PTS X OLIMPIADE-KIMIA

MULTIPLE CHOICE
1. Among the substance below, which one is the stable atom ?
a. 7K
b. 8I
c. 9M
d. 10A
e. 11O
2. Atom Cl has mass number 35 and atomic number 17, if atom Cl stable will form ion ...
a. Cl—
b. Cl+
c. Cl+2
d. Cl-2
e. Cl+3
3. The group of compounds below which are all bonded are ions
(A) CaCl2, CaO, H2O, dan N2O5
(B) MgCl2, SrO, NO2, dan SO2
(C) KCl, CaO, NaCl, dan MgCl2
(D) KCl, NaCl, SrCl2, dan PCl5
(E) BaCl2, CaCl2, SrCl2, dan SF6

4. Diketahui beberapa unsur dengan energi ionisasi (dalam kJ mol-1) sebagai berikut. Na = 500; Li = 520; B
= 800; Be = 900; F = 1.681; Ne = 2.081. Ikatan paling ionik dapat terbentuk antara pasangan unsur….
(A) Na dengan F
(B) F dengan Ne
(C) B dengan Be
(D) Na dengan Ne
(E) Na dengan Li

5. Di antara senyawa-senyawa berikut yang ikatannya polar, tetapi molekulnya nonpolar yaitu….
(A) PCl3
(B) NH3
(C) CH4
(D) HF
(E) H2O

6. Jika X2Y bersifat polar dan memenuhi kaidah oktet, maka ....
(A) atom pusat Y tidak mempunyai pasangan elektron bebas
(B) atom pusat Y mempunyai satu pasang elektron bebas
(C) atom pusat Y mempunyai dua pasang elektron bebas
(D) atom pusat Y mempunyai tiga pasang elektron bebas
(E) atom pusat Y mempunyai empat pasang elektron bebas

7. Element A forms the compound AF3 (F = fluorine) which fullfil (memenuhi) the octet rule statement that is
not true is ....
(A) element A has 5 valence electrons
(B) A atom has a pair of electrons free
(C) AF3 compounds are polar
(D) pyramid-shaped AF3 molecule triangle
(E) moment dipole of AF3 compound is 0

8. According to the repulsion theory of electron pairs, relationship data between the number of pairs electrons
in the correct molecular shapeis, except ....
 PEB PE Bentuk Molekul
I
(A) 1 3 Piramida trigonal
(B) 0 3 Bipiramida trigonal
(C) 2 2 Planar bentuk V
(D) 0 6 Oktahedron
(E) 2 4 Bujur sangkar

9. Which of the following statements about SO2 molecules is TRUE ? (16S, 8O)
a. the O=S=O bond angle is 180°
b. their shape is based on then having two lone pairs and two double bond pairs
c. their shape is based on then having one lone pair and two double bond pairs
d. they are trigonal planar
e. ionic compound

10. Which of the statements about ionic solids is FALSE?

a. ionic solids conduct electricity when dissolved in water.
b. Ionic solids have high melting temperatures.
c. Ionic solids are good conductors of electricity.
d. Ionic solids can be formed by reacting an alkali metal with a halogen.
e. Ionic solids form crystals.

11. Which bond has the highest melting points?

a. Covalent polar b. covalent non polar c. Ionic
d. vander waals e. Metallic

12. Which is the correct statement about electrolytes

A. substances if dissolved in water will become negative ions and positive ions.
B. Substances if dissolved in water, will break down into molecules.
C. Substances if dissolved in water will break down into atoms
D. Substances if dissolved in water, will break down into elements
E. Substances if dissolved in water will break down into certain gases.

