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Additionally, solutions are composed of solutes and solvents and can be classified according to
their phase or type of compound. Being used in virtually every experiment, it is no secret that
solutions are one of the most fundamental elements of laboratory work; that is why it is critical
to learn how to prepare them, with the correct process and use of glassware.
Composition
Solutions have two items present: The solvent, and the solute. The solute is the substance
that is being dissolved. The solvent is the substance in which the solute is dissolving. In usual
cases, the solvent is the substance that is present the most on the solution (Helmenstine, 2018,
Classification
Solutes and solvents can be gaseous, liquids, or solids; and they can mix in many
different ways. It is easy to imagine a liquid solution such as NaCl in water, or sugar in water.
However, there are also gaseous and solid solutions such as air (oxygen, nitrogen, Carbon
Dioxide, etc.) and steel (iron and carbon—mostly). It is important to note that the type of
solution is determined by the phase (solid, gas, liquid) of the solvent. As Anne Helmenstine
(2018, Solution Definition) says, “Even though materials of different phases may combine to
form a solution, the end result always exists of a single phase.” For example, solid NaCl
2
dissolved in liquid water creates a liquid solution (Helmenstine, 2017, Solute Definition and
Examples).
Solutions can also be classified into organic and inorganic solutions. Organic solutions
are solutions made with carbon-based compounds while inorganic solutions are made with
mostly compounds that do not contain carbon (Helmenstine, 2018, Difference between Organic
and Inorganic). It is essential to know the type and composition of the solutions that are going to
be used in the lab in order to know all the safety precautions that must be taken to have a safe
work environment. For example, most organic compounds are flammable and can irritate skin
Preparation
Solutions used in the laboratory are liquid, and preparing these solutions requires
knowledge on solution concentration and use of the appropriate glassware and tools. Solution
concentration is most often given in the unit of molarity (M), or mole per litre of the solution,
𝑀𝑜𝑙𝑒
. To prepare a solution with desired volume and molarity, chemists use one of two formulas:
𝐿
𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑜𝑙𝑢𝑡𝑒
𝑚𝑜𝑙𝑎𝑟𝑖𝑡𝑦 = when starting from scratch, or M1V1=M2V2 when diluting a known
𝑣𝑜𝑙𝑢𝑚𝑒 (𝐿)
molarity solution to create a lesser-molarity solution. The first one is rearranged for moles to get
the grams of solute using the desired amount of molarity and volume. The second formula is
solved for the initial volume (V1) using the molarity of the known solution (M1), the desired
molarity of the new solution (M2), and the desired volume of the new solution (V2). Figure 1 and
Figure 2 illustrate the process of preparing the solution after calculating the grams of solute and
the volume of the known solution respectively. It is recommended to weigh the grams of solute
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in an analytical balance, as it offers more accuracy. As it can be seen from Figure 1 and Figure 2,
an essential piece of glassware used for solution preparation is the volumetric flask. For both
calculations made above, the volume of the flask in which the prepared solution is going to be
stored is the desired volume. Last but not least, graduated cylinders (Figure 1) are used to hold
the water before the calculations are made, and volumetric pipettes (Figure 2) are used to extract
Figure 1- Preparing a solution from grams of the solute. The grams of solute previously calculated are measured,
placed in the flask of the desired volume, and finally filled up with water.
Source: Halpern, Joshua. (2018, July 20). 4.5: Concentration of Solutions. Retrieved 28 October 2018 from
https://chem.libretexts.org/Textbook_Maps/General_Chemistry/Map%3A_Chemistry_-
_The_Central_Science_(Brown_et_al.)/04._Reactions_in_Aqueous_Solution/4.5%3A_Concentration_of_Solutions
4
Figure 2- Using a solution to prepare a lesser-molarity solution. The volume of the solute previously calculated is
measured and held in a volumetric pipette, placed in the flask of the desired volume, and finally filled up with water.
Source: Halpern, Joshua. (2018, July 20). 4.5: Concentration of Solutions. Retrieved 28 October 2018 from
https://chem.libretexts.org/Textbook_Maps/General_Chemistry/Map%3A_Chemistry_-
_The_Central_Science_(Brown_et_al.)/04._Reactions_in_Aqueous_Solution/4.5%3A_Concentration_of_Solutions
Usage
because they make reactions occur more easily. When a compound is dissolved in water, its
molecules keep most of their reaction properties but are now flowing more smoothly. These
freely-moving particles come in contact with the other substance particles more often. This swift
collision of particles causes the reaction to occur faster and with less disturbance than it would
have had if the substances had been mixed in, for example, solid form.
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References
Helmenstine, Anne Marie, Ph.D. (2018, October 5). Solution Definition in Chemistry. Retrieved
Helmenstine, Anne Marie, Ph.D. (2018, October 5). The Difference Between Organic and
inorganic-603912
Helmenstine, Anne Marie, Ph.D. (2017, September 6). Solute Definition and Examples in
solute-and-examples-605922
Pruthu, Kala. (2014, October). Organic Solvents – Health Hazards [PDF Document]. Retrieved
https://www.jchps.com/specialissues/Special%20issue3/17%20jchps%20si3%20k.pruthu
%2083-86.pdf