CBSE TEST PAPER-04

CLASS - XII CHEMISTRY (Haloalkanes and Haloarenes)

[ANSWERS]
Topic:- Identification Question

Ans1. X= CH3 CH = CH2

Y= CH3 CH CH3

OH

Z= CH3 CH CH3

Cl

aq.H2SO4 ZnCl2 HCl alc

Ans2. A(C3H6) B C A
KOH

A = CH3 CH = CH2 B = CH3 CH CH3 C = CH3 CH CH3

OH Cl
The equations are
aq.H2SO4 ZnCl2 HCl
CH3 CH = CH2 CH3 CH CH3 CH3 CH CH3

OH Cl
alc KOH

CH3 CH = CH2

NH3 NaNO2 Cu/HCl

Ans3. A B C A
Cu2O HCl

Cl

A=

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 NH2 N2Cl

B = A n ilin e C= Bengene diazonium chloride

The reactions are

Cl NH2 N2Cl Cl

NH3 NaNO2, HCl Cu/HCl

Cu2O

Ans4. HBr alc

CH3 CH CH3 CH3 CH CH3 CH3 CH = CH2
KOH
OH (Y)
Br
(X) HBr peroxide

CH3CH2 CH2 Br
(Z)
Ans5. alc KOH Br2
C2 H5 Br CH2 = CH2 CH2 CH2

Br Br
(A)
(B)

N2Cl Br
Ans6.
NaNO2 CuBr
C6 H5 NH2 B
HCl

(A) (B)

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 Cl ONa OH
Ans7. +
NaOH H , H2O
623K1 Pressure

(A) (B)

Ans8. A is C5H12 (mol. Wt. 72)

Since its gives one mono chloro and two dichloro derivatives on photochemical
chlorination, it is
CH3

CH3 C CH3

CH3
The reactions are

CH3

CH3 C CH3 + Cl2

CH3
(A)

Cl2 hr

CH3 CH2 - Cl CH3

CH3 C CH2 - CH - 2 Cl + HCl CH3 C CH - Cl +
2 CH3 C CHCl
2
CH3 CH3 CH3
Dichloro - compounds

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