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INTRODUCTION
Plastics can be classified as a group of man-made or natural organic materials that can
be molded and then hardened, including many types of resins, polymers, cellulose
derivatives, casein materials, and proteins. Plastics made from non-renewable resources such
as petroleum products, are now very common and are being used almost everywhere as such;
in packing materials, in bottles, cell phones, plastic bags and more. They are being so
extensively used because of their durability, strength, malleability, low reactivity and cost
efficiency. However, together with all its benefits is the fact that it is highly pollutant and
plastics nowadays have become a big environmental issue. Nowadays, people are more aware
about the harmful effects of petrochemical derived plastic materials in the environment.
Researchers have conducted many researches for managing plastic waste on earth by finding
disposed in environment and can easily degrade through the enzymatic actions of
microorganisms.
Bioplastics are plastics derived from renewable biomass sources, such as vegetable
fats and oils, straw, woodchips, starch, etc. It was developed as an alternative material to
petroleum-based plastics that are harmful for our environment because it is synthetic and it
does not mix with nature. Though bioplastics are eco-friendly, its mass production causes
negative effect on the supply of food for human consumption. Instead of producing products
like grains for food supplies, they used it for production of bioplastic materials. The focus of
this research study is to produce practical alternative materials in comparison to some natural
component such as different kind of leftover rice. This study is focused on determining the
durability using several tests such as tensile strength test, water absorption test and
biodegradability test.
consumption and promoting a greener environment remain an important goal for the
bioplastics using leftover rice. These thousands of granules are subject to be collected as the
main ingredient of creating bioplastic. Through this, we can lessen the percentage of rice
wastage and help people how to process and convert those wastes into useful materials that
are eco-friendly.
The general goal of this study is to develop an alternative bioplastic material using
natural polymer that can be found on households and to extend the utility of “leftover rice” as
one of main component on fabricating bioplastic. This project is planned to somehow resolve
environmental problems due to the dilated usage of Petro-based plastics and to reduce
wastage of rice. Specifically, this research study aims to determine the proper mixtures in
fabricating bioplastic made by leftover rice using trial and error process. We are also aiming
to determine the durability of the fabricated bioplastic from leftover using several tests such
as tensile strength test, water absorption test and biodegradability test, and then we will
Bioplastics came from various materials such as corn starch, cassava starch, potato
starch, rice starch and the likes. Using bioplastics as an alternative material for petroleum
for producing bioplastic are vital part of food supply for human consumption we aim to find
alternative sources that doesn’t cause negative effect in food production. This study focuses
on developing bioplastic materials from leftover rice that is a food wastes, as its base. We
will prepare leftover rice and isolate the starch from it that will serve as polymer, glycerin
that acts as plasticizer which lubricates the plastic and make it more pliable, distilled water as
solvent and vinegar that will help to dissolve the starch and make plastic less brittle. These
ingredients will undergo in gelatinization process, we are going to mix these ingredients and
containers and let it dry in sunlight. When it is dry and ready, we are going to compare it with
the existing commercial bioplastic using several tests, such as tensile strength test,
biodegradability test and water absorption test. This research limits on testing our own
fabricated bioplastic from leftover rice and compare its characteristics on the existing
commercial bioplastic.
The result of this study will be very significant for the preservation and protection of
our environment from the harmful and destructive effects of non-biodegradable plastic
materials which is one of the biggest issues in the Philippines. It could also reduce food
wastes in our country since it uses leftover rice for its production.
