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REVIEW

SPs into the metal is determined by the skin


depth, which can be on the order of 10 nm—two
orders of magnitude smaller than the wavelength
Plasmonics: Merging Photonics and of the light in air. This feature of SPs provides
the possibility of localization and the guiding of
Electronics at Nanoscale Dimensions light in subwavelength metallic structures, and it
can be used to construct miniaturized optoelec-
tronic circuits with subwavelength components
Ekmel Ozbay*
(5). Such plasmonic optoelectronic circuits, or
plasmonic chips, will consist of various compo-
Electronic circuits provide us with the ability to control the transport and storage of electrons.
nents such as waveguides, switches, modulators,
However, the performance of electronic circuits is now becoming rather limited when digital
and couplers, which can be used to carry the
information needs to be sent from one point to another. Photonics offers an effective solution
optical signals to different parts of the circuit.
to this problem by implementing optical communication systems based on optical fibers and
Plasmonic waveguides are used to guide the
photonic circuits. Unfortunately, the micrometer-scale bulky components of photonics have
plasmonic signals in these circuits and can be
limited the integration of these components into electronic chips, which are now measured in
configured by using various geometries (6).
nanometers. Surface plasmon–based circuits, which merge electronics and photonics at the
Thin metal films of finite width embedded in
nanoscale, may offer a solution to this size-compatibility problem. Here we review the current
a dielectric can be used as plasmonic wave-
status and future prospects of plasmonics in various applications including plasmonic chips,
guides. This geometry offers the best propa-
light generation, and nanolithography.
gation results for a surface plasmon–based
waveguide, because the measured propaga-

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oday_s state-of-the-art microprocessors photonics called plasmonics. Plasmonic circuits tion length for operation with light at a wave-

T use ultrafast transistors with dimen-


sions on the order of 50 nm. Although
it is now routine to produce fast transistors,
offer the potential to carry optical signals and
electric currents through the same thin metal
circuitry, thereby creating the ability to com-
length of 1550 nm is reported to be as long as
13.6 mm. However, the localization for both
directions is on the order of a few micrometers
there is a major problem in carrying digital in- bine the superior technical advantages of pho- in this plasmonic waveguide geometry (7). To
formation to the other end of a microprocessor tonics and electronics on the same chip. achieve subwavelength localization, one can
that may be a few centimeters away. Whereas reduce the width of the wire and subsequently
copper wire interconnects carry digital infor- Plasmonic Chips: Light on a Wire use the SPs to guide the light underneath this
mation, interconnect scaling has been insuffi- What limits the integration of optical and elec- nanowire. In nanowires, the confinement of
cient to provide the necessary connections tronic circuits most is their respective sizes. the electrons in two dimensions leads to well-
required by an exponentially growing transis- Electronic circuits can be fabricated at di- defined dipole surface plasmon resonances, if
tor count. Unlike transistors, for which per- mensions below 100 nm. On the other hand, the lateral dimensions of the wire are much
formance improves with scaling, the delay of the wavelength of light used in photonics cir- smaller than the wavelength of the exiting
interconnects increases and becomes a substan- cuits is on the order of 1000 nm. When the light. By using this method, a 200-nm-wide
tial limitation to the speed of digital circuits dimensions of an optical component become and 50-nm-high gold nanowire was fabricated.
(1). This limitation has become more evident close to the wavelength of light, the propaga- This plasmonic waveguide was then locally
over the past 1 to 2 years, as the annual in- tion of light is obstructed by optical diffrac- excited at a light wavelength of 800 nm (8).
crease rate of the clock speed of microproces- tion (2), which therefore limits the minimum By direct imaging of the optical near field
sors slowed greatly. size of optical structures including lenses, fi- with subwavelength-resolution photon scanning
Optical interconnects such as fiber optic bers, and optical integrated circuits. Although tunneling microscopy, light transport was ob-
cables can carry digital data with a capacity the introduction of photonic crystals brings a served along the nanowire over a distance of a
91000 times that of electronic interconnects. partial solution to these problems, the pho- few micrometers. Although this is a clear dem-
Unfortunately, fiber optic cables are È1000 tonic crystal itself has to be several wave- onstration of subwavelength guiding, the losses
times larger compared with electronic com- lengths long, because the typical period is on associated with the resistive heating within the
ponents, and the two technologies are diffi- the order of half of a wavelength (3). metal limit the maximum propagation length of
cult to combine on the same circuit. External Surface plasmon–based photonics, or ‘‘plas- light within these structures. In order to avoid
optical interconnects that can connect differ- monics,’’ may offer a solution to this dilemma, the ohmic losses, one can envision using an
ent parts of the electronic chips via air or fiber because plasmonics has both the capacity of array of nanoparticle resonators. The resonant
cables have also been proposed. However, the photonics and the miniaturization of electronics. structure of the nanoparticles can be used to
resulting bulky configuration has limited the Surface plasmons (SPs) provide the opportunity guide the light, whereas the reduced metallic
implementation of this idea. The ideal solution to confine light to very small dimensions. SPs volume means a substantial reduction in ohmic
would be to have a circuit with nanoscale fea- are light waves that occur at a metal/dielectric losses. Stefan Maier and co-workers (9) used
tures that can carry optical signals and electric interface, where a group of electrons is collect- such a structure (Fig. 1A), in which nanoscale
currents. One such proposal is surface plasmons, ively moving back and forth (4). These waves gold dots were patterned on a silicon-on-
which are electromagnetic waves that propagate are trapped near the surface as they interact insulator wafer to define the plasmon propaga-
along the surface of a conductor. The interac- with the plasma of electrons near the surface tion path. Figure 1B shows scanning electron
tion of light with matter in nanostructured of the metal. The resonant interaction between micrographs (SEMs) of the fabricated plas-
metallic structures has led to a new branch of electron-charged oscillations near the surface monics waveguides designed for operation at a
of the metal and the electromagnetic field of wavelength of 1500 nm. The waveguide struc-
Nanotechnology Research Center, Bilkent University, the light creates the SP and results in rather ture is not uniform across its width where the
Bilkent, Ankara 06800 Turkey. unique properties. SPs are bound to the metallic size of the metal dots is reduced from 80 nm 
*To whom correspondence should be addressed. E-mail: surface with exponentially decaying fields in 80 nm at the center to 50 nm  50 nm at the
ozbay@bilkent.edu.tr both neighboring media. The decay length of edges. This has the effect of confining the

