Question Paper and Answers

FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS
CPT - 1 CODE:111269 PAPER - 1

BATCHES – One Year CRP (1819)
Time Allotted: 3 Hours Maximum Marks: 210
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Two Parts.
(i) Part-A (01 – 10) contains 10 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks and – 2 mark for wrong answer.
(ii) Part-C (01 – 10) contains 10 Numerical based questions with single digit integer as answer, ranging
from 0 to 9 (both inclusive) and each question carries +3 marks for correct answer and – 1 mark for
wrong answer.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
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IT2019One Year CRP (1819) (PAPER-1) (CPT-1)-(PCM) JEE ADV. (SET-A)-2
Useful Data
PHYSICS
2
Acceleration due to gravity g = 10 m / s
Planck constant h = 6.6 × 10–34 J-s
Charge of electron e = 1.6 × 10–19C
Mass of electron me = 9.1 × 10–31 kg
Permittivity of free space 0 = 8.85 × 10–12 C2/N-m2
Density of water water = 103 kg/m3
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K–1 mol–1
CHEMISTRY
Gas Constant R = 8.314 J K1 mol1

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No.: H=1, He=2, Li=3, Be=4, B=5, C=6, N=7, O=8, F=9, Na=11, Mg=12, Al = 13,
Si = 14, P = 15, S = 16, Cl = 17, Ar =18, K=19, Ca=20,Cr=24, Mn=25, Fe=26, Co=27, Ni=28,
Cu=29, Zn=30, As=33, Br = 35, Ag = 47, Si = 21, Sn = 50, Ti = 22,I = 53, Xe = 54, Ba = 56, Pb
= 82, U = 92, V = 50.
Atomic masses: H =1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16, F=19, Na=23, Mg=24,
Al=27, Si=28, P=31, S=32, Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59, Ni=58.7,
Cu=63.5, Zn = 65.4, As = 75, Br = 80, Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb =
207, U = 238.
SECTION – I : PHYSICS
PART – A : (One or more than one Options Correct Type)
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
1. The figure shows a block of mass m placed on a smooth

m
wedge of mass M. Calculate the value of M and tension in the
string, so that the block of mass m will move vertically 

downward with acceleration 10 m/s2 (Take g = 10 m/s2)
Mcot  Smooth
(A) the value of M is 
1  cot 
M tan 
(B) the value of M is
1  tan 
(C) the value of tension in the string is Mg sin 
Mg
(D) the value of tension is
cot 
2. A force F is applied vertically upward to the pulley and it is observed

that the pulley in the figure moves upward with a uniform velocity of F
2 m/s. The possible value(s) of F is/are (in newtons)
(A) 150 (B) 120 light pulley
(C) 75 (D) 400. 2
g=10m/s
10kg 6kg
Ground
3. Two blocks A and B of equal mass are initially in contact when B

released from rest on the fixed wedge of inclination  . The A
coefficients of friction between the inclined plan and A and B are 1
and  2 respectively. Select the correct option(s).
(A) If 1   2 the blocks will always remain in contact
 Fixed
(B) If 1   2 the blocks will slide down with different accelerations.
1
(C) If 1   2 , the blocks will have a common acceleration  1  2  gsin 
2
 g
(D) If 1   2 the blocks will have common acceleration 1 2 sin 
1  2
Space for rough work
4. The potential energy  in joule of a particle of mass 1 kg moving in the XY plane is given
by   3x  4y , where (x, y) are the co-ordinates of the particle in metre. If the particle is at rest at
(6, 4) at time t = 0, then which of the following is/are correct?
(A) The particle has constant acceleration and the co-ordinates of the particle at time t = 4 s are
(-18, -28)
(B) The work done by the field force from the position of rest of the particle and the instant of
the particle crossing X-axis is 25 joule.
(C) The speed of the particle when it crosses the Y-axis is 10 ms-1
(D) The speed of particle when it crosses y-axis in 20 ms-1
5. A simple pendulum of length L and mass (bob) M is oscillating in a plane about a vertical line
between angular limits  and  . For an angular displacement ,     the tension in the
string and velocity of the bob are T and V respectively. The following relations hold good under
the above conditions:
MV 2
(A) T cos   Mg (B) T  Mgcos  
L
(C) Tangential acceleration = g sin  (D) T  Mgcos 
6. A small block of mass m is released from rest from position A

