HINTS AND SOLUTIONS

CHEMISTRY

PART-A
1
7. Rate in weak acid = rate in strong acid
100
1
  H +  weak acid = H+ 
100   strong acid
1
  H +  weak acid = M = 10−2 M
100
 C = 10−2
 K a = 10−4

8.
Cl
AlCl3
AlCl4 P
aromatic
H

Na
NaH H2

aromatic Q

NH 2 2 CO3
100 115 C (R) aromatic
O O N
Mechanism

NH 4 CO3 2NH3 CO2 H2O
2

NH 3 O OH
O O NH NH2
O CH3 N
H

H2O

N
aromatic

HCl

Cl
O OH
(S)aromatic

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9. (A) Ice has cage-like structure in which each water molecule is surrounded by four other water
molecules tetrahedrally through hydrogen boding, due to this density of ice is less than water and it floats
in water.

(B) R − NH 2 + H − OH R − N H3 + OH −
( I)

( R )3 N + H − OH ( R )3 − N H+ OH −
( II)
The cation (I) more stabilized through hydrogen boding than cation ( II ) . So, R–NH2 is better base
than (R)3N in aqueous solution.
(C) HCOOH is stronger acid than CH3COOH due to inductive effect and not due to hydrogen bonding.
(D) Acetic acid dimerizes in benzene through intermolecular hydrogen bonding.
O H O
H3C C C CH3
O H O

10. OH
I
⎯⎯⎯→ I2
Rxn ( i )

CMe3
OH OH
Br

⎯⎯⎯
Br2
Rxn ( ii )
→

CMe3 CMe3
Br
OH
Cl Cl

⎯⎯⎯→
Cl2
Rxn ( iii )

CMe3
Cl
PART-C

h h
5. Since,  = = (since K.E.  T)
mV 2M K.E
1
 
MT
For two gases,
 He M Ne TNe 20 1000
= = 
 Ne M He THe 4 200

6. Black coloured sulphides PbS,CuS, HgS, Ag2S, NiS,CoS

* Bi2S3 in its crystalline form is dark brown but Bi2S3 precipitate obtained is black in colour.

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7. Cr (NH3 ) Cl2  Br is an octahedral compound and exists in two geometrical isomeric forms.
 4 
Cl Cl
H3N NH 3 H3N Cl

Cr Cr
H3N H3N
NH 3 NH 3
Cl NH 3

trans-form cis-form

K 4 Fe ( CN)6  + FeCl3 ⎯⎯

→ Fe4 Fe ( CN)6  + KCl
8. 3

( Secondary valency of 'Fe'is 6 )

10. NO, N2O, CO, OF2.

Mathematics
PART – A

2 −1 3 − 4 4 − 5
1. The given lines intersect if 1 1  = 0   = 0, – 1.
 2 1

 1 −2 1 3   1 −2 1 3   1 −2 1 3 
2. Augmented matrix 5 −1 −1 8  0 9 −6 −7  0 9 −6 −7 
 1 1 −1 7  0 3 −2 4  0 0 0 19 / 3 
System of equation has no solution. A = 0  n1 n2 n3  = 0  normals of plane are coplanar hence
they are not intersecting at any point and forming a triangular prism.
x y z
( x,y,z ) = (r,2r,3r ) does not satisfy any plane for any value of ‘r’ hence = = is parallel to each
1 2 3
plane. (x, y, z) = (r, 3r, 4r) satisfy by plane (1) & plane (2) for some value of ‘r’ but not satisfy by plane ‘3’
x y z
for any value of r. hence line = = does not interest plane ‘3’.
1 3 4

x − y − z − 
3. (A) We know that the plane ax + by + cz + d = 0 contains the line = = if
l m n
a + b + c + d = 0 and al + bm + cn = 0
Now since ( −1) − 2 ( 3 ) + 7 ( −2) + 21 = 0 and ( −3 )(1) + 2 ( −2) + 1( 7 ) = 0
The line given in (A) lies of the plane.
(B) Since, 0 − 2(7) + 7(−1) + 21 = 0
The point ( 0,7, −1) lies on the plane
(C) Direction ratios of the normal to the given planes are (1, −2,7 ) the plane is perpendicular
to the line.
(D) The direction ratios of the normal to the planes given in (D) are same as those of the given plane. So,
the plane in (D) is parallel to the given plane.

