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I. INTRODUCTION
In this laboratory experiment, the objectives of this is to be able to compare the smoke points of
several fats and oils, to be able to relate the chemical properties of oil samples with their smoke points
and to enumerate and discuss the factors that can affect smoke points of fats.
Lipids are one of the large groups of organic compounds, which are of great importance in the food
we eat because they are readily digested and utilized in the body. They are widely distributed and almost
every natural food has considerable quantities of them. Fats are also often added to foods during their
preparation, either as shortening, as a method of transferring heat in frying, or for flavor and richness
in preparing vegetables, puddings, etc. Occasionally lecithin is added as an emulsifying agent, but the
fats are by far the most important additives among lipids (Meyer, L.H 1968).
The smoke point is the temperature at which a fat or oil gives off a thin bluish smoke. It is measured
by a standard method in an open dish specified by the American Society for testing materials so that the
evolution of smoke can be readily seen (Meyer, L.H 1968).
The smoke point of a fat is not a specific temperature. As a fat is used at high temperatures over a
period of time, its smoke point will gradually drop until the flavor and appearance of the foods fried in it
are unacceptable. Different oils used for frying naturally have somewhat different original smoke points,
but the point is sufficiently above 190° C (374°F) that the most oils can be used satisfactorily for a
reasonable length of time before smoke point drops to frying temperature below (McWilliams, M., 2017).
Shortenings or other fats that have monoglycerides present quickly are altered so that the smoke
point is too low for acceptable fried products. This result is not surprising because only one fatty acid as to
be removed before glycerol is available to begin forming acrolein (McWilliams, M., 2017).
Materials:
Thermometers
Hot plate
Methods:
The samples for the determination of smoke point are the vegetable oils such as: coconut
oil, corn oil, soybean oil and olive oil and as well as solid fats like lard, shortening, butter and
margarine, which was bought from the local supermarket. 50 mL of the oils and fats are
transferred into small beakers for heating in the hot plate. Set a thermometer on stand with the
bulb submerged in the fat. Record the temperature at which the each sample starts to emit smoke.
80
70 70
66 65 65 65
60 60 60
TEMPERATURE IN CELCIUS
50 50
40
30
20
10
0
Corn Soybean Olive Coconut Lard Butter Margarine Shortening
FATS
For a given sample of oil or fat, the temperature is progressively higher for smoke point,
flash point and fire point. The temperatures vary with the amount of free fatty acids present in
oil or fat, decreasing with increased free fatty acids present in an oil or fat is important. The
smoke point of a fat used for deep fat frying decreases with the use of fat. Fats and oils with
lower molecular weight fatty acids have low smoke points, flash and fire points. The number
of double bonds present has little effect on the temperature required. Smoke, flash and fire
points are particularly useful in connection with fats used for any kind of frying. (Meyer
1968).
For high temperature cooking, select cooking oils with a high smoke point. For low
temperature cooking, or adding to dishes and salad dressings, chose oils with a higher
Omega-3 fatty acids since they promote healthy cells and decrease stroke and heart attack
risk
VI. REFERENCES
Belitz, H., Grosch, W., & Schieberle, P. (2004). Food chemistry. Berlin: Springer.
Edelstein, S. (2014). Food science an ecological approach. Burlington, MA: Jones & Bartlett
Learning.
Lawson, H. W. (1985). Standards for fats & oils. Westport, CT: AVI Pub. Co.
Sikorski, Z. E., & Kolakowska, A. (2003). Chemical and functional properties of food lipids.
