falsa posicion

it xa xb f(xa) f(xb) xr f(xr)

1 -1 0 433 -9 -0.02036199 -4.49638093
2 -1 -0.02036199 433 -4.49638093 -0.03043025 -2.26689137
3 -1 -0.03043025 433 -2.26689137 -0.03547981 -1.14807119
4 -1 -0.03547981 433 -1.14807119 -0.03803041 -0.58277074
5 -1 -0.03803041 433 -0.58277074 -0.03932338 -0.29616075
6 -1 -0.03932338 433 -0.29616075 -0.03998001 -0.15059523
7 -1 -0.03998001 433 -0.15059523 -0.04031378 -0.07659914
8 -1 -0.04031378 433 -0.07659914 -0.04048352 -0.03896747
9 -1 -0.04048352 433 -0.03896747 -0.04056987 -0.01982503
10 -1 -0.04056987 433 -0.01982503 -0.04061379 -0.01008654
11 -1 -0.04061379 433 -0.01008654 -0.04063614 -0.00513192
12 -1 -0.04063614 433 -0.00513192 -0.04064751 -0.00261109
13 -1 -0.04064751 433 -0.00261109 -0.0406533 -0.00132851
14 -1 -0.0406533 433 -0.00132851 -0.04065624 -0.00067594
15 -1 -0.04065624 433 -0.00067594 -0.04065774 -0.00034392
16 -1 -0.04065774 433 -0.00034392 -0.0406585 -0.00017499
17 -1 -0.0406585 433 -0.00017499 -0.04065889 -8.9032E-05
18 -1 -0.04065889 433 -8.9032E-05 -0.04065908 -4.5299E-05
19 -1 -0.04065908 433 -4.5299E-05 -0.04065918 -2.3048E-05
20 -1 -0.04065918 433 -2.3048E-05 -0.04065924 -1.1727E-05
21 -1 -0.04065924 433 -1.1727E-05 -0.04065926 -5.9667E-06
22 -1 -0.04065926 433 -5.9667E-06 -0.04065927 -3.0358E-06

METODO DE LA SECANTE
it xi xi-1 f(xi) f(xi-1) xi+1
1 0 -1 -9 433 -0.02036199
2 -0.020362 -1 -4.49638093 433 -0.03043025
3 -0.0304302 -1 -2.26689137 433 -0.03547981
4 -0.0354798 -1 -1.14807119 433 -0.03803041
5 -0.0380304 -1 -0.58277074 433 -0.03932338
6 -0.0393234 -1 -0.29616075 433 -0.03998001
7 -0.03998 -1 -0.15059523 433 -0.04031378
8 -0.0403138 -1 -0.07659914 433 -0.04048352
9 -0.0404835 -1 -0.03896747 433 -0.04056987
10 -0.0405699 -1 -0.01982503 433 -0.04061379
11 -0.0406138 0 -0.01008654 -9 -0.04065936
12 -0.0406594 1 1.6076E-05 27 -0.04065998
13 -0.04066 2 0.00015344 3409 -0.04066007
14 -0.0406601 3 0.00017381 18525 -0.0406601
15 -0.0406601 4 0.00018013 59283 -0.04066011
sicion
n error it xa xb f(xa)
-1946.93294 1 0 1 -9
-981.563962 33.0863% 2 0.25 1 -62.5078125
-497.114826 14.2322% 3 0.77376277 1 -83.8305203
-252.33973 6.7067% 4 0.94488517 1 -11.2651302
-128.237605 3.2880% 5 0.9611108 1 -0.85586782
-65.2077352 1.6424% 6 0.96230566 1 -0.06180237
-33.1674295 0.8279% 7 0.96239175 1 -0.00444618
-16.8729135 0.4193% 8 0.96239794 1 -0.00031978
-8.58423675 0.2128%
-4.36747328 0.1082%
-2.22211972 0.0550%
-1.13060016 0.0280%
-0.57524502 0.0142%
-0.29268322 0.0072%
-0.14891668 0.0037%
-0.07576859 0.0019%
-0.03855096 0.0010%
-0.01961468 0.0005%
-0.00997993 0.0002%
-0.00507777 0.0001%
-0.00258357 0.0001%
-0.00131452 0.0000%