www.sciencemag.org SCIENCE VOL 311 13 JANUARY 2006 189


REVIEW
energy more intently to the middle of the guide obviously too short for any application of these guides. The calculated gain requirements suggest
(Fig. 1A). This structure has been shown to plasmonic structures. The propagation distance that lossless, gain-assisted surface plasmon prop-
have a decay length longer than 50 mm, where- performance of the V groove–shaped SP wave- agation can be achieved in practice for infrared
as theoretical simulations predict a decay lengthguides has been recently extended to 250 mm wavelengths.
in the order of 500 mm. Figure 1A shows that (11). By using focused ion-beam milling tech- Recently, a new kind of SP geometry has
niques, 460-mm-long V groove–shaped plas-
although the localization along the x direction is been suggested to solve theoretically the issue
subwavelength, the localization extends a few monic waveguides were fabricated on gold of confinement versus propagation length (14).
periods along the y direction, which corresponds layers that were deposited on a substrate of The new mechanism for confining much more
to localization on the order of a wavelength. fused silica. Scanning near-field optical micro- field in the low-index region rather than in the
Therefore, the subwavelength localization of scope measurements of these structures were adjacent high-index region is based on the rel-
SPs is limited only to the x direction. made at optical communication wavelengths ative dispersive characteristics of different sur-
To achieve localization in both directions, (1425 to 1620 nm). For a structure with a face plasmon modes that are present in these
a new type of highly localized plasmon has 0.6-mm-wide and 1.0-mm-deep groove wedge structures. The structures have a subwavelength
been analyzed and experimentally demon- (corresponding to a È17- wedge angle), the modal size and very slow group velocity over
strated in metals with V-shaped grooves (10). SP propagation lengths were measured to be an unusually large frequency bandwidth. Sim-
The major features of plasmons in V grooves within 90 to 250 mm. The mode was well ulations show that the structures exhibit ab-
include a combination of strong localization, confined along the lateral direction, and the sorption losses limited only by the intrinsic loss
single-mode operation, the possibility of nearly measured mode width was 1.1 mm. of the metal. Currently, there is no experimen-
100% transmission through sharp bends, and a Thus there is a basic trade-off in all plas- tal data that supports these simulations. How-
high tolerance to structural imperfections. For mon waveguide geometries between mode ever, the new suggested SP structure is quite
the localization and guiding to occur, the wedge size and propagation loss. One can have a low promising and deserves attention from the ex-
angle (q) of the V groove should be smaller propagation loss at the expense of a large mode perimental research groups that are working on

