PRACTICE TEST

CLASS: XII
Unit 2: Solutions

Full marks: 35 DATE---------------------- Time: 40 Min

SN Question Marks
1 What is meant by reverse osmosis?Write its one use.
2 Increase in temperature of an aqueous solution will cause ..............in its molarity 1
3 What is Azeotropic Solution.Give one example of maximum boiling azeotrope 1
4 Explain why a solution of chloroform and acetone shows negative deviation from Raoult’s law. 1
5 Why NaCl is used to clear snow from roads ? 1
6 If the density of some lake water is 1.25 gm/ml and contains 92 gm of Na+ 1
+
Ions per kg of water, calculate the molality of Na ion in the lake.
7 On mixing liquid X and Y, volume of the resulting solution decreases. What type 1
of deviation from Raoultís law is shown by the resulting solution ? What change
in temperature would you observe after mixing liquids X and Y ?
8 Out of the following three solutions, which has the highest freezing point and why ? 1
(a) 0.1 M urea (b) 0.1M BaCl2 (c) 0.1M Na2SO4
9 Henry law constant for two gases are 21.5 and 49.5 atm, which gas is more 1
soluble ?
10 What is the Vanít Hoff factor in K4[Fe(CN)6] and BaCl2? 1
11 Why does a solution of ethanol & cyclohexane show positive deviation from 1
Raoult’s law?
12 An aqueous solution of 2% non-volatile exerts a pressure of 1.004 Bar at the 2
normal boiling point of the solvent. What is the molar mass of the solute ?
13 Define the term “Osmotic Pressure”. Describe how the molecular mass of a substance can be 2
determined by a method based on measurement of osmotic pressure?
14 Define Henryís law. Give their two application. 2
15 Define the following terms: 2
(i) Mole fraction (iii) Van’t Hoff factor (iii)Colligative Properties (iv)Molality of solution
16 Explain the following- 2
(i)Boiling point elevation constant for a solution
(ii)Vant Hoff factor
(iii)Isotonic solution
(iv) Ideal solution
17 Calculate the boiling point of a solution containing 0.61 g of benzoic acid in 5g of CS2. 3
0
Assume 84% dimerization of acid.The boiling point and Kb of CS2 are 46.2 C and 2.3 K kg mol-1
respectively.
18 Suggest the most important type of intermolecular attractive interaction in 3
the following pairs :
(a) n-hexane and n-octane (b) I2and CCl4 (c) NaClO4 and water
19 Calculate the mass of ascorbic acid (C6H8O6) to be dissolved in 75 g of acetic acid to lower its 3
melting point by 1.50C. [For acetic acid Kf = 3.9 K kg mol-1]
20 A solution containing 8 g of a substance in 100 g of diethyl ether boils at 36.860C, whereas pure 3
ether boils at 35.600C. Determine the molecular mass of the solute.
(For ether Kb= 202 K mol-1 kg )
21 100mg of a protein is dissolved in just enough water to make 10.0mL of 3
solution. If this solution has an osmotic pressure of 13.3 mm Hg at 250C,
what is the molar mass of the protein?
22 (a)Define Raoultís law of binary solution containing non-volatile solute in it. 5
(b) On dissolving 3.24 g of sulphur in 40 g of benzene, boiling point of solution was higher than
that of benzene by 0.81K (Kb= 2.53 K kg mol-1). What is molecular formula of sulphur ? (Atomic
mass S = 32 gmol-1)