CLASS XII CHEMISTRY Max.

Marks:70
TIME ALLOWED: 3 Hrs

Unit Title VSA SA-I SA-II LA TOTAL

no. 1mark 2marks 3marks 5mar MARKS
ks
1 Solutions 1(1) 2(21) 3(28) 6 23
2 Electrochemistry 1(2) 5(37) 6
3 Chemical kinetics 1(3) 2(22) 3(29) 6
OR
4 Surface chemistry 1(4) 3(30) 5
1(5)

5 General principles and 1(6) 3(31) 4 19

processes of isolation OR OR
of elements

6 p-Block elements 5(35) 5

7 d- and f- block 1(7) 3(32) 5
elements 1(8)
8 Coordination 1(9) 3(33) 5
compounds 1(10)
9 Haloalkanes and 1(11) 2(23) 5 28
haloarenes 1(12)
1(13)
10 Alcohols, phenols and 1(14) 2(24) 4
ethers 1(15)
11 Aldehydes, ketones 5(36) 5
and carboxylic acids
12 Organic compounds 1(16) 2(25) 4
containing nitrogen 1(17)

13 Biomolecules 1(18) 2(26) 4

1(19)
14 Polymers 1(20) 2(27) 3

15 Chemistry in everyday 3(34) 3

life

TOTAL QUESTIONS 20 7 7 3 37
 TOTAL MARKS 20 14 21 15 70

CODE 2019 SQA 1

General Instructions:

1. All questions are compulsory.

2. Question nos. 1 to 20 is very short answer questions and carries one mark each.
3. Question nos. 21 to 27 is short answer questions and carries two marks each.
4. Question nos. 28 to 34is also short answer questions and carries three marks each
5. Question nos. 35 to 37 are long answer questions and carries five marks each.

1 what is the condition upon which reverse osmosis will take place?
2 Name any two metals, which can be used, for cathodic protection of Fe?
3 What is the order of ester hydrolysis using dilute mineral acid?
4 Arrange the following ions in decreasing order of flocculating power of positive sols.
SO4-2 , [Fe(CN)6]-4 ,Cl- , PO4-3.
5 What is electroosmosis?
6 What is the use of limestone in the manufacture of pig iron from haematite?
7 Give reason: Zinc is soft whereas Cr is hard.
8 What is the effect of increase in PH onK2Cr2O7?
9 Identify hybridization of the central atom and the shape of: [Ni(CN)4 ]2-
10 Draw all the isomers (geometrical and optical) of: [Co(NH3)Cl(en)2] 2+
11 Which is more reactive towards SN1 mechanism? CH2 = CH- CH2Cl or CH3CH2CH2Cl?
12 Explain why the dipole moment of cyclohexyl chloride is higher than that of
chlorobenzene.
13 Give an illustration for Swarts reaction.
14 How will you convert phenol to benzene? Write chemical equation.
15 Although phenoxide ion has more number of resonating structures than carboxylate ion,
carboxylic acid is a stronger acid than phenol. Why?
16 How will you distinguish between ethylamine and aniline?
17 Arrange the following in the increasing order of basic character.
NH3 , C2H5NH2 , (C2H5)2NH ,(C2H5)3N (in aqueous solution)
18 Give one difference between Starch and Cellulose
19 What are the products of hydrolysis of DNA other than nitrogen containing heterocyclic
compounds?
20 Write the structure of monomers of nylon-2-nylon-6.
21 a) What type of deviation is exhibited by the mixture of phenol and aniline?
b) Give a graphical representation of s Henrys’ law for the solubility of a gas in a liquid.
22 Differentiate between molecularity and order of a reaction
OR
A first order reaction is found to have a rate constant, k = 5.5 x 10-14s-1. Find the half-life
period.
23 Explain why
(i)Grignard reagent should be prepared under anhydrous condition.
(ii)Haloalkanes react with KCN to form alkyl cyanide as main product while AgCN forms
iso cyanide as chief product.
24 Give IUPAC name and structure of the organic product obtained when:
a)tert-butyl alcohol is heated with copper at 573K.
b) Phenol is treated with Bromine in CS2
25 a) Identify A and B in the following processes.
NaNO2/HCl C6H5NH2
C6H5NH2 273-278K →A → B
b)How will you convert aniline to 2, 4, 6-tribromoaniline?
26 a) Differentiate between globular protein fibrous protein
b)What does primary structure of protein stand for?
27 Differentiate between co-polymerization and homo polymerization with example.