4. Equation of a plane passing through the line 3x − y + 2z − 1 = 0 = x + 2y − z − 2 is

3x − y + 2z − 1 +  ( x + 2y − z − 2) = 0
Since it is perpendicular to the given plane

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3
 = −
2
 Equation of the line of projection is 3x − 8y + 7z + 4 = 0 = 3x + 2y + z
Its direction ratios are < 11, − 9 , − 15 > and the point ( − 1,1,1) lies on the line
x +1 y −1 z −1
 = = is also the equation of the line of projection.
11 −9 −15

sin−1 ( sin x )
5. A = lim
x →0 cos−1 ( cos x )

sin−1 ( sin x ) x
lim− = lim− = −1
x →0 cos ( cos x )
−1
x →0 − x

sin−1 ( sin x ) x
lim+ = lim+ = 1
x →0 cos ( cos x )
−1
x →0 x

 A does not exist

B = lim
| x | = 0 as [|x|] = 0 when x → 0.
x →0 x

6. We have
Un+1 − 2Un + Un−1
/ 2 / 2 / 2
sin 2 ( n + 1) x sin 2 nx sin 2 ( n − 1) x
= 
0
sin 2 x
dx − 2 
0
sin 2 x
dx + 
0
sin 2 x
dx

/ 2
sin 2
( n + 1) x − sin 2 x − sin 2 nx − sin 2 ( n − 1) x
= 
0
sin 2 x
dx

/ 2
sin ( 2n + 1) x sin x − sin ( 2n − 1) x sin x
= 
0
sin 2 x
dx

/ 2 / 2

  cos 2nx dx
2cos 2nx sin x
= dx = 2
0
sin 2 x 0
/ 2
sin 2nx 1
= 2 = ( sin n − sin 0 ) = 0 − 0 = 0
2n 0 n
 Un−1 + Un+1 = 2Un i.e. Un−1 , Un, Un+1 form A.P.
 U1, U2, U3, … constitute an A.P.
/ 2 / 2 / 2
 sin 2 2x
 dx =  dx = 4  cos x dx = 
2
Now, U1 = and U2 = 2
2 sin x
0 0 0

 common difference of A.P. = U2 − U1 =
2
  n
Un = U1 + (n − 1) d = + ( n − 1) = .
2 2 2

7. We have u2 = a2 + b2 + 2 (a 2
)(
cos2  + b2 sin2   a2 sin2  + b2 cos2  )
 [u2 − (a2 + b2)2]2 = 4[(a4 + b4) sin2 cos2 + a2b2 (cos4 + sin4)]
 [u2 − (a2 + b2)]2 = (a4 + b4 − 2a2b2)2 sin22 + 4a2b2

3 3 
8. Points O, P, Q, R, S are (0, 0, 0), (3, 0, 0), (3, 3, 0) (0, 3, 0),  , ,3  respectively.
2 2 
 1 
 Angle between OQ and OS is cos−1  
 3

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Equation of plane containing the points O, Q and S is x − y = 0

 Perpendicular distance from P(3, 0, 0) to the plane
3−0 3
x − y = 0 is =
2 2
Perpendicular distance from O(0, 0, 0) to the line RS:
x y −3 z 15
= = is .
1 −1 2 2

9. lim  x sin x  = 0
x →0

10. The given differential equation can be written as

xdx + ydy x sin2 (x 2 + y 2 )
=
ydx − xdy y3
2xdx + 2ydy 2x sin2 (x 2 + y 2 )
 =
ydx − xdy y3
d(x 2 + y 2 ) 2x
 = 3 (ydx − xdy)
sin (x + y ) y
2 2 2

x x
 cosec 2 (x 2 + y 2 )d(x 2 + y 2 ) = 2   d  
y y
On integrating, we get
x x
 cosec (x + y )d(x + y ) = 2  y  d  y 
2 2 2 2 2

2
x
 − cot(x 2 + y 2 ) =   + c, which is the required solution.
y

PART – C

2
 2 3
2

 
2
1. A = 2  | cos x | dx = 2   cos x dx +  ( − cos x ) dx +  cos x dx 
0  0 
2
3
2


= 2 ( sin x )0 − ( sin x ) / 2 + ( sin x )3 / 2  = 2[(1 – 0) – (– 1 – 1) + (0 + 1)] = 8

/ 2 3 / 2 2

 

a 1 1
2. 1 a 1 =0
1 1 a
a = 1, a = –2
for a = 1, it has infinite solutions so a = – 2.

