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Reacción R 1.

987
1 2C + O2 = 2CO
2 CO2 = C + O2
GENERAL CO2 + C = 2CO
A B C
1 -53400 0 -41.9
2 94200 0 0.2
TOTAL 40800 0 -41.7

T (K) DG kp PCO %CO T (K)


300 28290 2.4493112E-21 4.9490516E-11 4.9490516E-09 300
350 26205 4.3202279E-17 6.572844E-09 6.572844E-07 350
400 24120 6.6123171E-14 2.5714423E-07 2.5714423E-05 400
450 22035 1.9836128E-11 4.4537669E-06 0.0004453767 450
500 19950 1.901689E-09 4.3607408E-05 0.0043607408 500
550 17865 7.9527285E-08 0.0002819661 0.0281966063 550
600 15780 1.7851034E-06 0.0013351854 0.133518536 600
650 13695 0.000024828 0.0049703721 0.4970372088 650
700 11610 0.0002370799 0.0152793152 1.5279315196 700
750 9525 0.0016756652 0.0401056307 4.0105630716 750
800 7440 0.009275092 0.0917813259 9.1781325922 800
850 5355 0.0419780273 0.1849686664 18.496866636 850
900 3270 0.1606459737 0.328452937 32.845293699 900
950 1185 0.5337836452 0.5109352084 51.093520841 950
1000 -900 1.5729363149 0.6938927707 69.38927707 1000
1050 -2985 4.1817436697 0.8337629628 83.376296277 1050
1100 -5070 10.171838841 0.917280992 91.728099202 1100
1150 -7155 22.901960346 0.9597775504 95.977755038 1150
1200 -9240 48.191792512 0.9800685089 98.006850893 1200
1250 -11325 95.548850923 0.9897476485 98.974764847 1250
1300 -13410 179.72657099 0.9944970607 99.449706074 1300
1350 -15495 322.60727645 0.9969193251 99.691932509 1350
1400 -17580 555.37810277 0.99820588 99.820587997 1400
1450 -19665 920.9443215 0.9989165097 99.891650975 1450
1500 -21750 1476.5053381 0.999323641 99.932364096 1500

100
100

80

60

40

20

0
300 500 700 900

CO2 FeO=Fe MgO CdO M


Reacción Reacción
FeO + CO = Fe + CO2 MgO + CO = Mg + CO2
1 FeO = Fe + 1/2 O2 1 MgO = Mg + 1/2 O2
2 C + 1/2 O2 = CO 2 CO = C + 1/2 O2
3 C + O2 = CO2 3 C + O2 = CO2
A B C A
1 63310 0 -15.62 1 144350
2 26700 0 20.95 2 26700
3 -94200 0 -0.2 3 -94200
DG -4190 0 5.13 DG 76850
DG kp PCO %CO T (K) DG kp
-2651 85.39097328 0.011575283 1.157528341 300 75082.25231 1.9865118E-55
-2394.5 31.28361254 0.030975468 3.097546778 350 74856.75026 1.792549E-47
-2138 14.7314535 0.063566917 6.356691706 400 74640.43079 1.640546E-41
-1881.5 8.200811153 0.108686069 10.86860694 450 74432.13961 7.0440874E-37
-1625 5.132698814 0.163060348 16.30603475 500 74230.98076 3.5561168E-33
-1368.5 3.49813653 0.222314284 22.23142836 550 74036.23846 3.7868416E-30
-1112 2.541436336 0.282371305 28.23713051 600 73847.32771 1.2557517E-27
-855.5 1.939407296 0.34020464 34.02046397 650 73663.76136 1.698027E-25
-599 1.538266925 0.393969598 39.39695979 700 73485.12745 1.1350393E-23
-342.5 1.258382555 0.442794777 44.2794777 750 73311.07305 4.3191715E-22
-86 1.055591909 0.486477883 48.64778829 800 73141.29237 1.0400966E-20
170.5 0.903977964 0.525216163 52.52161625 850 72975.51796 1.7185689E-19
427 0.787592658 0.559411562 55.94115616 900 72813.51386 2.0749178E-18
683.5 0.696219406 0.589546374 58.95463738 950 72655.0704 1.9237047E-17
940 0.623083346 0.616111306 61.6111306 1000 72500 1.4250329E-16
1196.5 0.563555428 0.639567989 63.95679886 1050 72348.13385 8.709979E-16
1453 0.51438895 0.66033234 66.03323405 1100 72199.31926 4.5095267E-15
1709.5 0.473253699 0.67876972 67.87697196 1150 72053.41742 2.0211306E-14
1966 0.438442727 0.695196257 69.51962571 1200 71910.30161 7.9847571E-14
2222.5 0.408682664 0.709883088 70.98830882 1250 71769.85567 2.8231166E-13
2479 0.38300793 0.723061653 72.30616532 1300 71631.97276 9.0484719E-13
2735.5 0.360675471 0.7349291 73.49291004 1350 71496.55423 2.6579852E-12
2992 0.3411058 0.745653326 74.56533257 1400 71363.50879 7.2232467E-12
3248.5 0.323841471 0.755377454 75.53774544 1450 71232.75163 1.8307286E-11
3505 0.308517354 0.76422372 76.42237201 1500 71104.20382 4.3578016E-11
900 1100 1300 1500

