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The physical quantity ‘viscosity’ gives information on how thick a fluid is and how
easily it flows. In scientific terms, viscosity is the measure of a fluid’s internal flow
resistance. It is the resistance which a fluid shows when being deformed.
This page focuses on how to define viscosity, the different types of viscosity, and
the different types of liquids which show either Newtonian or non-Newtonian flow
behavior. Viscosity is a physical parameter which is measured throughout industry
to gain insight into materials and their behavior.
Table of contents
Viscosity-related information
Viscosity measurement
Discover the different principles behind measuring viscosity
Viscosity Index
VI and the viscosity-temperature behavior of oils
Viscosity tables
From acetone to crude oil to whole blood –the official viscosity
tables
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Viscosity Calculators
Dynamic viscosity <> kinematic viscosity, ASTM standards,
Saybolt Furol and Saybolt universal, viscosity index
Viscometers
Solutions for viscosity measurement
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Articles about viscosity
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Discover more in-depth articles on viscosity and related topics:
Viscosity measurement
Understanding the viscosity index
A comparison of viscometer types
Rotational viscosity and choosing the right spindles
Why engine oil viscosity is so important in Formula 1
Flow curve and yield point determination
Viscosity tables
Viscometers
Anton Paar offers a wide range of viscometers to suit different applications and
industrial requirements:
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How to define viscosity
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In order to determine a fluid’s viscosity, you have to enter the field of viscometry, a
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subject area of a wider science called rheology. Rheology loginwith
the flow
behavior and deformation of materials.
Imagine all materials as classified on a virtual scale from solid to liquid. Scientists
specify solid materials as being elastic and liquids as being viscous. In everyday
life, we mostly come across viscoelastic materials. That is, substances which are
neither completely elastic, nor entirely viscous. According to a material’s
properties, we either classify it as a viscoelastic solid (like e.g. sweet jelly) or as a
viscoelastic liquid (like e.g. a yoghurt drink or shower gel).
The specific field of viscometry covers ideally viscous fluids, and – considering
certain restrictions – also viscoelastic liquids, i.e. viscous fluids that contain an
elastic portion. Fluids which flow easily show a low resistance to deformation.
They are low-viscosity fluids. High-viscosity fluids resist deformation.
Consequently, they do not flow easily.
Figure 1: Comparing high-viscosity fluid to low-viscosity fluid. At the same temperature, the
former flows slower than the latter.
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Figure 2: From ideally viscous liquids to elastic solids. Viscoelastic materials in everyday life.
Figure 3: The virtual viscous sandwich: the two-plates model. Laminar flow consisting of
infinitesimally thin layers.
1. The fluid does not glide along the plates but is in good contact with them.
Scientifically speaking, an adhesive force operates between fluid and plates.
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2. The flow isuses cookies
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of paper sheets (or
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The lower plate does not move. The upper plate drifts aside very slowly and
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subjects the fluid to a stress, which is parallel to its surface: stress (tau).
loginshear
the
The force applied to the upper plate (in newton) divided by this plate’s area (in
square meters) defines the shear stress. Force/area results in the unit N/m², which
is named pascal [Pa] after Blaise Pascal[2].
F N
τ = [ ]
2
A m
Figure 4: Using the two-plates model to calculate the shear stress. Shear stress is the force
moving the upper plate divided by the plate’s area.
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Figure 5: Using to all cookies
the two-plates model toin accordance
calculate with
the shear ourShear
rate. Cookie
ratePolicy.
is the velocity of the
moving plate divided by the distance between the plates.
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The two-plates model allows for calculating another parameter: the shear rate
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(gamma-dot or also D).
The shear rate is the velocity of the upper plate (in meters per second) divided by
the distance between the two plates (in meters). Its unit is [1/s] or reciprocal
second [s-1].
v m 1
−1
γ̇ = (D =) [ ][ ] = [s ]
h s ⋅ m s
τ Pa
τ = η⋅γ̇ → η = [P a ⋅ s] = [ ]
1
γ̇
s
Equation 3: Newton’s Law reformulated: Dynamic viscosity is shear stress divided by shear
rate.
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Figure 6. Viscosity functions show dynamic viscosity vs. shear rate. Different types of flow
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behavior: Newtonian = ideally viscous (1) | cookies More
Shear-thinning (2) info
| Shear-thickening (3)
flow resistance is independent of the external force – i.e. the
If a fluid’s internal
Such
shear rate – acting upon the fluid, it is ideally viscous. Web named
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fluids
‘Newtonian liquids’ after Sir Isaac Newton.
A viscosity function shows the viscosity over the shear rate. For a Newtonian
liquid, this function is a straight line (curve 1); see figure 6.
If its viscosity changes with the shear rate, a liquid is non-Newtonian and – for
exact definition – one has to specify the apparent viscosity.
Still, shear rate is not the only influencer. Three factors determine a substance’s
flow behavior.
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Figure 7. Three factors are responsible for a substance’s flow behavior: Inner molecular
structure, outside forces acting on the material, and current ambient conditions
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Figure 8. In laminar flow, molecules move in orderly layers, while in turbulent flow they follow no
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pattern.
Turbulent flow is not structured because molecules move at random. This leads to
eddies and vortices and causes erroneous results during measurement. The
viscosity appears higher than it is, because the test device falsely registers the
molecules’ random behavior as higher flow resistance.
