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BERTHOLD OTZISK
Kurita Europe
E
mulsions can cause fouling and groups are mainly used as • Water at the bottom
under-deposit corrosion prob- demulsifiers. • Persistent emulsion in the
lems in distillation columns, middle or below the water layer.
heat exchangers and reboilers. Typical applications in refineries To break such a persistent emul-
Commercial methods for breaking Tank farm treatment sion, chemicals have to be applied.
emulsions include settling, heating, Crude oil, intermediates and A number of demulsifiers are
distillation, centrifuging, electrical finished products are stored in the commercially available with vary-
treatment, chemical treatment and tank farm. It is the first facility in a ing degrees of performance and
filtration. These separation technol- refinery where free water can be selectivity. Generally, demulsifiers
ogies can be used in combination to removed by settling from the oil. are diluted with an organic solvent
secure optimum results. Pumped crude oil from the well and injected into crude oils. The
Emulsions can be classified as contains water in emulsified and nature of the emulsion changes
oil-in-water and water-in-oil types. free states. A crude oil emulsion from crude to crude, which can
The type of emulsion can be deter- consists of small globules of water influence the performance of the
mined by adding a drop of surrounded by oil. Water is the emulsion breaker programme. This
emulsion into a beaker containing internal phase and oil is the exter- necessitates the evaluation of cost
water and oil. If the emulsion is of effectiveness and performance in
the water-in-oil type, the drop breaking the emulsion.
diffuses through the oil but remains
The nature of the
in water. The oil-in-water emulsion
diffuses through the water, but not
emulsion changes Crude oil desalting
Crude oil fed from the tank farm to
through the oil. Both types of emul- from crude to crude, the crude distillation unit still
sions can co-exist in crude oil side contains water, salts, sludge and
by side. which can influence various kinds of impurities. This
can cause corrosion, fouling, plug-
Separation of water-in-oil emulsions the performance of ging and catalyst degradation in
In this type of emulsion, water is the downstream refining units. The
the internal dispersed or discontin- the emulsion breaker main purpose of electrostatic
uous phase, while oil is the external desalting is therefore to remove
or continuous phase. Separation by
programme impurities, such as inorganic
the different gravity of the two microparticles, suspended solids
phases is a very slow process, but nal phase, which can easily be and water-soluble contaminants,
can be accelerated by the assistance detected by microscope. With the together with the water.
of chemicals. The chemicals used help of gravity, small water drop- The major variables and effects
are termed demulsifiers, emulsion lets coalesce to form bigger on the desalter operation are:
breakers or wetting agents. These droplets. An adequate residence • Wash water mixing
additives are surfactants, which time is essential for separation into • Wash water quality and rate
migrate to the oil/water interface. two phases. The bigger droplets • Desalting temperature
They adsorb on the oil films finally settle down to be removed • Electric field
surrounding water droplets and by drainage. • Retention time
break the oil films. Then, water Most of the time, emulsified • Use of demulsifiers.
droplets aggregate to form water water cannot be separated effec- Wash water is added in front of
drops large enough to gravitation- tively by gravity settling only, as the mixing valve to the crude oil to
ally separate them from the oil. the emulsion can separate into prepare a temporary emulsion. A
Non-ionic surfactants having both three phases: key point of desalting is an appro-
lipophilic and hydrophilic • Oil on the top priate mixing of crude oil with the