This study may also help our next generation researchers to develop different kinds of
materials made from bioplastics that are not harmful for our environment, more durable,
Literature Review
Plastic pollution is not a new issue that humanity is facing right now. Long before, we
are already experiencing tons of environmental problems because of petroleum based plastics
or those plastics that are non-biodegradable. Yes, majority of the things around us are made
by plastics and it looks like there is nothing wrong about it but we cannot hide the increasing
Some environmental organization promotes recycling but the uses of petroleum based
polymers have numerous adverse impact on atmosphere. “Most of the plastic waste ended up
in the landfill creates pollution with the accumulation of chemicals, only 10% of plastics have
been recycled (I.M Shamsuddin 2017)”. It did not work, the demands of the petroleum based
plastics are continuously increasing. As a result, mass production of petroleum based plastic
continued as well. Another idea was introduced to us, namely reduce, it means if we cannot
avoid using plastics, why not try to reduce using it? The lesser the demands in using plastics
There are also studies and researches that could help us in solving our problems about
petro-plastic wastes. One is the use of biodegradable plastics that are made by starch or
Figure 1(http://handbag.bapala.org/biodegradable-poly-bags-manufacturers-in-india/)
Figure 1 “A biodegradable product breaks down into smaller compounds with the
help of biological organisms, such as fungi and bacteria. In aerobic conditions, biodegradable
products will break down to produce carbon dioxide, water and biomass.
In anaerobic conditions, they produce carbon dioxide, methane, water and biomass
(sciencelearn.org.nz).
Figure 2 https://www.advancedsciencenews.com/new-customized-compostable-
materials/
Figure 2 “A compostable product also breaks down into smaller compounds with the
warm, aerobic environment to produce compost that is non-toxic and can enhance soil and
There are various types of starch used in creating biodegradable plastics such as corn
starch, potato starch, rice starch, etc. but using rice, corn and potatoes as alternatives in
creating plastics may cause a negative effect in our food production. “Many of the bioplastics
are also contributing to the global food crisis by taking over large areas of land previously
previous part of the paragraph, a lot of materials we are using today are made out of plastics,
even inside our classrooms. The focus of this research is to create biodegradable plastic
materials as alternatives to petroleum-based plastics that could help to reduce plastic waste
problems using rice starch coming from leftover rice so that it would not affect food
productions and somehow help to reduce wastage of rice. Using bioplastics can be the best
depend less on fossil resources and decrease carbon emissions, biomaterials and
biodegradable plastics as substitutes of conventional petroleum based plastics have been the
focus of many material scientists, architects and industrial product designers.” (Gokce E.
2018). In this research we will also include different issues in bioplastics, like its
sustainability, its durability, resistance, and its lifespan. This study evaluates the
sustainability of bio-based plastics including all the stages of their life cycles to assist in
decision making about selection of these materials in today’s society, but throughout their life
cycles they contribute to pollution and depletion of non-renewable natural resources. Bio-
based plastics appear to be more environmentally friendly materials than their petroleum-
based counterparts when their origin and biodegradability are compared. But which of the
bio-based plastics currently on the market or soon to be on the market are preferable from an
environmental, health, and safety perspective? There are lots of researches that talks about
how to reduce the production of petroleum-based plastics. There are some are finding ways
https://www.naturalfoodseries.com/11-benefits-bitter-melon-bitter-gourd/
source for the production of bio-based plastics (BPs) and choline chloride/glycerol based
deep eutectic solvent (DES) was added as a plasticizer. In summary, using DES as a
plasticizer had significantly improved the properties of BPs and the BPs could provide a
broad range of applications for the food and nutraceutical industries. A starch graft
poly(methy1 acrylate) copolymer was developed having grafted side chains with molecular
weight of less than 500,ooO. This material can be easily extruded into a film which shows
excellent initial tensile strength and elongation. Tensile strength, however, falls off rapidly
after 70 hr of water immersion at 25OC. Starch graft poly(methy1 acrylate) films show
excellent susceptibility to fungal growth, some samples losing more than 40% of their weight
after 22 days of incubation with Aspergillus niger. Tensile tests and scanning electron
micrographs of the incubated samples, after being freed of mycelium, indicate substantial
biodegradation of the starch portion of the copolymer. This material may have application as
petroleum-based plastics. Ralstonia eutropha, the PHA production model organism, has been
Riedel and co-workers develop a high cell density cultivation process to produce P(HB-co-
HHx) from palm oil. Plant oils like palm oil are favourable carbon feedstock, due to their
higher carbon content and lower price, compared to refined sugars. Batch, extended batch,
and fed batch fermentation procedures were analyzed in this work. The highest yields of
polymer biosynthesis were achieved using a fed batch process with palm oil as the sole
carbon source and urea as the nitrogen source. Using this process, high levels of both biomass
and polymer were produced, with a uniquely high HHx monomer percentage. The high
productivity of this process suggests scalability for industrial PHA production. In our part, we
will create a bio-plastic product made of left over rice or spoiled rice. We target to design a
useful material like ruler, t-square, protractor, ballpen holder, and other product using this
substance.