inside a smooth hemispherical bowl of radius R as shown in figure.
Choose the wrong option.
(A) Acceleration of block is constant throughtout
(B) Acceleration of block is g at A
(C) Acceleration of block is 3g at B
(D) Acceleration of block is 2g at B
7. Two particles are projected with speed 4 m/s and 3m/s simultaneously from same point as shown
in the figure. Then:
(A) Their relative velocity is along vertical direction

(B) Their relative acceleration is non-zero and it is along vertical direction
(C) They will hit the surface simultaneously
(D) Their relative velocity is constant and has magnitude 1.4 m/s
8. The motion of a body falling from rest in a resisting medium is described by the equation
dv
 A  Bv , where A and B are constants. Then:
dt
(A) maximum possible velocity is A/B m/s (B) initial acceleration is A m/s2
(C) velocity at any time t is v =
A
B
1  e Bt 
(D) velocity at any time t is v =
A
B
1  e  At  
9. If three vectors along co–ordinate axis represent the adjacent sides of a cube of side “b”, then
which of the following cannot represent the unit vector along its diagonal passing through the origin
î  Jˆ  kˆ î  Jˆ  kˆ
(A) (B)
2 3b
î  Jˆ  kˆ
(C) î  Jˆ  kˆ (D)
3
10. A smooth track in form of a quarter circle of radius 6 m lies in the vertical
plane. A particle moves from P1 to P2 under the action of forces F1, F2 and
F3 . Force F1 is always towards P2 and is always 20 N in magnitude. Force
F2 always acts horizontally and is always 30 N in magnitude. Force
F3 always acts tangentially to the track and is of magnitude 15 N. Select
the correct alternative.
(A) Work done by F1 is 120 2 J (B) work done by F2 is 180 J
(C) Work done by F3 is 45 J (D) F1 is conservative in nature
PART – C : (Single digit integer)

This section contains 10 questions. The answer to each question is a single digit integer ranging from 0
to 9 (both inclusive).
1. Coefficient of friction between two blocks shown in figure is 1 kg 2 m/s

  0.4. Floor is smooth. The blocks are given velocities of 2 m/s
2 kg 8 m/s
and 8 m/s in the directions shown in figure at t = 0. The time when
relative motion between them will stop is (in sec.)
2. Two small particles of equal masses start moving in opposite directions from a V A 3V
point A in a horizontal circular orbit. Their tangential velocities are v and 3v
respectively, as shown in the figure. Between collisions, the particles move
with constant speeds. After making how many elastic collisions, other than
that at A, these two particles will again reach the point A?
3. A wedge and block are connected by a mass less

string passing over a frictionless pulley as shown
in the figure. At the instant shown, the speed of
the wedge is 1m/s. Assume all surfaces are m
wedge
smooth. The speed of the block with respect to 600
wedge at the instant shown is (3/k) m/s find the
value of k.
4. A projectile is moving at 80/3 m/s at its highest point, where it breaks into two parts (mass ratio is
1:2) due to an internal explosion. Lighter part move vertically up at 60 m/s with respect to ground.
The other part will move at 10m/s, find the value 
5. A block is kept on a horizontal surface and a rod PQ is

resting on it as shown in figure. End ‘P’ of rod in P
slipping down the block with speed 4 cm/s while block

is moving towards right with speed 3 cm/sec. Speed (in
m/sec) of end ‘Q’ of rod at the instant shown will
6. A block is slipping down a rough incline plane having angle of inclination = 37°, friction between
block and the plane is  = (0.25 m–1)x where x is distance from the top of plane. Initially block is
kept at the top of plane and released. Speed of block will be max at x = (in m)
7. Two particles A and B of mass m each are connected together by a

