Академический Документы
Профессиональный Документы
Культура Документы
Volume 19
of Issue 2/2019
FOUNDRY ENGINEERING 85 – 90
10.24425/afe.2019.127121
15/2
Published quarterly as the organ of the Foundry Commission of the Polish Academy of Sciences
Abstract
The paper is concerned with comparing the methods for determining the ferrite content in castings from duplex stainless steels. It uses
Schaeffler diagram, empirical formula based calculation, image analysis of metallographic sample, X-ray diffraction and measurement
with a feritscope. The influence of wall thickness of the casting on the ferrite content was tested too. The results of the experiments show
that the casting thickness of 25 or 60 mm does not have a significant effect on the measured amount of ferrite. The image analysis of
metallographic sample and the measurement with the feritscope appear to be the most suitable methods. On the contrary, predictive
methods, such as Schaeffler diagram or empirical formula based calculation are only indicative and cannot replace the real measurements.
X-ray diffraction seems to be the least suitable measuring method. Values of ferrite content measured in such a way often deviated from
the values measured by image analysis and with feritscope.
Keywords: Non-destructive testing, Duplex cast steel, Metallographic evaluation, Feritscope, XRD
Image analysis was performed on samples etched with the in the diagram in Figure 2. As can be seen here, the lowest ferrite
Beraha II etching agent when the austenite remains white, while content can be estimated in the melt 248, namely, about 17 %. In
the ferrite is coloured black. The LECO IA32 program was used contrast, the highest ferrite content around 50 % is predicted by
for the actual analysis. On each sample, 20 observations and the diagram for the melt 243 and, similarly, for melt 247, too. For
evaluations of structure were carried out. The following values are the remaining melts 244, 246 and 249, about 40 % of ferrite can
the averages of these twenty measurements. be estimated in their structures. Table 2 provides a clearer view of
Measurements using X-ray diffraction were carried out on the these data. The numbers shown are only subjective readings of the
diffractometer XPert Panalytical in the Bragg-Brentan diagram shown in Figure 2.
arrangement, using Cu-Kα radiation. Before measuring, the
samples were etched for 5 minutes in the etching agent 80% H2O2 Table 2.
+ 20% HF in order to remove the surface layer of crystals Ferrite content according to the Schaeffler diagram
deformed by polishing. sample 243 244 246 247 248 249
For measurements using the magneto-inductive method a %F 50 35 40 50 17 37
Feritscope Fisher FMP30 was used. Ten measurements were
carried out on each of the samples; the results are their arithmetic
means.
3.2 Formula-based calculation
Another option used for estimating the ferrite content in
3. Measurement results and discussion individual melts is the calculation by formula (3). The results are
listed in Table 3.
Below, the results will be listed of predicting and measuring
the ferrite content in experimental samples by using individual Table 3.
methods described above. Resulting ferrite contents by formula (3)
sample 243 244 246 247 248 249
3.1 The Schaeffler diagram %F 51.8 46.8 49.7 52.2 31.5 55.6
The Schaeffler diagram can be used for an approximate It can be seen that, although the calculation shows the trend of
prediction of the resulting casting structure. Creq and Nieq were the lowest ferrite content in structure of the sample 248, i.e.
calculated from the chemical composition of cast melts by Table 1 similarly to the Schaeffler diagram, the numerical values of the
using formulas (1) and (2) with their values subsequently plotted ferrite contents are often significantly different (see e.g. samples
248 or 249).
3.3 Imageanalysis
A method, which is very frequently used in practice, is the
image analysis of a metallographic sample. Here it is the real
Table 5.
Ferrite content determined using X-ray diffraction
sample %F sample %F
243-Y25 73.7 243-Y60 72.5
244-Y25 54.4 244-Y60 29.5
246-Y25 54.3 246-Y60 50.4
247-Y25 63.5 247-Y60 71.5
248-Y25 34.3 248-Y60 38.9
249-Y25 61.4 249-Y60 60.7
Table 7.
Summarized measured data
Y25 Y60
calculation Schaeffler
sample image analysis XRD feritscope image analysis XRD feritscope
%F %F %F %F %F %F %F %F
243 52.7 73.7 67.4 54.0 72.5 66.7 51.8 50
244 55.3 54.4 54.5 60.2 29.5 55.9 46.8 35
246 61.4 54.3 60.5 61.0 50.4 60.3 49.7 40
247 60.4 63.5 65.9 57.2 71.5 64.8 52.2 50
248 37.4 34.3 33.6 33.0 38.9 36.0 31.5 17
249 71.8 61.4 65.8 68.8 60.7 62.4 55.6 38
Therefore, we will only deal with the methods of measurement on the sample 243-Y25 where, using the image analysis, the ferrite
a real sample. It is, however, also apparent that the ferrite contents content of 52.7 % was detected while by the X-ray diffraction it
determined by different methods on the same sample are often was 73.7 %. This means a difference of 21 %! On the contrary, a
significantly different. The most striking difference is the one for minimum difference of 0.9 % was registered in the sample 244-