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than a critical angle. For V grooves made from size, or a high propagation loss with highly plasmonic waveguides.
silver with a vacuum wavelength of 0.6328 mm, confined light. A hybrid approach, where both Plasmonic chips will have optical input and
this critical wedge angle is found to be 102-. plasmonic and dielectric waveguides are used, output ports, and these ports will be optically
The measured lateral localization of a structure has been suggested as a solution to this trade- connected to conventional diffraction-limited
with a 40- wedge angle is È300 nm, which is off (12). These waveguides are designed for photonic devices by plasmonic couplers (8).
superior to the nanoparticle-based plasmonic 1500-nm operation and exhibit losses on the The couplers should have high conversion effi-
waveguides. However, the reported experimen- order of –1.2 dB/mm, and they can guide light ciency, along with a transmission length that is
tal and theoretical decay lengths for the same around 0.5-mm bends. Light can also be ef- longer than the optical wavelength to avoid the
V groove–shaped plasmonic waveguide are ficiently coupled between more convention- direct coupling of the propagating far-field light
1.5 mm and 2.25 mm, respectively, which are al silicon waveguides, where these plasmon to the nanophotonic devices inside the plasmonic
waveguides with compact couplers chip. A promising candidate for this feature
and surface plasmon optical devices can be fabricated by combining hemispher-
can be constructed by using planar ical metallic nanoparticles that work as a plas-
circuit fabrication techniques. Introduc- monic condenser and a nanodot-based plasmonic
ing gain to the plasmonic waveguides waveguide (15). When the focused plasmons
can also bring a solution to the limited move into the coupler, the transmission length
propagation distances. This situation is through the coupler is 4.0 mm. Nanodots can
theoretically investigated by consider- also be used for focusing SPs into a spot of
ing the propagation of SPs on metallic high near-field intensity having a subwave-
waveguides adjacent to a gain medium length width (16). Figure 2A shows the SEM
(13). The analytic analysis and numeric image of such a sample containing 19 200-nm
simulation results show that the gain through-holes arranged on a quarter circle with
Fig. 1. (A) FDTD simulations show the electric field medium assists the SP propagation by a 5-mm radius. The SPs originating from these
produced within the plasmon waveguide structure. (B) A compensating for the metal losses, nanodots are coupled to a metal nanostrip wave-
plasmon waveguide consists of nanoscale gold dots on a making it possible to propagate SPs with guide. A near-field scanning optical microsco-
silicon-on-insulator surface. [Adapted from (9)] little or no loss on metal boundaries and py (NSOM) image of this structure was taken
at 532-nm incident wavelength with horizontal
polarization. The near-field image (Fig. 2B)
shows that the focused SPs propagate along
the subwavelength metal guide, where they par-
tially penetrate into the 100-nm-wide bifurca-
tion at the end of the guide, thus overcoming
the diffraction limit of conventional optics.
The measured propagation distance is limited
to 2 mm, and the propagation distances are
expected to be much longer with improved
fabrication processes and by using properly
designed metal-dielectric hybrid structures.
The combination of focusing arrays and nano-
waveguides may serve as a basic element in
planar plasmonic circuits.
Fig. 2. (A) SEM image of a nanodot focusing array coupled to a 250-nm-wide Ag strip guide. (B) Active control of plasmons is needed to
NSOM image of the SP intensity showing subwavelength focusing. [Adapted from (15)] achieve plasmonic modulators and switches.