For example, submitting a fluid to a too high shear rate during the test can result
in turbulent flow. That could happen if a glass capillary viscometer is too wide for
the tested substance (i.e. the run times become too short) or if the spindle of a
rotational viscometer turns too fast.
Temperature
Figure 10
Apart from the shear rate, temperature strongly influences a fluid’s viscosity. A
substance’s viscosity decreases with increasing temperature and vice versa. This
inversely proportional relation applies to all substances.
Any change in temperature always influences viscosity, but for different fluids, the
size of this influence varies. Certain fluids react with a 10 % increase in viscosity if
temperature decreases by 1 °C.
Pressure
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Figure 11: Pressure has less influence on viscosity than temperature. Raising the pressure by a
factor 300, results in a viscosity increase of approximately 10 %.
Most liquids react to a significantly altered pressure (from 0.1 MPa to 30 MPa)
with a viscosity change of about 10 %. For comparison: This same change in
viscosity is usually provoked by a minor temperature change of 1 K (1 °C).
In case the pressure goes up from 0.1 MPa to 200 MPa, the viscosity can rise to 3
to 7 times the original value. This applies to most low-molecular liquids. Highly
viscous mineral oils react with a viscosity increase of times 20000 under identical
circumstances.
For synthetic oil this pressure change can even result in a viscosity increase by a
factor of up to 8 million. For example, lubricants in cogwheels or gears can be
submitted to pressures of 1 GPa and higher.
In most liquids, pressure reduces the free volume in the internal structure, and
thus limits the movability of molecules. Consequently, internal friction and viscosity
increase.
Dynamic viscosity
The Greek symbol η (eta) represents the dynamic viscosity. In order to obtain
dynamic viscosity (sometimes also known as shear viscosity), one has to
reformulate Newton’s Law:
τ Pa
τ = η⋅γ̇ → η = [P a ⋅ s] = [ ]
1
γ̇
s
Dynamic viscosity is preferably used in the fields of life science and research.
Kinematic viscosity
The kinematic viscosity ν (ny) reflects the influence of the gravitational force on a
substance’s flow. Dynamic viscosity divided by density ρ (rho), gives kinematic
viscosity. As density is defined as mass per volume, gravity comes into the
equation via the quantity mass.
2
η m m kg
ν = [ ] ρ = [ ]
3
ρ s V m
SI units:
[ms2/s] square meters per second or [mm2/s] square millimeters per second
1 m2/s = 1 000 000 mm2/s
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2
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m ⎡ Pa ⋅ s ⎤ ⎡ 2 ⎤
m ⋅s
[ ] = =
kg kg
s I accept
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3 3
m m
kg ⋅ m
[N ] = [
s
2
]
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2 3
m kg ⋅ m m
[ ] = [ ⋅ s ⋅ ]
2 2
s s ⋅ m kg
Equation 6. Deriving the SI unit of kinematic viscosity via the reformulated Newton’s Law.
Kinematic viscosity is widely used for all petrochemical fluids such as fuels or lube
oils.
Relative viscosity
A polymer’s quality is strongly linked to its molar mass. The majority of polymers
show a distinct relation between molar mass and viscosity. Therefore, in order to
determine molar mass, one can measure viscosity instead. As a rule, the viscosity
of polymer solutions increases with increasing molar mass. In fact, most polymer
solutions are shear-dependent (i.e. non-Newtonian).
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The relative viscosity ηr is the base for calculating other parameters, which are
relevant in polymer quality control:
η
ηr = [1]
η0
Equation 7: Relative viscosity is the viscosity of the polymer solution divided by the viscosity of
pure solvent.
Apparent viscosity
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Figure 12: Viscosity function of a shear-thinning fluid (e.g. shampoo). Apparent viscosity at a
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shear rate of 60⁻¹ shown as an example.
Newtonian fluids have constant viscosity for all shear rate
Ideally viscous or
the
values. For shear-dependent fluids, on the other hand,
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varies.
Therefore, you need to specify at which shear rate a viscosity value was
determined. This is the “apparent viscosity” or “apparent shear viscosity”. Each
apparent value is one point of the viscosity function (eta over shear rate).
Example:
−1
η(γ̇ = 60s ) = 398 mP a ⋅ s
References
1. Mezger, T. (2011). The Rheology Handbook. 3rd revised ed. Hanover: Vincentz
Network, pp.21-24.
2. Adamson, D. (1995). Blaise Pascal: mathematician, physicist and thinker about
God. Basingstoke: Palgrave Macmillan.
3. Newton, I. (1687). Philosophiae naturalis principia mathematica (“Principia”).
London.
4. Mezger, T. (2011). The Rheology Handbook. 3rd revised ed. Hanover: Vincentz
Network.
5. Mezger, T. (2011). The Rheology Handbook. 3rd revised ed. Hanover: Vincentz
Network, pp.85-87.
6. Wikipedia, (2017). International System of Units. [online] Available at:
en.wikipedia.org/wiki/International_System_of_Units [Accessed 06 Mar. 2017]
7. Pfitzner, J. (1976), Poiseuille and his law. Anaesthesia, 31: 273–275.
doi:10.1111/j.1365-2044.1976.tb11804.x
8. Wilson, D. B. (1987), Kelvin and Stokes: A Comparative Study in Victorian
Physics. Bristol: Adam Hilger.
9. Kulicke, W.-M. and Clasen, C. (2004). Viscosimetry of Polymers and
Polyelectrolytes. Berlin Heidelberg: Springer-Verlag.
RECOM M END ED
Density
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