rigid massless rod of length 20 cm. Initially rod is vertical and
particle A is given velocity V horizontally, while particle B is at rest.
Consider the adjacent figure. Find the minimum value of V (in m/s)
for which particle B loose contact with ground immediately after
giving velocity V.
(Take g = 10 m/s2)
8. A cyclist rides along the circumference of a circular horizontal track of radius r. The coefficient of
 r
friction   0  1   where 0 = 0.8 is a constant, R = 2 and r is the distance from the centre of
 R
the circle. Calculate the maximum velocity of the cyclist.
9. A force time (F & t) plot for a linear motion is shown in the figure.
The linear momentum gained between 0 and 6 seconds is 2K
m/s. Calculate the value of K.
10. A spring is attached with a block of mass 1.2 kg and fixed ceiling. The
block is lying on a smooth horizontal table and initially the spring is vertical
and unstretched. Natural length of spring is 3l0. A constant horizontal force
F is applied on the block so that block moves in direction of force. When
length of spring becomes 5l0 block leaves contact with table. Find the
constant force F (in N), if initial and final velocity of block is zero.
SECTION – II : CHEMISTRY
1. To a saturated solution of AgCl containing sufficient amount of solid AgCl, NH3 is gradually
added such that its concentration becomes 0.2 M. Which of the following options containing
concentration of ions is correct? [Given : Ksp of AgCl = 10–10, K f1 of Ag NH3 2  103 , Kf of
Ag NH3 2  108 ]
(A) [Cl–] = 2 × 10–2 M (B) [Ag(NH3)2]+ = 2 × 10–2 M
(C) [Ag(NH3)]+ = 10–6 M (D) [Ag+] = 5 × 10–9 M
2. Which of the following compound contain both ionic and covalent bond :
(A) NH4Cl (B) KCN (C) CuSO4.5H2O (D) NaOH
3. Which of the following carbonates do not evolve CO2 on heating

(A) Li2CO3 (B) MgCO3 (C) Na2CO3 (D) K2CO3
4. Half life period is related as :

a = initial concentration
1 1
(A) for 2nd order t 1  (B) for 0th order t 1 
a a
2 2
(C) for 3rd order t 1  a 2 (D) for 1st order t 1 does not depend on a
2 2
5. The wave function of 3s and 3pz orbitals are given by

3
½
1  1   Z  2 
3s       6  6    e 2
9 3  4   a0 
3
½
1  3   Z  2  2
3pz   4   a   4    e cos  ;
9 3   0
2Zr

na0
Where a0 = 1st Bohr radius, Z = charge number 0 nucleus, r = distance from nucleus
From this, we can conclude:
(A) Total number of nodal surface is same for 3s and 3px orbitals.

(B) The angular nodal surface of 3pz orbital occur at   .
2
(C) The radial nodal surface of 3s and 3pz orbitals are at equal distance from nucleus.
(D) 3s electrons have greater penetrating power into the nucleus compared to 3p z electron.
6. The correct statement(s) is / are :

(A) pH of 10–8 M HCl is 8
(B) The conjugate base of H2PO4– is HPO42–
(C) Auto protolysis constant of water increases on increase in temperature
(D) In the titration of weak a weak monoprotic acid and strong base, the pH at half neutralization
point is equal to 1/2pKa.
7. Which of the following statements are not correct about lithium ?

(A) Lithium is least reactive of all alkali metals.
(B) It is the weakest reducing agent among all alkali metals (in aq. Solution)
(C) Lithium carbonate is thermally unstable
(D) LiHCO3 is a while crystalline solid
8. Calcium oxide can be used for drying of