There are many research topics related to the use of starch in making biodegradable
plastics. We can check the usage of corn starch, banana peel or even potato starch on
polymers amylose and amylopectin [Gadhave R.V, Das A., Mahanwar P.A, Gadekar P.T,
2018, Open Journal of Polymer Chemistry, pg. 24]. Several tests have been conducted as well
to prove its durability to become a Petroleum- Based Plastic alternative. As of now, Starch-
based plastics were somehow improving its characteristics in some aspects like its water
resistance, tensile strength and processing properties. Among its advantages, the starch is
cheap, abundant and renewable also. In relation to that, our research will not only conserve
this attribute but will try to improve its economic advantage by using cooked/spoiled rice.
Hence, the usage of rice starch has been popular with regards to Bioplastic creation [Kapoor
A., Sharma R., Shrivastava S., 2017, Journal of Advance Research in Biotechnology]. With
this research proposal, we will test the probability of using Cooked/Spoiled rice as our
specimen and try to produce a sustainable kind of material in terms of bioplastic production.
This research will promote also the consolidation of solutions on the problem we are
petroleum-based plastics and secondly, the wastage of rice. That’s why we agreed to use
cooked/left-over or spoiled rice instead of raw rice or ordinary rice starch because of rice
shortage scare.
The product of this research project can be helpful to others as well as the students.
Because of the wide range application of plastics in our society, this research can serve as
substitute to other plastic educational necessities just like Pen holder, Ruler and even T-
square used by Architecture students. Through expanding need of the consumers, it is not
only the environment that we can help to improve but the upgraded use of eco-friendly
material as well.
Conceptual Model
The Bioplastic material was made through the mixture of different significant components.
Different studies show that starch from altered environmental friendly elements such as corn,
potato, rice, jicama etc. are being used in making biodegradable plastic material. Findings
show also that plastic produced using starch as polymer can be compared to the existing
commercial plastics in terms of its durability and usage for daily purposes. This research
study was originated from the said concept producing a bioplastic material using “left-over”
rice. Aside from the starch (polymer), different ingredients are needed such as distilled water
(solvent), vinegar (acid), glycerin/glycerol (plasticizer) together with several tools in order to
In creating bioplastic using “left-over” rice, different operational terms were used for
the process, components and materials. The following list provides definition for the terms
Leftover rice - are cooked rice that are subjected for food wastage
Compostable - these materials are added to compost piles, which are designated sites with
Biodegradable - refers to the ability of materials to break down and return to nature. In order
for packaging products or materials to qualify as biodegradable, they must completely break
down and decompose into natural elements within a short time after disposal – typically a
year or less.
Gelatinization - Starch gelatinization is the process where starch and water are subjected to
heat causing the starch granules to swell. As a result, the water is gradually absorbed in an
irreversible manner. This gives the system a viscous and transparent texture. The result of the
reaction is a gel, which is used in sauces, puddings, creams and other food products,
Polymer -Polymers are made up of many molecules all strung together to form really long
chain
Petroleum based plastic - plastics that are made from synthetic polymer.
of quality and reliability that is associated with long lasting items that don't break with stress.
Chapter 3
RESEARCH METHODOLOGY
EXPERIMENTAL DETAILS
Petroleum-based plastics are very useful materials in so many areas from mass
productions in Industrial field down to the simplest materials inside our households, but there
is a huge problem on the waste management of plastics in our country. Petro plastic cause’s
major toxic pollutants like [1] Dioxins, Furans, Mercury and Polychlorinated Biphenyls into
the atmosphere it has the potential to cause great harm to the environment in the form of air,
One solution for the wastes problem caused by petroleum based plastics is to use
bioplastics or eco-friendly materials that came from corn starch, cassava starch, potato starch,
rice starch, etc. but using products that are vital for human food consumption as alternatives
for petroleum-based plastic may cause negative effect from the supply of food production.
