Jee Adv Chemistry Paper 1

CHEMISTRY – JEE ADVANCED PAPER – 1
SECTION – 1
1. Which of the following set represent correct formula for Malachite, Magnetite, Calamine & Cryolite?
(a) CuCO3 , Fe2O3 , ZnO, Al2O3 (b) CuCO3 , Cu  OH 2 , Fe3O4 , ZnCO3 , Na3 AlF6
(c) CuCO3 , Fe3O4 , ZnCO3 , Al2O3 (d) CuCO3 .Cu  OH 2 , Fe2O3 , ZnCO3 , Na3 AlF6
Solution:
(B)
Malachite  CuCO3.Cu(OH)2
Magnetite  Fe3O4
Calamine  ZnCO3
Cryollite  Na3AlF6
2. Find the correct acidic strength order:
(i) HC = C – COOH (ii) H2C = CH – COOH (iii) (iv) CH3 – CH2 – COOH
(a) i > ii > iv > iii (b) i > ii > iii > iv (c) iii > ii > i > iv (d) iii > i > iv > ii
Solution:
(B)
3. Sodium stearate is a strong electrolyte. Which of the following plot is correct regarding its conductance:
(a) (b) (c) (d)
Solution:
(B)
1
By definition,  m
C
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4. Which green coloured compound of chromium is formed in borax bead test?
(a) Cr  BO2 3 (b) Cr2O3 (c) CrB (d) CrBO3
Solution:
(A)
 Cr  BO2 3
Cr2O3  B2O3 
green
SECTION – 2
5. Choose the reaction, for which the standard enthalpy of reaction is equal to the standard enthalpy of formation:
3
(a) 2C g   3H 2 g   C2 H 6 g  (b) O  O3 g 
2 2 g 
1
(c) S  O2 g   SO2 g  (d) 2H 2 g   O2 g   2H 2O  
8 8 s 
Solution:
(B, C)
By definition,
Enthalpy of formation is defined as the Enthalpy change occurring when, a compound is formed from its
constituent elements in standard state.
6. A Tin – chloride ‘P’ gives following reaction (unbalanced reaction)

P  Cl  
 X [Monoanion pyramidal geometry]
P  Me3 N 
Y
P  CuCl2 
 Z  CuCl
Then which of the following is/are correct.
(a) Y contains co-ordinate bond (b) X is sp3 hybridised.
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(c) Oxidation state of Sn is X is +1. (d) X contain lone pair on central atom.
Solution:
(A, B, D)
SnCl2  Cl  
 SnCl3
 P X 
 SnCl2  N Me3 
SnCl2  Me3 N 
 P Y 
SnCl2  CuCl2 
 SnCl2  CuCl
 P Z 
234 234 234 230

7. 238
92 U 
x1
90 Th 
x2
91 Pa 
x3
 Z 
x4
90 Th
x1 , x2 , x3 , x4 , are either particles or radiation. Then
(a) x1 is deflected toward negatively charged plate.
(b) x2 is β-particle.
(c) x3 is γ-radiation.
238
(d) z is isotope of U
Solution:
(A, B, D)
X1  α – decay
X2  β – decay
X3  β – decay
X4  α – decay
8. Fusion of MnO2 along with KOH and O2 forms X. Electrolytic oxidation of X yields Y. X undergoes
disproportionation reaction in acidic medium to MnO2 and Y. The Manganese in X and Y is in the form W & Z
respectively, then
(a) W & Z are coloured (b) W is diamagnetic and Z is paramagnetic
(c) Both W & Z are tetrahedral in shape (d) Both W & Z involve pπ-dπ bonding for π bond
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Solution:
(A, C, D)
 3
C6 H10O  Q   S
1 CH MgBr Conc. HCl
9.  2  H 2O
 Major   Major 
 2
Q   R 
 2 Br2 / hv  T
20% H3 PO4 1 H / Ni
 Major 
360 K
 Major   Major 
(a) (b) (c) (d)
Solution:
(C, D)
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10. Which of the following are true.