(A) Cl2 (B) H2 (C) NH3 (D) CO2
9. The wave function for 2s orbital is given as

3
 1  1  2  r  r 2a0
   2   .e
 4 2   a0   a0 
Where a0 = First Bohr’s radius in H-atom = 0.529 Å.
Read the given statement and pick out the correct statement(s).
(A) The number of radial nodes is equal to three
(B) The probability density is independent of direction.
(C) The probability density of finding electron at nucleus is non-zero
(D) The radial node occur at a distance 2a0 from nucleus.
10. Amongst the following molecules find those which have 1 > 2, as well as, x > y where 1, 2 are
bond angles and x, y are bond lengths.
(A) (B)
(C) (D)

1. A cylinder source of light which emits radiation radially

(from curved surface) only, placed at the centre of
hollow, metallic cylindrical surface, as shown in
diagram.
The power of source is 90 watt and it emits light of
wavelength 4000 Å only. The emitted photons strike
the metallic cylindrical surface which results in ejection
of photoelectrons. All ejected photoelectrons reaches
to anode (light source). The magnitude of photocurrent
(in amp) is:
[Given : h = 6.4 × 10–34 J/sec]
(Note : report your answer sum of the digits for
example If your answer is 42 then express it 4 + 2 = 6)
2. Find the total number of correct orders among the following.

(a) order of electron affinity : S > O–
(b) order of ionic radius : Al3+ < Mg2+ < O2–
(c) order of electronegativity : Si < P < C < N
(d) order of atomic radius : O < C < S < Se
(e) order of second ionization energy : C < N < F < O
(f) order of ionic radii : S2– < Cl– < K+ < Ca2+
3. Count the total number of unshared electrons on I3–  x

Count the total number of p-d bonds in PO3–4 y
Count the total number of lone pairs in XeF4  z
Hence, find the value of x – z – y
4. Number of unpaired electrons in Mn+7 = a

Number of d-subshell electrons in Cr = b
Numbers of f-subshell electrons in Hf
(atomic number = 72) = c
Find the value of c – b + a.
5. Find the number of acid(s) from the following in which X—H bond is/are present? [X = central
atom]
H3PO2, H5P3O10, H4P2O7, H3PO3, H2S2O6, H4P2O5, H3BO3, H2SO4
6. For the first reaction : A (g)  2B (g) + C (g) the half life for the decomposition of A is 3 min at
300 K. Calculate the time (in min) in which partial pressure of A (g) will drop from 2 bar to 0.5 bar
at 400 K. Given activation energy of the reaction is 840 R.
[Take : In 2 = 0.7]
7. A substance undergoes first order parallel reaction as shown. Calculate net activation energy if it
is a known that B, C and D are formed in a molar ratio of 2 : 3 : 4 respectively.
al
3B
Kc
=8
Ea
Ea= 6Kcal
A 2C
E
a =
3K
ca
l
D
8. A substance ‘A’ undergoes disproportionation reaction to form A3+ and A2– obeying first order
kinetics. The rate constant is obtained by measuring volume of an oxidizing agent capable of
oxidizing A, A3+ and A2– to A2+, A4+, A1+ respectively. From the following data, calculate moles of
A2–, 6 minutes after start of the reaction if initially 10 moles of A was taken.
Time (min) 0 4 min
Volume of oxidizing agent 20 21.5 ml
9. In the titration of a solution of a weak base BOH and HCl the pH is 8.2 after 10 ml of HCl solution
has been added and 7.6 after 20 ml of HCl solution has been added. Calculate the value of pKb of
the base.
10. Which of the following has less than two bond order?
F2 , Cl2 , Br2 , O22 , O2 , N2 , O22 , O2 , Li2 , He2
SECTION – III : MATHEMATICS

1. Let f: [2, 4]  R is a continuous positive function, differentiable on (2, 4), then

2f (  )
f(4)
(A) there exists   (2, 4) such that  e f(  )
f(2)
f() f()
(B) there exists   (2, 4) such that f() = 
2 4
(C) there exists   (2, 4) such that f() = 0
(D) there exists   (2, 4) such that f() = 2f()
2. Let f : R  (0, ) and g : R  R be twice differentiable function such that f” and g” are continuous
f(x)g(x)
functions on R. Suppose f’(2) = g(2) = 0, f”(2)  0, and g”(2)  0 if Lt 1
x 2 f '(x)g'(x)
(A) f has a local minimum at x = 2 (B) f has a local maximum at x = 2
(C) f”(2) > f(2) (D) f(x) – f”(x) = 0 for at least one x  R
 –1
 2
3. Let f(x)  e x x  0 then ( where fn(x) is nth derivative of f(x))
 0 x0

(A) fIII (0) = 0 (B) fIV(0) = 0 (C) fV(0) = 0 (D) f’VI(0) = 0
4. Which of the following are incorrect ?

