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PHYSICS
1. A shell is fired from a fixed artillery gun with an initial 5. The truth table for the circuit given in the fig. is :
speed u such that it hits the target on the ground at a distance
R from it. If t1 and t2 are the values of the time taken by it to
hit the target in two possible ways, the product t1t2 is : A Y
(1) R/4g (2) R/g (3) R/2g (4) 2R/g B
2. The trajectory of a projectile near the surface of the earth is
given as y = 2x – 9x2. If it were launched at an angle θ0 with A B Y A B Y
0 0 1 0 0 1
speed v0 then (g = 10 ms–2):
1 5 0 1 1 0 1 0
(1) θ0 = sin–1 and v0 = ms–1 (1)
(2)
5 3
1 0 1
1 0 0
2 3 1 1 1 1 1 0
θ0 = cos–1 and v0 = ms–1
(2)
5 5
A B Y A B Y
1 5 0 0 1 0 0 0
(3) θ0 = cos–1 and v0 = ms–1
5 3 0 1 1 0 1 0
(3) (4)
2 3
θ0 = sin and v0 = ms–1
(4) –1 1 0 0 1 0 1
5 5 1 1 0 1 1 1
3. Shown in the figure is a shell made of a conductor. It has 6. A circular disc of radius b has a hole of radius a at its centre
inner radius a and outer
radius b, and carries charge Q. At (see figure). If the mass per unit area of the disc varies as
its centre is a dipole P as shown. In this case : σ0
r , then the radius of gyration of the disc about its axis
(2) s is :
3i − 4 j −4 k + 3 j
(1) s = (2) s =
5 5
−3 j + 4 k
(3) s = (4) s = 3 j − 3k
5 5
12. A magnetic compass needle oscillates 30 times per minute
at a place where the dip is 45o, and 40 times per minute
(3)
where the dip is 30o. If B1 and B2 are respectively the total
magnetic field due to the earth and the two places, then the
ratio B1/B2 is best given by :
(1) 1.8 (2) 0.7 (3) 3.6 (4) 2.2
13. At 40oC, a brass wire of 1 mm radius is hung from the
ceiling. A small mass, M is hung from the free end of the
(4) wire. When the wire is cooled down from 40oC to 20oC
it regains its original length of 0.2 m. The value of M is
close to:
(Coefficient of linear expansion and Young’s modulus of
9. To verify Ohm’s law, a student connects the voltmeter brass are 10–5/oC and 1011 N/m2, respectively; g = 10 ms–2)
across the battery as, shown in the figure. The measured (1) 9 kg (2) 0.5 kg (3) 1.5 kg (4) 0.9 kg
voltage is plotted as a function of the current, and the 14. A galvanometer of resistance 100 Ω has 50 divisions on
following graph is obtained : its scale and has sensitivity of 20 µA/division. It is to
be converted to a voltmeter with three ranges, of 0–2V,
0–10 V and 0–20 V. The appropriate circuit to do so is :
(1)
(2)
(3)
E1 K1 K 2 K3
(1) =
E2 ( K1 + K 2 + K 3 )( K 2 K 3 + K 3 K1 + K1 K 2
E1 ( K1 + K 2 + K 3 )( K 2 K3 + K3 K1 + K1 K 2
(2) =
E2 K1 K 2 K3
244
E1 9 K1 K 2 K3 28. A concave mirror has radius of curvature of 40 cm. It is
(3) = at the bottom of a glass that has water filled up to 5 cm
E2 ( K1 + K 2 + K 3 )( K 2 K 3 + K 3 K1 + K1 K 2 )
(see figure). If a small partricle is floating on the surface of
E1 ( K1 + K 2 + K 3 )(K 2 K3 + K3 K1 + K1 K 2
(4) = water, its image as seen, from directly above the glass, is
E2 9 K1 K 2 K3
at a distance d from the surface of water. The value of d is
24. A person of mass M is, sitting on a swing of length L and close to :
swinging with an angular amplitude θ0. If the person stands
up when the swing passes through its lowest point, the (Refractive index of water = 1.33)
work done by him, assuming that his centre of mass moves
by a distance l (l<<L), is close to :
(1) mgl (1– θ02) (2) mgl (1+θ02)
θ 2
(3) mgl (4) Mgl 1 + 0