VII. APPENDICES
Table 3.1. Data for the determination of smoke point of liquid fats
Formula of converting 0C to 0F
T (0F) = T (0C) x 1.8 + 32
o
C to 0F (Corn) 660C x 1.8 + 32 = 150.80F
o
C to 0F (Soybean) 600C x 1.8 + 32 = 1400F
650C x 1.8 + 32 = 1490F o
C to 0F (Coconut)
o
C to 0F (Olive) 700C x 1.8 + 32 = 1580F
Table 3.2 Data for the determination of smoke point of the solid fats
Formula of converting oC to 0F
T (0F) = T (0C) x 1.8 + 32
o
C to 0F (Lard) o
C to 0F (Margarine)
50oC x1.8 + 32 = 122oC 60oC x 1.8 + 32 = 140o C
o
C to 0F (Butter) o
C to 0F (Shortening)
65oC x 1.8 +32 = 149oC 65oC x 1.8 + 32 = 149oC
I. Introduction
In certain food systems, fats must be mixed and remained mixed. The extent to which fats can
absorb water is called water-absorbing capacity and is important in food systems such as cakes. Fats
differ in their ability to absorb water, largely based on differences in their composition. Now slosh some
cream around for a few minutes, and inevitably the fat will separate from the milk and you will get butter.
Butter keeps longer than fresh milk or cream and can be made from the milk of any lactating animal.
Because water droplets are suspended in the fat it is referred to as a water-in-oil emulsion. The objectives
of this experiment are to demonstrate the water- absorbing capacity of commercial fats, relate the
chemistry of fats and oils with their water absorbing capacity, enumerate and discuss the factors that
affect the emulsifying capacity of fats and to be able to discuss the relevance of water absorption of fat in
foods.
II. Review of Related Literature
Butter is used for cooking and especially baking because of its flavor. Butter is so popular as a
spread that other nondairy spreads called “butter”, such as peanut butter or apple butter. Clarified, or
drawn, butter is melted butter from which all of the milk solids and most of the water have been removed,
which makes it suitable for high-temperature cooking because it does not burn easily.
Unlike other liquids made from water, which vaporize at 100 ℃, fats maintain their liquid states
well past 200 ℃. Giving them the ability to brown and crisp the surface of the food, something steam and
boiling could never do.
Cold fats can be solid. Fats are integral part of cell membranes and the production of hormones
and they are essential for brain development and activity and the workings of the nervous system and
liver.
Materials:
Methods:
Transfer 100 g of fat into a
bowl
Figure 1.6: Shows the procedure on the water absorbing capacity of fats
Solid fats such as lard, butter, margarine and shortening are the samples used on the absorbing capacity of
fats. Prepare 25 mL burettes with distilled water. Note the initial volume of the burettes. Transfer 100g of
each fat onto a small bowl at room temperature. At slow speed, run water from the burette into the fat and
beat until separation occurs. Observe and take note of the final volume of the water in the burette to
25
20
Volume of water absorbed
15
10
0
Lard Butter Margarine Shortening
Fats
As shown in Table 6, the solid fat samples varied in water absorption capacity. Lard and butter
showed a low and similar capacity of absorption because of its high saturated fatty acid component. On the
other hands, Margarine have a high water absorption since it is made from vegetable oils, which contains
unsaturated fats such as polyunsaturated and monounsaturated fats. Shortening, a semi solid fat, have
greater water absorption capacity than lard and butter because it is hydrogenated vegetable oil.
Lipids are soluble in organic solvents but not in water. Water insolubility is the analytical
property used as basis for their facile separation from proteins and carbohydrates. According to Belitz,
they are greasy to the touch and have lubricating properties. They are not volatile and do not leave any
residue when burned. The factors which affect the emulsifying capacity of fats depends on its droplets
characteristics and emulsion appearance; droplet concentration affect appearance, flavor, texture and shelf
life. Emulsion appearances determine product desirability, perceived product quality and consumer
sensory expectations. Fats composed mainly of saturated fatty acids that are solid at room temperature
and the greater the saturated fat content; the higher will be the temperature of melting. Oils on the other
hand, generally stay liquid at cooler temperatures because of the greater degree of unsaturation most oils
have. These oils may also be referred to as polyunsaturated fats. Examples of these fats are corn, soy,
sesame, and sunflower. There are also fats called monosaturated fats wherein they only have one double
or triple bond in their chains. Examples of these kinds of fats are olive, peanut, and canola oils.