190 13 JANUARY 2006 VOL 311 SCIENCE www.sciencemag.org


REVIEW
Plasmonic signals in a metal-on-dielectric wave- Plasmonics can be used to solve this efficiency calized surface plasmons in metal nanostruc-
guide containing a gallium section a few mi- problem (21). When InGaN/GaN quantum wells tures. The enhancement factors of the optical
crons long can be effectively controlled by (QWs) are coated by nanometer silver or alu- near-field and voltage signal are 1.8 and 2,
switching the structural phase of gallium (17). minum films, the resulting SPs increase the den- respectively. Reducing the nano-aperture re-
The switching can be achieved by either chang- sity of states and the spontaneous emission rate duces the optical resolution of the VCSEL probe
ing the waveguide temperature or by external in the semiconductor. This leads to the enhance- from 240 nm to 130 nm. These results show that
optical excitation. The signal modulation depth ment of light emission by SP-QW coupling, plasmon enhancement will be helpful for real-
can exceed 80%, and switching times are which results in large enhancements of internal izing high-resolution optical near-field VCSEL
expected to be in the picosecond time scale. quantum efficiencies. Time-resolved photolu- probes.
The realization of an active plasmonic device minescence spectroscopy measurements were SPs also play a key role in the transmis-
by combining thin polymer films containing used to achieve a 32-fold increase in the spon- sion properties of single apertures and the en-
molecular chromophores with thin silver film has taneous emission rate of an InGaN/GaN QW at hanced transmission through subwavelength
also been reported (18). The molecular plas- 440 nm (22). This enhancement of the emission hole arrays (26, 27). There has been intense
monic device consists of two polymer layers, rates and intensities results from the efficient controversy on the physical origin of the en-
one containing donor chromophore molecules energy transfer from electron-hole pair recom- hanced transmission in these structures (28).
and the other containing acceptor fluorophore bination in the QW to electron vibrations of Recent theoretical and experimental analyses
molecules. Coupled SPs are shown to provide SPs at the metal-coated surface of the semi- suggest that the enhanced transmission can be
an effective transfer of excitation energy from conductor heterostructure. This QW-SP cou- explained by diffraction assisted by the enhanced
donor molecules to acceptor molecules on op- pling is expected to lead to a new class of super fields associated with SPs (29, 30). Although
posite sides of metal film up to 120 nanometers bright and high-speed LEDs that offer realistic SPs are mostly studied at optical frequencies,
thick. The donors absorb incident light and alternatives to conventional fluorescent tubes. they can also be observed at the microwave,
transfer this excitation energy by dipole-dipole Similar promising results were obtained millimeter-wave, and THz frequencies (31).