(A) If f(x) and g(x) have a local minima at x = a only then y = f(x) + g(x) has only one point of local
minima at x = a
(B) If f(x) is strictly increasing continuous function, then it is injective function.
(C) If f(x) is not differentiable at a point, it mean f(x) has no tangent at that point.
(D) Let f : A A be a function, which is one-one then it must be onto.
max f  t  ,0  t  x for 0  x  1

5. Let f(x) = x3  4x2  6x  1 and g  x    then
 13  x, 1  x  3

(A) g (x) is continuous at x = 1 (B) g (x) is differentiable at x = 1
(C) g (x) is not continuous at x = 1 (D) g (x) is not differentiable at x = 1
6. Let f(x) = cosec–1 [1 + sin2x], where [] denotes the greatest integer function. Then
(A) The domain of f is R (B) The domain of f is [1, 2]
 
(C) The range of f is [1, 2] (D) The range of f is  , cosec 12
2 
7. If f(x) = 2{x}, where {x} denotes the fractional part of x. Then which of the following is true?
1
1
(A) f is periodic (B)  2{x} dx 
0
ln2
1 100
(C)  2{x} dx  log2 e (D)  2{x} dx  100log2 e
0 0
8. If f(x) = log x , (x R+ – {1}, then

x2
(A) f is one-one
(B) f is many one
(C) f(2) = 1
(D) f is a constant function within its domain
9. Let the function f(x) be defined as follows :

 x 3  x 2  10x ; 1  x  0

f(x) =  cos x ; 0  x  /2
 1  sin x ; /2  x  

Then which of the following statement(s) is/are correct
(A) Local maximum at x = 0 (B) Local maximum at x = /2
(C) Absolute maxima at x = – 1 (D) Absolute minima at x = 
f(a) f(a)
4x
10. Let f (x) =
4x  2
, I1 =  xf (x(1  x)) dx and I2 =  f(x(1  x)) dx where f (a) > f (1  a), then
f(1a) f(1 a)
I1
find the value of .
I2
1 1
(A) (B) (C) 1 (D) 2
2 3

1. The number of integral values of a for which x3  3x +a=0 has three real and distinct roots is
________

2. If f () = 2 and   f(x)  f (x) sin x dx  5 , then f (0) is
0

3. The value of  ln(1  cos x)dx = K.ln2 then |[K]|
0
3 cos 2x  1
4. If  cos x
dx = a sin1  
3 sin x  2 sin1  
b tan x  c , then a + b = ____
 
3
log 1/ 4 x log27 x 2 1
2 2 3  2x dy
5. Let y  4log49 x
and  ax  b , then the value of a + b is __________.
7  x 1 dx
h–1(x) – h–1(1)
6. If f(x) = x + 1, g–1 (x) = x3 + x + 1, g(f(x)) = h(x), then lt is equal to :
x 1 x –1
7. Let f : R  R defined as f(x) = x3 + x + 1, 1  x  2. The graph of y = g(x) is reflection of graph of

y = f(x) about the line y = x if the domain of g(x) is [a, b], then |b – a| is
8. Let f(x) be a cubic polynomial which has local maximum at x = –1 and f’(x) has a local minimum
at x = 1. If f(–1) = 10 and f(3) = –22, then the distance between its local maxima point and local
minima point is :
x2 2
t  5t  4
9. The total number of extremum(s) of y =  2  et
dt are
0
10. lim
 
