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MASS TRANSFER
(Heat Transfer by J. P. Holman, 10th Edition)
A B
𝐶𝐴 B
A B
Fig. 1
Arranged by Prof. Dr. Asad Naeem Shah
PHYSICAL MECHANISM OF DIFFUSION
Cont.
Clearly, mass diffusion is in the direction of
decreasing concentration as shown in Fig. 2.
Apparently, both the species are transported by
diffusion and gradually mix with each other.
→ (1)
where
o D is in square centimeters per second, T is in degrees
Kelvin, p is the total system pressure in pascals.
o 𝑉𝐴 and 𝑉𝐵 are the molecular volumes of constituents A
and B as calculated from the atomic volumes in Table 1.
o 𝑀𝐴 and 𝑀𝐵 are the molecular weights of constituents A
and B.
𝑚𝐴 𝐴 𝑑𝑃𝐴
𝑁𝐴 = = −𝐷𝐴𝐵 &
𝑀𝐴 𝑅0 𝑇 𝑑𝑥
𝑚𝐵 𝐴 𝑑𝑃𝐵
𝑁𝐵 = = −𝐷𝐵𝐴
𝑀𝐵 𝑅0 𝑇 𝑑𝑥
The total pressure of the
system remains constant at Fig.1
steady state, so that
𝑃 = 𝑃𝐴 + 𝑃𝐵
𝑑𝑃𝐴 𝑑𝑃𝐵
− = → (6)
𝑑𝑥 𝑑𝑥
Arranged by Prof. Dr. Asad Naeem Shah
STEADY STATE EQUIMOLAL COUNTER
DIFFUSION Cont.
As each molecule of A is replacing a molecule of B, so
𝑁𝐴 = −𝑁𝐵
𝐴 𝑑𝑃𝐴 𝐴 𝑑𝑃𝐴
−𝐷𝐴𝐵 = 𝐷𝐵𝐴 −
𝑅0 𝑇 𝑑𝑥 𝑅0 𝑇 𝑑𝑥
𝐷𝐴𝐵 = 𝐷𝐵𝐴 = 𝐷 → (𝟖)
The calculation of D may be made with Gilliland’ s
semi-empirical equation discussed earlier.
Moreover, eqn. (4) may be integrated to obtain the
mass flux of component A corresponding to the
nomenclature of Fig.1 as:
𝑚𝐴 𝑀𝐴 (𝑃𝐴2 −𝑃𝐴1 )
= −𝐷 → (9)
𝐴 𝑅0 𝑇 ∆𝑥
Arranged by Prof. Dr. Asad Naeem Shah
DIFFUSION OF WATER
VAPOURS THROUGH AIR
Isothermal evaporation of water from a surface
and the subsequent diffusion through a stagnant
air layer is shown in Fig.1.
𝐷𝐴𝑀𝑎 𝑑𝑃𝑎
𝑚𝑎 = − → (1)
𝑅0 𝑇 𝑑𝑥
Arranged by Prof. Dr. Asad Naeem Shah
DIFFUSION OF WATER VAPOURS
THROUGH AIR Cont.
This must be balanced by the upward bulk mass transfer
of air so that
𝑃𝑎 𝑀𝑎
𝑚𝑎 = −𝜌𝑎 𝐴𝑣 = − 𝐴𝑣 → (2)
𝑅0 𝑇
Comparison of eqns. (1) & (2) leads to bulk mass velocity:
𝐷 𝑑𝑃𝑎
𝑣= → (3)
𝑃𝑎 𝑑𝑥
The mass diffusion of water vapor upward is:
𝐷𝐴𝑀𝑤 𝑑𝑃𝑤
𝑚𝑤 = − → (4)
𝑅0 𝑇 𝑑𝑥
The bulk transport of water vapors carried upward is:
𝑃𝑤 𝑀𝑤
𝑚𝑤 = 𝜌𝑤 𝐴𝑣 = 𝐴𝑣 → (5)
𝑅0 𝑇
Arranged by Prof. Dr. Asad Naeem Shah
DIFFUSION OF WATER VAPOURS
THROUGH AIR Cont.
The total mass transport is the sum of those given in
Equations (4) & (5):
𝐷𝐴𝑀𝑤 𝑑𝑃𝑤 𝑃𝑤 𝑀𝑤
𝑚𝑤,𝑡𝑜𝑡𝑎𝑙 = − + 𝐴𝑣
𝑅0 𝑇 𝑑𝑥 𝑅0 𝑇
Making the use of eqn. (3) in above equation:
𝐷𝐴𝑀𝑤 𝑑𝑃𝑤 𝑃𝑤 𝑀𝑤 𝐷 𝑑𝑃𝑎
𝑚𝑤,𝑡𝑜𝑡𝑎𝑙 = − + 𝐴
𝑅0 𝑇 𝑑𝑥 𝑅0 𝑇 𝑃𝑎 𝑑𝑥
𝑑𝑃𝑤 𝑑𝑃𝑎
As 𝑃 = 𝑃𝑤 + 𝑃𝑎 − =
𝑑𝑥 𝑑𝑥
𝐷𝐴𝑀𝑤 𝑃 𝑑𝑃𝑤
𝑚𝑤,𝑡𝑜𝑡𝑎𝑙 =− → (6)
𝑅0 𝑇 𝑃 − 𝑃𝑤 𝑑𝑥
Above relation is called Stefan’s law for diffusion, and it
may be integrated to give: Arranged by Prof. Dr. Asad Naeem Shah
DIFFUSION OF WATER VAPOURS
THROUGH AIR Cont.
𝐷𝐴𝑃𝑀𝑤 𝑃 − 𝑃𝑤2
𝑚𝑤,𝑡𝑜𝑡𝑎𝑙 = ln → (7)
𝑅0 𝑇 𝑥2 − 𝑥1 𝑃 − 𝑃𝑤1
𝐷𝐴𝑃𝑀𝑤 𝑃𝑎2
𝑚𝑤,𝑡𝑜𝑡𝑎𝑙 = ln → (8)
𝑅0 𝑇 𝑥2 − 𝑥1 𝑃𝑎1
→ (6)
→ (7)
𝜕𝐶𝐴 𝜕𝐶𝐴 𝜕 2 𝐶𝐴
𝑢 +𝜗 = 𝐷 2 → (8)
𝜕𝑥 𝜕𝑦 𝜕 𝑦
It is clear from eqns. (6) & (8) that the velocity and
concentration profiles will have the same shape when
𝜗
𝜗 = 𝐷, thus 𝑆𝑐 = is important in problems where both
𝐷
convection and mass transfer are important.
Arranged by Prof. Dr. Asad Naeem Shah
THE MASS-TRANSFER COEFFICIENT Cont.
→ (9)