3. The lines should intersect or be parallel

Let ( 2t + 1, −t,2t ) be any point on the first line
−31
Putting it in both the planes we get  = .
7
There is no  for which both the lines are parallel.

4. The plane passes through the point of intersection of lines ( 0,1,1)

The point ( 2,3,2) lies on the line, whose projection on the second line is (1,2,0 )
 the required plane has normal (1,1,2 )
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 Equation of the plane is 1( x − 0 ) + 1( y − 1) + 2 ( z − 1) = 0

x + y + 2z − 3 = 0
(k, −2,0 ) lies on the plane
 k = 5.

5. cotA, cotB, cotC are in A.P.  cotB − cotA = cotC − cotB

sin ( A − B ) sin (B − C )
 =  sin(A − B) . sin(A + B) = sin(B − C). sin(B + C)
sin A sinB sinCsinB
 4R2 (sin2A − sin2B) = 4R2 (sin2B − sin2C)  a2 − b2 = b2 − c2  a2, b2, c2 are in A.P.

6. Let P (E1) = x, P (E2) = y and P (E3) = z

then (1 − x) (1 − y) (1 − z) = p
x (1 − y) (1 − z) = 
(1 − x) y(1 − z) = 
(1 − x) (1 − y) (1 − z) = 
1− x p 
so = x=
x  +p

similarly z =
 +p
  +p p
1+
P (E1 )  + p  
so = = =
P ( E3 )  +p p
1+
 +p  
 2 5
also given =p=  =
 − 2  − 3  + 4
  5     5
Substituting back   − 2   p =
   + 4    + 4
 p – 6p = 5
p
+1
p  p  
  + 1 = 6  + 1  = 6.
    p
+1


7. 3x – y – z = 0
– 3x + z = 0
y=0
and z = 3x
 x2 + y2 + z2 = x2 + z2 = x2 + 9x2 = 10x2  100
 x2  10
 x = 0,  1,  2,  3
There are such seven points.

8.  +  +  = 2, kˆ  (kˆ  a ) = 0  k̂ = a   =  = 0, hence  = 2.

x − 0 y −1 z −1
9. Line through (0, 1, 0) and perpendicular to plane x + 2y + 2z = 0 is given by = = =r.
1 2 2
2
Let P(r, 2r + 1, 2r) be the foot of perpendicular on the straight line then r = −
9
 2 5 4 4 + 25 + 16 5
 Point is given by  − , , −   Required perpendicular distance = = units.
 9 9 9 81 3

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(cos )
2
−1
x 3x
10.  1 − 9x 2
+
1 − 9x 2
dx , in 1st substitute t = 1 − 9x2 and in second substitute u = cos−1x

PHYSICS
Part–A
1. A, B
Process AB is isothermal process

2. A, B

3. A, C

4. A, D

5. A, B, C
Using snell’s law B
1 1
sin−1  sin−1 O 60 135
3 2
Net deviation is 90 P
C
45
6. A, C
For photoelectric emission 90 30 75
 hc  1  A D
V0 =   −
 e  e

7. A, C

8. A, B, C, D

9. A, D

10. A, D
Part–C
1. 2
2. 7
c+v
fapp = f0
c−v
2f0 c
df = dv
(c − v)2
where c is speed of sound
1.2
df = f0
100
hence dv  7 km/hr.

3. 3

4. 4

5. 3

6. 3
For maxima,

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4 2
d + x2 − d2 + x2 = m, m
3 is an integer
So, x2 = 9m22 − d2
 p=3

7. 5
vi
= 6.25
vf
2
 nf 
   = 6.25
 ni 
nf 5
 = 2.5 =
ni 2
 minimum value of nf is 5.

8 8

9. 6

10. 2

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