(6 tan x) e x  x  1  3x3  x 4  x5
 K K is finite & non-zero then value of n.
x 0 n
x
Answer Key
FIITJEE - JEE (Paper - 1)

Phase-1
BATCHES-1819
SET-A
ANSWERS
PHYSICS CHEMISTRY MATHEMATICS

Part - A Part – A Part - A
1 A 1 ABCD 1 AB
2 B 2 ABCD 2 AD
3 AB 3 CD 3 ABCD
4 ABC 4 ACD 4 ACD
5 BC 5 ABD 5 AD
6 AC 6 BC 6 AD
7 AD 7 BD 7 ABCD
8 ABC 8 BC 8 BD
9 ABC 9 BCD 9 ABC
10 ABC 10 AD 10 A
Part - C Part - C Part - C
1 1 1 1 1 3
2 3 2 5 2 3
3 2 3 3 3 4
4 5 4 9 4 8
5 6 5 3 5 3
6 3 6 3 6 4
7 2 7 4 7 8
8 2 8 5 8 4
9 6 9 6 9 5
10 5 10 7 10 5
Solutions
Physics
1. M' g  T  M'a …(i) R

T = Ma …(ii)
M' g  a(M  M') T M
M'g
a
(M  M')
Mg
ma sin   mgcos 
a  gcot 
M'g
gcot  
(M  M')
cot  M  cot M'  M' masin
Mcot 
M' 
(1  cot ) ma
T=Ma

= M. g cot 
mgcos
Mg mgsin
T .
tan  + macos
2. B
F
For the two values of F, F = 120 N; the tensions in the string are T  = 60 N. The accelerations
2
of the two masses are zero.
6. Acceleration of block is not constant throughout. Acceleration of block at B is v 2 / R
Where v 2  2gR
Integer
1. mg  0.4110  4N is the friction force.

 a1  4m / s2
a2  2m / s2
2  4t  8  2t
 t  1s
2. 3 collisions
6. VQ = VP tan  + VBlock = 6 cm/s
6. V is max when a = 0 i.e. sin 37° – 0.25.x cos 37° = 0

 x = 3m
7. When normal contact force approaches zero


a cm gjˆ
In C.M. frame for particle A (In C.M. frame fbd of A)
2
v
m 
mv 2
T   
2
/2 2
and for particle B in ground frame
mv 2
 N = mg – T = mg –
2
mv 2
particle B will break off when mg  0
2
 2g  v
0 gR
8.
2
1
10. F (4I0) – k(2I0 )2  0
2
KI0
F
2
3
2kI0 cos  = mg  2kI0. = mg
5
5mg 5mg
 KI0    5N
6 12
Chemistry
1. AgCl  s 
 Ag  Cl  aq K sp  sx
s
Ag NH3 2

Ag  2NH3 108 
 0.2 
2
x 0.2 s x
2
s
10 2 
 0.2 
2
Cl   s  2  102 M   Ag NH3 2 


 
10 10
x = [Ag+] =  5  10 9 M
2  10 2
 Ag NH3   
Ag+ + NH3 Ag (NH3)+ k = 103 =  
5  10 9  0.2
[Ag(NH3)+] = 10–6 M
3. Li2CO3  Li2O  CO2

MgCO3 MgO + CO2
4. t 1  [A0 ]1n for nth order.

2
6. HPO42– is a conjugate base of H2PO4–. Always ionisation constant increases on increase in

temperature.
7. Lithium is strongest reducing agent among the alkali metals, LiHCO 3 does not exist in solid state.
8. CaO can not be used to dry Cl2 on CO2 as it reacts with these
CaO + CO2 CaCO3
H O
CaO + Cl2 
2
 CaOCl2
9. No. of radial nodes = 2 – 0 – 1 = 1 (n – l – 1)

Probability density 2
Since  contains No.  or  terms – probability of finding electron does not depend upon
direction.
3
 1  1  2
Also, since at r = 0,       . 2;
 4 2   a0 
2 is non zero at r = 0
 r  r
 = 0 when the term  2   vanishes putting 2  0
 a0  a0
 r = 2a0
at r = 2a0  = 0 : corresponds to radial node.
10. (a) 2 < , x > y (b) 2 > , x > y