VI. References
Daniel, JR. and Weaver, CM. (2003) The Food Chemistry Laboratory: A Manual for
Experimental Foods, Dietetics, and Food Scientists Second Edition. (57) CRC Press Book.
United Kingdom
Joachin, D., Schloss, A., and Handle, A P., (2008). The Science of Good Food. (73-74, 218-
219). Toronto Ont.: Robert Rose
VII. Appendices
Shallow-fat frying good heat control is the key to a successful shallow-fat frying. The food should
be frying briskly, but with little spattering and no smoking of the fat. If the heat is too high, the fat will start
to smoke. The food will become tough and dry or may even be burned on the exterior if the fat is too hot.
Too low a heat creates greasy food due to the absorption of extra fat during the extended frying period.
Deep fat frying a thermometer is an important adjunct to successful deep fat frying. For temperature
control, must be maintained if the food is to be cooked through without burning or becoming greasy. Most
deep fat fried frying is done at 190°C, and the fat should be heated to this temperature before any food is
added. If it is not hot enough, excess grease will be absorbed by the food.
According to McWilliams (2013), fats that are absorbed by a food during frying is dependent on
the time of cooking, temperature of the cooking fat, the total surface area of the food and the composition
and nature of the food. In terms of time, the longer the food is cooked in oil, the more oil would be absorbed
by the food. With some foods cooked at high temperature, coagulate material or a hardened crust may
prevent greater fat absorption with longer cooking. When foods that are high in fat percent it may lose fat
because solid fats (such as store animal fats) that are heated turn into liquid state. When cooking in deep
fried foods are cooked at high temperature, foods absorb less oil than usual. This is due to the fast
coagulation of food materials or quick formation of the crust at high temperature. Some foods are cooked
at moderate temperatures to thoroughly cook the food without excessive browning. The larger the surface
for a given weight of material the greater the area over which fats may be absorbed. Cracks caused by
handling or expansion in cooking, rolling thin rather than thick, roughened surfaces, due to little mixing or
other causes, stretching and pulling the material out of shape in handling, all increase the surface area and
thus tend to increase the fat absorption. The composition and nature of the food may also affect the fat
absorption. For example, if a product is composed of large amount of flour may tend to have more fat
absorbed because of absorption of fats by the flour. Other foods with smooth surface like egg may not
absorb much oil because of the coagulation of the proteins which is not absorbing oil rather oils are just at
the surface of the egg itself. Foods that contain sugar, fat, liquid, egg, flour and baking powder may show
different amount of fat absorbed; it only depends on the type of treatment being used, such as; time being
cooked, surface area, type of oil and additional ingredients and mixing time.
According to Joachim and Schloss (2008); there are different types of oil; one is from animal fat
and the other is from plant fat. Butter is concentrated far from milk, usually cow’s milk, and butter taste of
sweet, fresh dairy. It can be salted for flavor and to extend shelf life. Butter is about 82% fat, 62% saturated.
Butter is used for cooking and especially baking because of its flavor. Lard also known as pig fat, lard is
100% fat 61% unsaturated. The quality of lard depends on where on the pig the fat came from. The highest-
quality lard, known as leaf lard, comes from the dense, dry fat that surrounds the kidneys. The nest highest
grade, called fat back, is from the fat that lies along the spine right under the skin. Most lard is rendered
from mixture of fatback and lesser pig fats. Poultry fats is generally rendered fat from poultry and it is about
98% fat and 30% saturated, making it a healthy fat. Suet; the hard, dry fat that surrounds the kidneys of the
beef and sheep is 99% fat and 52% saturated. Because of its high saturation and lack of moisture, rendered
suet, called tallow, is very dense and stores extremely well, which made it a favorite fat before the advent
of refrigeration.
Margarine is a generic term for butter substitute because this came from a plan source. Is it made
from vegetable oils hydrogenated to be solid at room temperature and flavored with skimmed milk and salt.