ECANTE
error it xi xi-1
1 1 0
33.0863% 2 0.25 -1
14.2322% 3 0.09231376 -1
6.7067% 4 0.02309803 -1
3.2880% 5 -0.009166 -1
1.6424% 6 -0.0248707 -1
0.8279% 7 -0.0326856 -1
0.4193% 8 -0.0366175 -1
0.2128% 9 -0.0386068 -1
0.1082% 10 -0.039616 -1
0.1121% 11 -0.0401287 0
0.0015% 12 -0.0406601 1
0.0002% 13 -0.0406674 2
0.0001% 14 -0.0406684 3
0.0000% 15 -0.0406688 4
16 -0.0406689 5
17 -0.040669 6
18 -0.040669 7
19 -0.040669 8
20 -0.0406691 9
21 -0.0406691 10

it xi xi-1 f(xi) f(xi-1)

1 2 -3 19 -1
2 -3 -2.75 -1 0.890625
3 -2.75 -2.8677686 0.890625 0.08748386
4 -2.867768595 -2.8805968 0.08748386 -0.0092115
5 -2.8805967907 -2.8793747 -0.0092115 7.982E-05
6 -2.8793747337 -2.8793852 7.982E-05 7.173E-08
7 -2.8793852321 -2.8793852 7.173E-08 -5.6488E-13
8 -2.8793852416 -2.8793852 -5.6488E-13 0
9 -2.8793852416 -2.8793852 0 0

datos experimentale
componentes P (kPa) x1
1 propanol 9.57 0.00000
2 agua 15.252 0.04620
17.412 0.09570
Temperatura del sistema (°C) 18.505 0.17510
45 19.132 0.28150
19.838 0.47780
20.078 0.60460
19.985 0.76940
19.585 0.85890
17.738 1.00000

Psat (1) kPa 17.738

Psat (2), kPa 9.57

A12 2.134
A21 1.3002
 f(xb) xr f(xr) n error
27 0.25 -62.5078125 562.570313
27 0.7737627651 -83.8305203 5240.06244 67.6904%
27 0.9448851695 -11.2651302 944.36173 18.1104%
27 0.9611107968 -0.85586782 9.64146251 1.6882%
27 0.9623056624 -0.06180237 0.05289466 0.1242%
27 0.9623917468 -0.00444618 0.00027478 0.0089%
27 0.9623979389 -0.00031978 1.4218E-06 0.0006%
27 0.9623983842 -2.2999E-05 7.3547E-09 0.0000%

f(xi) f(xi-1) xi+1 error

27 -9 0.25
-62.5078125 433 0.09231376 170.8155%
-29.2937805 433 0.02309803 299.6607%
-14.0995759 433 -0.00916603 351.9960% it xi
-6.97356329 433 -0.02487071 63.1453% 1 1
-3.49819517 433 -0.03268562 23.9093% 2 4
-1.76722979 433 -0.03661753 10.7378% 3 1.5454545455
-0.89592886 433 -0.03860677 5.1526% 4 1.9969343961
-0.45501512 433 -0.03961598 2.5475% 5 4.1050634736
-0.23129636 433 -0.04012872 1.2777% 6 2.2946990578
-0.1176278 -9 -0.04066013 1.3070% 7 2.4787263038
0.00018737 27 -0.04066736 0.0178% 8 2.7513680292
0.00178852 3409 -0.04066843 0.0026% 9 2.6830844744
 0.00202589 18525 -0.04066876 0.0008% 10 2.6903981337
0.00209961 59283 -0.0406689 0.0004% 11 2.6906484962
0.00213134 145111 -0.04066898 0.0002% 12 2.6906474479
0.00214775 300957 -0.04066902 0.0001%
0.00215731 557289 -0.04066905 0.0001%
0.00216335 950095 -0.04066906 0.0000%
0.00216741 1520883 -0.04066908 0.0000%
0.00217027 2316681 -0.04066909 0.0000% it xi
1 1.570796327
2 0
3 0.6110154703
4 0.7715332725
xi+1 error 5 0.738120741
-2.75 6 0.7390783371
-2.8677686 -0.0410662824 7 0.7390851347
-2.8805968 -0.0044533118 0.7390851332
-2.8793747 -0.0004244175
-2.8793852 -3.6460803067E-06
-2.8793852 -3.2794683343E-09
-2.8793852 -2.5910734756E-14
-2.8793852 0
#DIV/0! #DIV/0!