The primary aim of this research is to find alternative source of biodegradable plastic
that would not cause negative effect on the food production. That’s why we came up with an
idea to use left over rice as alternative base materials in producing bioplastics. The edge of
this research is that through bioplastics we may be able to produce various useful materials
while helping to reduce plastic pollutions and at the same time reduce wastage of rice, using
left over rice as an alternative. Figure 3.1 shows the annual food wastage globally the figure
3.2 shows the environmental impact of wastage of rice and how does it affect our economy.
Figure 3.3 Annual food waste globally
Procedure
The first process we need to be done is the preparation and cleaning of ingredient
specifically the left-over rice through the use of water, this process was made in order to
remove some unwanted residue. We will use weighing scale to determine the proper weight
of the ingredients, syringe to measure the volume of our liquid ingredients, a blender to crush
leftover rice and some cooking utensils such as hot pan, spatula, gas stove, plastic containers
and aluminum. We will crush 250g. of left-over rice with 125ml. of water using blender until
it reaches the desired texture for the process of extracting starch from leftover rice. We will
add 100ml of water to the crushed leftover rice then boil it on a hot pan, after boiling, we will
filtrate it using screen mesh and put it on a plastic container and wait until it cools. Filtration
process needs to be done in order to separate the starch granules from the residue of the rice
After extracting the starch from leftover rice, the starch polymer needs to be mixed
with other ingredients such as 150ml distilled water (solvent), 10ml white vinegar (acid) and
10ml Glycerin/Glycerol (plasticizer). We will mix the following ingredients on a pan and stir
it in counter clockwise motion for 5 minutes. After mixing is the boiling process, we will
continuously stir the mixed ingredients on the pan, turn on the stove into hot temperature
until it reaches the boiling point, when it produces bubbles and turns its physical appearance
into emulsion, turn off the stove but continuously stir the mixture to maintain its thickness
The paste will be configured to a mold and will be formed depending to the design of
mold we are using. After that, we will let it dry on a cool and dry area for a day or two.
List of materials
Starch from leftover rice – serves as the polymer (Polymer is a substance that has a
molecular structure consisting chiefly or entirely of a large number of similar units bonded
together) ; Vinegar - we are going to vinegar so that the starch came from leftover rice may
dissolve more easily because of its acetic contents ; Distilled water - use as solvent to help
for the bioplastics (optional) ; Spatula, Small pot, Tray, Aluminum foil, Measuring cups,
First is the tensile strength test, we will conduct the trial of tensile test with the use
marbles that weights 1.8g each. We will hook marbles and add more until the bioplastic was
torn apart. The test will use three samples of bioplastic from left over rice. The commercial
bioplastic will be tested with the same method as well as comparison of its tensile strength
Next is the water absorption test, we are going to check the durability of bioplastic
through the use of water. We are going to place the product to a container filled with water
for five hours and we will examine the state of the plastic after the immersion process.
leftover rice, we are going to cut three samples of 25𝑐𝑚2 of bioplastic then engrave it for 48
leftover rice.
