NMR spectrum of diphenyl disulfide

https://www.chemicalbook.com/SpectrumEN_882-33-7_1HNMR.htm

http://www.rsc.org/suppdata/c5/ra/c5ra16879a/c5ra16879a1.pdf

http://www.molbase.com/en/hnmr_139-66-2-moldata-15766.html

https://pubchem.ncbi.nlm.nih.gov/compound/Diphenyl-disulfide#section=1H-NMR-Spectra

https://spectrabase.com/compound/EEcspTOnjX0#IkTtTyWY3zZ

https://pdfs.semanticscholar.org/daa3/efbbba346396e80d85af46b1e07c8629fc8a.pdf

ester

https://www2.chemistry.msu.edu/faculty/reusch/VirtTxtJml/Spectrpy/nmr/nmr1.htm

https://en.wikipedia.org/wiki/Proton_nuclear_magnetic_resonance

https://www.ecosia.org/search?q=nmr+spectroscoy+methil++ethanothioate

http://guweb2.gonzaga.edu/faculty/cronk/CHEM440pub/thioesters.html

Thiols and their derivatives are important functional groups in organic synthesis, ~6 and they
are also present in many biologically active compounds. 6 The most common starting materials
for preparing sulfur-containing molecules are halides, alcohols, and their derivatives.

Los tioles y sus derivados son grupos funcionales importantes en la síntesis orgánica, ~ 6 y
también están presentes en muchos compuestos biológicamente activos. 6 Los materiales de
partida más comunes para preparar moléculas que contienen azufre son los haluros, los
alcoholes y sus derivados.

Thioesters have many uses in organic synthesis as intermediates, mild acyl transfer agents and
thiol sources . Thioesters can be synthesized in the laboratory by means of different methods
using diverse reagents and substrates [20-26]. The reaction of active carboxylic acid derivatives
with thiols [27-41] and the coupling of thiols with carboxylic acids using activating agents [42-
45] have been mainly used for the synthesis of thioesters in organic synthesis. Thiol-based
reactions have a foul smell, making them unpleasant. Thioesters can also be prepared through
the conjugate addition and nucleophilic displacement reactions using thioacid nucleophiles.
bvmhhkLos tioésteres tienen muchos usos en la síntesis orgánica como intermedios, agentes
de transferencia de acilo suaves y fuentes de tiol [1-19]. Los tioésteres se pueden sintetizar en
el laboratorio mediante diferentes métodos utilizando diversos reactivos y sustratos [20-26].
La reacción de derivados activos de ácido carboxílico con tioles [27-41] y el acoplamiento de
tioles con ácidos carboxílicos utilizando agentes activadores [42-45] se han utilizado
principalmente para la síntesis de tioésteres en síntesis orgánica. Las reacciones a base de tiol
tienen un olor desagradable, lo que las hace desagradables. Los tioésteres también se pueden
preparar mediante la adición de conjugado y las reacciones de desplazamiento nucleófilo
utilizando nucleófilos tioácidos.

Thioesters are important class of organosulfur compounds that play a fundamental role in the
construction of pharmaceutical, biological, industrial and natural products. In this respect,
thioesters synthesis is one of the most important tasks in organosulfur chemistry. The
esterification of thiols is the best and most common strategy for the synthesis of thioesters.
During the last decade (from 2005 to 2015), the application of a diverse range of reagents as
activating or promoter agents for the acylation of thiols in order to synthesize thioesters have
been investigated by various research teams. In this review, we have summarized and studied
recently reported synthetic protocols in the arena of acylation of thiols. ( aqui hay varias cosa
)klk

Thioesters are esters in which the linking oxygen atom is replaced by sulfur. They are
the product of dehydration reaction between a carboxylic acid derivative and a thiol.
Thioesters are common intermediates in biochemistry, for example, in acetyl-CoA,
malonyl-CoA, acetoacetyl-CoA, and propionyl-CoA. Thioesters are intermediates in
several key processes in which ATP is either used or regenerated. Thioesters are
involved in the synthesis of all biological esters, including those found in lipids. They
also participate in the synthesis of a number of other cellular components, including
peptides, fatty acids, sterols, terpenes, and porphyrins. The carbonyl group in thioesters
is electrophilic, thus thioesters and amines combine to give amides:
RNH2+ R′SCOR′′→ RNHCOR′′+ R′SH
https://link.springer.com/referenceworkentry/10.1007%2F978-3-642-11274-4_1586

Thiols and their derivatives are important functional groups in organic synthesis, ~6 and they
are also present in many biologically active compounds. 6 The most common starting materials
for preparing sulfur-containing molecules are halides, alcohols, and their derivatives. 2'3'5
Reliable methods for their conversions to thiols and derivatives are known) 5 In view of the
complex and sensitive nature of many target molecules synthesized today, mild and high-yield
synthetic routes to thiols are desirable.

Los tioles y sus derivados son grupos funcionales importantes en la síntesis orgánica, ~ 6 y
también están presentes en muchos compuestos biológicamente activos. 6 Los materiales de
partida más comunes para preparar moléculas que contienen azufre son los haluros, los
alcoholes y sus derivados. 2'3'5 Se conocen métodos confiables para sus conversiones a tioles
y derivados) 5 En vista de la naturaleza compleja y sensible de muchas moléculas diana
sintetizadas hoy en día, son deseables rutas sintéticas suaves y de alto rendimiento para los
tioles.

Thioesters are a class of important synthetic intermediates in organic synthesis, that are
applied for peptide coupling,[1] acyl transfer,[2] protecting groups for thiols,[3] and also as
coupling partners in organometallic reactions. They are also key intermediates in various
biological systems,[5] and are widely present in a number of biologically active and medicinal
agents.[6] Traditionally, thiols[7] or thiocarboxylates[8] are required for the synthesis of such
versatile compounds.

Los tioésteres son una clase de intermedios sintéticos importantes en síntesis orgánica, que se
aplican para el acoplamiento de péptidos, [1] transferencia de acilo, [2] grupos protectores
para tioles, [3] y también como socios de acoplamiento en reacciones organometálicas. [4]
También son intermedios clave en varios sistemas biológicos, [5] y están ampliamente
presentes en varios agentes biológicamente activos y medicinales. [6] Tradicionalmente, se
requieren tioles [7] o tiocarboxilatos [8] para la síntesis de tales compuestos versátiles.

Thioesters from Thiols and Aldehydes

Furthermore, thioesters have been frequently utilized as useful intermediates for the
syntheses of various natural products.[13] Accordingly, many thioesterification procedures
have been reported.( Thioesters from Thiols and Aldehydes in1.2)