datos experimentales
y1 x2 y2 ϒ1 exp. ϒ2 exp. GE/RT Exp. GE/x1x2^2*RT
0.00000 1.00000 1.00000
0.39360 0.95380 0.60640 7.32546605 1.01325028 0.10455581 2.4876629589
0.48180 0.90430 0.51820 4.9419559 1.04260931 0.19063904 2.4359863047
0.52110 0.82490 0.47890 3.10469803 1.12258875 0.29376296 2.4655186254
0.54550 0.71850 0.45450 2.09012412 1.26460691 0.37620442 2.5887609294
0.59810 0.52220 0.40190 1.39997697 1.59539081 0.40468798 3.105992632
0.64110 0.39540 0.35890 1.20025475 1.90434358 0.36505187 3.8620073996
0.72420 0.23060 0.27580 1.0604882 2.49762466 Chart Title
0.25626381 6.2634915551
0.80260 0.14110 0.19740
25 1.03175238 2.86306872 0.17527034 10.2497151703
1.00000 0.00000 0.00000
20

15
x1 GE/x1x2^2*RT r
0.00000
12 10

10 5
f(x) = 1.3001880678x + 2.1303591781
R² = 0.9941183137
8
 15
r
12 10
0.04620 2.4876629589
0.09570 2.4359863047 10 5
0.17510 2.4655186254 f(x) = 1.3001880678x + 2.1303591781
R² = 0.9941183137
0.28150 2.5887609294 8
0
0.47780 3.105992632 0 0.2 0.4 0.6 0.8 1 1.2
0.60460 3.8620073996 6

0.76940 6.2634915551
4
0.85890 10.2497151703
1.00000 2

0
0 1 2 3 4 5 6 7
xi-1 f(xi) f(xi-1) xi+1 error IT a
4 -6 27 1.54545455 1 1
1.54545455 27 -6.0856499 1.9969344 0.22608647 2 -2.0909091
1.9969344 -6.08564989 -5.01222485 4.10506347 0.5135436 3
4.10506347 -5.01222485 30.4735742 2.29469906 0.78893326 4
2.29469906 30.4735742 -3.4482197 2.4787263 0.07424266 5
2.4787263 -3.44821974 -2.05866533 2.75136803 0.09909315 6
2.75136803 -2.05866533 0.68787554 2.68308447 0.02544965
2.68308447 0.68787554 -0.0825143 2.69039813 0.00271843
2.69039813 -0.08251428 -0.00273115 2.6906485 9.3049E-05
 2.6906485 -0.00273115 1.1484E-05 2.69064745 3.8961E-07
2.69064745 1.1484E-05 -1.5869E-09 2.69064745 5.3831E-11
2.69064745 -1.5869E-09 0 2.69064745 0

xi-1 f(xi) f(xi-1) xi+1 error

0 1.57079633 -1 0.61101547
0.61101547 -1 -0.2080504 0.77153327 0.2080504
0.77153327 -0.2080504 0.05469081 0.73812074 0.04526703
0.73812074 0.05469081 -0.0016137 0.73907834 0.00129566
0.73907834 -0.0016137 -1.1374E-05 0.73908513 9.1973E-06
0.73908513 -1.1374E-05 2.4233E-09 0.73908513 1.9591E-09
0.73908513 2.4233E-09 -3.8858E-15 0.73908513 0
0.73908513 -3.4417E-15 0 0.73908513 0

x1/x2 Ln ϒ1 Ln ϒ2 ϒ1 ϒ2 P cal (kPa) y1 cal. x1 cal

2.134 0 8.44859369 1 9.57 0
0.04843783 1.87128452 0.00617015 6.49663607 1.00618922 14.5083251 0.36695929 0.04955405
0.10582771 1.6145911 0.02571897 5.02583242 1.02605256 17.411098 0.49000265 0.09409798
0.21226815 1.25340954 0.08204015 3.50226374 1.0854994 19.4470146 0.55935394 0.163125
0.39178845 0.85932167 0.19797651 2.36155824 1.21893376 20.173287 0.58452763 0.26270486
0.91497511 0.36465052 0.49562849 1.44001066 1.64152959 20.4078706 0.59802427 0.4778605
1.52908447 0.17600404 0.71630314 1.19244287 2.04685228 20.5334721 0.62279911 0.62236611
3.33651344 0.04525035 0.99733132 1.04628976 2.71103728 20.2621931 0.70472935 0.79065741
6.08717222 0.01397026 1.13275128 1.0140683 3.10418525 19.6411663 0.78658777 0.87638426
1 1

m
12

10

8
 m
12

10

8
1 1.2
6

0
0.00000 0.10000 0.20000 0.30000 0.40000 0.50000 0.60000 0.70000 0.80000 0.90000 1.00000
6 7
m
b f(a) f(b) c f© f(a)*f© error
4 -6 27 -2.0909091 -22.885049 137.310293
4 -22.885049 27 -2.8082745 -42.920002 982.226347 -0.255447