2
25. Two moles of helium gas is mixed with three moles (1)
6.7 cm (2) 13.4 cm (3) 8.8 cm (4) 11.7 cm
of hydrogen molecules (taken to be rigid). What is the
molar specific heat of mixture at constant volume? 29. An excited He+ ion emits two photons in succession, with
(R = 8.3 J/mol K) wavelengths 108.5 nm and 30.4 nm, in making a transition
(1) 19.7 J/mol L (2) 15.7 J/mol K to ground state. The quantum number n, corresponding to
(3) 17.4 J/mol K (4) 21.6 J/mol K its initial excited state is (for photon of wavelength λ,
26. A submarine (A) travelling at 18 km/hr is being chased 1240eV
along the line of its velocity by another submarine (B) energy E =
travelling at 27 km/hr. B sends a sonar signal of 500 Hz to λ(innm)
detect A and receives a reflected sound of frequency v. The n = 4
(1) (2) n = 5 (3) n = 7 (4) n = 6
value of v is close to : 30. In a double slit experiment, when a thin film of thickness t
(Speed of sound in water = 1500 ms–1)
having refractive index µ is introduced in front of one of the
(1) 504 Hz (2) 507 Hz
(3) 499 Hz (4) 502 Hz slits, the maximum at the centre of the fringe pattern shifts
27. A man (mass = 50 kg) and his son (mass = 20 kg) are by one fringe width. The value of t is (λ is the wavelength
standing on a frictionless surface facing each other. The of the light used) :
man pushes his son so that he starts moving at a speed of 2λ λ
0.70 ms–1 with respect to the man. The speed of the man (1) (2)
(µ − 1) 2(µ − 1)
with respect to the surface is :
(1) 0.28 ms–1 (2) 0.20 ms–1 λ λ
(3) (4)
(3) 0.47 ms
–1
(4) 0.14 ms–1 (µ −1) (2µ − 1)
CHEMISTRY
31. An example of a disproportionation reaction is: 35. The major product(s) obtained in the following reaction is/
(1) 2MnO4– + 10I– + 16H+ → 2Mn2+ + 5I2+ 8H2O are :
(2) 2NaBr + Cl2 → 2NaCl + Br2 (i) KOtBu
(3) 2KMnO4 → K2MnO4 + MnO2 + O2
(ii) O3/Me2S
(4) 2CuBr → CuBr2 + Cu
Br
32. The mole fraction of a solvent in aqueous solution of a
solute is 0.8. The molality (in mol kg–1) of the aqueous (1)
solution is : (2)
(1) 13.88×10–2 (2) 13.88×10–1
(3) 13.88
(4) 13.88×10–3 (3)
33. An ideal gas is allowed to expand from 1 L to 10 L against t
O Bu
a constant external pressure of 1 bar. The work done in kJ
is : (4)
OHC
CHO
(1) – 9.0 (2) + 10.0 (3) – 0.9 (4) – 2.0
36. The metal that gives hydrogen gas upon treatment with
34. Which of the following is a thermosetting polymer ? both acid as well as base is :
(1) Bakelite (2) Buns-N (1) magnesium (2) mercury
(3) Nylon 6 (4) PVC (3) zinc (4) iron
245
37. The major product of the following reaction is: 43. The basic structural unit of feldspar, zeolites, mica, and
asbestos is :
(1) (SiO3)2– (2) SiO2
HO
(1) CrO
3
(2) SOCl2/ (3) (SiO4)4– (4)
n
HO (3)
(3) (4)
40. Given :
(C)
Co3+ + e– → Co2+ ; Eo = + 1.81 V
Pb4+ + 2e– → Pb2+ ; Eo = + 1.67 V
Ce4+ + e– → Ce3+ ; Eo = + 1.61 V
Bi3+ + 3e– → Bi ; Eo = + 0.20 V (D)
oxidizing power of the species will increase in the order:
(1) Ce4+ < Pb4+ < Bi3+ < Co3+
(1) (A) < (C) < (D) < (B) (2) (C) < (A) < (D) < (B)
(2) Bi3+ < Ce4+ < Pb4+ < Co3+
(3) (B) < (D) < (A) < (C) (4) (B) < (D) < (C) < (A)
(3) Co3+ < Ce4+ < Bi3+ < Pb4+
46. The electrons are more likely to be found :
(4) Co3+ < Pb4+ < Ce4+ < Bi3+
41. Which of the following statements is not true about RNA?
(1) It controls the synthesis of protein.
(2) It has always double stranded α-helix structure.
(3) It usually does not replicate.
(4) It is present in the nucleus of the cell.