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interactions to the acceptors. The acceptors then for organic LEDs (OLEDs), which are now By texturing the metallic surface with a subwave-
emit their characteristic fluorescence. These re- becoming popular as digital displays. In an length pattern, we can create SPs that are re-
sults are preliminary demonstrations for active OLED, up to 40% of the power that can be sponsible for enhanced transmission observed at
control of plasmonic propagation, and future coupled into air is lost due to quenching by microwave and millimeter wave frequencies for
research should focus on the investigation of SP modes. A periodic microstructure can be 1D and 2D gratings with subwavelength aper-
electro-optic, all-optical, and piezoelectric mod- used to recover the power that is normally tures (32, 33). A subwavelength circular aper-
ulation of subwavelength plasmon waveguide lost to SPs. Using this approach, strong photo- ture with concentric periodic grooves can be
transmission. luminescence has been reported from a top- used to obtain enhanced microwave transmis-
Extensive research efforts are being put emitting organic light-emitting structure, where sion near the surface plasmon resonance fre-
forth in order to achieve an all-plasmonic chip. emission takes place through a thin silver film quency (34). These results show that enhanced
In the near term, plasmonic interconnects may (23). The results indicate that the addition of a transmission from a subwavelength circular
be used to address the capacity problem in nanopatterned dielectric overlayer to the cath- annular aperture with a grating is assisted by
digital circuits including microprocessors. Con- ode of top-emitting OLEDs should increase the guided mode of the coaxial waveguide and
ventional electronic interconnects may be used light emission from these structures by two or- coupling to the surface plasmons. A 145-fold
to transfer the digital data among the local ders of magnitude over a similar planar struc- enhancement factor is obtained with a subwave-
arrays of electronic transistors. But, when a lot ture. The dielectric layer acts to couple the length circular annular aperture surrounded
of data need to travel from one section of a surface plasmon-polariton modes on the two by concentric periodic grooves. The same
chip to another remote section of the chip, metal surfaces, whereas its corrugated morphol- structure also exhibits beaming properties that
electronic information could be converted to ogy allows the modes to scatter to light. An are similar to the beaming effects observed from
plasmonic information, sent along a plasmonic OLED using a p-conjugated polymer emissive a subwavelength aperture at optical wavelengths
wire, and converted back to electronic informa- layer sandwiched between two semitransparent (35). Figure 3 shows the electromagnetic waves
tion at the destination. Unfortunately, the cur- electrodes was also reported (24). One of the from a subwavelength circular annular aperture
rent performance of plasmonic waveguides is electrodes was an optically thin gold film anode, surrounded by concentric periodic grooves. The
insufficient for this kind of application, and whereas the cathode was in the form of an radiated electromagnetic waves have a very
there is an urgent need for more work in this optically thick aluminum (Al) film with pat- strong angular confinement around the sur-
area. If plasmonic components can be suc- terned periodic subwavelength two-dimensional face mode resonance frequency, in which the
cessfully implemented as digital highways into (2D) hole array that showed anomalous trans- angular divergence of the beam is T3-. En-
electronic circuits, this will be one of the ‘‘killer mission in the spectral range of the polymer hanced transmission at THz wavelengths is
applications’’ of plasmonics. photoluminescence band. At similar current also reported for a freestanding metal foil per-
densities, a sevenfold electroluminescence ef- forated with periodic arrays of subwavelength
Plasmonic Light Sources ficiency enhancement was obtained with the apertures (36). The peak transmission at the
The emerging field of plasmonics is not only patterned Al device compared with a control lowest frequency resonance is È0.6 for each
limited to the propagation of light in structures device based on imperforated Al electrode, aperture array, which is a factor of È5 larger
with subwavelength dimensions. Plasmonics can demonstrating that the method of patterning than the fractional area occupied by the aper-
also help to generate and manipulate electro- the electrodes into 2D hole arrays is efficient tures. Doped semiconductors exhibit a behavior
magnetic radiation in various wavelengths from for this structure. Plasmonics can also be used at THz frequencies similar to that of metals at
optics to microwaves. Since their introduction to enhance the performance of lasers (25). A optical frequencies, thus they constitute an op-
by Nakamura in 1995 (19), InGaN-based semi- metal nano-aperture was fabricated on top of timal material for THz plasmonics (37). Enhanced
conductor light emitting diodes (LEDs) have a GaAs vertical cavity surface emitting laser transmission of THz radiation is observed by
become promising candidates for a variety of (VCSEL) for subwavelength optical near-field using arrays of subwavelength apertures struc-
solid-state lightning applications (20). How- probing. The optical near-field intensity and tured in n-type silicon. This enhancement can
ever, semiconductor-based LEDs are also no- the signal voltage of nano-aperture VCSELs be explained by the resonant tunneling of
torious for their low light-emission efficiencies. exhibit record high values because of the lo- SPs that can be excited at THz wavelengths

www.sciencemag.org SCIENCE VOL 311 13 JANUARY 2006 191


REVIEW
30 to 80 nm with exposure depths ranging from
12 to 45 nm can be achieved.
The performance of plasmonic nanolithog-
raphy can be boosted by using the ‘‘superlens’’
concept introduced by Pendry (40). A superlens
can be used to enhance evanescent waves via
the excitation of surface plasmons. The gain
obtained from plasmonic excitation inside the
superlens compensates for the loss of the eva-
nescent waves outside of the superlens. The
reconstructed evanescent waves can then be
used to restore an image below the diffraction
limit on the other side of the lens. This unusual
lens can be constructed by using a thin slab of
material with negative permittivity or perme-
ability, or both. By using silver as a natural
optical superlens, sub–diffraction-limited imag-
ing with 60 nanometer half-pitch resolution, or
one-sixth of the illumination wavelength, was
demonstrated (41). By proper design of the work-
Fig. 3. Calculated (A) and measured (B) electric field distribution from a subwavelength circular ing wavelength and the thickness of silver, which
annular aperture with a grating at the resonance frequency. The measured electric field intensity is allows access to a broad spectrum of subwave-