Oils are fats from plants that tend to be bland and less saturated than the animal’s fats. Soy oil, sold, as
vegetable oil is the most common type, accounting for about a quarter of the world consumption. Oils are
liquid at room temperature, giving then limited uses in baking, but are convenient for use in cold and
uncooked foods. Shortening are vegetable oils that are hydrogenated into shortening in order to make them
look like an animal’s fat. Compared to liquid oils, shortening is less prone to rancidity and has a higher
smoke point.
III. Materials and Methods
Experiment 2.9: Fat Absorption
Materials:
Prepare a mixing bowl and sift 2 ½ cups of flour with calumet baking powder. Add sugar, butter, egg and
milk and stir 30 times. Mix with a wooden spoon or electric beater to a total of 80 strokes. Dust the
baking sheet with flour and roll the dough for an entire 50 strokes, unless otherwise stated. Cut the dough
into doughnut form using a 1/3 measuring cup. Record the weight of oil before frying. Note the time for
the doughnuts to be cooked. The temperature of the fat should reach the specified temperature and
maintained during the whole cooking process. Record the weight of the doughnuts after cooking and the
weight of fat after frying. Observe and evaluate the doughnut samples’ flavour, color, tenderness and
Treatment Observations
Flavor Color Tenderness Greasiness
Coconut oil 8 Golden-Brown 7 5
Corn oil 4 Golden-brown 5 6
Shortening 5 golden-brown 6 4
Increased 5 Light golden- 5 7
mixing time brown
Coconut Oil 7 Dark brown 7 6
(150°C)
Coconut Oil 7 Light brown 7 6
(210°C)
Double sugar 7.5 Dark brown 8 7
tenderness even with differences in temperature, sugar and fat treatment. The use of corn oil,shortening and
increasing the mixing time into 160 strokes showed slight preference in flavour, tenderness and greasiness..
0.14
0.12
0.1
0.08
0.06
0.04 Series 1
Series 3
0.02 Series 2
0 Series 1
Series 3
Variations
The doughnuts varied in treatment in terms of fat used for frying and its temperature; mixing time, and
sugar and fat treatment. As shown in the figure doughnuts fried in coconut oil at 210°C and doughnuts with
double sugar treatment significantly absorbed more fats than other variations. Usage of coconut oil, corn
and shortening as fat at 180°C and doughnuts prepared with double fat have similar fat absorbed. Coconut
VI. References
Drummond, K. E. (2004). Nutrition for food service and culinary professionals. Hoboken, NJ:
John Wiley & Sons.
Joachim, D., Schloss, A., & Handel, A. P. (2008). The science of good food. Toronto, Ont.:
Robert Rose.
VII. Appendices
Table 9.1 Quality observations of the cooked donuts
Legends:
Treatment Observations
Flavor Color Tenderness Greasiness
Coconut oil 8 Golden-Brown 7 5
Corn oil 4 Golden-brown 5 6
Shortening 5 golden-brown 6 4
Increased 5 Light golden- 5 7
mixing time brown
Coconut Oil 7 Dark brown 7 6 Table
(150°C) 9.1
shows the different qualities of donuts when fried at different oils, temperature and doubled ingredient
such as sugar and fat. In terms of flavor the sweetest was the double sugared donuts, then the 210°C, and
the coconut oil that has given a sweet after taste. Other treatments gave a not so sweet taste (corn oil),
taste like a bread (150°C), salty flavor (lard), raw dough taste (Increased mixing time) and a buttery taste
(double fat). In terms of color lard gave the lightest color, the corn oil, double sugar and increased mixing
time treatment resulted into a Light golden brown color; both coconut oil and 150°C treatment gave a
golden-brown color, the double fat gave a dark golden brown color while the 210°C treatment gave a very
dark brown in color. In terms of tenderness only the 150°C treatment had a spongy feel. And in terms of
greasiness, 150°C treatment had the least greasy texture, increasing mixture time, corn oil and double
sugar are quite greasy, and the double fat and coconut oil treatment has the greasiest test.
In this table the most amount of fat absorbed is the donuts cooked using shortening within 2 seconds.