(c) y > x; 2 > 1 (d) x > y ; 1 > 2
Integer
1. Number of photoelectrons emitted
90 4000  10 10 1
  34
  1020
3 6.4  10  3  10 8
1.6
 Magnitude of charge passing per second
1
  1020  1.6  10 19  10Å
1.6
2. Correct order is S2– > Cl– > K+ > Ca2+
3.
4. a = 0, b = 5, c = 14
 (t )  E  1 1
6. ln  1/ 2 1   a  – 
 (t1/ 2 )2  R  T1 T2 
 3  840R  1 1 
ln   –
 (t1/ 2 )2  R  300 400 

 (t/12) = 1.5 min.

PA  2  0.5 (2 half-lives)  t = 3 min.
3K1 2 2K 2 3
7.  
2K 2 3 K3 4
K1 4 K2 3 9
  
K2 9 K 3 8 24
K1 : K2 : K3
4 : 9 : 24
K1E1  K 2E2  K 3E3
E
K1  K 2  K 3
4x  8  9x  6  24x  3

37x
32  54  72
= 4
37
8. A  A3+ + 3e– × 2 Using KMnO4

A + 2e–  A2– × 3 A  A2+
 nf = 2
5A  2A3+ +3A2– A3+  A4+
t = 0 10 nf = 1
t = t 10 – 5x 2x 3x A2–  A1+
At t = 0
10 × 2 = N × 20
At t = 4 min
(10 – 5x) 2 + 2x × 1 + 3x × 3 = N × 21.5
20 – 10x + 11x = N × 21.5
20  x N  21.5

20 N  20
x 215 43
1  
20 200 40
x 3

20 40
x = 1.5 mole
5x = 1. 5 × 5 = 7.5 mole or 75% of reaction in 4 mint. T1/2 = 2 min
After 6 min = 5x = 8.75  x = 1.75
n 2–  3x  5.25 moles  5
A
9. BOH  HCl BCl  H2O

C 10 M – –
C–10 M – 10M
10M  200M 
5.8 = pKb + log ;6.4  pKb  log  
C – 10M  C – 20M 
 20M   10M 
 log   – log    0.6
 C – 20M   C – 10M 
20M (C – 10M)
  4
(C – 20M) 10M
 C = 30 M
 pKb = 6.1
Mathematics
5. f '  x   3x  8x  6  0 x, since discriminant is < 0
2
6. cosec–1 [1 + sin2x] is defined when [1 + sin2x]  1 or  –1

But 1  1 + sin2x  2
Since 0  sin2x  1
Now, [1 + sin2x] = 1 or 2
cosec–1[1 + sin2x] = cosec–1 1 or cosec–12

= , cosec–12
2
7. Clearly, f(x) = 2{x} is periodic with period 1

x dx  2x dx   2  1  2  1 = 1  log e .
1 1 x
 2   
 ln2  0 ln2 ln2 ln2
2
0 0
100 1
 2  dx  100  2 dx = 100 log2e.

x x
Now,
0 0
ln x
8. f(x) = log x =½
x2
ln x 2

3x 2  2x  10 ; 1  x  0


9. f '(x) :   sin x ; 0x
 2
 
1  cos x ; x
 2
Then using first derivative test
4x 41 x
10. f (x) + f (1  x) =  =1
4x  2 41 x  2
f(a)
So I1 =  (1  x) f (1  x) (x) dx
f(1a)
I1 1
 I1 = I2  I1   .
I2 2

   
 0

2. I =  f(x) sin x   f (x)cos x dx  sin x  f (x)dx   cos x f (x)dx
 
 0 0 0 0
 
 0   sin x f(x)dx  f (x)sin x 0  cos x f(x) 0   f(x)sin x dx
 
= f(x)cos x 0  cos x  f (x)dx
0 0
=   f()cos   f(0)  cos(0) = 5
 2 + f (0) = 5  f (0) = 3.
  