42. The group number, number of valence electrons, and
valency of an element with atomic number 15, respectively,
are :
(1) 16, 5 and 2 (2) 15, 5 and 3
(3) 16, 6 and 3 (4) 15, 6 and 2 (1) in the region a and c (2) in the region a and b
(3) only in the region a (4) only in the region c
246
47. The correct sequence of thermal stability of the following (3) NO, NO2, O3 and hydrocarbons
carbonates is : (4) N2, O2, O3 and hydrocarbons
(1) BaCO3 < CaCO3 < SrCO3 < MgCO3
53. Peptization is a :
(2) MgCO3 < CaCO3 < SrCO3 < BaCO3
(3) MgCO3 < SrCO3 < CaCO3 < BaCO3 (1) process of bringing colloidal molecule into solution
(4) BaCO3 < SrCO3 < CaCO3 < MgCO3 (2) process of converting precipitate into colloidal solution
48. The complex ion that will lose its crystal field stabilization (3) process of converting a colloidal solution into
energy upon oxidation of its metal to +3 state is : precipitate
(4) process of converting soluble particles to form colloidal
solution
54. The correct statement among the following is :
(1) (SiH3)3N is planar and less basic than (CH3)3N.
(2) (SiH3)3N is pyramidal and more basic than (CH3)3N.
(3) (SiH3)3N is pyramidal and less basic than
(1) [Co(phen)3]2+ (2) [Ni(phen)3]2+ (CH3)3N.
(3) [Zn(phen)3]
2+
(4) [Fe(phen)3]2+
(4) (SiH3)3N is planar and more basic than (CH3)3N.
49. But 2-ene on reaction with alkaline KMnO4 at elevated
temperature followed by acidification will give : 55. Enthalpy of sublimation of iodine is 24 cal g–1 at 200oC.
If specific heat of I2(s) and I2(vap) are 0.055 and 0.031 cal
CH 3 − CH − CH − CH 3 g–1K–1 respectively, then enthalpy of sublimation of iodine
(1) | |
OH OH at 250oC in cal g–1 is :
(2) one molecule of CH3CHO and one molecule of (1) 2.85 (2) 5.7 (3) 22.8 (4) 11.4
CH3COOH 56. An element has a face-centred cubic (fcc) structure with
(3) 2 molecules of CH3COOH a cell edge of a. The distance between the centres of two
(4) 2 molecules of CH3CHO
nearest tetrahedral voids in the lattice is :
50. Complete removal of both the axial ligands (along the a 3
z-axis) from an octahedral complex leads to which of the (1) 2a (2) a (3) (4) a
2 2
following splitting patterns ? (relative orbital energies not
57. What is the molar solubility of Al(OH)3 in 0.2 M NaOH
on scale)
solution ? Given that, solubility product of Al(OH)3 =
dx 2 – y 2 dz 2 2.4×10–24 :
(1) 3×10–19 (2) 12×10–21
dxy dx 2 – y 2
(1) (2)
(3) 3×10–22 (4) 12×10–23
E E
dz2 dxz, dyz 58. The major products of the following reaction are :
dxy OH
dxz, dyz
MATHEMATICS
61. If A is a symmetric matrix and B is a skew-symmetrix 66. The number of ways of choosing 10 objects out of 31
2 3 objects of which 10 are identical and the remaining 21 are
matrix such that A + B = , then AB is equal to :
5 −1 distinct is :
(1) 220 – 1 (2) 221 (3) 220 (4) 220+1
− 4 −1 4 −2
(1)
−1 4 (2) −1 − 4 2 x3 − 1
67. The integral ∫ x 4 + x dx is equal to :
4 −2 − 4 2
(3) (4) (Here C is a constant of integration)
1 − 4 1 4
1 x3 + 1 1 ( x3 + 1) 2
dy d 2 y + C (2) log +C
62. If ey + xy = e, the ordered pair , 2 at x = 0 is (1) log e 2
e
x3
2 x2
dx dx
equal to : x3 + 1 x3 + 1
(3) log e log e
+ C (4) +C
1 1 1 1 x x2
(1) , − 2 − , 2
(2)
e e e e 68. The equation y = sin x sin (x + 2) – sin2 (x + 1) represents a
straight line lying in :
1 1 1 1
(3) , 2 (4) − , − 2 (1) second and third quadrants only
e e e e
(2) first, second and fourth quadrant
63. If the angle of intersection at a point where the two circles
(3) first, third and fourth quadrants
with radii 5 cm and 12 cm intersect is 90o, then the length
(4) third and fourth quadrants only
(in cm) of their common chord is :
69. Let f : R → R be a continuously differentiable function such
13 120 60 13
(1) (2) (3) (4) 1
5 13 13 2 that f(2) = 6 and f'(2) = .
48
64. If the area (in sq. units) of the region {(x, y) : y2 ≤ 4x, f ( x)
If ∫6 4t3dt = (x – 2) g (x), then lim g(x) is equal to :
x + y ≤ 1, x ≥ 0, y ≥ 0} is a 2 + b, then a – b is equal to : x→2