28 (a)What would be the value of Vant Hoff factor for weak electrolytes?
(b) 200cm3 of an aqueous solution of a protein contains 1.26 g of the protein. The
osmotic pressure of such a solution at 300K is found to be 2.57 x 10 -3 bar. Calculate the
molar mass of the protein.
29 The rate of chemical reaction doubles for an increase of 10K in absolute temperature
from 298K to 308K.Calculate energy of activation (Ea).
30 Explain what is observed
(a) When a beam of light is passed through As2S3 sol
(b) When an electrolyte NaCl is added to hydrate ferric oxide sol.
(c)When electric current is passed through Au sol.
31 Outline the basic principles of the following.
a)Mond’s Process
b)ZoneRefining
(c)Electrolytic refining
OR
Explain the role of
a) Cryolite in the metallurgy of Al
b) NaCN in Froth Floatation
c) Silica in the metallurgy of Copper
32 a) The Eo value forCu+2/ Cu is positive (+0.34), unlike the remaining members of the
first transition series. Why?
b) Give the formula of the ore used in the preparation of Potassium dichromate.
c) Write equation for the reaction of KMnO4 solution with manganous salt in presence
of zinc sulphate.
33 a) Why do complexes with different ligands give different colors in dilute solutions?
b)Name the compound Ni(CO)4 and draw its structure.
c) Name the following compounds according to IUPAC rules: Na2[Fe(CN)5NO]
34 a) What are tranquilizers? Give one example.
b) Why it is not advisable to take sleeping pills without consulting doctors?
c)What is the role played by antagonists coming under drugs?
35 a) Give balanced chemical equations for the following
i)SO2 gas is passed through potassium permanganate solution
ii)XeF4 is hydrolyzed
 b) What inspired Bartlett for carrying out reaction between Xe and PtF 6?
c) Oxygen stabilizes the higher oxidation states better than Fluorine. Why?
d)Which form of Sulphur shows paramagnetic property?
OR
a)How are the following industrially prepared?
(i)Chlorine (ii) sulphuryl chloride
b)Give balanced chemical equations for the following
a)SO2 gas is passed through NaOH solution
b)Ammonia is treated with excess chlorine.
ii)Interhalogen are generally more reactive than halogens. Why?
36 (a)Write the products of the following reaction:

(i) 2 C6H5CHO + conc. NaOH →

(ii)CH3COOH + Cl2/Red P→
(iii)CH3COCl +4[H ]Pd-BaSO4→

(b)Give simple chemical tests to distinguish between the following pairs of the
compounds:

(i)Benzaldehyde and benzoic acid

(ii)Ethanal and Propanol

OR

(a) Write the structures of A, B, C, and D in the following reaction:

C6H6 + CH3Cl ( Anhy.AlCl3) →A ( KMnO4 /Heat ) → B → NH3/heat →C
(b) Draw the structure of semicarbazone of ethanal.
(c)Arrange the following in increasing order of the property indicated:
Benzoic acid, 4-nitrobenzoic acid, 3,4- dinitrobenzoic acid, 4-methoxy benzoic acid.
(acid strength)
37 (a)What is a fuel cell?
(b)Copper Sulphate solution cannot be stored in a Zinc pot. Why?
(b)The cell in which the following reaction occurs.
2Fe3+aq +2I-aq →2Fe2+aq + I2(s) has E0cell=0.236 v at 298 k.
Calculate the standard Gibbs energy and the equilibrium constant(KC) of the cell.
OR
(a)Why does the Conductivity of a solution decrease with dilution?
(b)The electrical resistance of a column of 0.05 mol L-1NaOH solution of diameter 1 cm
and
length 50 cm is 5.55x103 ohm. Calculate its resistivity, conductivity and molar
conductivity?