3. Let    ln 1  cos x  dx   ln 1  cos x  dx  2   ln 1  cos2 x dx  
0 0 0
 /2 /2
 
 2 lnsin xdx  4  lnsin xdx    2  lnsin xdx  2     ln2   ln2
0 0 0  2

3 2cos2 x  1  1  6 cos 2 x  4
4. I=  cos2 x
dx =  cos2 x
dx
6  4 sec 2 x
=  6  4 sec 2 xdx =  dx
6  4 sec 2 x
dx sec 2 x
= 6 dx  4  dx
6  4 sec 2 x 6  4 sec 2 x
cos x sec 2 x
I = 6 dx  4  dx
6 cos2 x  4 2  4 tan2 x
cos x sec 2 x
= 6 dx  4  dx
2  6 sin2 x 2  4 tan2 x
Put sin x = t, tan x = z
1 dz
I = 6 dt  4 
2  6t 2
2  4z 2
6 1 4 dz
=  dt  
   
2 2 2 2
1 3 t 1 2 z
sin1  3 t  sin1  2z  c
= 3 2 2 2
3 2
= 6 sin 1
 
3 sin x  2 sin 1
 
2 tan x  c
5. 3
y simplifies to (using log properties)
x 4  (x 2  1)  2x
y
x2  x  1

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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS

CPT - 1 CODE:111269 PAPER - 1

Time Allotted: 3 Hours Maximum Marks: 210

B. Filling of OMR Sheet

C. Marking Scheme For All Two Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

Planck constant h = 6.6 × 10–34 J-s

Charge of electron e = 1.6 × 10–19C

Mass of electron me = 9.1 × 10–31 kg

Permittivity of free space 0 = 8.85 × 10–12 C2/N-m2

Density of water water = 103 kg/m3

Atmospheric pressure Pa = 105 N/m2

Gas constant R = 8.314 J K–1 mol–1

Gas Constant R = 8.314 J K1 mol1

1. The figure shows a block of mass m placed on a smooth

2. A force F is applied vertically upward to the pulley and it is observed

3. Two blocks A and B of equal mass are initially in contact when B

Space for rough work

6. A small block of mass m is released from rest from position A

(A) Their relative velocity is along vertical direction

Space for rough work

Space for rough work

PART – C : (Single digit integer)

1. Coefficient of friction between two blocks shown in figure is 1 kg 2 m/s

3. A wedge and block are connected by a mass less

5. A block is kept on a horizontal surface and a rod PQ is

slipping down the block with speed 4 cm/s while block

Space for rough work

7. Two particles A and B of mass m each are connected together by a

Space for rough work

3. Which of the following carbonates do not evolve CO2 on heating

4. Half life period is related as :

5. The wave function of 3s and 3pz orbitals are given by

Space for rough work

6. The correct statement(s) is / are :

7. Which of the following statements are not correct about lithium ?

8. Calcium oxide can be used for drying of

9. The wave function for 2s orbital is given as

Space for rough work

PART – C : (Single digit integer)

1. A cylinder source of light which emits radiation radially

2. Find the total number of correct orders among the following.

3. Count the total number of unshared electrons on I3–  x

4. Number of unpaired electrons in Mn+7 = a

Space for rough work

Space for rough work

SECTION – III : MATHEMATICS

1. Let f: [2, 4]  R is a continuous positive function, differentiable on (2, 4), then

4. Which of the following are incorrect ?

Space for rough work

8. If f(x) = log x , (x R+ – {1}, then

9. Let the function f(x) be defined as follows :

Space for rough work

PART – C : (Single digit integer)

Space for rough work

7. Let f : R  R defined as f(x) = x3 + x + 1, 1  x  2. The graph of y = g(x) is reflection of graph of

Space for rough work

FIITJEE - JEE (Paper - 1)

PHYSICS CHEMISTRY MATHEMATICS

1. M' g  T  M'a …(i) R

Batch :__ Date of Examination :_