Figure 3.4
Chapter 4
This chapter presents the project description, and structure, capabilities and
limitations, project test results, and final evaluation outcome of the study about the
Project Description
The mixture of the ingredients formed a nontransparent and thick paste that serves to be the
final product of our emulsion process. After several hours of parching and exposing the paste
to the sunlight, it became solidified with an opaque appearance. The bioplastic films
produced was translucent, yellowish in color and elastic. The residue of the rice was visible
on each sample since it is the base/polymer used in creating such bioplastic and the plasticity
Figure 4.0
Project Structure
There were several processes that have been conducted by our team in order to form a
bioplastic film using “left-over rice”. One of those processes was the extraction of the starch
from our main ingredient which was the “leftover rice”. First, we added water to the rice and
grinded it using an electronic blender until it acquired paste-like appearance. Then we placed
the crushed rice to a metal container and expose it to heat for several minutes, we let the
pasted rice to extract starch until it attain its boiling point. After the extraction, we filtered the
rice for several times with the use of screen mesh/strainer. The starch was mixed with 100ml
of distilled water, 10ml of white vinegar and 10ml of pure glycerin. After combing of
ingredients, the mixture was exposed to the stove again with a very low setting for the
emulsion process. We mixed the ingredients until it reach its boiling point and became thick
paste. We transferred the mixture to several kind of container disc and form a plastic film
The focus of this research study is to fabricate bioplastic material from leftover rice as
an alternative source rather than perennial products that are food source for human. The
fabricated bioplastic films are translucent, thick, elastic and can be form depending in your
molder. A 36𝑐𝑚2 bioplastic film from leftover rice can carry an approximate weight of 220g.
- 250g. . It can dissolve on water for hours and it is more compostable than the existing
commercial bioplastics. The fabricated bioplastic is not capable of carrying wet, sharp and
heavy loads.
Project Evaluation
Test Results
These are the results of durability test of bioplastic films from leftover rice that we
conducted including tensile strength test, water absorption test and biodegradability test. We
conducted the tests in March 3 – March 15, 2019 at Malagasang 1 – C, City of Imus Cavite.
The bioplastic was tested and compared to the commercial biodegradable plastic
using the tensile strength test. We prepared three (3) 36cm2 films of our bioplastics for our
sample and named it as A1, A2, A3, We also prepared three (3) 36cm2 strips of commercial
biodegradable plastic and named as B1, B2, B3. The focus of this test was to determine the
tensile strength of the fabricated bioplastic from leftover rice and compare it to the existing
sample and the biodegradable plastic to see the tensile strength of films, we used pieces of
marble weighing 1.8 grams and a hook. On the first trial, we placed 50 pieces of marble to
the A1 and B1, the weight of the marbles are equal to 90 grams. Each sample has shown
stability and strength on the first trial, then we added another 90 grams of marbles but same
result happened, we added more and more loads by 10’s (18 grams) until it reaches a total of
130 marbles which is equal to 234 grams, at this point, sample A1 started to tore apart and
break into two but sample B1 remains. We repeated the same procedure on sample A2, A3 and
B2, B3 . Sample A2 tore apart at 216 grams, A3 at 234 grams but sample B2 and B3 showed the
same result with sample B1. Figure 4.1 shows that commercial biodegradable plastic remains
its structure at 234 grams of loads while figure 4.2 shows bioplastic from leftover rice tore
Table 4.1 below shows the data and the results of the tensile strength conducted for
the bioplastic film from leftover rice and the commercial biodegradable plastic.
Table 4.1
This test was conducted to determine the water absorption of bioplastic film from
leftover rice. We soaked three samples of bioplastic films and commercial biodegradable
plastic on a container with water that has a temperature of 26o – 28o Celsius. After 5 hours we
have observed that the texture of the three samples of bioplastic film changes as they turn into
jelly-like material but the commercial bioplastic is still the same. After 12 hours, the
bioplastic samples started to break but the commercial biodegradable plastic remains its
structure, and after 48 hours, all samples of bioplastic from leftover rice break into small
pieces but the samples from biodegradable plastic doesn’t have any changes. This shows that
the fabricated bioplastic films from leftover rice can withstand water for a shorter period of
time compare to the existing biodegradable plastic and it can dissolve faster than the
commercial biodegradable plastic. In Figure 4.3, shows the appearance of bioplastic films
Biodegradability Test
This test was conducted to compare the biodegradability of bioplastic film from
leftover rice to the existing commercial biodegradable plastic. We buried three samples of
36cm2 bioplastic films and commercial biodegradable plastic on a compost soil and waited
for 48 hours. We named the samples from bioplastics as A1, A2 and A3, then the commercial
Figure 4.4 and 4.5 shows the appearance of the bioplastic films from leftover rice
B1 No significant change
B2 No significant change
B3 No significant change
our main component. The mixture of several ingredients such as starch from left-over rice,
glycerin, distilled water and vinegar produced a bioplastic film that has been tested in several
Summary of Findings
The bioplastic made with leftover rice starch displays similar characteristics as can be
seen on a regular biodegradable plastics on the market based on the tests executed. For its
tensile strength, the test showed that the bioplastic needs improvement for its stability and
bioplastic material. While the result of its water solubility test proves that the bioplastic can
be easily dissolved in water and it will not cause clog in drainage or gutter in case of glitch in
Conclusions
The result of the tests on the bioplastic film made from the left-over rice starch shows
that the bioplastic material can be an effective alternative to the existing starch-based
bioplastics in terms of its appearance and characteristics. We were able to utilize the usage of
the leftover rice and develop an innovative bioplastic with its starch. This research study
demonstrates the proper mixture of the ingredients like glycerin, distilled water and vinegar
in fabricating such kind of bioplastic as well. We were also managed to determine its physical
characteristics with the use of different test methods such as tensile strength test, water
solubility test and biodegradability test together with the existing biodegradable plastic.
