Advanced Chemical Problemset 2

Engineering Thermodynamics
EdwinRodríguez

Postulate 1 For a closedsimple systems withgiveninternalrestraints

says
there exist stable equilibriumstate which can be characterizedcompletelyby two
independently variable properties in aditionto themassesoftheparticular chemical
species initially charged
In this case the stable equilibriumstate es characterized
by temperature
andpressure Since it is pure water andthe tablecontainsinformation
about an intensive properfie Density The system is completely defined

f f It PN since q os intensive f ftp.T

Postulate 2 says In processesforwhich there is no neteffecton the
environment all
systems withgiveninternalrestraints will change on suchaway
as to approach One andonly one stable equilibriumstate foreachsymple
subsystem

In thisthe density is unique for a given T and P It can beshown that p

is a function Of Pand T and represents a stable equilibriumstate
 Ü Since the man pusheshimself his internalenergy is
kinetic
µ beingtransform on energy
The man es notgetting or loosing
energy only
transforming it
AE tw DE AU tAEK O
AU AEK tq Exit
a
AV Exi Exp mi 1am
O
taMUI MUY

From the pointof view of the woman we need to add the movement
of the Train
Wman EmanDX

Wtrain
f twain DX
f tq UtVf
Eman M dumann Emandt MdUman
dt o se
Eman
tq M UtVp U Mvp Feraindt

Nman Ímair Udt a Feraindt UMA Wman

DE tw DE AU tAEK O
UMUf AUTExp Ex AU t Mtutus
laMU
AV UMVf.iqMU 1am tuit 2mgtuya
AV UNA112MW
la MM UNG Mvp
AV LaMUY

sin con
O

The block is transforming his potential energy into kinetic energy

go p
DE tw AUIAEK.ttAEp O
AU AEK AEP Exp Exi Epg Epi
1amVi mvp mhig mhj.gr lolnofrictio
111100 gravity
muy t m sino 1g n

what is 4 100 friction 1 los

más EE Gravity Friction 1nogravity sin
m EE Sinoym losOgmµ
de
vffottsinog cosogugdt ls.int cost gtf
AU sino losftp.ljtmsinolg
Iam y
the internal because theblockas loosing energy
energy is changing
there were nofriction thepotential
continuos
1g duetofriction if
energy wouldchange to kinetic energy without changing the internal
energy of the block
So ultimately friction rs the only responsable internalenergy tochange
for the

m m 2M

DE AU t AEK O AU AEK Exi Exp mi Vi 1amfvf

122mVE MUE MU

ZU
t
µ
point doesnothave
tocompensate the object
nightmust have U su
theµ
sincethisobjectas the reference
velocity
any on

AU AEK Exi Exp 1am121 121am 10 Izmir 2mV

 50mph 50Mpts
00mA
c L pq
Damage
100mph 100mph
y a
view same
fixed
Point
9
One possible explanation couldbe that the materialdeformation in thecars
helps to reduce the apparentdamage The wall os an absolutely solid object
Therefore it doesnot absorb any energyby deformation
The otherthing accountthat the cars willstop after the
is having into
collision in Order to have a fixed viewpoints in One of the cars the
referencepointshould move at the same speed If the Cars stop from
the point of view of the Observer is like the cars accelerate in opposite
direction so the
energy that is not Used an the collision is used in
accelerating the cars So the scenario and are not
equal

dwtota EFi.dk O
Itis Fia DM O F mia tt
tj mdvii Fifi ma
de
mini dri vi dt dri
 fmidaf
1mi vi dvi
dWtot Ia mi Avia d Emivia

Vi vi tkm km 1M Emivi
MUcm Emivi 0

EmUi Emvi Emiten

mui 0

d Kut d EYa mi 1Vi't km

DEYamiVi 1 DEYamiVin DEmivi km
DEYamiVi 1 DEYamiVin kmDEmivi
dHot LE mi Vi t la FYamiVim

dWta ti dri
Éi FistFit dvi
Ei fijodri t.EE t.dk
F Fijo dlVisitNj MgdZam
Fij.dk MgdZam
t FijadA
Ii
Fijodk.j Mgdz.sn dNtoe MgdZim
DE ktot dulzor 0 Since this as notthethermodynamical definition work
of
DE 0
dkinztdkcma dp mgdzc.sn DU
DU DKent tdp d Ya mi vía tal Fis dk