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confined to a narrow spatial region and propagates without diffracting into a wide angular region, length features, arbitrary nanostructures can also
which is in good agreement with the simulations. be imaged with good fidelity. Figure 4 com-
pares the performance of this superlens-based
plasmonic nanolithography to conventional nano-
lithography. A 365-nm exposure wavelength
was used for both nanolithography experiments.
The word ‘‘NANO’’ was printed as a mask by a
focused ion beam (FIB) system (Fig. 4A). Figure
4B was obtained with the superlens, and the
resulting image on the resist is almost perfect.
Figure 4C shows the diffraction limited image
obtained from the conventional lithography.
Figure 4D numerically compares both methods.
Although the resolution achieved by convention-
al methods is limited to È320 nm, the plasmonic
nanolithography method was able to generate an
image with Èfour times better resolution. Super-
resolution imaging using the same method was
also reported for a 50-nm-thick planar silver
Fig. 4. The images of an arbitrary object obtained by different methods. (A) FIB image of the superlens at wavelengths around 365 nm (42).
object. (B) The image obtained on photoresist with a silver superlens. (C) The image obtained on Gratings with periods down to 145 nm can be
photoresist with conventional lithography. (D) Comparison of both methods. [Adapted from (40)] resolved, which agrees well with the FDTD simu-
lations. These are the preliminary demonstrations
in doped semiconductors. The transmission in- falls within the sensitivity range of a photo- of superlens-based plasmonic nanolithography,
creases markedly as the aperture size is aug- resist, the resulting enhanced optical field that and additional research for further improvements
mented and as the array thickness is reduced. is close to the metal surface can locally cause in subwavelength resolution, aerial coverage, and
increased exposure of a thin layer of resist uniformity is needed. After these improvements,
Plasmonic Nanolithography directly below the mask. Because the tech- plasmonic nanolithography may be a viable al-
The minimum feature size used within state- nique is not diffraction limited, it can produce ternative to other nanolithography systems.
of-the-art electronic circuits is on the order of subwavelength structures using broad beam
50 nm, and new lithography techniques need illumination of standard photoresist with vis- Future Directions and Challenges
to be developed to fabricate these integrated ible light. Using this technique, sub–100-nm The field of plasmonics offers several research
circuits with nanometer-scale dimensions. Op- lines have been patterned photolithographically opportunities. These include plasmonic chips
tical projection lithography at shorter optical at a wavelength of 436 nm (38). Theoretical that function as ultra–low-loss optical inter-
wavelengths can be used to reach the desired simulations of plasmonic nanolithography pre- connects, plasmonic circuits and components
feature sizes. However, the change of the illu- dict even better performance (39). Finite dif- that can guide light within ultracompact op-
mination wavelength to shorter wavelengths ference time domain (FDTD) simulations of tically functional devices, nanolithography at
means new light sources, photoresists, and op- isolated silver particles on a thin resist lay- deep subwavelength scale, superlenses that en-
tics that are becomingly increasingly more com- er show that broad beam illumination with able optical imaging with unprecedented resolu-
plex as the wavelength becomes smaller. SPs p-polarized light at a wavelength of 439 nm can tion, and new light sources with unprecedented
result in a strongly enhanced nanoscale spa- produce features as small as 30 nm, or l/14, performance. To fulfill the promise offered by
tial distribution of an electrical field near the where l is the wavelength. Depending on the plasmonics, more research needs to be done in
metal surface. When the resonance frequency exposure time, lateral spot sizes ranging from these areas. Some of the challenges that face

192 13 JANUARY 2006 VOL 311 SCIENCE www.sciencemag.org


REVIEW
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Press, Cambridge, 1999). (2005). 10.1126/science.1114849

www.sciencemag.org SCIENCE VOL 311 13 JANUARY 2006 193


Plasmonics: Merging Photonics and Electronics at Nanoscale Dimensions
Ekmel Ozbay

Science 311 (5758), 189-193.


DOI: 10.1126/science.1114849

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