Recommendations
For additional research study with regards to this experimentation, we recommend the
following suggestions:
1. Determine more accurate mixture or additional composition to improve the plasticity and
1. [1] Verma R.* , Vinoda K. S., Papireddy M., Gowda A.N.S * (2016). Toxic Pollutants from
https://ac.els-cdn.com/S187802961630158X/1-s2.0-S187802961630158X-
main.pdf?_tid=8cad8b30-8911-4ece-88b7-
b7c4dfe53881&acdnat=1548475948_1e99669401d08f40cf9bc21a3290570f
Shawai, Saleh Yusuf, Mahmud Lateefah, Ibrahim Aminu. (2017) Bioplastics as Better
10.11648/j.abb.20170504.13
3. Esen Gokce Ozdamar Namık Kemal Üniversitesi, Murat Ates Namık Kemal Üniversitesi
March 2012, Journal of Cleaner Production Volume 23, Issue 1, Pages 47-56
5. Muhammad Hakimin Shafie,, Dalina Samsudin, Rizan Yusof, Chee-yuen Gan, June 2018,
8. Gadhave R.V, Das A., Mahanwar P.A, Gadekar P.T, 2018, Open Journal of Polymer
Chemistry, pg. 24
9. Kapoor A., Sharma R., Shrivastava S., 2017, Journal of Advance Research in
Biotechnology
10. https://www.pslc.ws/macrog/kidsmac/basics.htm
11.https://www.searca.org/phocadownload/lectures/2017_2018_Casiana_Blanca_J_Villarino.
pdf
Researchers Profile
ALPHERT G. DE GUZMAN
09756970032
Yahoo-mail: alphertdeuguzman_019@yahoo.com
Gmail: deguzmanalphert24@gmail.com
Skills/Competencies:
- Drawing
- Directing Camps
Work Experiences:
Gender : Male
Citizenship : Filipino
carcetadanilo@gmail.com
Mobile #: 09336228550
OBJECTIVE:
My objective is to obtain a challenging position where I can suitably apply
my knowledge and skills that I have acquired from my previous line of duties and
responsibilities. To be able to work in a company where my personal growth and
development are encouraged. If given a chance to help in achieving the company’s
goals and objective.
PERSONAL DATA:
Sex : Male
Citizenship : Filipino
Height : 5’ 8”
Weight : 74 kg.
Religion : Christian
EDUCATIONAL BACKGROUND:
2018- Present
2008 – 2011
2004 – 2008
1998 - 2004
VOCATIONAL TRAINING:
WORKING EXPERIENCE:
CHARACTER REFERENCES
Teacher 1
EMMAN VELASQUEZ
Project In-charge
PERSONAL INFORMATION:
EDUCATIONAL ATTAINMENT:
CAREER HIGHLIGHTS:
PROFICIENCIES:
Computer Literate
Microsoft Office
SKILLS AND TALENTS:
I hereby certify that all the information’s above are true and correct.
_________________________
John Mark T. Montemor
Bachelor of Technical Teacher
Education Major in Mechanical