed in order to quantify the the cycle corresponding to 25..-30 before TDC.
influence of the above parameters on the overall performance of Finally, Fig. 11 shows the influence of the gasifier air factor and
the system. biomass moisture on the indicted power of the engine running at
As expected, the mathematical model of the engine indicates the full throttle conditions at the speed of 1800 rpm. The air factor
that replacement of gasoline as fuel by syngas results in the was varied between 0.25 and 0.4 and the moister content was risen
considerable reduction in the power output and this is mainly due from 5 to 20%. Calculations show that the further rise in the
to the lower calorific value of syngas which reduces the heat release biomass moisture content reduces the calorific value of syngas
rate during the combustion process and results in lower values of produced in the gasification process and, consequently, decreases
the maximum pressure and temperature in the cylinder. The the engine’s power output. For a fixed value of the moisture content
reduction in the power output is also affected by a decrease in the the indicated power sharply reduces with an increase in the air
volumetric ratio of the engine. factor from 0.25 to 0.4. For the constant value of the air factor the
Figs. 9e11 present some of results obtained. It can be seen in indicted power of the engine increases with a rise in the moisture
Fig. 9 that the indicated power of the engine fuelled by syngas rises content from 5 to 20%. In both the cases the rise in the indicated
with an increase in the engine speed and the power de-rating power is a result of the improvement in the calorific value of syngas
compared to the case, when gasoline is used as fuel, is about due to the greater concentrations of CH4 and H2, formed in the
50e60% for the engine’s speed varying between 1500 and gasification process.
2000 rpm. These calculations were conducted for the full throttle Judgment based Uncertainty Analysis [30] was used for evalu-
ation of experimental data presented in Table 8 on the chemical
composition of the syngas and in Fig. 8 on the electrical power