(a) Monosachharides can not be hydrolysed to give polyhydroxy aldehydes and ketones.
(b) Hydrolysis of sucrose gives dextrorotatory glucose and laevorotatory fructose
(c) Oxidation of glucose with bromine water gives glutamic acid.
(d) The two six membered hemiacetal form of D(+) glucose are anomers.
Solution:
(A, B, D)
11. Identify the option where all four molecules possess permanent dipole moment at room temperature.
(a) BF , O3 , SF6 , XeF6 (b) BeCl2 , CO2 , BCl3 , CHCl3
(c) SO2 , C6 H5Cl , H 2 Se, BrF5 (d) NO2 , NH3 , POCl3 , CH3Cl
Solution:
(C, D)
(C) 
(D) 
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12. Which of the following is/are correct regarding root mean square speed (Urms) & average translation K.E. (Eav)
of molecule in a gas at equilibrium.
(a) Eav is doubled when its temperature is increased 4 times
(b) Urms is inversely proportional to the square root of its molecular mass
(c) Eav at a given temperature doesn’t depend on its molecular mass
(d) Urms is doubled when its temperature is increased 4 times
Solution:
(B, C, D)
3
Ea  RT (independent of Mass)
2
3RT
urms 
M
SECTION – 3
13. XeF4  O2 F2 
 product. The total number of lone pairs on the xenon containing product is: (l)
Solution:
(19)
XeF4  O2 F2 
 XeF6  O2
Distorted octahedral shape
14. For the following reaction, equilibrium constant Kc at 298 K is 1.6 × 1017
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Fe2aq   S2aq  FeS  s 
When equal volume of 0.06 M Fe+2 and 0.2 M S-2 solution are mixed, then equilibrium concentration of Fe+2 is
found to be Y × 10-17 M. Y is:
Solution:
8.93 or 8.92
Fe2  S 2 
 FeS
ini 0.06 0.2 0
After mix 0.03 0.1
At 0 q/m x 0.07
1
KC   1.6 1017
 x  0.07
  Fe2   8.928 1017
 y 1017
 y  8.93 or 8.92
15.
Number of atoms of Br in compound ‘T’
Solution:
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(4)
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Total Br atoms = 4
16. Which of the following compounds contain bond between same type of atoms.
N2O4 , B3 N3 H 6 , H 2 S2O3 , N2O, H 2 S2O8 , B2 H 6
Solution:
N2O4 , H 2 S2O3 , N2O, H 2 S2O8
17. A + B + C  Product
Ex. No [A] [B] [C] Rate of reaction

1. 0.2 0.1 0.1 6 × 10-5
2. 0.2 0.2 0.1 6 × 10-5
3. 0.2 0.1 0.2 1.2 × 10-4
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4. 0.3 0.1 0.1 9 × 10-5
When [A] = 0.15
[B] = 0.25
[C] = 0.15
Rate of reaction is Y × 10-5 M/s Find Y.
Solution:
(6.75)
Let r  K  A  B  C 
x y z
From (1), (2)  y = 0
(1), (3)  z = 1
(1), (4)  x = 1
 rate law becomes
r  K  A  B  C 
1 0 1
From (2)
K  3 103
When  A  0.15,  B  0.25, C   0.15
r  3 103 0.15 0.15

1 1
 6.75 105 mol l 1s 1
 y 106
 y  6.75
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18. On dissolving 0.5 g of non-volatile, non-ionic solute to 39 g of benzene, its vapour pressure decreases from 650
mm of Hg to 640 mm of Hg. The depression of freezing point of benzene (in K) upon addition of the solute is
_________.
[Given data: Molar mass & molar freezing point depression of benzene is 78 g mol-1 & 5.12 K Kg mol-1]
Solution:
(1.02)
P  PS nsolute

PS nsolvent
650  640 1 0.5  78


640 M  39
 M  64 g
0.5 1000
T f  K f m  5.12 
64  39
 T f  1.02
11
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Jee Adv Chemistry Paper 1

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CHEMISTRY – JEE ADVANCED PAPER – 1

2. Find the correct acidic strength order:

(a) (b) (c) (d)

4. Which green coloured compound of chromium is formed in borax bead test?

(a) Cr  BO2 3 (b) Cr2O3 (c) CrB (d) CrBO3

6. A Tin – chloride ‘P’ gives following reaction (unbalanced reaction)

234 234 234 230

x1 , x2 , x3 , x4 , are either particles or radiation. Then

(a) x1 is deflected toward negatively charged plate.

(a) (b) (c) (d)

10. Which of the following are true.

Distorted octahedral shape

Fe2aq   S2aq  FeS  s 

ini 0.06 0.2 0

After mix 0.03 0.1

  Fe2   8.928 1017

Number of atoms of Br in compound ‘T’

N2O4 , H 2 S2O3 , N2O, H 2 S2O8

Ex. No [A] [B] [C] Rate of reaction

4. 0.3 0.1 0.1 9 × 10-5

When [A] = 0.15

Rate of reaction is Y × 10-5 M/s Find Y.

From (1), (2)  y = 0

 rate law becomes

When  A  0.15,  B  0.25, C   0.15

r  3 103 0.15 0.15

 6.75 105 mol l 1s 1

650  640 1 0.5  78

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