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c. In an infra-red spectrum, what do the two axes represent? Which axis is 1.5
related to energy of the light being absorbed?
e. Compound Z absorbs light of wavelength 320 nm. A 1.0 X10-3 mol dm-3
2
solution of a compound Z gives an absorbance reading of 0.15 when
placed in a solution of path length 1 cm. What is the value of the molar
extinction coefficient of Z?
2
f. Balance the given following redox reaction in acidic medium
BH4- + ClO3- H2BO3- + Cl-
2. a. 2
The wave function of 1s orbital is given by the following equation.
3
Z
1/ 2
1
2
1s 2
a e 2
0 4
Radial part Angular part
Draw the radial plot, radial probability plot and radial distribution of 1s
orbital for hydrogen. What information do you get about the 1s orbital
from these plots? (ρ = 2Zr/na)
b. Identify the nodal plane for 2pz orbital, the angular wave function for 2
which is given by the following equation.
1/ 2
3
Y ( pz ) cos( )
4
Also calculate the orbital angular momentum and total number of nodes for
this orbital.
c. State the conditions for acceptable wave functions. Explain why sin x is
1.5
an acceptable wave function in wave mechanics while tan x is not over the
range x = 0 and x = 2.
f. The standard electrode potential for Daniel cell is 1.1 V. Calculate the 2
standard Gibbs free energy of reaction
Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)