13. Decomposition of electrolyte substances into positive and negative ions is called ...
A. Corrosion D.oxidation
B. Ellimination E. reduction
C. ionization

14. The following are the results of experimental data on electrical conductivity of some wastewater.
Waste Light Gases Dissociation (α)
K Dead A little bubble gas α=0
L Dimmer A little bubble gas α <1

M Bright Lots bubble gas α=1

N Off A little bubble gas α=0

15. Based on the data in the table, strong electrolyte and weak electrolytes solutions are ………
A. K and L
B. M and N
C. L and N
D. M and L
 E. N and K

16. From the following solution, the strongest electrolyte is...

A. HCl
B. H2SO4
C. CH3COOH
D. NH3
E. NaOH

17. Three compounds are CrCl2, Cr2(SO4)3, and K2CrO4. Oxidation numbers of Chromium are respectively ...
A. +2, +3, +5
B. +2, +3, +6
C. +3, +5, +6
D. +3 , +5, +7
E. +4, +5, +6
18. In the reaction:
2S (s) + 2 SO2 (g) + 2 H2O (l) + 4 Cl– (aq) → 4 HCl (aq) + 2 S2O32- (aq)
oxidation number S changes from ...

A. 0 and +4 become +3 D. 0 and +2 becomes +4

B. +2 and +4 become 0 E. 0 and +4 becomes +2

C. 0 and +4 become +1

19. Consider the following statement

(1) hydrogen release reaction
(2) decrease in the oxidation number
(3) electron release reaction
(4) electron binding reaction
From the statement above which is the concept of the reduction reaction is ....
A. (1), (2), (3)
B. (1), (3)
C. (1), (2)
D. (2), (4)
E. (3) (4)

20. Among the following reactions, which is classified as Autoredox reactions is

A. CuO(s) + 2 HCl(aq)  CuCl2(aq) + H2O(l)
B. 2FeCl3 (aq) + H2S (s) → 2FeCl2 (aq) + 2HCl (aq) + S(s)
C. 3I2 (s) + 6 KOH (aq) → 5 KI (aq) + KIO3 (aq) + 3H2O (l)
D. SO2 (g) + 2H2S (g) → 3S(s) + 2H2O (l)
E. 2CuSO4 (aq) + 4 KI (aq) → 2 CuI (aq) + I2 (s) + 2K2SO4 (aq)

21. Reaction:
2KMnO4(aq) + FeSO4(aq) + 8H2SO4(aq) → K2SO4(aq) + 2MnSO4(aq) + 5Fe2(SO4)3(aq) + 8H2O(l)
The correct statement of the above reaction is ...
A. KMnO4 acts as reductant
 B. FeSO4 acts as an oxidant
C. S in H2SO4 decreases in the oxidation number
D. MnSO4 as a result of reduction
E. 5Fe2(SO4)3 as a result of reduction

22. The ratio of Na : S : O atoms in Natrium sulfate is

A. 1 : 1 : 4
B. 1 : 2 : 4
C. 2 : 2 : 4
D. 2 : 1 : 4
E. 3 : 1 : 4

23. The chemical name of Ba3(PO4)2 is ....(56Ba)

A. Barium diphosphate
B. Barium diphosphate
C. Barium (III) phosphate
D. Barium (II) fospitable
E. Barium phosphate

24. The chemical formula of the Calcium Chloride compound is ... (20Ca , 17Cl , 55Cs)
A. CaCl
B. CaCl2
C. Ca2Cl
D. CsCl
E. CsCl2
25. Chemical formula of iron (II) chloride heptahidrate
A. FeCl2.7H2O
B. FeCl2.6H2O
C. IrCl2.7H2O
D. IrCl2.6H2O
E. Fe2Cl.H2O

ESSAY
1. Explain, why the NaCl solid can conduct electricity if dissolved in water?

2. Write the ionisation reaction from Ba3(PO4)2 !

3. Determine the molecular shape of XeOF4 based on VSEPR theory !!!

4. These coumpound name written as follows !

Cemical Name of Compound

formula
a KMnO4
b Mangan (IV) Sulfate
c P2O5
d Silicon tricloride

5. Titik didih alkohol (R - OH) lebih tinggi daripada titik didih molekul eter (R - O - R) walaupun rumus molekulnya
sama. Hal ini terjadi karena . . (Gaya antar molekul)