MgO CdO MoO2


Reacción Reacción
MgO + CO = Mg + CO2 CdO + CO = Cd + CO2
MgO = Mg + 1/2 O2 1 2 CdO = 2 Cd + O2
CO = C + 1/2 O2 2 CO = C + 1/2 O2
C + O2 = CO2 3 C + O2 = CO2
B C A B C
2.95 -33.95 1 87250 0 -49.95
0 20.95 2 26700 0 20.95
0 -0.2 3 -94200 0 -0.2
2.95 -13.2 DG 19750 0 -29.2
PCO %CO T (K) DG kp PCO %CO
1 100 300 10990 9.8430133E-09 1.0000000 99.99999902
1 100 350 9530 1.118684E-06 0.9999989 99.99988813
1 100 400 8070 3.8939643E-05 0.999961062 99.99610619
1 100 450 6610 0.0006158571 0.999384522 99.9384522
1 100 500 5150 0.0056072548 0.994424011 99.44240111
1 100 550 3690 0.0341670805 0.96696174 96.69617404
1 100 600 2230 0.1540479243 0.866515141 86.65151411
1 100 650 770 0.5509105187 0.644782525 64.47825248
1 100 700 -690 1.642273683 0.378461931 37.84619309
1 100 750 -2150 4.232153455 0.191125893 19.11258927
1 100 800 -3610 9.6891972103 0.093552395 9.355239503
1 100 850 -5070 20.123032692 0.047341687 4.73416869
1 100 900 -6530 38.5329072407 0.025295382 2.529538225
1 100 950 -7990 68.9082702323 0.014304459 1.430445921
1 100 1000 -9450 116.269809859 0.008527344 0.852734392
1 100 1050 -10910 186.648669635 0.005329108 0.532910786
1 100 1100 -12370 287.009155076 0.003472112 0.347211185
1 100 1150 -13830 425.125310667 0.002346728 0.234672754
1 100 1200 -15290 609.424262034 0.001638205 0.163820487
1 100 1250 -16750 848.809625214 0.001176734 0.117673414
1 100 1300 -18210 1152.47721241 0.000866944 0.086694387
1 100 1350 -19670 1529.7333249 0.000653282 0.065328166
1 100 1400 -21130 1989.82361825 0.000502305 0.050230467
1 100 1450 -22590 2541.7782086 0.000393271 0.039327063
1 100 1500 -24050 3194.27658482 0.000312962 0.031296195
Reacción
1/2 MoO2 + CO = 1/2 Mo + CO2
1 1/2 MoO2 = 1/2 Mo + 1/2 O2
2 CO = C + 1/2 O2
3 C + O2 = cO2
A B C
1 70250 2.3 -28.4
2 26700 0 20.95
3 -94200 0 -0.2
DG 2750 2.3 -7.65
T (K) DG kp PCO %CO
300 2164.213666 0.026499701 0.974184404 97.41844043
350 2120.474776 0.047403054 0.954742299 95.47422994
400 2083.895192 0.072663839 0.932258517 93.22585169
450 2053.574952 0.100592422 0.908601568 90.8601568
500 2028.815505 0.129757354 0.885145821 88.51458208
550 2009.058802 0.15907707 0.862755399 86.27553987
600 1993.848726 0.187793696 0.841897042 84.18970424
650 1982.805468 0.215409618 0.822767885 82.27678847
700 1975.607844 0.241621957 0.805398128 80.53981283
750 1971.980679 0.266267205 0.789722735 78.97227345
800 1971.685576 0.289278362 0.775627692 77.56276916
850 1974.514 0.310653285 0.762978289 76.29782886
900 1980.281995 0.330431974 0.751635574 75.16355735
950 1988.826078 0.348680601 0.741465399 74.14653993
1000 2000 0.365480437 0.732342971 73.23429712
1050 2013.672157 0.380920314 0.724154747 72.41547468
1100 2029.723493 0.395091564 0.716798829 71.67988294
1150 2048.045788 0.408084706 0.710184548 71.01845477
1200 2068.540239 0.419987338 0.704231632 70.42316317
1250 2091.116287 0.43088287 0.698869223 69.88692231
1300 2115.690623 0.440849825 0.694034855 69.40348554
1350 2142.186351 0.449961521 0.689673474 68.96734743
1400 2170.532275 0.458286016 0.685736535 68.57365351
1450 2200.662287 0.465886212 0.68218119 68.21811896
1500 2232.514844 0.472820064 0.678969566 67.89695662